Aboelella et al., 2006 - Google Patents
Effects of Thioether Substituents on the O2 Reactivity of β-Diketiminate− Cu (I) Complexes: Probing the Role of the Methionine Ligand in Copper MonooxygenasesAboelella et al., 2006
View HTML- Document ID
- 16504455631168762960
- Author
- Aboelella N
- Gherman B
- Hill L
- York J
- Holm N
- Young V
- Cramer C
- Tolman W
- Publication year
- Publication venue
- Journal of the American Chemical Society
External Links
Snippet
The activation of dioxygen by dopamine β-monooxygenase (DβM) and peptidylglycine α- hydroxylating monooxygenase (PHM) is postulated to occur at a copper site ligated by two histidine imidazoles and a methionine thioether, which is unusual because such thioether …
- 239000010949 copper 0 title abstract description 300
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/002—Osmium compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0046—Ruthenium compounds
- C07F15/0053—Ruthenium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/02—Boron compounds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/02—Iron compounds
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Aboelella et al. | Effects of Thioether Substituents on the O2 Reactivity of β-Diketiminate− Cu (I) Complexes: Probing the Role of the Methionine Ligand in Copper Monooxygenases | |
Goetz et al. | Experimental evidence for p K a-driven asynchronicity in C–H activation by a terminal Co (III)–oxo complex | |
Taki et al. | Fine-tuning of copper (I)-dioxygen reactivity by 2-(2-pyridyl) ethylamine bidentate ligands | |
Aboelella et al. | Dioxygen Activation at a Single Copper Site: Structure, Bonding, and Mechanism of Formation of 1: 1 Cu− O2 Adducts | |
Reynolds et al. | Characterization of a 1: 1 Cu− O2 adduct supported by an anilido imine ligand | |
Goldsmith et al. | C− H bond activation by a ferric methoxide complex: Modeling the rate-determining step in the mechanism of lipoxygenase | |
Kumar et al. | Oxygen atom transfer reactions from isolated (oxo) manganese (V) corroles to sulfides | |
Yang et al. | Mechanistic insights into catalytic H2 oxidation by Ni complexes containing a diphosphine ligand with a positioned amine base | |
Chen et al. | Spectroscopic and Electronic Structure Studies of the Diamagnetic Side-On CuII-Superoxo Complex Cu (O2)[HB (3-R-5-i Prpz) 3]: Antiferromagnetic Coupling versus Covalent Delocalization | |
Zhou et al. | Dinuclear nickel complexes in five states of oxidation using a redox-active ligand | |
Lee et al. | Mechanistic insights into the oxidation of substituted phenols via hydrogen atom abstraction by a cupric–superoxo complex | |
York et al. | Heterobimetallic activation of dioxygen: characterization and reactivity of novel Cu (I)− Ge (II) complexes | |
Drummond et al. | Radical rebound hydroxylation versus H-atom transfer in non-heme iron (III)-hydroxo complexes: reactivity and structural differentiation | |
Peterson et al. | Stepwise protonation and electron-transfer reduction of a primary copper–dioxygen adduct | |
Spencer et al. | Copper chemistry of β-diketiminate ligands: monomer/dimer equilibria and a new class of bis (μ-oxo) dicopper compounds | |
Rohde et al. | Nonheme oxoiron (IV) complexes of tris (2-pyridylmethyl) amine with cis-monoanionic ligands | |
Viswanathan et al. | Functional models for catechol 1, 2-dioxygenase. Synthesis, structure, spectra, and catalytic activity of certain tripodal iron (III) complexes | |
Imbert et al. | Influence of ligand rigidity and ring substitution on the structural and electronic behavior of trivalent iron and gallium complexes with asymmetric tridentate ligands | |
Coggins et al. | Correlation Between Structural, Spectroscopic, and Reactivity Properties Within a Series of Structurally Analogous Metastable Manganese (III)–Alkylperoxo Complexes | |
Fujisawa et al. | Structural and spectroscopic characterization of mononuclear copper (I) nitrosyl complexes: end-on versus side-on coordination of NO to copper (I) | |
Brown et al. | Ligand structural effects on Cu2S2 bonding and reactivity in side-on disulfido-bridged dicopper complexes | |
Wu et al. | Tuning the Photoinduced O2-Evolving Reactivity of Mn4O47+, Mn4O46+, and Mn4O3 (OH) 6+ Manganese− Oxo Cubane Complexes | |
Gordon et al. | Tuning the Fe (II/III) redox potential in nonheme Fe (II)–hydroxo complexes through primary and secondary coordination sphere modifications | |
Chambers et al. | Iron in a trigonal tris (alkoxide) ligand environment | |
Park et al. | Fe (II) complexes that mimic the active site structure of acetylacetone dioxygenase: O2 and NO reactivity |