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Vlcek et al., 1967 - Google Patents

Redox reactions of cobalt-cyanide complexes. II. Reaction of pentacyanocobaltate (II) with p-benzoquinone. Properties of decacyano [. mu.-hydroquinnonato (2-)] …

Vlcek et al., 1967

Document ID
5218199440014031786
Author
Vlcek A
Hanzlik J
Publication year
Publication venue
Inorganic Chemistry

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Pentacyanocobaltate (II) ion reacts very rapidly with/>-benzoquinone to form the bridge species [(CN) sCoOCeH4OCo (CN) s] 6~(I). The organic ligand in I is isoelectronic with the dianion of hydroquinone, but owing to the influence of Co atoms, it shows a higher degree …
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