MX2016014076A - Copolimeros de propileno-etileno aleatorios y proceso para su preparacion. - Google Patents
Copolimeros de propileno-etileno aleatorios y proceso para su preparacion.Info
- Publication number
- MX2016014076A MX2016014076A MX2016014076A MX2016014076A MX2016014076A MX 2016014076 A MX2016014076 A MX 2016014076A MX 2016014076 A MX2016014076 A MX 2016014076A MX 2016014076 A MX2016014076 A MX 2016014076A MX 2016014076 A MX2016014076 A MX 2016014076A
- Authority
- MX
- Mexico
- Prior art keywords
- ethylene copolymers
- preparation
- random propylene
- content
- ethylene
- Prior art date
Links
- 229920005653 propylene-ethylene copolymer Polymers 0.000 title abstract 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 abstract 2
- 239000005977 Ethylene Substances 0.000 abstract 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- 238000002844 melting Methods 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/04—Monomers containing three or four carbon atoms
- C08F210/06—Propene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/34—Polymerisation in gaseous state
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6421—Titanium tetrahalides with organo-aluminium compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/642—Component covered by group C08F4/64 with an organo-aluminium compound
- C08F4/6423—Component of C08F4/64 containing at least two different metals
- C08F4/6425—Component of C08F4/64 containing at least two different metals containing magnesium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/62—Refractory metals or compounds thereof
- C08F4/64—Titanium, zirconium, hafnium or compounds thereof
- C08F4/646—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64
- C08F4/6465—Catalysts comprising at least two different metals, in metallic form or as compounds thereof, in addition to the component covered by group C08F4/64 containing silicium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/04—Broad molecular weight distribution, i.e. Mw/Mn > 6
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/12—Melt flow index or melt flow ratio
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
- C08F2500/26—Use as polymer for film forming
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
Copolímeros de propileno-etileno que muestran un contenido de etileno entre un 0,1% y un 10% en peso, una distribución del peso molecular (MWD), expresada en términos de Mw/Mn, mayor a 3,0 y un contenido de fracción soluble en xileno (XS) y contenido de etileno (C2) tal que el punto definido por los valores cae debajo de la línea dada por la ecuación XS= 1,0296·e0,435C2 muestran una alta transparencia y una temperatura de fusión baja.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP14167178 | 2014-05-06 | ||
PCT/EP2015/059919 WO2015169831A1 (en) | 2014-05-06 | 2015-05-06 | Random propylene-ethylene copolymers and process for their preparation |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2016014076A true MX2016014076A (es) | 2017-02-14 |
Family
ID=50639342
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2016014076A MX2016014076A (es) | 2014-05-06 | 2015-05-06 | Copolimeros de propileno-etileno aleatorios y proceso para su preparacion. |
Country Status (9)
Country | Link |
---|---|
US (1) | US9676883B2 (es) |
EP (1) | EP3140328B1 (es) |
JP (1) | JP6307178B2 (es) |
KR (1) | KR101764561B1 (es) |
CN (1) | CN106232643B (es) |
BR (1) | BR112016024633B1 (es) |
MX (1) | MX2016014076A (es) |
RU (1) | RU2662152C2 (es) |
WO (1) | WO2015169831A1 (es) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
