[go: up one dir, main page]
More Web Proxy on the site http://driver.im/ Skip to main content
Log in

Microstructural effect and wear performance of high chromium white cast iron alloyed with V, W, and different Cr contents

  • Original Paper
  • Published:
MRS Advances Aims and scope Submit manuscript

Abstract

The present work analyzes the effect of V, W, and different Cr contents on the microstructure and wear behavior of a high chromium white cast iron. The alloys were characterized by scanning electron microscopy and X-ray diffraction. Results show that the simultaneous addition of V and W promoted the formation of the W6C and VC carbides. This modification allowed obtaining a predominantly martensitic matrix in the as-cast alloyed irons. Wear test showed a decrease in the volume losses for the V and W alloyed irons in the as-cast condition attributed to VC and W6C carbides in the microstructure and the transformation to martensite, increasing the hardness. After destabilization, carbide precipitation and matrix transformation produced a secondary hardening in 11wt%Cr alloys. However, after destabilization, V and W alloyed irons with 17wt%Cr showed a decrease in hardness due to excessive C reduction in the austenitic matrix transformed to low-carbon martensite.

Graphical abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Subscribe and save

Springer+ Basic
£29.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (United Kingdom)

Instant access to the full article PDF.

Fig. 1
Fig. 2

Similar content being viewed by others

Data availability

The data that support the findings of this study are available from the corresponding author upon request. In addition, some data are provided as supplementary material.

References

  1. E. Cortés-Carrillo, A. Bedolla-Jacuinde, I. Mejía, C.M. Zepeda, J. Zuno-Silva, F.V. Guerra-Lopez, Effects of tungsten on the microstructure and on the abrasive wear behavior of a high-chromium white iron. Wear 376–377, 77–85 (2017)

    Article  Google Scholar 

  2. A. Sánchez-Cruz, A. Bedolla-Jacuinde, F.V. Guerra, I. Mejía, Microstructural modification of a static and dynamically solidified high chromium white cast iron alloyed with vanadium. Results Mater. 7, 100114 (2020)

    Article  Google Scholar 

  3. V.G. Efremenko, K. Shimizu, A.P. Cheiliakh, T.V. Kozarevskaya, K. Kusumoto, K. Yamamoto, Effect of vanadium and chromium on the microstructural features of V-Cr-Mn-Ni spheroidal carbide cast irons. Int. J. Miner. Metall. Mater. 21(11), 1096–1108 (2014). https://doi.org/10.1007/s12613-014-1014-6

    Article  CAS  Google Scholar 

  4. K. Ibrahim, Effect of titanium addition on structure and properties of the as-cast high Cr-Mo white iron. J. Mater. Res. 103, 362–370 (2012)

    Article  CAS  Google Scholar 

  5. S. Reyna, A. Bedolla-Jacuinde, F.V. Guerra, I. Mejía, M. García, Effect of amount and distribution of primary TiC on the wear behavior of a 12%Cr–3%C white iron under dry sliding conditions. Wear 476, 203718 (2021)

    Article  CAS  Google Scholar 

  6. C. Kim, X-ray method of measuring retained austenite in heat treated white cast irons. J. Heat. Treat. 1(2), 43–51 (1979). https://doi.org/10.1007/BF02833237

    Article  CAS  Google Scholar 

  7. J.-P. Lai, Q.-L. Pan, Y.-W. Sun, C.-A. Xiao, Effect of Si content on the microstructure and wear resistance of high chromium cast iron. ISIJ Int. 58(8), 1532–1537 (2018)

    Article  CAS  Google Scholar 

  8. A. Bedolla Jacuinde, W.M. Rainforth, The wear behaviour of high-chromium white cast irons as a function of silicon and Mischmetal content. Wear 250(1), 449–461 (2001)

    Article  Google Scholar 

  9. Z. Liu, X. Chen, Y. Li, Hu. Kaihua, Effect of chromium on microstructure and properties of high boron white cast iron. Metall. and Mater. Trans. A. 39(3), 636–641 (2008). https://doi.org/10.1007/s11661-007-9385-1

    Article  CAS  Google Scholar 

  10. M. Ali, T. Nyo, A. Kaijalainen, J. Hannula, D. Porter, J. Kömi, Influence of chromium content on the microstructure and mechanical properties of thermomechanically hot-rolled low-carbon bainitic steels containing niobium. Appl. Sci. 10(1), 344 (2020)

    Article  CAS  Google Scholar 

  11. A. Bedolla-Jacuinde, L. Arias, B. Hernández, Kinetics of secondary carbides precipitation in a high-chromium white iron. J. Mater. Eng. Perform. 12(4), 371–382 (2003). https://doi.org/10.1361/105994903770342881

    Article  CAS  Google Scholar 

  12. C.K. Kim, S. Lee, J.-Y. Jung, Effects of heat treatment on wear resistance and fracture toughness of duo-cast materials composed of high-chromium white cast iron and low-chromium steel. Metall. Mater. Trans. A 37(3), 633–643 (2006). https://doi.org/10.1007/s11661-006-0035-9

    Article  Google Scholar 

  13. V. Efremenko, Y. Chabak, M. Brykov, Kinetic parameters of secondary carbide precipitation in high-Cr white iron alloyed by Mn-Ni-Mo-V complex. J. Mater. Eng. Perform. 22, 1378–1385 (2012)

    Article  Google Scholar 

Download references

Acknowledgments

The authors are very grateful to the Universidad Michoacana de San Nicolás de Hidalgo for supporting this research. One of the authors, Adán Zárate, also acknowledges CONACyT for the scholarship during his master's degree studies.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to F. V. Guerra.

Ethics declarations

Conflict of interest

On behalf of all authors, the corresponding author states that there is no conflict of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary Information

Below is the link to the electronic supplementary material.

Supplementary file1 (PDF 466 kb)

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Guerra, F.V., Zárate-Rangel, A., Bedolla-Jacuinde, A. et al. Microstructural effect and wear performance of high chromium white cast iron alloyed with V, W, and different Cr contents. MRS Advances 7, 1017–1021 (2022). https://doi.org/10.1557/s43580-022-00367-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1557/s43580-022-00367-3