MX2009008421A - Proceso para la oxidacion de ciertas sulfiliminas sustituidas a sulfoximinas insecticidas. - Google Patents
Proceso para la oxidacion de ciertas sulfiliminas sustituidas a sulfoximinas insecticidas.Info
- Publication number
- MX2009008421A MX2009008421A MX2009008421A MX2009008421A MX2009008421A MX 2009008421 A MX2009008421 A MX 2009008421A MX 2009008421 A MX2009008421 A MX 2009008421A MX 2009008421 A MX2009008421 A MX 2009008421A MX 2009008421 A MX2009008421 A MX 2009008421A
- Authority
- MX
- Mexico
- Prior art keywords
- oxidation
- certain substituted
- formula
- sulfoximines
- substituted sulfilimines
- Prior art date
Links
- 230000003647 oxidation Effects 0.000 title abstract 2
- 238000007254 oxidation reaction Methods 0.000 title abstract 2
- 125000005555 sulfoximide group Chemical group 0.000 title abstract 2
- 230000000749 insecticidal effect Effects 0.000 title 1
- 238000000034 method Methods 0.000 title 1
- 229910052783 alkali metal Inorganic materials 0.000 abstract 1
- 150000001340 alkali metals Chemical class 0.000 abstract 1
- 229910001927 ruthenium tetroxide Inorganic materials 0.000 abstract 1
- GLBQVJGBPFPMMV-UHFFFAOYSA-N sulfilimine Chemical compound S=N GLBQVJGBPFPMMV-UHFFFAOYSA-N 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/24—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with substituted hydrocarbon radicals attached to ring carbon atoms
- C07D213/28—Radicals substituted by singly-bound oxygen or sulphur atoms
- C07D213/32—Sulfur atoms
- C07D213/34—Sulfur atoms to which a second hetero atom is attached
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/61—Halogen atoms or nitro radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/60—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D213/62—Oxygen or sulfur atoms
- C07D213/63—One oxygen atom
- C07D213/64—One oxygen atom attached in position 2 or 6
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D409/00—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
- C07D409/02—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings
- C07D409/04—Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms containing two hetero rings directly linked by a ring-member-to-ring-member bond
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Pyridine Compounds (AREA)
- Plural Heterocyclic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Abstract
Se producen en forma eficiente sulfoximinas insecticidas de la fórmula (la) y con alto rendimiento mediante la oxidación de la sulfilimina correspondiente de la fórmula (I) con tetróxido de rutenio o un permanganato de metal álcali. En la fórmula (la) y fórmula (I), Het, R1, R2, R3, L y n son tal como se define en las reivindicaciones adjuntas.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PCT/US2007/003783 WO2008097235A1 (en) | 2007-02-09 | 2007-02-09 | Process for the oxidation of certain substituted sulfilimines to insecticidal sulfoximines |
Publications (1)
Publication Number | Publication Date |
---|---|
MX2009008421A true MX2009008421A (es) | 2009-11-02 |
Family
ID=38616361
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
MX2009008421A MX2009008421A (es) | 2007-02-09 | 2007-02-09 | Proceso para la oxidacion de ciertas sulfiliminas sustituidas a sulfoximinas insecticidas. |
Country Status (13)
Country | Link |
---|---|
EP (1) | EP2114885B1 (es) |
JP (1) | JP5254999B2 (es) |
KR (1) | KR101379070B1 (es) |