ES2743475T3 (es) * | 2014-05-06 | 2020-02-19 | Basell Poliolefine Italia Srl | Copolímeros aleatorios de propileno-etileno |
EP3347384B1 (en) * | 2015-09-10 | 2020-03-25 | Basell Poliolefine Italia S.r.l. | Catalyst for the polymerization of olefins |
EP3170864B1 (en) | 2015-11-17 | 2018-10-17 | Borealis AG | High flow tpo composition with excellent balance in mechanical properties for automotive interior |
EP3548556B1 (en) | 2016-12-05 | 2020-10-07 | Basell Poliolefine Italia S.r.l. | Heterophasic propylene copolymers |
CN110831985B (zh) * | 2017-07-19 | 2022-05-13 | 巴塞尔聚烯烃意大利有限公司 | 丙烯共聚物 |
EP3802633A4 (en) * | 2018-06-11 | 2022-05-25 | W. R. Grace & Co.-Conn | PROPYLENE-ETHYLENE COPOLYMER COMPOSITIONS SUITABLE FOR THE HEAT PACKAGING OF FOOD PRODUCTS |
US11680118B2 (en) * | 2018-06-29 | 2023-06-20 | Borealis Ag | C2C3 random copolymer composition |
WO2020038746A1 (en) * | 2018-08-22 | 2020-02-27 | Basell Poliolefine Italia S.R.L. | Random propylene-ethylene copolymers |
WO2020239583A1 (en) * | 2019-05-29 | 2020-12-03 | Borealis Ag | C2c3 random copolymer |
KR20240076546A (ko) | 2022-11-22 | 2024-05-30 | 한화토탈에너지스 주식회사 | 공중합성이 개선된 프로필렌계 공중합체의 제조방법 |
Family Cites Families (38)
Publication number | Priority date | Publication date | Assignee | Title |
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JPS5494591A (en) * | 1978-01-09 | 1979-07-26 | Mitsubishi Petrochem Co Ltd | Production of olefin polymer |
JPS5490382A (en) * | 1977-12-28 | 1979-07-18 | Mitsubishi Petrochem Co Ltd | Preparation of olefin polymer |
IT1096661B (it) | 1978-06-13 | 1985-08-26 | Montedison Spa | Procedimento per la preparazione di prodotti in forma sferoidale solidi a temperatura ambiente |
IT1098272B (it) | 1978-08-22 | 1985-09-07 | Montedison Spa | Componenti,di catalizzatori e catalizzatori per la polimerizzazione delle alfa-olefine |
JPS5582103A (en) | 1978-12-15 | 1980-06-20 | Mitsubishi Petrochem Co Ltd | Production of alpha-olefin polymer |
JPH06104693B2 (ja) | 1986-01-06 | 1994-12-21 | 東邦チタニウム株式会社 | オレフイン類重合用触媒 |
EP0268685B2 (en) | 1986-05-06 | 1996-08-07 | Toho Titanium Co. Ltd. | Catalyst for polymerizing olefins |
JP2514015B2 (ja) | 1987-01-07 | 1996-07-10 | 東邦チタニウム株式会社 | オレフイン類重合用固体触媒成分 |
IT1221653B (it) | 1987-11-27 | 1990-07-12 | Ausimonti Spa | Copolimeri cristallini del propilene |
IL117114A (en) | 1995-02-21 | 2000-02-17 | Montell North America Inc | Components and catalysts for the polymerization ofolefins |
IT1275573B (it) | 1995-07-20 | 1997-08-07 | Spherilene Spa | Processo ed apparecchiatura per la pomimerizzazione in fase gas delle alfa-olefine |
JP3264148B2 (ja) | 1995-08-31 | 2002-03-11 | 住友化学工業株式会社 | プロピレン−エチレンランダム共重合体、その製法及びフィルム |
IT1282691B1 (it) * | 1996-02-27 | 1998-03-31 | Montell North America Inc | Processo per la preparazione di copolimeri random del propilene e prodotti cosi' ottenuti |
DE19746741A1 (de) | 1996-10-30 | 1998-05-07 | Idemitsu Petrochemical Co | Propylen-Copolymer und Folie daraus |
JP3569739B2 (ja) | 1996-11-25 | 2004-09-29 | 出光石油化学株式会社 | プロピレン系ランダム共重合体の製造方法 |
JP4531137B2 (ja) | 1997-03-29 | 2010-08-25 | バセル テクノロジー カンパニー ビー.ブイ. | 塩化マグネシウム―アルコール付加物その製造法およびそれから得られた触媒成分 |
JP2002506468A (ja) * | 1997-06-05 | 2002-02-26 | ソルヴェイ ポリオレフィンズ ユーロープ ベルギウム | プロピレンポリマーの連続製法 |
CN1086191C (zh) | 1998-03-17 | 2002-06-12 | 中国石油化工集团公司 | 用于乙烯聚合或共聚合的催化剂及其制法 |
DE19813399A1 (de) | 1998-03-26 | 1999-09-30 | Basf Ag | Statistische Propylencopolymerisate |
EP1873172B1 (en) * | 1998-06-25 | 2009-06-24 | Idemitsu Kosan Co., Ltd. | Propylene polymer and composition containing the same, molded object and laminate comprising these, and processes for producing propylene polymer and composition containing the same |
