Hashidzume et al., 1995 - Google Patents
Electrochemistry of Octamethyl [3] ruthenocenophane: Synthesis and Structure of the First Dicationic Derivative of Ruthenocene,[{. eta. 5:. eta. 5-C5Me4 (CH2) …Hashidzume et al., 1995
- Document ID
- 11694709796931300222
- Author
- Hashidzume K
- Tobita H
- Ogino H
- Publication year
- Publication venue
- Organometallics
External Links
Snippet
The redox behavior of group 8 metallocenes has been extensively studied since the discovery of ferrocene in 1951.1 Nevertheless, the redox chemistry of ruthenocene and osmocene has made only slow advances relative to that of ferrocene. Ruthenocene has …
- FZHCFNGSGGGXEH-UHFFFAOYSA-N Ruthenocene 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 [Ru+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 0 title abstract description 19
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F17/00—Metallocenes
- C07F17/02—Metallocenes of metals of Groups 8, 9 or 10 of the Periodic System
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- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0073—Rhodium compounds
- C07F15/008—Rhodium compounds without a metal-carbon linkage
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- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0033—Iridium compounds
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- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0086—Platinum compounds
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- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
- C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group
- C07F15/0013—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System compounds of the platinum group without a metal-carbon linkage
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- C07—ORGANIC CHEMISTRY
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- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
- C07F9/02—Phosphorus compounds
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- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic System
- C07F5/02—Boron compounds
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- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
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- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D213/00—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
- C07D213/02—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members
- C07D213/04—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
- C07D213/06—Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members having three double bonds between ring members or between ring members and non-ring members having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom containing only hydrogen and carbon atoms in addition to the ring nitrogen atom
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Chisholm et al. | Reactions of metal-metal multiple bonds. 14. Synthesis and characterization of triangulo-W3 and-Mo2W oxo-capped alkoxide clusters. Conproportionation of MM triple bonds and. sigma. 2. pi. 4 and d0 metal-oxo groups: M. tplbond. M+ M. tplbond. O. fwdarw. M3 (. mu. 3-O) | |
Hashidzume et al. | Electrochemistry of Octamethyl [3] ruthenocenophane: Synthesis and Structure of the First Dicationic Derivative of Ruthenocene,[{. eta. 5:. eta. 5-C5Me4 (CH2) 3C5Me4} Ru (NCMe)](PF6) 2 | |
Bhattacharya et al. | Charge distribution in bis (quinone) complexes of ruthenium and osmium. Structural, spectral, and electrochemical properties of the Os (bpy)(Cat) 2 (Cat= catecholate, 3, 5-di-tert-butylcatecholate, tetrachlorocatecholate) series | |
Cotton et al. | Formamidinate complexes of dirhenium, Re2n+, cores with n= 4, 5, and 6 | |
Carugo et al. | Using platinum (II) as a building block to two-electron redox systems. Crystal structure and redox behavior of cis-[PtII (3-ferrocenylpyridine) 2Cl2] | |
Detty et al. | Chemical and electrochemical oxidation of CpRe (PAr3) 2H2 complexes to give stable 17-electron radical cations. Disproportionation to diamagnetic species via electron-transfer catalysis | |
Dong et al. | Mixed-Valence Biferroceniums: Pronounced Effects of Cation-Anion Interactions on the Intramolecular Electron-Transfer Rate | |
Helberg et al. | Rhenium (I) Coordination Chemistry: Synthesis, Reactivity, and Electrochemistry of Terpyridyl Complexes | |
Bianchini et al. | Chemical and electrochemical oxidation of the phosphoniodichalcogenoformate complexes (triphos) RhCl (X2CPEt3)(triphos= MeC (CH2PPh2) 3; X= S, Se). Synthesis of metal dichalcogenocarbonates from oxygen and phosphonium-betaine-like complexes. X-ray structure of [(triphos) Rh (S2CH (PEt3))](BPh4) 2 | |
Ishii et al. | Preparation and properties of molybdenum and tungsten dinitrogen complexes. 47. Bimetallic arylation of molecular nitrogen | |
Herberich et al. | Borole derivatives. 20. Three-center Fe-HB bonding in (borole)(cyclopentadienyl) hydridoiron derivatives | |
Blackburn et al. | A New Approach to Bis (arene) titanium (0) and‐titanium (–I) Complexes; Structure of Bis (arene) titanates (1–) | |
Butler et al. | Ferrocenyl anthracenes: Synthesis and molecular structure | |
Saadeh et al. | Syntheses, properties, and X-ray crystal structures of the molybdenum dimers [# Cp2Mo2Br2 (CO) 2] and [# Cp2Mo2Br4](# Cp=. eta. 5-1-(2, 5-dimethoxyphenyl)-2, 3, 4, 5-tetraphenylcyclopentadienyl) |