CN (1) | CN101605760B (es) |
AU (1) | AU2007346136B2 (es) |
BR (1) | BRPI0721218A2 (es) |
CA (1) | CA2676700C (es) |
DK (1) | DK2114885T3 (es) |
ES (1) | ES2561355T3 (es) |
IL (1) | IL199938A (es) |
MX (1) | MX2009008421A (es) |
PL (1) | PL2114885T3 (es) |
WO (1) | WO2008097235A1 (es) |
Families Citing this family (27)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE102008041695A1 (de) | 2008-08-29 | 2010-03-04 | Bayer Cropscience Ag | Methoden zur Verbesserung des Pflanzenwachstums |
WO2010074751A1 (en) * | 2008-12-26 | 2010-07-01 | Dow Agrosciences, Llc | Stable sulfoximine-insecticide compositions |
EP2381781B1 (de) | 2008-12-29 | 2016-06-08 | Bayer Intellectual Property GmbH | Verfahren zur verbesserten nutzung des produktionspotentials genetisch modifizierter pflanzen |
EP2223602A1 (de) | 2009-02-23 | 2010-09-01 | Bayer CropScience AG | Verfahren zur verbesserten Nutzung des Produktionspotentials genetisch modifizierter Pflanzen |
EP2223598A1 (de) | 2009-02-23 | 2010-09-01 | Bayer CropScience AG | Insektizide Zusammensetzungen mit verbesserter Wirkung |
US20110306643A1 (en) | 2010-04-23 | 2011-12-15 | Bayer Cropscience Ag | Triglyceride-containing dormancy sprays |
CN103547566B (zh) | 2011-02-18 | 2017-05-31 | 阿萨纳生物科技有限责任公司 | 氨基茚满化合物及其治疗疼痛的用途 |
EP2545964A1 (en) | 2011-07-13 | 2013-01-16 | Phenex Pharmaceuticals AG | Novel FXR (NR1H4) binding and activity modulating compounds |
CN104244713B (zh) | 2012-02-21 | 2016-08-24 | 拜耳知识产权有限责任公司 | 除草的亚磺酰亚氨酰基苯甲酰基衍生物和磺酰亚氨酰基苯甲酰基衍生物 |
US9044482B2 (en) | 2012-08-15 | 2015-06-02 | Asana Biosciences, Llc | Use of aminoindane compounds in treating overactive bladder and interstitial cystitis |
EP2873668A1 (en) | 2013-11-13 | 2015-05-20 | Syngenta Participations AG. | Pesticidally active bicyclic heterocycles with sulphur containing substituents |
CN105481743B (zh) * | 2015-11-25 | 2017-09-01 | 南阳师范学院 | 一种硫亚胺氧化为砜亚胺的方法 |
CA2968836A1 (en) | 2016-06-13 | 2017-12-13 | Gilead Sciences, Inc. | Fxr (nr1h4) modulating compounds |
PL3730487T3 (pl) | 2016-06-13 | 2022-08-16 | Gilead Sciences, Inc. | Pochodne azetydyny jako modulatory fxr (nr1h4) |
WO2018099812A1 (en) | 2016-12-01 | 2018-06-07 | Syngenta Participations Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
SI3600309T1 (sl) | 2017-03-28 | 2022-10-28 | Gilead Sciences, Inc. | Terapevtske kombinacije za zdravljenje bolezni jeter |
US10894792B2 (en) | 2017-05-02 | 2021-01-19 | Syngenta Participations Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
WO2019219689A1 (en) | 2018-05-18 | 2019-11-21 | Syngenta Participations Ag | Pesticidally active heterocyclic derivatives with sulfoximine containing substituents |
WO2019229089A1 (en) | 2018-05-31 | 2019-12-05 | Syngenta Participations Ag | Pesticidally active heterocyclic derivatives with sulfur containing substituents |
AR115495A1 (es) | 2018-06-06 | 2021-01-27 | Syngenta Crop Protection Ag | Derivados heterocíclicos con sustituyentes que contienen azufre activos como plaguicidas |
MA52751A (fr) | 2018-06-06 | 2021-04-14 | Syngenta Crop Protection Ag | Dérivés hétérocycliques à action pesticide comportant des substituants contenant de la sulfoximine |
TW202035404A (zh) | 2018-10-24 | 2020-10-01 | 瑞士商先正達農作物保護公司 | 具有含亞碸亞胺的取代基之殺有害生物活性雜環衍生物 |
LT3911647T (lt) | 2019-01-15 | 2024-03-25 | Gilead Sciences, Inc. | Izoksazolo junginys kaip fxr agonistas ir jį apimančios farmacinės kompozicijos |
