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Majumdar et al., 2014 - Google Patents

Versatile reactivity of a solvent-coordinated diiron (II) compound: Synthesis and dioxygen reactivity of a mixed-valent FeIIFeIII species

Majumdar et al., 2014

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Document ID
16438480906548479517
Author
Majumdar A
Apfel U
Jiang Y
Moënne-Loccoz P
Lippard S
Publication year
Publication venue
Inorganic chemistry

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A new, DMF-coordinated, preorganized diiron compound [Fe2 (N-Et-HPTB)(DMF) 4](BF4) 3 (1) was synthesized, avoiding the formation of [Fe (N-Et-HPTB)](BF4) 2 (10) and [Fe2 (N-Et- HPTB)(μ-MeCONH)](BF4) 2 (11), where N-Et-HPTB is the anion of N, N, N′, N′-tetrakis [2 …
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