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Auburn et al., 1980 - Google Patents

Synthesis of bis-µ-diorganosilanediyl-af-dihydridobis (triorganophosphine) diplatinum complexes: crystal and molecular structure of [{PtH (µ-SiMe 2)[P (C 6 H 11) 3]} 2 …

Auburn et al., 1980

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Document ID
1909697610554663939
Author
Auburn M
Ciriano M
Howard J
Murray M
Pugh N
Spencer J
Stone F
Woodward P
Publication year
Publication venue
Journal of the Chemical Society, Dalton Transactions

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The compound [{Pt (µ-H)(SiMe2Ph)[P (C6H11) 3]} 2] decomposes in hexane at reflux to give in low yield (10%) the diplatinum complex [{PtH (µ-SiMe2)[P (C6H11) 3]} 2]. A single-crystal X-ray diffraction study shows that the crystals are monoclinic, space group P21/c, with Z= 2 …
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    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6571—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus and oxygen atoms as the only ring hetero atoms
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    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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