Hegedus et al., 1982 - Google Patents
Reactions of transition-metal nucleophiles with transition-metal electrophiles. Reactions of acyliron, acylnickel, and cobalt carbonyl anions with (. pi.-allyl) palladium …Hegedus et al., 1982
- Document ID
- 3584234257077279595
- Author
- Hegedus L
- Tamura R
- Publication year
- Publication venue
- Organometallics
External Links
Snippet
(ir-Allyl) palladium chloride complexes react with anionic acyliron tetracarbonyl complexes and anionic acylnickel carbonyl complexes to produce, ß-and ß,-unsaturated ketones, resulting from acylation of the-allyl ligand. A varietyof-allyl complexes and acylmetal …
- KDLHZDBZIXYQEI-UHFFFAOYSA-N palladium data:image/svg+xml;base64,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 data:image/svg+xml;base64,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 [Pd] 0 title abstract description 72
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0086—Platinum compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/04—Nickel compounds
- C07F15/045—Nickel compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
- C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/02—Iron compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F1/00—Compounds containing elements of Groups 1 or 11 of the Periodic System
- C07F1/08—Copper compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/02—Boron compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
- C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic System without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
- C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Thorn | Hydrido formyl, methoxycarbonyl, hydroxymethyl, and methyl complexes of iridium: syntheses and reactivities | |
| Burkhardt et al. | Synthesis and reactions of nickel and palladium carbon-bound enolate complexes | |
| Gell et al. | Preparation of zirconium (II) complexes by ligand-induced reductive elimination. Bis (. eta. 5-cyclopentadienyl) bis (phosphine) zirconium (II) complexes and their reactions | |
| King et al. | Polytertiary phosphines and arsines. III. Metal complexes of the tritertiary phosphine bis (2-diphenylphosphinoethyl) phenylphosphine | |
| Monaghan et al. | Oxidation of dimethylplatinum (II) complexes with alcohols: synthesis and characterization of alkoxoplatinum (IV) complexes | |
| Green et al. | Synthesis, characterization and reactivity of alkoxide and hydroxide complexes of rhodium (I) and iridium (I) | |
| Clark et al. | Chemistry of metal hydrides. XIII. Insertion and isomerization reactions of allylic compounds with cationic platinum (II)-hydrido complexes | |
| Jia et al. | Synthesis and reactivity of ruthenium hydride complexes containing chelating triphosphines. 4. Reactions of ruthenium hydride complexes containing triphosphines with olefins | |
| Shuchart et al. | Propargyl complexes of ruthenium | |
| Van der Zeijden et al. | Orthometalation of m-bis (dimethylaminomethyl) benzene: crystal structure and chemistry of trans-Rh (III) Cl2 [C6H3 (CH2NMe2) 2-o, o'](H2O) | |
| Hegedus et al. | Reactions of transition-metal nucleophiles with transition-metal electrophiles. Reactions of acyliron, acylnickel, and cobalt carbonyl anions with (. pi.-allyl) palladium complexes | |
| Anderson et al. | Carborane Complexes of Ruthenium: A Convenient Synthesis of [Ru (CO) 3 (. eta. 5-7, 8-C2B9H11)] and a Study of Reactions of This Complex | |
| Khairul et al. | Transition metal alkynyl complexes by transmetallation from Au (C [triple bond, length as m-dash] CAr)(PPh 3)(Ar= C 6 H 5 or C 6 H 4 Me-4) | |
| Kovar et al. | Organometallic derivatives of cymantrene. Formation of (fulvalene) hexacarbonyldimanganese | |
| Reger et al. | Preparation of cationic. eta. 2-alkene and. eta. 2-alkyne complexes of the (. eta. 5-C5H5) Fe (CO)[P (OPh) 3] system and reduction of these complexes to. sigma.-alkyl and vinyl derivatives | |
| Dimauro et al. | Carbon-carbon bond activation via formal β-methyl-elimination from [η5-6, 6-dimethylcyclohexadienyl) Ru (DPPE)(CH2Cl2)] PF6 | |
| Koh et al. | The PtP (C6H11) 3 (C2H4) 2 mediated activation of aldehyde C H bonds via chelate-assisted oxidative addition reactions | |
| Jia et al. | Synthesis and characterization of ruthenium acetate complexes containing triphosphines | |
| Holah et al. | Production of Ni (I) complexes from reactions between Ni (II) and NaBH4 in the presence of triphenylphosphine and some bidentate phosphines | |
| Tanaka et al. | Polynuclear Rhodium Complexes with Dinucleating PNNP Ligand: Dynamic and Diverse M⊙⊙⊙ M Interactions in [(μ-X) Rh2 (PNNP)(CO) 2] n+ and [(μ4-X) Rh4 (PNNP) 2 (CO) 4] n+[X= H, O, C⋮ C− R, R− C⋮ C− R, C⋮ C, CH CH2, SMe2; n= 0, 1: PNNP= 3, 5-bis (diphenylphosphinomethyl) pyrazolato] | |
| Planas et al. | C–O and C–S bond activation of allyl esters, ethers, and sulfides by low valent ruthenium complexes | |
| Vrtis et al. | Reaction chemistry of [M (R3SiOCCOSiR3)(dmpe) 2Cl](M= tantalum, niobium): isolation and structural characterization of the first (dihydroxyacetylene) metal complexes and removal of the disiloxyacetylene ligand as an alkene | |
| King III et al. | Reactions at the rhodium vertex of isomeric closo-bis (triphenylphosphine) hydridorhodacarboranes, alkenyl acetate cleavage and subsequent reactions | |
| Blake et al. | Reactions of carbonato and oxalato complexes of platinum (II). Formation of cationic clusters of platinum | |
| Vuzman et al. | Reactivity and stability of platinum (II) formyl complexes based on PCP-type ligands. The significance of sterics |