Kumar et al., 2022 - Google Patents
Hydroformylation of olefins by metals other than rhodiumKumar et al., 2022
View PDF- Document ID
- 16051036699961103137
- Author
- Kumar R
- Chikkali S
- Publication year
- Publication venue
- Journal of Organometallic Chemistry
External Links
Snippet
Metal catalyzed hydroformylation of alkenes is an atom economic transformation to construct useful aldehydes and is being industrially practiced for decades. The most commonly used metal for this transformation on an industrial scale is rhodium. However, rhodium is rare …
- 238000007037 hydroformylation reaction 0 title abstract description 213
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
- C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Kumar et al. | Hydroformylation of olefins by metals other than rhodium | |
Liu et al. | Selective palladium-catalyzed carbonylation of alkynes: an atom-economic synthesis of 1, 4-dicarboxylic acid diesters | |
Weber | Phosphorus heterocycles: From laboratory curiosities to ligands in highly efficient catalysts | |
Wu et al. | Ruthenium-catalyzed hydroformylation/reduction of olefins to alcohols: extending the scope to internal alkenes | |
Börner et al. | Hydroformylation: Fundamentals, Processes, and Applications in Organic Synthesis, 2 Volumes | |
Trzeciak et al. | Structural and mechanistic studies of Pd-catalyzed CC bond formation: The case of carbonylation and Heck reaction | |
Chakraborty et al. | Nickel and iron pincer complexes as catalysts for the reduction of carbonyl compounds | |
Pospech et al. | Alternative metals for homogeneous catalyzed hydroformylation reactions | |
Pinault et al. | Homogeneous catalysts based on water-soluble phosphines | |
Li et al. | A new class of PN3-pincer ligands for metal–ligand cooperative catalysis | |
Onishi et al. | CO2 hydrogenation catalyzed by iridium complexes with a proton-responsive ligand | |
Jessop et al. | Recent advances in the homogeneous hydrogenation of carbon dioxide | |
Garcia-Alvarez et al. | Iminophosphorane–phosphines: Versatile ligands for homogeneous catalysis | |
Oren et al. | Metal–Ligand Cooperation as Key in Formation of Dearomatized NiII–H Pincer Complexes and in Their Reactivity toward CO and CO2 | |
Moustani et al. | Novel aqueous-phase hydrogenation reaction of the key biorefinery platform chemical levulinic acid into γ-valerolactone employing highly active, selective and stable water-soluble ruthenium catalysts modified with nitrogen-containing ligands | |
Takaoka et al. | Hydrogenation of Carbon Dioxide with Organic Base by PCIIP-Ir Catalysts | |
Cadierno et al. | Neutral and cationic (η6-arene)-ruthenium (II) complexes containing the iminophosphorane–phosphine ligand Ph2PCH2P ( Np-C5F4N) Ph2: influence of the arene ring in catalytic transfer hydrogenation of cyclohexanone | |
Takahashi et al. | Mechanistic investigations of the ruthenium-catalyzed synthesis of acrylate salt from ethylene and CO2 | |
Shin et al. | Ligand-controlled direct hydroformylation of trisubstituted olefins | |
Xu et al. | Ethylene as a synthon in carbonylative synthesis | |
Liu et al. | Phosphine-ligated Ir (III)-complex as a bi-functional catalyst for one-pot tandem hydroformylation-acetalization | |
Ramarou et al. | Synthesis of Rh (I) alkylated-PTA complexes as catalyst precursors in the aqueous-biphasic hydroformylation of 1-octene | |
Baber et al. | Phenylphosphatrioxa-adamantanes: bulky, robust, electron-poor ligands that give very efficient rhodium (I) hydroformylation catalysts | |
Liu et al. | Ir-catalyzed tandem hydroformylation-transfer hydrogenation of olefins with (trans-/cis-) formic acid as hydrogen source in presence of 1, 10-phenanthroline | |
Bertoux et al. | Advances in transition-metal catalyzed hydroxycarbonylation reactions in aqueous-organic two-phase system |