MX2013003145A - Mezclas de agentes de reticulacion. - Google Patents
Mezclas de agentes de reticulacion.Info
- Publication number
- MX2013003145A MX2013003145A MX2013003145A MX2013003145A MX2013003145A MX 2013003145 A MX2013003145 A MX 2013003145A MX 2013003145 A MX2013003145 A MX 2013003145A MX 2013003145 A MX2013003145 A MX 2013003145A MX 2013003145 A MX2013003145 A MX 2013003145A
- Authority
- MX
- Mexico
- Prior art keywords
- multifunctional
- aliphatic
- reaction products
- cyclic
- group
- Prior art date
Links
- 239000000203 mixture Substances 0.000 title abstract 2
- 239000003431 cross linking reagent Substances 0.000 title 1
- -1 aliphatic aldehyde Chemical class 0.000 abstract 4
- 239000007795 chemical reaction product Substances 0.000 abstract 4
- 239000004971 Cross linker Substances 0.000 abstract 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract 3
- 125000001931 aliphatic group Chemical group 0.000 abstract 3
- 235000013877 carbamide Nutrition 0.000 abstract 2
- ZMGMDXCADSRNCX-UHFFFAOYSA-N 5,6-dihydroxy-1,3-diazepan-2-one Chemical compound OC1CNC(=O)NCC1O ZMGMDXCADSRNCX-UHFFFAOYSA-N 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 abstract 1
- 150000001541 aziridines Chemical class 0.000 abstract 1
- 239000004202 carbamide Substances 0.000 abstract 1
- 150000001718 carbodiimides Chemical class 0.000 abstract 1
- 150000002118 epoxides Chemical class 0.000 abstract 1
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
- 239000012948 isocyanate Substances 0.000 abstract 1
- 150000002513 isocyanates Chemical class 0.000 abstract 1
- 150000002989 phenols Chemical class 0.000 abstract 1
- QQOWHRYOXYEMTL-UHFFFAOYSA-N triazin-4-amine Chemical compound N=C1C=CN=NN1 QQOWHRYOXYEMTL-UHFFFAOYSA-N 0.000 abstract 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08L61/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/10—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with acyclic compounds having the moiety X=C(—N<)2 in which X is O, S or —N
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/04—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C08G12/10—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with acyclic compounds having the moiety X=C(—N<)2 in which X is O, S or —N
- C08G12/12—Ureas; Thioureas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
- C08G12/30—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds with substituted triazines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G12/00—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08G12/02—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes
- C08G12/40—Chemically modified polycondensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G14/00—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00
- C08G14/02—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes
- C08G14/04—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols
- C08G14/06—Condensation polymers of aldehydes or ketones with two or more other monomers covered by at least two of the groups C08G8/00 - C08G12/00 of aldehydes with phenols and monomers containing hydrogen attached to nitrogen
- C08G14/08—Ureas; Thioureas
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
- C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
- C08G16/025—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with heterocyclic organic compounds
- C08G16/0256—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with heterocyclic organic compounds containing oxygen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G16/00—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00
- C08G16/02—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes
- C08G16/025—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with heterocyclic organic compounds
