[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

Kevill et al., 1984 - Google Patents

Perchlorate esters. Part 8. Kinetics and mechanism of the methanolysis of methyl perchlorate in benzene

Kevill et al., 1984

Document ID
7053097647708764424
Author
Kevill D
Posselt H
Publication year
Publication venue
Journal of the Chemical Society, Perkin Transactions 2

External Links

Snippet

Methyl perchlorate reacts with 0.07–0.4 M-methanol in benzene with a kinetic order of ca. 2.3 in methanol. The reaction is accelerated by addition of nitromethane but, in contrast to the corresponding methanolysis of triphenylmethyl chloride, decelerated by added phenol …
Continue reading at pubs.rsc.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P-C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/09—Esters of phosphoric acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/54—Quarternary phosphonium compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic System
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P-C bonds
    • C07F9/38—Phosphonic acids RP(=O)(OH)2; Thiophosphonic acids, i.e. RP(=X)(XH)2 (X = S, Se)
    • C07F9/44—Amides thereof
    • C07F9/4403—Amides thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4423—Amides of poly (thio)phosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F7/00—Compounds containing elements of Groups 4 or 14 of the Periodic System
    • C07F7/02—Silicon compounds
    • C07F7/08—Compounds having one or more C-Si linkages

Similar Documents

Publication Publication Date Title
Yang et al. Electron exchange between ferrocene and ferrocenium ion. Effects of solvent and of ring substitution on the rate
Swain Kinetic Evidence for a Termolecular Mechanism in Displacement Reactions of Triphenylmethyl Halides in Benzene Solution
Bunton et al. Reactions of the tri-p-anisylmethyl carbonium ion with nucleophiles
US4568700A (en) Process for the production of halomethylating agents which are of low volatility
Müller et al. SN2 Reactions with Carboxylic Esters. Selective cleavage of methyl esters
Blake et al. Stereochemical course of addition of hydrogen halides to iridium (I) complexes. The effect of solvents
Bellucci et al. Comparison of molecular bromine and tribromide ion as brominating reagents. 1. Kinetic evidence for different mechanisms of addition to cyclohexene
Garegg et al. A phosphorus nuclear magnetic resonance spectroscopic study of the conversion of hydroxy groups into iodo groups in carbohydrates using the iodine–triphenylphosphine–imidazole reagent
Evans et al. Reactions of cation radicals of EE [electron capture] systems. III. Chlorination of 9, 10-diphenylanthracene
IL99204A (en) Process for producing tetrabromobisphenol a of high quality
Kevill et al. Perchlorate esters. Part 8. Kinetics and mechanism of the methanolysis of methyl perchlorate in benzene
ES8504693A1 (en) Method for preparation of salts of N-phosphonomethylglycine.
Hasegawa et al. Preparation and structure of certain phosphorus-centred radical cations. An electron spin resonance study
de Namor et al. Calix [4] arene urea derivatives: The pathway from fundamental studies to the selective removal of fluorides and phosphates from water
JP2897372B2 (en) Production method of high quality tetrabromobisphenol A
Russell et al. Aliphatic semidiones. 33. Ion pair formation in alkali metal salts of 1, 2-semidiones
Pocker et al. Electrophilic Catalysis in Nucleophilic Substitution and Elimination. IV. Kinetics of Reaction of 2-Octyl Bromide with Tetraethylammonium and Silver Perchlorates and Nitrites in Acetonitrile1, 2
US4104309A (en) Phosphine oxides having polyfluorinated-chain and their preparation
Sutton Some studies in inorganic complexes. III. Antimony (III), Arsenic (III), and Phosphorus (III)
US4761493A (en) Preparation process of quaternary phosphonium hydroxide
Hirohara et al. Anionic polymerization of styrene in 2-methyltetrahydrofuran
Corriu et al. Analogies between silicon and phosphorus stereochemistry—II: Influence of the attacking anion upon the stereochemistry of nucleophilic displacement at tetrahedral phosphorus
Harger Acid-catalysed methanolysis of (N-aryl) methylphenylphosphinic amides: changes in the stereochemistry resulting from nucleophilic participation by chloride ion
Warshawsky et al. Thermoregulated ion complexation effects in polymeric crown ethers 2. Polymeric sulfonamidobenzo-18-crown-6
US4473710A (en) Process for the synthesis of tertiary phosphine oxides, and new tertiary phosphine oxides