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Beckmann et al., 2003 - Google Patents

tert‐Butoxysilanols as model compounds for labile key intermediates of the sol–gel process: crystal and molecular structures of (t‐BuO) 3SiOH and HO [(t‐BuO) 2SiO] …

Beckmann et al., 2003

Document ID
2149175790191740437
Author
Beckmann J
Dakternieks D
Duthie A
Larchin M
Tiekink E
Publication year
Publication venue
Applied organometallic chemistry

External Links

Snippet

The tert‐butoxychlorosilanes (t‐BuO) 3SiCl (1),(t‐BuO) 2SiCl2 (2), and [(t‐BuO) 2SiCl] 2O (3) were prepared by the reaction of SiCl4 or (Cl3Si) 2O with t‐BuOK. Subsequent hydrolysis afforded the tert‐butoxysilanols (t‐BuO) 3SiOH (4),(t‐BuO) 2Si (OH) 2 (5), HO [(t‐BuO) 2SiO] …
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    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/18—Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1812—Compounds having Si-O-C linkages having (C1)a-Si-(OC2)b linkages, a and b each being >=1 and a+b = 4, C1 and C2 being hydrocarbon or substituted hydrocarbon radicals
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    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/18—Compounds having one or more C-Si linkages as well as one or more C-O-Si linkages
    • C07F7/1804—Compounds having Si-O-C linkages
    • C07F7/1872—Preparation; Treatments not provided for in C07F7/20
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    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
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    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/12—Organo silicon halides
    • C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
    • C07F7/122—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
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    • C07F7/02—Silicon compounds
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    • C07F7/0896—Compounds with a Si-H linkage
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    • C07F7/0834—Compounds having one or more O-Si linkage
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