- C08G16/0268—Condensation polymers of aldehydes or ketones with monomers not provided for in the groups C08G4/00 - C08G14/00 of aldehydes with heterocyclic organic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G8/00—Condensation polymers of aldehydes or ketones with phenols only
- C08G8/04—Condensation polymers of aldehydes or ketones with phenols only of aldehydes
- C08G8/08—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ
- C08G8/10—Condensation polymers of aldehydes or ketones with phenols only of aldehydes of formaldehyde, e.g. of formaldehyde formed in situ with phenol
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/04—Condensation polymers of aldehydes or ketones with phenols only
- C08L61/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/26—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/30—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with heterocyclic and acyclic or carbocyclic compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L61/00—Compositions of condensation polymers of aldehydes or ketones; Compositions of derivatives of such polymers
- C08L61/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C08L61/32—Modified amine-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/29—Compounds containing one or more carbon-to-nitrogen double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
- Phenolic Resins Or Amino Resins (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
La invención se refiere a una composición reticuladora que comprende un producto de la reacción de una urea cíclica U y un aldehído alifático multifuncional A, y al menos un agente de reticulación seleccionado del grupo que consiste de los productos de la reacción de una aminotriazina y al menos un aldehído seleccionado del grupo que consiste de monoaldehídos alifáticos y los aldehídos alifáticos multifuncionales que tienen la estructura Y (CHO)n, en donde Y es un residuo alifático n-funcional, y n es mayor que 1, los productos de la reacción de urea y/o de ureas cíclicas y el formaldehido; alcoxicarbonil-aminotriazinas; isocianatos multifuncionales que pueden ser bloqueados parcial o completamente; los productos de la reacción de los fenoles y los monoaldehídos alifáticos; epóxidos multifuncionales; aziridinas multifuncionales; y carbodiimidas multifuncionales, en donde cualquiera de los agentes de reticulación que tienen grupos hidroxilo pueden ser eterificados con uno o más alcoholes alifáticos lineales, ramificados, o cíclicos.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP10185094A EP2436710A1 (en) | 2010-09-30 | 2010-09-30 | Mixtures of crosslinking agents |
PCT/US2011/053020 WO2012044544A1 (en) | 2010-09-30 | 2011-09-23 | Mixtures of crosslinking agents |
Publications (2)
Publication Number | Publication Date |
---|---|
MX2013003145A true MX2013003145A (es) | 2013-05-01 |
MX356642B MX356642B (es) | 2018-06-07 |
Family
ID=43302041
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2013003145A MX356642B (es) | 2010-09-30 | 2011-09-23 | Mezclas de agentes de reticulacion. |
Country Status (10)
Country | Link |
---|---|
US (1) | US9267028B2 (es) |
EP (2) | EP2436710A1 (es) |
JP (1) | JP5849096B2 (es) |
KR (1) | KR101824755B1 (es) |
CN (1) | CN103154064B (es) |
BR (1) | BR112013007728B1 (es) |
CA (1) | CA2811220C (es) |
MX (1) | MX356642B (es) |
TW (1) | TWI541260B (es) |
WO (1) | WO2012044544A1 (es) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2436709A1 (en) * | 2010-09-30 | 2012-04-04 | Cytec Technology Corp. | Non-etherified reaction product of a cyclic urea and a multifunctional aldehyde |
PT2731976T (pt) * | 2011-07-15 | 2017-06-15 | Akzo Nobel Coatings Int Bv | Sistema adesivo |
US10125297B2 (en) | 2015-01-19 | 2018-11-13 | Microtek Laboratories, Inc. | Dimensionally stable phase change material and a continuous process for making same |
