[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

Johnson et al., 2010 - Google Patents

Insights into the intramolecular acetate-mediated formation of ruthenium vinylidene complexes: a ligand-assisted proton shuttle (LAPS) mechanism

Johnson et al., 2010

Document ID
11916276918905934856
Author
Johnson D
Lynam J
Slattery J
Welby C
Publication year
Publication venue
Dalton Transactions

External Links

Snippet

The ruthenium bis-acetate complex Ru (κ2-OAc) 2 (PPh3) 2 reacts with HCCPh to afford the vinylidene-containing species Ru (κ1-OAc)(κ2-OAc)(CCHPh)(PPh3) 2. An experimental study has demonstrated that this reaction occurs under very mild conditions, with significant …
Continue reading at pubs.rsc.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F17/00—Metallocenes
    • C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/153—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used
    • C07C29/156—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof
    • C07C29/157—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases characterised by the catalyst used containing iron group metals, platinum group metals or compounds thereof containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/10—Preparation of carboxylic acids or their salts, halides or anhydrides by reaction with carbon monoxide

Similar Documents

Publication Publication Date Title
Johnson et al. Insights into the intramolecular acetate-mediated formation of ruthenium vinylidene complexes: a ligand-assisted proton shuttle (LAPS) mechanism
Burkhardt et al. Tungsten and molybdenum 2-oxaallyl [. eta. 1-(C)-enolate] complexes: functional group transformations, photochemical aldol reactions, and alkyne/carbon monoxide migratory insertion reactions
Li et al. Non-noble metal-catalysed carbonylative transformations
Hameury et al. Metal complexes with oxygen-functionalized NHC ligands: synthesis and applications
Jonasson et al. Synthesis and Characterization of a Family of POCOP Pincer Complexes with Nickel: Reactivity Towards CO2 and Phenylacetylene
Breit et al. Mechanistic insight into the ruthenium-catalysed anti-Markovnikov hydration of alkynes using a self-assembled complex: a crucial role for ligand-assisted proton shuttle processes
JP6071079B2 (en) Bimetallic catalyst for CO2 hydrogenation and H2 production from formic acid and / or its salts
Nair et al. Ruthenium (ii) complexes of hemilabile pincer ligands: Synthesis and catalysing the transfer hydrogenation of ketones
US9399613B2 (en) Direct carbon dioxide hydrogenation to formic acid in acidic media
Bange et al. Zirconium-catalyzed intermolecular hydrophosphination using a chiral, air-stable primary phosphine
Sutradhar et al. Application of molybdenum complexes for the oxidation of cyclohexane in acetonitrile, ionic liquid and supercritical CO2 media, a comparative study
Holmes et al. Chelating N-heterocyclic carbene–carboranes offer flexible ligand coordination to Ir III, Rh III and Ru II: effect of ligand cyclometallation in catalytic transfer hydrogenation
Hänninen et al. Elucidation of the resting state of a rhodium NNN-pincer hydrogenation catalyst that features a remarkably upfield hydride 1 H NMR chemical shift
Zhang et al. Efficient methanol carbonylation to methyl acetate catalyzed by a cyclic (alkyl)(amino) carbene iridium complex
Labinger Alkane Functionalization via Electrophilic Activation
Torres et al. Unusual reactivity of rhodium carbenes with allenes: an efficient asymmetric synthesis of methylenetetrahydropyran scaffolds
Hiett et al. Ruthenium carboxylate complexes as easily prepared and efficient catalysts for the synthesis of β-oxopropyl esters
Hao et al. Ruthenium carbonyl complexes with pyridine-alkoxide ligands: synthesis, characterization and catalytic application in dehydrogenative oxidation of alcohols
Leclerc et al. A closer look at the reactivity between N-heterocyclic carbenes and fluoroalkenes
Coles et al. Heterobimetallic complexes of 1, 1-diphosphineamide ligands
Saadeh et al. Syntheses, properties, and X-ray crystal structures of the molybdenum dimers [# Cp2Mo2Br2 (CO) 2] and [# Cp2Mo2Br4](# Cp=. eta. 5-1-(2, 5-dimethoxyphenyl)-2, 3, 4, 5-tetraphenylcyclopentadienyl)
Keitz Diastereocontrol in Olefin Metathesis: the Development of Z‐Selective Ruthenium Catalysts
Fuganti et al. Triphosphines-containing ruthenium-acetato complexes: Synthesis, characterization, DFT, mer/fac isomerization and formic acid dehydrogenation
Belli The role of the M− PR2 fragment in hydrophosphination: from mechanisms to catalysis
Scappaticci Synthesis and Characterization of Sterically Encumbered β-Diketonate Supported Iron Complexes for the Mechanistic Investigation of Iron-Catalyzed Kumada Cross-Coupling