[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

Arii et al., 2008 - Google Patents

Spectroscopic and structural studies of thermally unstable intermediates generated in the reaction of [Pt (PPh3) 2 (η2-C2H4)] with dihydrodisilanes

Arii et al., 2008

Document ID
13934750084419879483
Author
Arii H
Takahashi M
Noda A
Nanjo M
Mochida K
Publication year
Publication venue
Organometallics

External Links

Snippet

The reaction of [Pt (PPh3) 2 (η2-C2H4)](1) with 1, 2-dihydrodisilane HSiR2SiR2H (R= Ph, Me) was investigated by NMR spectroscopy and X-ray diffraction analysis. In the case of R= Ph, the treatment of 1 with HSiPh2SiPh2H at− 60° C afforded the disilanylplatinum hydride …
Continue reading at pubs.acs.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/12—Organo silicon halides
    • C07F7/121—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20
    • C07F7/122—Preparation or treatment not provided for in C07F7/14, C07F7/16 or C07F7/20 by reactions involving the formation of Si-C linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/0803—Compounds with Si-C or Si-Si linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages
    • C07F7/0834—Compounds having one or more O-Si linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/025—Silicon compounds without C-silicon linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
    • C07F5/02—Boron compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • C08G77/382—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon
    • C08G77/398—Polysiloxanes modified by chemical after-treatment containing atoms other than carbon, hydrogen, oxygen or silicon containing boron or metal atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2282—Unsaturated compounds used as ligands
    • B01J31/2295—Cyclic compounds, e.g. cyclopentadienyls
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/48—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule in which at least two but not all the silicon atoms are connected by linkages other than oxygen atoms

Similar Documents

Publication Publication Date Title
Sugiyama et al. Synthesis and properties of a new kinetically stabilized digermyne: New insights for a germanium analogue of an alkyne
Wang et al. Planar, twisted, and trans-bent: conformational flexibility of neutral diborenes
Douthwaite et al. Cationic nickel (II) complexes of chelating N-heterocyclic carbenes
Turculet et al. Coordination Chemistry and Reactivity of New Zwitterionic Rhodium and Iridium Complexes Featuring the Tripodal Phosphine Ligand [PhB (CH2PiPr2) 3]-. Activation of H− H, Si− H, and Ligand B− C Bonds
Jansen et al. Trans-[RuIICl (MeCN) 5][RuIIICl4 (MeCN) 2]: a reactive intermediate in the homogeneous catalyzed hydrosilylation of carbon dioxide
Sangtrirutnugul et al. Silyl derivatives of [bis (8-quinolyl) methylsilyl] iridium (III) complexes: catalytic redistribution of arylsilanes and dehydrogenative arene silylation
Iimura et al. A dialkylsilylene-Pt (0) complex with a DVTMS ligand for the catalytic hydrosilylation of functional olefins
Schmedake et al. Two Trigonal Ni (silylene) 3 Complexes
Arii et al. Spectroscopic and structural studies of thermally unstable intermediates generated in the reaction of [Pt (PPh3) 2 (η2-C2H4)] with dihydrodisilanes
Singh et al. Lewis Base Stabilized Group 14 Metalylenes
Konkol et al. Rare-earth metal alkyl and hydrido complexes containing a thioether-functionalized bis (phenolato) ligand: Efficient catalysts for olefin hydrosilylation
Dysard et al. Synthesis and Reactivity of (Pentamethylcyclopentadienyl) ruthenium Complexes of the Stable Neutral Silylene Si (tBuNCH CHNtBu)
Kim et al. Cis and trans isomers of Pt (SiHAr2) 2 (PR3) 2 (R= Me, Et) in the solid state and in solutions
Tanabe et al. Dinuclear palladium and platinum complexes with bridging silylene ligands. Preparation using (aminosilyl) boronic ester as the ligand precursor and their reactions with alkynes
Levchinsky et al. Reaction of a symmetrical diplatinum complex containing bridging μ-η2-H− SiH (IMP) ligands (IMP= 2-isopropyl-6-methylphenyl) with PMe2Ph. Formation and characterization of {(PhMe2P) 2Pt [μ-SiH (IMP)]} 2
Hashimoto et al. Synthesis and X-ray structure of a platinum η 2-disilene complex
Kim et al. Mechanistic study of alkene hydrosilylation catalyzed by a β-dialdiminate cobalt (I) complex
Tanaka et al. Ring expansion of cyclic triplatinum (0) silylene complexes induced by insertion of alkyne into a Si–Pt bond
Braddock-Wilking et al. Formation and X-ray crystal structure determination of the novel triplatinum cluster [(Ph3P) Pt (μ-SiC12H8)] 3 from reaction of silafluorene with (Ph3P) 2Pt (η2-C2H4)
Casty et al. Synthesis and Reactivity of d0 Bis (imido) Silyl and Germyl Complexes of Molybdenum and Tungsten
Tanabe et al. Ligand exchange of diplatinum complexes with bridging silyl ligands involving Si− H bond cleavage and formation
Ozawa et al. Reactions of cis-and trans-Silyl (methyl) platinum (II) Complexes with Phenylacetylene. Remarkable Effect of Cis and Trans Configurations on the Reactivity
Yamada et al. Palladium− Platinum Heterobimetallic Complexes with Bridging Silicon Ligands. Structure and Reaction with Isonitrile to Afford a Platinacyclopentane Containing Si, N, and C Atoms
Osakada et al. Structure and Chemical Properties of Chlorohydrido (diarylsilyl) rhodium (III) Complexes, mer-RhCl (H)(SiHAr2)(PMe3) 3. Thermally Induced Chloro Transfer from Rhodium to Silicon in the Complexes and Silane Exchange
Tobita et al. Synthesis, Structure, and Reactivity of a Bis (silylene) carbonylruthenium Complex and a Novel Addition Reaction of Photochemically Generated Dimethylsilylene to Bis (silylene) Complexes Cp (OC) M {SiMe2⊙⊙⊙ O (Me)⊙⊙⊙ SiMe2}(M= Ru, Fe)