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Speier et al., 1956 - Google Patents

The addition of silicon hydrides to olefinic double bonds. Part I. The use of phenylsilane, diphenylsilane, phenylmethylsilane, amylsilane and tribromosilane

Speier et al., 1956

Document ID
2737839976763880020
Author
Speier J
Zimmerman R
Webster J
Publication year
Publication venue
Journal of the American Chemical Society

External Links

Snippet

Phenylsilane adds to the double bond of certain compounds including octene-1, cyclohexene, allyl acetate, allyloxytri-methylsilane, diallyl ether, N-allylhexamethyldisilazane , o-allylphenyl acetate, methyl oleate, dicyclopentenyl acetate, acro-lein diacetate, acrolein …
Continue reading at pubs.acs.org (other versions)

Classifications

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    • C07F7/00Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C-Si linkages
    • C07F7/18Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
    • C07F7/1804Compounds having Si-O-C linkages
    • C07F7/1812Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals
    • C07F7/1816Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals a and b being alternatively specified
    • C07F7/182C1 containing aliphatic or cycloaliphatic unsaturated bonds or heteroatoms
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    • C07F7/02Silicon compounds
    • C07F7/08Compounds having one or more C-Si linkages
    • C07F7/0834Compounds having one or more O-Si linkage
    • C07F7/0838Compounds with one or more Si-O-Si sequences
    • C07F7/0872Preparation and treatment thereof
    • C07F7/0876Reactions involving the formation of bonds to a Si atom of a Si-O-Si sequence other than a bond of the Si-O-Si linkage
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    • C07F7/18Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
    • C07F7/1804Compounds having Si-O-C linkages
    • C07F7/1812Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals
    • C07F7/1836Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals a being 1, b being 3
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    • C07F7/0834Compounds having one or more O-Si linkage
    • C07F7/0838Compounds with one or more Si-O-Si sequences
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    • C07F7/121Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
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