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Faizullina et al., 2020 - Google Patents

Michael adducts of levoglucosenone with α-ethoxycarbonyl-and α-nitrocyclododecanones: transformation into chiral macrolides

Faizullina et al., 2020

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Document ID
8148947301979192361
Author
Faizullina L
Galimova Y
Salikhov S
Valeev F
Publication year
Publication venue
Chemistry of Heterocyclic Compounds

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Levoglucosenone reacted with α-ethoxycarbonyl-and α-nitrocyclododecanones, leading to the formation of diastereomeric Michael adducts in high yields. Methods were developed for the denitration of the respective nitroadducts by treatment with Raney nickel and Bu3SnH …
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