Nioradze et al., 2011 - Google Patents
Quasi-steady-state voltammetry of rapid electron transfer reactions at the macroscopic substrate of the scanning electrochemical microscopeNioradze et al., 2011
View HTML- Document ID
- 14393079593532490872
- Author
- Nioradze N
- Kim J
- Amemiya S
- Publication year
- Publication venue
- Analytical chemistry
External Links
Snippet
We report on a novel theory and experiment for scanning electrochemical microscopy (SECM) to enable quasi-steady-state voltammetry of rapid electron transfer (ET) reactions at macroscopic substrates. With this powerful approach, the substrate potential is cycled widely …
- 239000000758 substrate 0 title abstract description 289
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/28—Electrolytic cell components
- G01N27/30—Electrodes, e.g. test electrodes; Half-cells
- G01N27/327—Biochemical electrodes electrical and mechanical details of in vitro measurements
- G01N27/3271—Amperometric enzyme electrodes for analytes in body fluids, e.g. glucose in blood
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means
- G01N27/26—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating electrochemical variables; by using electrolysis or electrophoresis
- G01N27/416—Systems
- G01N27/48—Polarography, i.e. measuring changes in current under a slowly-varying voltage
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N33/00—Investigating or analysing materials by specific methods not covered by the preceding groups
- G01N33/48—Investigating or analysing materials by specific methods not covered by the preceding groups biological material, e.g. blood, urine; Haemocytometers
- G01N33/50—Chemical analysis of biological material, e.g. blood, urine; Testing involving biospecific ligand binding methods; Immunological testing
- G01N33/53—Immunoassay; Biospecific binding assay
- G01N33/543—Immunoassay; Biospecific binding assay with an insoluble carrier for immobilising immunochemicals
- G01N33/54366—Apparatus specially adapted for solid-phase testing
- G01N33/54373—Apparatus specially adapted for solid-phase testing involving physiochemical end-point determination, e.g. wave-guides, FETS, gratings
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N27/00—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means
- G01N27/02—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating the impedance of the material
- G01N27/04—Investigating or analysing materials by the use of electric, electro-chemical, or magnetic means by investigating the impedance of the material by investigating resistance
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Nioradze et al. | Quasi-steady-state voltammetry of rapid electron transfer reactions at the macroscopic substrate of the scanning electrochemical microscope | |
Zevenbergen et al. | Fast electron-transfer kinetics probed in nanofluidic channels | |
Tanimoto et al. | Discrimination of inner-and outer-sphere electrode reactions by cyclic voltammetry experiments | |
Manica et al. | Characterization of electrode fouling and surface regeneration for a platinum electrode on an electrophoresis microchip | |
Sun et al. | Electrochemistry of individual molecules in zeptoliter volumes | |
Miao et al. | Solution viscosity effects on the heterogeneous electron transfer kinetics of ferrocenemethanol in dimethyl sulfoxide− water mixtures | |
Dawson et al. | Electroanalysis at single gold nanowire electrodes | |
Martin et al. | Theory and experiment for the substrate generation/tip collection mode of the scanning electrochemical microscope: application as an approach for measuring the diffusion coefficient ratio of a redox couple | |
Cox et al. | Steady-state voltammetry of a microelectrode in a closed bipolar cell | |
McKelvey et al. | Fabrication, characterization, and functionalization of dual carbon electrodes as probes for scanning electrochemical microscopy (SECM) | |
Byers et al. | Single molecule electrochemical detection in aqueous solutions and ionic liquids | |
Demaille et al. | Scanning electrochemical microscopy. 33. Application to the study of ECE/DISP reactions | |
Tan et al. | Impact of adsorption on scanning electrochemical microscopy voltammetry and implications for nanogap measurements | |
Yu et al. | Toward more reliable measurements of electron-transfer kinetics at nanoelectrodes: next approximation | |
Rooney et al. | Achievement of near-reversible behavior for the [Fe (CN) 6] 3-/4-redox couple using cyclic voltammetry at glassy carbon, gold, and platinum macrodisk electrodes in the absence of added supporting electrolyte | |
Zhang et al. | Electrochemistry of nanopore electrodes in low ionic strength solutions | |
Amemiya et al. | Generalized theory for nanoscale voltammetric measurements of heterogeneous electron-transfer kinetics at macroscopic substrates by scanning electrochemical microscopy | |
Dumitrescu et al. | Electron transfer kinetics at single-walled carbon nanotube electrodes using scanning electrochemical microscopy | |
Bae et al. | Diffuse layer effect on electron-transfer kinetics measured by scanning electrochemical microscopy (SECM) | |
Bano et al. | Electrode kinetics associated with tetracyanoquinodimethane (TCNQ), TCNQ•–, and TCNQ2–redox chemistry in acetonitrile as determined by analysis of higher harmonic components derived from fourier transformed large amplitude ac voltammetry | |
Shan et al. | Plasmonic-based imaging of local square wave voltammetry | |
Cornut et al. | Accurate and simplified consideration of the probe geometrical defaults in scanning electrochemical microscopy: theoretical and experimental investigations | |
Kim et al. | Scanning electrochemical microscopy of individual single-walled carbon nanotubes | |
Duay et al. | Facile fabrication of carbon ultramicro-to nanoelectrode arrays with tunable voltammetric response | |
Mampallil et al. | Redox couples with unequal diffusion coefficients: effect on redox cycling |