Rafiee et al., 2019 - Google Patents
Electrochemical aminoxyl-mediated oxidation of primary alcohols in lignin to carboxylic acids: polymer modification and depolymerizationRafiee et al., 2019
View HTML- Document ID
- 1805210704304304293
- Author
- Rafiee M
- Alherech M
- Karlen S
- Stahl S
- Publication year
- Publication venue
- Journal of the American Chemical Society
External Links
Snippet
An electrochemical process has been developed for chemoselective oxidation of primary alcohols in lignin to the corresponding carboxylic acids. The electrochemical oxidation reactions proceed under mildly basic conditions and employ 2, 2, 6, 6-tetramethyl-1 …
- 229920005610 lignin 0 title abstract description 511
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/02—Preparation of oxygen-containing organic compounds containing a hydroxy group
- C12P7/04—Preparation of oxygen-containing organic compounds containing a hydroxy group acyclic
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12P—FERMENTATION OR ENZYME-USING PROCESSES TO SYNTHESISE A DESIRED CHEMICAL COMPOUND OR COMPOSITION OR TO SEPARATE OPTICAL ISOMERS FROM A RACEMIC MIXTURE
- C12P7/00—Preparation of oxygen-containing organic compounds
- C12P7/24—Preparation of oxygen-containing organic compounds containing a carbonyl group
- C12P7/26—Ketones
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B15/00—Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
- C08B15/02—Oxy-cellulose; Hydrocellulose; Cellulosehydrate, e.g. microcrystalline cellulose
- C08B15/04—Carboxycellulose, e.g. prepared by oxidation with nitrogen dioxide
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Rafiee et al. | Electrochemical aminoxyl-mediated oxidation of primary alcohols in lignin to carboxylic acids: polymer modification and depolymerization | |
| Das et al. | Lignin conversion to low-molecular-weight aromatics via an aerobic oxidation-hydrolysis sequence: comparison of different lignin sources | |
| Li et al. | Ru-catalyzed hydrogenolysis of lignin: base-dependent tunability of monomeric phenols and mechanistic study | |
| Luo et al. | Oxidative catalytic fractionation of lignocellulosic biomass under non-alkaline conditions | |
| Schutyser et al. | Chemicals from lignin: an interplay of lignocellulose fractionation, depolymerisation, and upgrading | |
| O’Dea et al. | 100th anniversary of macromolecular science viewpoint: polymers from lignocellulosic biomass. Current challenges and future opportunities | |
| Chatel et al. | Oxidation of lignin using ionic liquids An innovative strategy to produce renewable chemicals | |
| Mei et al. | Selectively transform lignin into value-added chemicals | |
| Liu et al. | Visible-light-induced oxidative lignin C–C bond cleavage to aldehydes using vanadium catalysts | |
| Graglia et al. | Lignin refinery: Towards the preparation of renewable aromatic building blocks | |
| Zijlstra et al. | Mild organosolv lignin extraction with alcohols: the importance of benzylic alkoxylation | |
| Ma et al. | An electrocatalytic strategy for C–C bond cleavage in lignin model compounds and lignin under ambient conditions | |
| Lahive et al. | Advanced model compounds for understanding acid-catalyzed lignin depolymerization: identification of renewable aromatics and a lignin-derived solvent | |
| Li et al. | Catalytic transformation of lignin for the production of chemicals and fuels | |
| Renders et al. | Synergetic effects of alcohol/water mixing on the catalytic reductive fractionation of poplar wood | |
| Galkin et al. | Lignin valorization through catalytic lignocellulose fractionation: a fundamental platform for the future biorefinery | |
| Ouyang et al. | Catalytic conversion of lignin in woody biomass into phenolic monomers in methanol/water mixtures without external hydrogen | |
| Wang et al. | Preserving both lignin and cellulose chemical structures: flow-through acid hydrotropic fractionation at atmospheric pressure for complete wood valorization | |
| Li et al. | Photocatalytic cleavage of aryl ether in modified lignin to non-phenolic aromatics | |
| Li et al. | Paving the way for the lignin hydrogenolysis mechanism by deuterium-incorporated β-O-4 mimics | |
| Hülsey et al. | Sustainable routes for the synthesis of renewable heteroatom-containing chemicals | |
| Sun et al. | Fragmentation of woody lignocellulose into primary monolignols and their derivatives | |
| Huang et al. | Effective release of lignin fragments from lignocellulose by Lewis acid metal triflates in the lignin‐first approach | |
| Upton et al. | Strategies for the conversion of lignin to high-value polymeric materials: review and perspective | |
| Lancefield et al. | Investigation of the chemocatalytic and biocatalytic valorization of a range of different lignin preparations: the importance of β-O-4 content |