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MX173254B - Catalizador de deshidrogenacion - Google Patents

Catalizador de deshidrogenacion

Info

Publication number
MX173254B
MX173254B MX012056A MX1205688A MX173254B MX 173254 B MX173254 B MX 173254B MX 012056 A MX012056 A MX 012056A MX 1205688 A MX1205688 A MX 1205688A MX 173254 B MX173254 B MX 173254B
Authority
MX
Mexico
Prior art keywords
calculated
percent
weight
compound
dehydrogenation catalyst
Prior art date
Application number
MX012056A
Other languages
English (en)
Inventor
Roland Albert Charles Garin
Pierre Eugene Dejaifve
Jacques Julien Jean Dufour
Jean-Paul Darnanville
Original Assignee
Shell Int Research
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Int Research filed Critical Shell Int Research
Publication of MX173254B publication Critical patent/MX173254B/es

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/62—Platinum group metals with gallium, indium, thallium, germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/835—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with germanium, tin or lead
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
    • B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/56—Platinum group metals
    • B01J23/63—Platinum group metals with rare earths or actinides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/83—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with rare earths or actinides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/32—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by dehydrogenation with formation of free hydrogen
    • C07C5/327—Formation of non-aromatic carbon-to-carbon double bonds only
    • C07C5/333—Catalytic processes
    • C07C5/3332—Catalytic processes with metal oxides or metal sulfides

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

La presente invención serefiere a un catalizador de deshidrogenación que comprende: 1 a 25 por ciento en peso de un compuesto de metal alcalino, calculado como óxido de metal alcalino estable; 0,5 a 20 por ciento en peso de un compuesto de un metal de las tierras raras, calculado como óxido; 0,1 a 10 por ciento en peso de un compuesto de calcio, calculado como CaO; 0,5 A 10 por ciento en peso de un compuesto de germanio, estaño y/o plomo, calculado como dióxido; y 35 a 97,9 por ciento en peso de un compuesto de hierro, calculado como Fe2O3.
MX012056A 1987-06-29 1988-06-27 Catalizador de deshidrogenacion MX173254B (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8709149A FR2617060A1 (fr) 1987-06-29 1987-06-29 Catalyseur de deshydrogenation, application a la preparation de styrene et styrene ainsi obtenu

Publications (1)

Publication Number Publication Date
MX173254B true MX173254B (es) 1994-02-14

Family

ID=9352629

Family Applications (1)

Application Number Title Priority Date Filing Date
MX012056A MX173254B (es) 1987-06-29 1988-06-27 Catalizador de deshidrogenacion

Country Status (16)

Country Link
US (1) US4857498A (es)
EP (1) EP0297657B1 (es)
JP (1) JPS6427646A (es)
KR (1) KR890000150A (es)
CN (1) CN1021637C (es)
AU (1) AU599813B2 (es)
BR (1) BR8803152A (es)
CA (1) CA1310952C (es)
DE (1) DE3872777T2 (es)
ES (1) ES2042710T3 (es)
FI (1) FI883072A (es)
FR (1) FR2617060A1 (es)
GR (1) GR3005209T3 (es)
MX (1) MX173254B (es)
PL (1) PL159228B1 (es)
RU (1) RU1836141C (es)

