Abstract
Effect of Si on the microstructures and mechanical properties of high-chromium cast iron was investigated. The eutectic carbides are refined greatly and a transformation of matrix from austenitic matrix to pearlite is observed with increase in Si content from 0.5 to 1.5 wt.%. The refinement of eutectic microstructure is attributed to the decrease in the eutectic temperature, while the transformation from austenite matrix to pearlite is associated with the increase in solubility of carbon in the matrix. In the pearlite matrix, two types of pearlite are observed: one with lamellar pearlite, distributing at the periphery, and the second one with granular pearlite at the center. The density of secondary carbides precipitated from the matrix increases greatly with addition of Si from 0.5 to 1.5 wt.%, which is associated with more carbon and chromium elements confined in the matrix in the alloy containing 1.5 wt.%. More rod-like particles are observed in the alloy containing 0.5 wt.% Si, while the morphology of secondary carbides of alloy containing 1.5 wt.% is granular. The mechanical properties are improved with a 7% increase in tensile strength from 586 to 626 MPa and impact toughness from 5.8 to 7.3 J cm−2.
Similar content being viewed by others
References
X.J. Wu, J.D. Xing, H.G. Fu, and X.H. Zhi, Effect of Titanium on the Morphology of Primary M7C3 Carbides in Hypereutectic High Chromium White Cast Iron, Mater. Sci. Eng., A, 2007, 457, p 180–185
C.P. Tabrett and I.R. Sare, Fracture Toughness of High-Chromium White Irons: Influence of Cast Structure, J. Mater. Sci., 2000, 35, p 2069–2077
S.D. Carpenter and D. Carpenter, X-ray Diffraction Study of M7C3 Carbide within a High Chromium White Cast Iron, Mater. Lett., 2003, 57, p 4456–4459
X.H. Zhi, J.D. Xing, H.G. Fu, and Y.M. Gao, Effect of Titanium on the as-Cast Microstructure of Hypereutectic High Chromium Cast Iron, Mater. Charact., 2008, 59, p 1221–1226
A. Bedolla-Jacuinde, R. Correa, J.G. Quezada, and C. Maldonado, Effect of Titanium on the as-Cast Microstructure of a 16% Chromium White Iron, Mater. Sci. Eng., A, 2005, 398, p 297–308
X.H. Zhi, J.D. Xing, H.G. Fu, and Y.M. Gao, Effect of Titanium on the as-Cast Microstructure of Hypereutectic High Chromium Cast Iron, Mater. Charact., 2008, 59, p 1221–1226
X.H. Zhi, J.D. Xing, H.G. Fu, and B. Xiao, Effect of Niobium on the as-Cast Microstructure of Hypereutectic High Chromium Cast Iron, Mater. Lett., 2008, 62, p 857–860
M. Filipovic, Z. Kamberovic, M. Korac, and M. Gavrilovski, Microstructure and Mechanical Properties of Fe–Cr–C–Nb White Cast Irons, Mater. Des., 2013, 47, p 41–48
V. Efremenko, K. Shimizu, and Y. Chabak, Effect of destabilizing heat treatment on solid-state phase transformation in high-chromium cast irons, Metall. Mater. Trans. A, 2013, 44A, p 5434–5446
A.B. Jacuinde and W.M. Rainforth, The Wear Behavior of High-Chromium White Cast Irons as a Function of Silicon and Mischmetal Content, Wear, 2001, 250, p 449–461
G.L.F. Powell and G. Laird, Structure, Nucleation, Growth and Morphology of Secondary Carbides in High Chromium and Cr–Ni White Cast Irons, J. Mater. Sci., 1992, 27, p 29–35
A. Wiengmoon, J.T. Pearce, and T. Chairuangsri, Relationship Between Microstructure, Hardness and Corrosion Resistance in 20 wt.% Cr, 27 wt.% Cr and 36 wt.% Cr High Chromium Cast Irons, Mater. Chem. Phys., 2011, 125, p 739–748
A. Bedolla-Jacuinde, L. Arias, and B. Hernandez, Kinetics of Secondary Carbides Precipitation in a High-Chromium White Iron, J. Mater. Eng. Perform., 2003, 12, p 371–382
Acknowledgments
The authors would like to thank the Chang Gao Advanced Materials Co., Ltd. for their financial support.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Lai, J.P., Pan, Q.L., Peng, H.J. et al. Effects of Si on the Microstructures and Mechanical Properties of High-Chromium Cast Iron. J. of Materi Eng and Perform 25, 4617–4623 (2016). https://doi.org/10.1007/s11665-016-2331-x
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11665-016-2331-x