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Cabeza et al., 2008 - Google Patents

Reactivity of N-Heterocyclic Carbenes with [Ru3 (CO) 12] and [Os3 (CO) 12]. Influence of Ligand Volume and Electronic Effects

Cabeza et al., 2008

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Document ID
300941609089379128
Author
Cabeza J
del Río I
Miguel D
Pérez-Carreño E
Sánchez-Vega M
Publication year
Publication venue
Organometallics

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The room-temperature reactions of [Ru3 (CO) 12] and [Os3 (CO) 12] with a variety of N- heterocyclic carbenes (NHCs) have been studied.[Ru3 (CO) 12] reacts easily with N, N′- dimethylimidazol-2-ylidene (Me2Im), more slowly with N-methyloxazol-2-ylidene (MeOx) …
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    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073Rhodium compounds
    • C07F15/008Rhodium compounds without a metal-carbon linkage
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    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0086Platinum compounds
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    • C07F15/00Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/06Cobalt compounds
    • C07F15/065Cobalt compounds without a metal-carbon linkage
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    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02Phosphorus compounds
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    • C07F17/00Metallocenes
    • C07F17/02Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
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    • C07F13/00Compounds containing elements of Groups 7 or 17 of the Periodic System

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