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Agosta et al., 1969 - Google Patents

Convenient synthesis of 2, 2-dimethylcyclobutanone

Agosta et al., 1969

Document ID
4776218510347098241
Author
Agosta W
Herron D
Publication year
Publication venue
The Journal of Organic Chemistry

External Links

Snippet

We now describe two side products encountered in the methyl ester series. The first arose in variable yield (up to 18%) in the bromine oxidation of 2a and appeared to be favored at the expense of 3a if the reaction mixture, which became heterogeneous as oily 3a separated …
Continue reading at pubs.acs.org (other versions)

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    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/61—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups
    • C07C45/67—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton
    • C07C45/68—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reactions not involving the formation of >C = O groups by isomerisation; by change of size of the carbon skeleton by increase in the number of carbon atoms
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    • C07D307/93—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom ortho- or peri-condensed with carbocyclic rings or ring systems condensed with a ring other than six-membered
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