Wooster et al., 1935 - Google Patents

The Structure of Metal Ketyls. IV. The Nature of the Intermediate Product in the Reaction with Alkyl Halides

Wooster et al., 1935

Document ID: 18360913210357642383
Author: Wooster C; Dean J
Publication year: 1935
Publication venue: Journal of the American Chemical Society

External Links

Cited by

Snippet

It has been shown1 that the reaction between the metal ketyl, sodium benzophenone, and ethyl bromide involves at least twosuccessive reac-tions which may be expressed by Equations 1 and 2, writing the formula of the ketyl as C13HioONa to avoid prejudice …

Continue reading at pubs.acs.org (other versions)

238000006243 chemical reaction 0 title abstract description 35

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P-C bonds
- C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/04—Metal peroxides or peroxyhydrates thereof; Metal superoxides; Metal ozonides; Peroxyhydrates thereof
- C01B15/043—Metal peroxides or peroxyhydrates thereof; Metal superoxides; Metal ozonides; Peroxyhydrates thereof of alkali metals, alkaline earth metals or magnesium or beryllium or aluminium
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/01—Hydrogen peroxide
- C01B15/013—Separation; Purification; Concentration
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/087—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B11/00—Oxides or oxyacids of halogens; Salts thereof
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System

Similar Documents

Publication	Publication Date	Title
Schlesinger et al.	1953	Uranium (IV) borohydride1
HURD	1948	Complex metal alkyls
Shore et al.	1958	Chemical evidence for the structure of the “diammoniate of diborane.” II. The preparation of ammonia-borane
Auten et al.	1952	Studies Relating to Boron. V. Chemistry of the Dibutylboron Group1
Wooster et al.	1935	The Structure of Metal Ketyls. IV. The Nature of the Intermediate Product in the Reaction with Alkyl Halides
Armstrong et al.	1960	Volatile organic matter in algal culture media and sea water
Bergstrom	1937	THE DIRECT INTRODUCTION OF THE AMINO GROUP INTO THE AROMATIC AND HETEROCYCLIC NUCLEUS. III. FURTHER OBSERVATIONS CONCERNING THE ACTION OF THE ALKALI AMIDES ON QUINOLINE AND ISOQUINOLINE
McGee et al.	1947	Investigation of the Properties of Cellulose Oxidized by Nitrogen Dioxide. V. Study of Mechanism of Oxidation in Presence of Carbon Tetrachloride1
Schumb et al.	1938	Studies in Organo-silicon Synthesis. I. The Wurtz Reaction with Silicon Chlorides
Heal	1961	“Onium” base borohydrides—II: Some phenyl compounds
US4112118A (en)	1978-09-05	Process for preparing phosphate salts
US3361528A (en)	1968-01-02	Purification of orthophosphorous acid
Cox Jr et al.	1969	Carbonium ion formation in solvolysis of phosphate triesters
Schenck et al.	1953	The reaction of bisulfite with epoxy compounds
Lamberton et al.	1949	357. Studies on nitroamines. Part VII. The decomposition of methylenedinitroamine in aqueous solutions
Kraus et al.	1933	The Action of Sodium upon Trimethylgallium and Dimethylgallium Chloride in Liquid Ammonia
US3579570A (en)	1971-05-18	Ethane-1,2 - dicarboxy - 1,2-dihydroxy-1,2-diphosphonic acid,lower alkyl esters,alkali metal salts thereof and process for preparing same
Dunstan et al.	1905	CLIII.—The rusting of iron
Jagur et al.	1963	Chemistry of radical ions. Part 2.—Alternative method for determining the equilibrium constant of dissociation
Hamrick Jr et al.	1959	The Reversible Addition of Sodiodiphenylmethide to Benzophenone in Liquid Ammonia, Base-catalyzed Cleavage of 1, 1, 2, 2-Tetraphenylethanol1, 2
Marvel et al.	1938	Diaryl Ketone Peroxides
US2488363A (en)	1949-11-15	Stabilization of formaldehyde
US2386484A (en)	1945-10-09	Anhydrous hydrogen peroxide and method of making same
Bachmann	1933	The Action of Sodium Alcoholate and of Sodium Amalgam on Aromatic Pinacols
Addison et al.	1952	71. The oxidation of sodium hyponitrite and sodium α-oxyhyponitrite with dinitrogen tetroxide