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Crandall et al., 1978 - Google Patents

Peracid oxidation of methylenecyclopropanes

Crandall et al., 1978

Document ID
5715841953835285732
Author
Crandall J
Conover W
Publication year
Publication venue
The Journal of Organic Chemistry

External Links

Snippet

Subsequent to our initial disclosure of the synthesis of an oxaspiropentane derivative, 2 several laboratories have described the generation of this highly strained heterocyclic system, eitherby the epoxidation of methylenecyclopropanes3 or by the condensation of …
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    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
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    • C07C45/673—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by change of size of the carbon skeleton
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    • C07C2101/16—The ring being unsaturated
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