O'Regan et al., 1990 - Google Patents
A study of high-oxidation-state complexes of the type [W (. eta. 5-C5Me5) Me2X] 2 (. mu.-N2), including x-ray structures of [W (. eta. 5-C5Me5) Me2 (OC6F5)] 2 (. mu …O'Regan et al., 1990
- Document ID
- 7559397498425077308
- Author
- O'Regan M
- Liu A
- Finch W
- Schrock R
- Davis W
- Publication year
- Publication venue
- Journal of the American Chemical Society
External Links
Snippet
A high yield route (80-90%) to the bridging dinitrogen complex [WCp* Me3] 2^-N2)(1) consists of the reduction of WCp* Me3 (OTf) by sodium amalgam in the presence of dinitrogen. 1 reacts with HÓTf (2 or excess (6) equiv) to give [WCp* Me2 (OTf)] 2 (M-N2) or …
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- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic System
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