Families Citing this family (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5711930A (en) * 1989-03-10 1998-01-27 Thiele Kaolin Company Process for improving the phyiscal properties of formed particles
US5866496A (en) * 1989-03-10 1999-02-02 Thiele Kaolin Company Cracking catalyst and process for preparing same
US5171914A (en) * 1991-08-30 1992-12-15 Shell Oil Company Dehydrogenation catalyst and process
US5376613A (en) * 1993-05-04 1994-12-27 The Dow Chemical Company Dehydrogenation catalyst and process for preparing same
JP4376966B2 (ja) * 1994-12-14 2009-12-02 シエル・インターナシヨネイル・リサーチ・マーチヤツピイ・ベー・ウイ 再構造化された酸化鉄
ES2222468T3 (es) * 1994-12-14 2005-02-01 Shell Internationale Research Maatschappij B.V. Proceso de preparacion de catalizadores de deshidrogenacion.
CA2207560A1 (en) * 1994-12-14 1996-06-20 Shell Internationale Research Maatschappij B.V. Large particle dehydrogenation catalyst and process
WO1996034685A1 (en) * 1995-05-02 1996-11-07 Tricat Industries, Inc. Catalyst and process for preparing same
DE19535416A1 (de) * 1995-09-23 1997-03-27 Basf Ag Verfahren zur Herstellung von Katalysatoren für selektive Dehydrierungen
CN1050535C (zh) * 1995-11-15 2000-03-22 中国石油化工总公司 用于生产不饱和芳烃的脱氢催化剂
AU2002304805A1 (en) 2001-04-10 2002-10-28 Basf Aktiengesellschaft Iron oxides with a higher degree of refining
ITMI20020702A1 (it) * 2002-04-05 2003-10-06 Univ Degli Studi Milano Catalizzatore per deidrogenazione dell'etilbenzene a stirene
CN100391605C (zh) * 2005-01-26 2008-06-04 中国石油化工股份有限公司 用于制备烷烯基芳烃的脱氢催化剂
JP5096751B2 (ja) 2007-01-26 2012-12-12 クラリアント触媒株式会社 物理的強度が改良されたアルキル芳香族化合物脱水素触媒およびその製造方法並びに脱水素化方法
DE102008036724A1 (de) * 2008-08-07 2010-02-11 Uhde Gmbh Hochporöse Schaumkeramiken als Katalysatorträger zur Dehydrierung von Alkanen
US20100081855A1 (en) * 2008-09-30 2010-04-01 Fina Technology, Inc. Semi-Supported Dehydrogenation Catalyst
EP2353712A4 (en) * 2008-11-07 2012-08-01 Sued Chemie Catalysts Jp Inc DEHYDRATION CATALYST FOR ALKYLAROMATIC COMPOUNDS WITH HIGH PERFORMANCE IN THE PRESENCE OF HIGH-CONCENTRATED CO2, METHOD OF PREPARATION THEREOF AND DEHYDRATION METHOD THEREWITH
US20110105818A1 (en) * 2009-10-31 2011-05-05 Fina Technology, Inc. Dehydrogenation Catalyst with a Water Gas Shift Co-Catalyst
AU2010313369B2 (en) 2009-11-02 2014-02-13 Shell Internationale Research Maatschappij B.V. Process for the conversion of mixed lower alkanes to aromatic hydrocarbons
US8779224B2 (en) 2010-04-12 2014-07-15 Shell Oil Company Process for the production of gasoline blending components and aromatic hydrocarbons from lower alkanes
WO2011131647A1 (en) 2010-04-23 2011-10-27 Shell Internationale Research Maatschappij B.V. Process for producing aromatic hydrocarbons and ethylene
CN102892730A (zh) 2010-05-12 2013-01-23 国际壳牌研究有限公司 低级烷烃转化为芳香烃的方法
CN106582692B (zh) * 2015-10-16 2019-05-14 中国石油化工股份有限公司 高活性的低水比乙苯脱氢催化剂
CN106582687B (zh) * 2015-10-16 2019-05-14 中国石油化工股份有限公司 低水比乙苯脱氢的催化剂及其制备方法
CN106582827B (zh) * 2015-10-16 2019-04-12 中国石油化工股份有限公司 高活性低水比乙苯脱氢催化剂
CN106582674B (zh) * 2015-10-16 2019-05-14 中国石油化工股份有限公司 乙苯脱氢的低稀土催化剂

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US181999A (en) * 1876-09-05 Improvement in the manufacture of vinegar
US3364277A (en) * 1965-05-21 1968-01-16 Shell Oil Co Dehydrogenating olefins to diolefins in the presence of a yellow iron oxide catalyst
FR2266738B1 (es) * 1974-04-08 1977-10-14 Raffinage Cie Francaise
JPS6027651B2 (ja) * 1981-08-13 1985-06-29 工業技術院長 アルカンポリオ−ルの製造方法
JPS58177148A (ja) * 1982-04-13 1983-10-17 Mitsubishi Petrochem Co Ltd スチレン製造用触媒
DE3442636A1 (de) * 1984-11-22 1986-05-22 Süd-Chemie AG, 8000 München Dehydrierungskatalysator
FR2592375B1 (fr) * 1985-12-27 1988-04-08 Shell Int Research Procede de deshydrogenation sans oxydation

Also Published As

Publication number Publication date
ES2042710T3 (es) 1993-12-16
RU1836141C (ru) 1993-08-23
AU1845688A (en) 1989-01-05
FI883072A (fi) 1988-12-30
BR8803152A (pt) 1989-01-31
KR890000150A (ko) 1989-03-11
EP0297657B1 (en) 1992-07-15
EP0297657A1 (en) 1989-01-04
DE3872777D1 (de) 1992-08-20
PL159228B1 (pl) 1992-11-30
PL273341A1 (en) 1989-03-20
FR2617060A1 (fr) 1988-12-30
AU599813B2 (en) 1990-07-26
GR3005209T3 (es) 1993-05-24
CN1032119A (zh) 1989-04-05
US4857498A (en) 1989-08-15
FI883072A0 (fi) 1988-06-27
JPS6427646A (en) 1989-01-30
CN1021637C (zh) 1993-07-21
DE3872777T2 (de) 1993-02-25
CA1310952C (en) 1992-12-01

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