KR102371790B1 (ko) * | 2015-08-18 | 2022-03-07 | 마이크로텍 라보라토리즈, 인코포레이티드 | 저 잔류 유리 포름알데하이드 마이크로캡슐의 제조 방법 및 이를 이용하여 제조된 마이크로캡슐 |
BR112018013296B1 (pt) * | 2015-12-30 | 2022-04-05 | Allnex Netherlands B.V. | Produto de reação h, composição de revestimento, e, método de uso de um produto de reação h |
KR20200018582A (ko) * | 2017-06-13 | 2020-02-19 | 엘리멘티스 스페셜티즈, 인크. | 코팅 시스템 |
EP3421559A1 (en) * | 2017-06-29 | 2019-01-02 | INEOS Melamines GmbH | Curable aminoplast acrylic polyol compositions, process for their preparation and methods of use |
TWI718848B (zh) * | 2020-01-17 | 2021-02-11 | 長春人造樹脂廠股份有限公司 | 胺基樹脂組合物及包含其之清漆、塗層與製品 |
CN118085724B (zh) * | 2024-04-02 | 2024-08-02 | 安徽凯瑞捷成新材料科技有限公司 | 一种金属用免喷砂耐高温涂料及其制备方法 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5344567A (en) * | 1976-09-30 | 1978-04-21 | Nippon Kayaku Co Ltd | Cyclic urea-glyoxal reaction products, their use and their preparation |
US4263190A (en) * | 1979-12-26 | 1981-04-21 | American Cyanamid Company | Adhesion of textile cords to rubber using a butadiene-styrene vinylpyridine rubber latex and an aldehyde condensate-glyoxal reaction products mixture |
JP2599793B2 (ja) * | 1989-07-14 | 1997-04-16 | 株式会社クラレ | 紙製のラベル用アルカリ洗浄性接着剤 |
DE19510520A1 (de) * | 1995-03-23 | 1996-09-26 | Hoechst Ag | Wäßrige Dispersionen von Aminoplastharzen, Verfahren zu ihrer Herstellung und ihre Verwendung als Härtungsmittel für wäßrige Kunstharze |
US7381347B2 (en) * | 2003-03-31 | 2008-06-03 | Cytec Technology Corp. | Crosslinking composition |
US7034086B2 (en) | 2003-03-31 | 2006-04-25 | Cytec Technology Corp. | Melamine and guanamine-based crosslinking composition |
US20070082187A1 (en) * | 2005-06-27 | 2007-04-12 | Chemco, Inc. | Celluosic products comprising substantially voc-free compositions |
FR2898128A1 (fr) * | 2006-03-02 | 2007-09-07 | Clariant Specialty Fine Chem | Composition liante comprenant une resine aminoplaste ou phenoplaste a base d'au moins un monoacetal du glyoxal et au moins un compose polysocyanate, et son utilisation. |
EP2220152B1 (en) * | 2007-12-06 | 2012-07-04 | Cytec Technology Corp. | Process for the preparation of a crosslinker composition |
-
2010
- 2010-09-30 EP EP10185094A patent/EP2436710A1/en not_active Withdrawn
-
2011
- 2011-09-23 BR BR112013007728A patent/BR112013007728B1/pt active IP Right Grant
- 2011-09-23 EP EP11761812.4A patent/EP2621978B1/en active Active
- 2011-09-23 JP JP2013531682A patent/JP5849096B2/ja active Active
- 2011-09-23 MX MX2013003145A patent/MX356642B/es active IP Right Grant
- 2011-09-23 WO PCT/US2011/053020 patent/WO2012044544A1/en active Application Filing
- 2011-09-23 US US13/876,559 patent/US9267028B2/en active Active
- 2011-09-23 KR KR1020137008227A patent/KR101824755B1/ko active Active
- 2011-09-23 CN CN201180047594.6A patent/CN103154064B/zh active Active
- 2011-09-23 CA CA2811220A patent/CA2811220C/en active Active
- 2011-09-26 TW TW100134638A patent/TWI541260B/zh active
Also Published As
Publication number | Publication date |
---|---|
US9267028B2 (en) | 2016-02-23 |
CA2811220A1 (en) | 2012-04-05 |
MX356642B (es) | 2018-06-07 |
EP2436710A1 (en) | 2012-04-04 |
CA2811220C (en) | 2018-09-11 |
WO2012044544A1 (en) | 2012-04-05 |
TWI541260B (zh) | 2016-07-11 |
US20130189438A1 (en) | 2013-07-25 |
JP2013545830A (ja) | 2013-12-26 |
CN103154064B (zh) | 2016-02-10 |
EP2621978B1 (en) | 2017-08-30 |
KR20140001855A (ko) | 2014-01-07 |
BR112013007728A2 (es) | 2017-10-03 |
BR112013007728B1 (pt) | 2020-01-28 |
KR101824755B1 (ko) | 2018-02-01 |
BR112013007728A8 (pt) | 2018-07-31 |
EP2621978A1 (en) | 2013-08-07 |
TW201229078A (en) | 2012-07-16 |
CN103154064A (zh) | 2013-06-12 |
JP5849096B2 (ja) | 2016-01-27 |
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