RU2223974C2 (ru) | 1998-07-08 | 2004-02-20 | Монтелл Текнолоджи Компани Б.В. | Способ и устройство для газофазной полимеризации |
SG147306A1 (en) | 2001-11-06 | 2008-11-28 | Dow Global Technologies Inc | Isotactic propylene copolymers, their preparation and use |
CN1304435C (zh) * | 2002-06-17 | 2007-03-14 | 日本波利凯姆株式会社 | 丙烯聚合物 |
CN101423635A (zh) | 2002-10-07 | 2009-05-06 | 陶氏环球技术公司 | 含低量二甲苯可溶物的高结晶聚丙烯 |
ATE341581T1 (de) | 2002-12-18 | 2006-10-15 | Borealis Tech Oy | Flachfolie zum thermoformen und verfahren zu ihrer herstellung |
CA2558097A1 (en) | 2004-03-03 | 2005-10-13 | Basell Poliolefine Italia S.R.L. | Method for controlling the polymer flow in a polymerization process |
US20070202285A1 (en) | 2004-12-15 | 2007-08-30 | Fina Technology, Inc. | Articles having improved clarity, prepared from propylene-ethylene copolymers |
DE602006007572D1 (de) | 2005-05-12 | 2009-08-13 | Basell Poliolefine Srl | Propylen-ethylen-copolymere und herstellungsverfahren dafür |
US20090118451A1 (en) * | 2005-10-21 | 2009-05-07 | Basell Polyolefine Gmbh | Polypropylene Random Copolymers Having High Melt Flow Rates for Injection Molding and Melt Blown Applications |
US20090270560A1 (en) * | 2005-11-15 | 2009-10-29 | Basell Poliolefine Italia S.R.L. | Propylene-Ethylene Copolymers and Process for Their Preparation |
EP1903070B9 (en) * | 2006-08-25 | 2009-12-23 | Borealis Technology Oy | Blown film of polypropylene |
EP2398830B1 (en) * | 2009-02-20 | 2014-04-16 | Ineos USA, LLC | Broadening the molecular weight distribution of polyolefins materials made in a horizontal stirred gas phase reactor |
EP2281851B1 (en) | 2009-07-01 | 2011-09-07 | Borealis AG | High flow polypropylene composition |
US8569195B2 (en) * | 2010-02-24 | 2013-10-29 | Basf Corporation | Internal and external donor compounds for olefin polymerization catalysts II |
JP2013531711A (ja) * | 2010-06-10 | 2013-08-08 | イネオス ユーエスエイ リミテッド ライアビリティ カンパニー | 水平撹拌床反応器におけるh2分布の制御 |
CN102453181A (zh) * | 2010-10-29 | 2012-05-16 | 中国石油化工股份有限公司 | 一种丙烯乙烯无规共聚物 |
EP3140330B1 (en) | 2014-05-06 | 2020-12-09 | Basell Poliolefine Italia S.r.l. | Multilayer film random propylene-ethylene copolymers |
ES2743475T3 (es) * | 2014-05-06 | 2020-02-19 | Basell Poliolefine Italia Srl | Copolímeros aleatorios de propileno-etileno |
-
2015
- 2015-05-06 JP JP2016564999A patent/JP6307178B2/ja active Active
- 2015-05-06 RU RU2016145451A patent/RU2662152C2/ru active
- 2015-05-06 US US15/309,042 patent/US9676883B2/en active Active
- 2015-05-06 EP EP15719487.9A patent/EP3140328B1/en active Active
- 2015-05-06 WO PCT/EP2015/059919 patent/WO2015169831A1/en active Application Filing
- 2015-05-06 CN CN201580021191.2A patent/CN106232643B/zh active Active
- 2015-05-06 MX MX2016014076A patent/MX2016014076A/es unknown
- 2015-05-06 BR BR112016024633-0A patent/BR112016024633B1/pt active IP Right Grant
- 2015-05-06 KR KR1020167032707A patent/KR101764561B1/ko active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
RU2662152C2 (ru) | 2018-07-24 |
WO2015169831A1 (en) | 2015-11-12 |
US9676883B2 (en) | 2017-06-13 |
CN106232643A (zh) | 2016-12-14 |
CN106232643B (zh) | 2019-02-26 |
KR101764561B1 (ko) | 2017-08-02 |
US20170073444A1 (en) | 2017-03-16 |
RU2016145451A3 (es) | 2018-06-07 |
KR20160143857A (ko) | 2016-12-14 |
BR112016024633B1 (pt) | 2022-05-03 |
JP6307178B2 (ja) | 2018-04-04 |
EP3140328A1 (en) | 2017-03-15 |
BR112016024633A2 (pt) | 2017-08-15 |
JP2017514000A (ja) | 2017-06-01 |
EP3140328B1 (en) | 2020-11-18 |
RU2016145451A (ru) | 2018-06-07 |
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