US11524005B2 (en) | 2019-02-19 | 2022-12-13 | Gilead Sciences, Inc. | Solid forms of FXR agonists |
BR112023025278A2 (pt) | 2021-06-02 | 2024-02-27 | Syngenta Crop Protection Ag | Derivados heterocíclicos com substituintes contendo sulfoximina ativos em termos pesticidas |
CN113582258B (zh) * | 2021-08-24 | 2022-12-23 | 内蒙古工业大学 | 一种从钌催化氧化低阶煤解聚液中回收钌的方法 |
WO2025017547A1 (en) | 2023-07-18 | 2025-01-23 | Adama Makhteshim Ltd. | Method for preparing an n-cyano sulfilimine compound |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1307271A (en) * | 1970-06-25 | 1973-02-14 | Shell Int Research | Sulphoximine derivatives and their use in herbicidal compositions |
JPH01172360A (ja) * | 1987-12-25 | 1989-07-07 | Agency Of Ind Science & Technol | ベンゾイルギ酸の製造法 |
DE4233099A1 (de) * | 1992-10-01 | 1994-04-07 | Hoechst Ag | Verfahren zur stereoselektiven Synthese von 3-substituierten 2-Thiomethylpropionsäuren |
JPH0782226A (ja) * | 1993-09-16 | 1995-03-28 | Mitsui Toatsu Chem Inc | アミド化合物の製造方法 |
UA75051C2 (en) * | 1999-09-03 | 2006-03-15 | Syngenta Participations Ag | Tetrahydropiridines as pesticides, a composition, a method for the preparation thereof and a method of controlling pests |
CA2558647C (en) * | 2004-04-08 | 2013-05-28 | Dow Agrosciences Llc | Insecticidal n-substituted sulfoximines |
PE20061193A1 (es) * | 2005-03-25 | 2006-12-02 | Glaxo Group Ltd | DERIVADOS DE 3,4-DIHIDROPIRIMIDO[4,5-d]PIRIMIDIN-2-[1H]-0NA COMO INHIBIDORES DE QUINASA p38 |
TWI398433B (zh) * | 2006-02-10 | 2013-06-11 | Dow Agrosciences Llc | 殺蟲性之n-取代(6-鹵烷基吡啶-3-基)烷基磺醯亞胺 |
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2007
- 2007-02-09 EP EP07750610.3A patent/EP2114885B1/en active Active
- 2007-02-09 WO PCT/US2007/003783 patent/WO2008097235A1/en active Application Filing
- 2007-02-09 ES ES07750610.3T patent/ES2561355T3/es active Active
- 2007-02-09 CN CN2007800511217A patent/CN101605760B/zh active Active
- 2007-02-09 CA CA2676700A patent/CA2676700C/en not_active Expired - Fee Related
- 2007-02-09 KR KR1020097016448A patent/KR101379070B1/ko active Active
- 2007-02-09 DK DK07750610.3T patent/DK2114885T3/en active
- 2007-02-09 PL PL07750610T patent/PL2114885T3/pl unknown
- 2007-02-09 BR BRPI0721218-6A patent/BRPI0721218A2/pt not_active Application Discontinuation
- 2007-02-09 JP JP2009549058A patent/JP5254999B2/ja active Active
- 2007-02-09 MX MX2009008421A patent/MX2009008421A/es active IP Right Grant
- 2007-02-09 AU AU2007346136A patent/AU2007346136B2/en active Active
-
2009
- 2009-07-19 IL IL199938A patent/IL199938A/en active IP Right Grant
Also Published As
Publication number | Publication date |
---|---|
CN101605760A (zh) | 2009-12-16 |
KR20100014384A (ko) | 2010-02-10 |
AU2007346136B2 (en) | 2012-10-25 |
JP5254999B2 (ja) | 2013-08-07 |
WO2008097235A1 (en) | 2008-08-14 |
BRPI0721218A2 (pt) | 2013-01-01 |
EP2114885A1 (en) | 2009-11-11 |
KR101379070B1 (ko) | 2014-03-28 |
IL199938A (en) | 2015-05-31 |
AU2007346136A1 (en) | 2008-08-14 |
JP2010518078A (ja) | 2010-05-27 |
CA2676700C (en) | 2013-12-17 |
CA2676700A1 (en) | 2008-08-14 |
PL2114885T3 (pl) | 2016-07-29 |
CN101605760B (zh) | 2012-06-20 |
HK1139151A1 (en) | 2010-09-10 |
DK2114885T3 (en) | 2016-05-09 |
EP2114885B1 (en) | 2016-01-27 |
ES2561355T3 (es) | 2016-02-25 |
IL199938A0 (en) | 2010-04-15 |
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Legal Events
Date | Code | Title | Description |
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FG | Grant or registration |