Becker et al., 1956 - Google Patents
Spectroscopic studies of reactive molecules by the matrix isolation methodBecker et al., 1956
- Document ID
- 14447220974022459027
- Author
- Becker E
- Pimentel G
- Publication year
- Publication venue
- The Journal of Chemical Physics
External Links
Snippet
The matrix isolation method for the study of reactive molecules is described. The properties that should be possessed by a material suitable for use as a matrix are discussed with particular reference to spectroscopic investigations. Tests of the method have been …
- 239000011159 matrix material 0 title abstract description 76
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/087—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/083—Compounds containing nitrogen and non-metals and optionally metals containing one or more halogen atoms
- C01B21/084—Compounds containing nitrogen and non-metals and optionally metals containing one or more halogen atoms containing also one or more oxygen atoms, e.g. nitrosyl halides
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using infra-red, visible or ultra-violet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/25—Colour; Spectral properties, i.e. comparison of effect of material on the light at two or more different wavelengths or wavelength bands
- G01N21/31—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry
- G01N21/35—Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry using infra-red light
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Becker et al. | Spectroscopic studies of reactive molecules by the matrix isolation method | |
Milligan et al. | Infrared spectrum of CF2 | |
Schott et al. | Shock Waves in Chemical Kinetics: The Decomposition of N2O5 at High Temperatures1 | |
Horn et al. | Adsorption of stratospherically important molecules on thin D 2 O ice films using reflection absorption infrared spectroscopy | |
Bondybey et al. | Hydrogen dibromide radical: Infrared detection through the matrix isolation technique | |
Harmony et al. | Infrared spectrum and thermodynamic functions of the NF2 radical | |
Bigeleisen et al. | Deuterium isotope effect in the reaction of hydrogen molecules with chlorine atoms and the potential energy of the H2Cl transition complex | |
Hunt et al. | Photolysis of hydrogen and fluorine in solid argon. Matrix infrared spectra of (HF) 2,(HF)(DF), and (DF) 2 | |
Deakin et al. | Electronically excited iodine atoms, I (5 p 5 2 P ½). A kinetic study of collisional quenching by time-resolved atomic absorption, I (5 p 4 6 s (2 P [fraction three-over-two]) â†� 5 p 5 (2 P° ½)) at λ= 206.23 nm | |
Johnsson et al. | A matrix isolation study of the chlorine superoxide radical | |
Jacox et al. | Matrix isolation study of the interaction of excited neon atoms with BF3: Infrared spectra of BF2, BF+ 2, BF+ 3, and BF− 3 | |
Rebbert et al. | The Photolysis and Radiolysis of CH3N2CH3 and CH3N2CH3-CD3N2CD3 Mixtures1 | |
Clifford et al. | Preparation and Properties of Pentafluorosulfanyliminosulfur Difluoride, SF5N= SF2 | |
Prochaska et al. | Raman, infrared and ultraviolet spectra of the chlorine difluoride free radical in solid nitrogen | |
Andrews et al. | Optical spectra of calcium atoms in inert matrices: A new red absorption for Ca2 | |
Groth et al. | The photolysis of nitrous oxide in the far ultraviolet | |
Addison et al. | Infrared and Raman spectra of solutions of zinc, cadmium, and mercury (II) nitrates in acetonitrile | |
Sonobe et al. | Energy disposal in the photofragmentation of ketene | |
Wollrab et al. | Lifetime of gas‐phase carbon monosulfide | |
Diem et al. | Some observations on molecular complexes of carbon monoxide in argon and oxygen nutrices | |
Jacox et al. | The production and spectroscopy of molecular ions isolated in solid neon | |
Christe et al. | Structure of the Tetrafluorochlorate (III) Anion, ClF4 | |
Yu et al. | Sulfur (VI)-nitrogen compounds which contain trifluoromethyl sulfur tetrafluoride (1-) | |
Odom et al. | Spectra and structure of phosphorus-boron compounds. II. Vibrational and nuclear magnetic resonance spectral investigation of phosphine-trichloroborane | |
Jacobs et al. | Synthesis and properties of sulfur cyanide trifluoride, SF3CN, sulfur dicyanide difluoride, SF2 (CN) 2, and sulfinyl cyanide fluoride, FS (O) CN |