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Schulz et al., 2019 - Google Patents

Formyltetrahydrofolate decarbonylase synthesizes the active site CO ligand of O2-tolerant [NiFe] hydrogenase

Schulz et al., 2019

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Document ID
10332315074206643402
Author
Schulz A
Frielingsdorf S
Pommerening P
Lauterbach L
Bistoni G
Neese F
Oestreich M
Lenz O
Publication year
Publication venue
Journal of the American Chemical Society

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Snippet

[NiFe] hydrogenases catalyze the reversible oxidation of molecular hydrogen into two protons and two electrons. A key organometallic chemistry feature of the NiFe active site is that the iron atom is co-coordinated by two cyanides (CN–) and one carbon monoxide (CO) …
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