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Opris et al., 2004 - Google Patents

Syntheses and chemistry of hypervalent cyclo-R 4 Sb 4, cyclo-(RSbE) n [R= 2-(Me 2 NCH 2) C 6 H 4, E= O, S] and precursors

Opris et al., 2004

Document ID
8518507327494890293
Author
Opris L
Silvestru A
Silvestru C
Breunig H
Lork E
Publication year
Publication venue
Dalton Transactions

External Links

Snippet

The cyclostibane R4Sb4 (1)(R= 2-(Me2NCH2) C6H4) was synthesized by reduction of RSbCl2 with Mg in THF or with Na in liquid NH3. The reaction of 1 with [W (CO) 5 (THF)] gives the stibinidene complex RSb [W (CO) 5] 2 (2). RSbCl2 and (RSbCl) 2E [E= O (6), E= S …
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    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
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    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic System
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    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
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