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Ngo et al., 2002 - Google Patents

Preparation and Characterization of Half‐Sandwich (Pentamethylcyclopentadienyl)(triflato) titanium (IV) Complexes: Solid‐State Structural Motifs and Catalysis …

Ngo et al., 2002

Document ID
8242973575818100225
Author
Ngo S
Toscano P
Welch J
Publication year
Publication venue
Helvetica chimica acta

External Links

Snippet

Abstract Half‐sandwich (pentamethylcyclopentadienyl)(triflato) titanium (IV) complexes of the type [Ti (Cp*)(TfO) 2X](X= MeO (1), Me (2), 2, 4, 6‐Me3C6H2O (5)) or [Ti (Cp*)(o‐ OC6H4O)(TfO)](7) were readily synthesized via methathesis of the corresponding chloride …
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    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/64Titanium, zirconium, hafnium or compounds thereof
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    • C08F4/00Polymerisation catalysts
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    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
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    • C08F4/659Component covered by group C08F4/64 containing a transition metal-carbon bond
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    • C08F4/60Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
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