Schlesinger et al., 1938 - Google Patents
Hydrides of boron. VIII. The structure of the diammoniate of diborane and its relation to the structure of diboraneSchlesinger et al., 1938
- Document ID
- 12629316607110372418
- Author
- Schlesinger H
- Burg A
- Publication year
- Publication venue
- Journal of the American Chemical Society
External Links
Snippet
The structure of diborane (B2Hg) is a problem of very general interest because it raises the im-portant question of the occurrence, in simple compounds, of covalent bonds involving less than a pair of electrons. 1 Such bonds are not required by the structure advocated by …
- DMJZZSLVPSMWCS-UHFFFAOYSA-N diborane B1[H]B[H]1 0 title abstract description 92
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/06—Hydrides of aluminium, gallium, indium, thallium, germanium, tin, lead, arsenic, antimony, bismuth or polonium; Monoborane; Diborane; Addition complexes thereof
- C01B6/10—Monoborane; Diborane; Addition complexes thereof
- C01B6/13—Addition complexes of monoborane or diborane, e.g. with phosphine, arsine or hydrazine
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B15/00—Peroxides; Peroxyhydrates; Peroxyacids or salts thereof; Superoxides; Ozonides
- C01B15/04—Metal peroxides or peroxyhydrates thereof; Metal superoxides; Metal ozonides; Peroxyhydrates thereof
- C01B15/043—Metal peroxides or peroxyhydrates thereof; Metal superoxides; Metal ozonides; Peroxyhydrates thereof of alkali metals, alkaline earth metals or magnesium or beryllium or aluminium
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B21/00—Nitrogen; Compounds thereof
- C01B21/082—Compounds containing nitrogen and non-metals and optionally metals
- C01B21/087—Compounds containing nitrogen and non-metals and optionally metals containing one or more hydrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B17/00—Sulfur; Compounds thereof
- C01B17/16—Hydrogen sulfides
- C01B17/161—Preparation from elemental sulfur
- C01B17/162—Preparation from elemental sulfur from elemental sulfur and hydrogen
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B35/00—Boron; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B9/00—General methods of preparing halides
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C3/00—Cyanogen; Compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B6/00—Hydrides of metals including fully or partially hydrided metals, alloys or intermetallic compounds ; Compounds containing at least one metal-hydrogen bond, e.g. (GeH3)2S, SiH GeH; Monoborane or diborane; Addition complexes thereof
- C01B6/24—Hydrides containing at least two metals; Addition complexes thereof
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C215/00—Compounds containing amino and hydroxy groups bound to the same carbon skeleton
- C07C215/02—Compounds containing amino and hydroxy groups bound to the same carbon skeleton having hydroxy groups and amino groups bound to acyclic carbon atoms of the same carbon skeleton
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01C—AMMONIA; CYANOGEN; COMPOUNDS THEREOF
- C01C1/00—Ammonia; Compounds thereof
Similar Documents
Publication | Publication Date | Title |
---|---|---|
Schlesinger et al. | Hydrides of boron. VIII. The structure of the diammoniate of diborane and its relation to the structure of diborane | |
Schlesinger et al. | Sodium borohydride, its hydrolysis and its use as a reducing agent and in the generation of hydrogen1 | |
Schlesinger et al. | The preparation of other borohydrides by metathetical reactions utilizing the alkali metal borohydrides1 | |
Schlesinger et al. | Reactions of diborane with alkali metal hydrides and their addition compounds. New syntheses of borohydrides. Sodium and potassium borohydrides1 | |
Nystrom | Reduction of organic compounds by mixed hydrides. I. Nitriles | |
US6358488B1 (en) | Method for generation of hydrogen gas | |
Wartik et al. | Reactions of Lithium Aluminum Hydride with Representative Elements of the Main Groups of the Periodic System1 | |
Schlesinger et al. | Procedures for the Preparation of Methyl Borate1 | |
Mayer | Symmetrical cleavage of diborane by ammonia in solution | |
Parry et al. | Chemical Evidence for the Structure of the “Diammoniate of Diborane.” IV. The Reaction of Sodium with Lewis Acids in Liquid Ammonia | |
Wartik et al. | Reactions of carbon dioxide with sodium and lithium borohydrides | |
Schlesinger et al. | Reaction of the Boron Halides with the Alkali Metal Hydrides and with Their Addition Compounds; A New Synthesis of Diborane1 | |
US12129179B2 (en) | Method for catalytic synthesis of ammonia under normal pressures | |
Burg et al. | Hydrides of Boron. III. Dimethoxyborine | |
Auten et al. | Studies Relating to Boron. V. Chemistry of the Dibutylboron Group1 | |
Brown et al. | Dissociation of the addition compounds of trimethylboron with n-Butyl-and neopentyldimethylamines; interaction of trimethylboron and boron trifluoride with highly hindered Bases1, 2 | |
Shore et al. | Chemical evidence for the structure of the “diammoniate of diborane.” V. A tracer study of the reaction between sodium and the “diammoniate of diborane” | |
Whatley et al. | A Kinetic Study of the Diborane-Ethylene Reaction1 | |
Brown et al. | The exchange of hydrogen gas with lithium and sodium borohydrides | |
Teal et al. | Compounds of Germanium and Hydrogen. III. Monoalkylgermanes. IV. Potassium Germanyl. V. Electrolysis of Sodium Germanyl1 | |
CA1229218A (en) | Process for producing silane | |
Swindell et al. | Extensively rearranged derivatives of sulfur tetrafluoride, trifluoromethylsulfur trifluoride, and bis (trifluoromethyl) sulfur difluoride from hexafluoroisopropylideniminolithium reactions | |
Van Eck et al. | Preparation and analysis of crystalline alkalides | |
Durand et al. | Alkylammonium decomposition on montmorillonite surfaces in an inert atmosphere | |
US5693306A (en) | Production process for refined hydrogen iodide |