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Gassman et al., 1971 - Google Patents

Reactions of trans-fused cyclopropanes. Synthesis and solvolysis of 4-hydroxy-trans-bicyclo [5.1. 0] octane p-bromobenzenesulfonate

Gassman et al., 1971

Document ID
5654133696118567069
Author
Gassman P
Seter J
Williams F
Publication year
Publication venue
Journal of the American Chemical Society

External Links

Snippet

4-Hydroxy-íranj-bicyclo [5.1. 0] octane p-bromobenzenesulfonate (1) has been prepared via a 13-step synthesis startingwith commercially available materials. The solvolysis of 1 was found to be pseudo first order in buffered acetic acid. Although the cyclopropyl moiety of 1 …
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    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
    • C07C45/72—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms by reaction of compounds containing >C = O groups with the same or other compounds containing >C = O groups
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    • C07C2101/00—Systems containing only non-condensed rings
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    • C07C2101/16—The ring being unsaturated
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