[go: up one dir, main page]
More Web Proxy on the site http://driver.im/

Freeman et al., 1970 - Google Patents

Carbonium ion rearrangements in the deltacyclane ring system

Freeman et al., 1970

Document ID
6080095229934491937
Author
Freeman P
Balls D
Blazevich J
Publication year
Publication venue
Journal of the American Chemical Society

External Links

Snippet

The acetolyses of exo- and e «efo-8-deltacyclyl brosylate, a mixture of exo-and e «ifo-8- deltacyclyI chloride, as well as deamination of 8-deltacyclylamine in acetic acid, all leadto exo-8-deltacyclyl acetate (less than 0.4% endo epimer). Chlorodecarboxylation of …
Continue reading at pubs.acs.org (other versions)

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/385—Saturated compounds containing a keto group being part of a ring
    • C07C49/487—Saturated compounds containing a keto group being part of a ring containing hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/587—Unsaturated compounds containing a keto groups being part of a ring
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
    • C07C49/04—Saturated compounds containing keto groups bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/013—Preparation of halogenated hydrocarbons by addition of halogens
    • C07C17/02—Preparation of halogenated hydrocarbons by addition of halogens to unsaturated hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C43/00—Ethers; Compounds having groups, groups or groups
    • C07C43/02—Ethers
    • C07C43/03—Ethers having all ether-oxygen atoms bound to acyclic carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids

Similar Documents

Publication Publication Date Title
Baldwin et al. Stability and symmetry of the 8, 9-dihydro-2-adamantyl cation
Haywood-Farmer et al. Synthesis and solvolytic reactivity of 8-tricyclo [3.2. 1.0] octane derivatives
Grutzner et al. Bicycloaromaticity. Stability and rearrangements of the bicyclo [3.2. 2] nonatrienyl anion cation
Stille et al. The Addition of Hydrogen Chloride and Hydrobromic Acid to 2, 3-Dideuterionorbornene
Freeman et al. Carbonium ion rearrangements in the deltacyclane ring system
Buechi et al. Synthesis of (-)-aromadendrene and related sesquiterpenes
Schleyer et al. Stereochemistry of cyclopropylcarbinyl rearrangements. Synthesis and solvolysis of cyclopropylcarbinyl-1, 1', 1'-trans-2, 3, 3-d6 methanesulfonate
Gassman et al. Transition Metal Complex Promoted Rearrangements. Bicyclo [2.1. 0] pentane and 1-Carbomethoxybicyclo [2.1. 0] pentane
Poulter et al. Stereospecific homoallylic ring expansions and contractions
Spurlock et al. Nature of the carbonium ion. X. 2-Protoadamantyl cation
Peet et al. Synthesis and acid-catalyzed rearrangements of tricyclo [4.3. 2.0] undecanones
Stille et al. Additions of protonic acids to 2, 3-dideuterionorbornene. Evidence for the existence of a classical norbornyl cation
Baldwin et al. Thermal isomerization of 3, 6-dideuterio-and 1, 2, 7, 8, 9, 9-hexadeuterio-cis-bicyclo [6.1. 0] nona-2, 4, 5-triene
Sauers et al. Carbonium ion reactions of 3-nortricyclylcarbinyl systems
Zupan et al. Fluorination with xenon difluoride. Stereochemistry of fluorine addition to phenyl-substituted olefins
Hammons et al. Acid-catalyzed cleavage of 1-methylnortricyclene
Gajewski Alkyl shifts in thermolyses. II. Rearrangement of isopropenylspiropentane and its axially dissymmetric 4-methyl derivatives
Paquette et al. Chiral perturbation of olefins by deuterium substitution. The optical activity and circular dichroism behavior of (1S)-[2-2H] norbornene and deuterated apobornenes
Kondratenko et al. A Synthetic and X-Ray Crystallographic Study of Cobalt and Molybdenum Cluster Complexes of the 2-Fenchyl Cation: Metal-Mediated Wagner-Meerwein Rearrangements
Russell et al. Application of electron spin resonance spectroscopy to studies of valence isomerization. V. Aliphatic semidiones. XXVIII. Formation of bicyclo [3.2. 0] hept-2-ene-6, 7-semidiones from bicyclo [3.2. 0] and-[2.2. 1] precursors
Freeman et al. Reactions of exo-and endo-8-carbenatricyclo [3.2. 1.02, 4] octane
Cope et al. Molecular asymmetry. VIII. trans-Bicyclo [8.2. 2]-tetradeca-5, 10, 12, 13-tetraene
Bertelli et al. Synthesis and study of pseudo-aromatic compounds. VI. Synthesis of 6, 7-dihydrocyclohepta [de] naphthalene and a conformational analysis of 1, 2-benzoheptafulvene
Nordlander et al. Acetolysis of 4-homoadamantyl tosylate. Multiple degenerate rearrangements and mechanism
Hine et al. Chemistry of cycloheptadienones. VI. Structure and thermal isomerization reactions of protonated cyclohepta-3, 5-dienones in superacids. Convenient preparation of cyclohepta-2, 4-dienone