[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

Nordlander et al., 1966 - Google Patents

Solvolysis of 1-Adamantylcarbinyl and 3-Homoadamantyl Derivatives. Mechanism of the Neopentyl Cation Rearrangement1

Nordlander et al., 1966

Document ID
11106751460980297576
Author
Nordlander J
Jindal S
von R. Schleyer P
Fort Jr R
Harper J
Nicholas R
Publication year
Publication venue
Journal of the American Chemical Society

External Links

Snippet

The solvolyses of 1-adamantylcarbinyl arenesulfonates in various solvents have been studied as a model for interpretation of the corresponding reactions of neopentyl derivatives. Whereas the later yield products derived entirely from the f-amyl cation, it has not been …
Continue reading at pubs.acs.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
    • C07C69/02—Esters of acyclic saturated monocarboxylic acids having the carboxyl group bound to an acyclic carbon atom or to hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/16—Preparation of halogenated hydrocarbons by replacement by halogens of hydroxyl groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C5/00—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
    • C07C5/22—Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms by isomerisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers

Similar Documents

Publication Publication Date Title
Nordlander et al. Solvolysis of 1-Adamantylcarbinyl and 3-Homoadamantyl Derivatives. Mechanism of the Neopentyl Cation Rearrangement1
Schlosser et al. 2-Alkenyl anions and their surprising endo preference. Facile and extreme stereocontrol over carbon-carbon linking reactions with organometallics of the allyl type
Roberts et al. Rearrangements in Carbonium Ion-Type Reactions of C14-Labeled Norbornyl Derivatives1, 2
Corey et al. A method for deoxygenation of allylic and benzylic alcohols
Baldwin et al. Stability and symmetry of the 8, 9-dihydro-2-adamantyl cation
Pritchard et al. The meso and racemic forms of 2, 4-pentanediol and certain of their derivatives
Marshall et al. Reasons for the nonequivalence of the exo-exo and endo-endo vicinal NMR coupling constants in norbornanes
Stille et al. The Addition of Hydrogen Chloride and Hydrobromic Acid to 2, 3-Dideuterionorbornene
Fahey et al. Polar Additions to Olefins and Actylenes. III. The Kinetics and Stereochemistry of Addition in the System 1-Phenylpropyne-Hydrogen Chloride-Acetic Acid1
Brown et al. Additions to bicyclic olefins. VII. Electrophilic additions of hydrogen chloride and deuterium chloride to norbornene, 2-methylenenorbornane, and related bicyclic olefins. Evidence for a carbonium ion process and the capture of unsymmetrical (classical) 2-norbornyl cations
Harvey et al. Metal-ammonia reduction. IV. Single-stage reduction of polycyclic aromatic hydrocarbons
Thompson Synthesis of triptindane
Bly et al. Unsaturated Neopentyl Compounds. The Acetolysis of 2, 2-Dimethyl-3-buten-1-yl and 2, 2, 4-Trimethyl-3-penten-1-yl p-Bromobenzenesulfonates. π-Electron Delocalization in the Absence of Steric Strain1
Schaefer et al. Bimolecular displacement reactions. I. Reaction of endo-Norbornanol and 7-Norbornanol with triphenylphosphine and bromine
Poulter et al. Stereospecific homoallylic ring expansions and contractions
Bly et al. π-Electron Participation in the Acetolysis of β-(syn-7-Norbornenyl) ethyl p-Bromobenzenesulfonate
Spurlock et al. Nature of the carbonium ion. X. 2-Protoadamantyl cation
Bordwell et al. Favorskii reactions. I. Nature of the rate-determining step
Lenoir et al. Chemistry of protoadamantane. VI. Bridged and classical polymethyl 2-adamantyl cations
Johnson et al. Olefinic Cyclizations. VII. Formolysis of cis-and trans-5, 9-Decadienyl p-Nitrobenzenesulfonate and of Some Isomeric Monocyclic Esters*, 1, 2
Karabatsos et al. Carbonium ion rearrangements. VI. Mechanism of the rearrangement of neopentyl compounds
Sauers et al. Synthesis and Chemistry of the Tricyclo [3.2. 1.03, 6] octane System
Meinwald et al. Highly Strained Bicyclic Systems. IX. The Acetolysis of 5, 5-Dimethylbicyclo [2.1. 1] hexyl 2β-p-Toluenesulfonate
Mueller et al. The stability of bridgehead and rigid tertiary carbenium ions in the gas phase and their rate of formation in solvolysis reactions
Mishra et al. Preparation, absolute configuration, and thermolysis of (3R: 5R)-(+)-trans-3, 5-dimethyl-1-pyrazoline