Brucite is the mineral form of magnesium hydroxide, with the chemical formula Mg(OH)2. It is a common alteration product of periclase in marble; a low-temperature hydrothermal vein mineral in metamorphosed limestones and chlorite schists; and formed during serpentinization of dunites. Brucite is often found in association with serpentine, calcite, aragonite, dolomite, magnesite, hydromagnesite, artinite, talc and chrysotile.
| Brucite | |
|---|---|
 | |
| General | |
| Category | Oxide mineral |
| Formula (repeating unit) | Mg(OH)2 |
| IMA symbol | Brc[1] |
| Strunz classification | 4.FE.05 |
| Crystal system | Trigonal |
| Crystal class | Hexagonal crystal family (3m) H-M symbol: (3 2/m) |
| Space group | P3m1 |
| Unit cell | a = 3.142(1) Å, c = 4.766(2) Å; Z = 1 |
| Identification | |
| Color | White, pale green, blue, gray; honey-yellow to brownish red |
| Crystal habit | Tabular crystals; platy or foliated masses and rosettes – fibrous to massive |
| Cleavage | Perfect on {0001} |
| Fracture | Irregular |
| Tenacity | Sectile |
| Mohs scale hardness | 2.5 to 3 |
| Luster | Vitreous to pearly |
| Streak | White |
| Diaphaneity | Transparent |
| Specific gravity | 2.39 to 2.40 |
| Optical properties | Uniaxial (+) |
| Refractive index | nω = 1.56–1.59 nε = 1.58–1.60 |
| Birefringence | 0.02 |
| Other characteristics | Pyroelectric |
| References | [2][3][4] |
It adopts a layered CdI2-like structure with hydrogen-bonds between the layers.[5]
Discovery
editBrucite was first described in 1824 by François Sulpice Beudant[6] and named for the discoverer, American mineralogist, Archibald Bruce (1777–1818). A fibrous variety of brucite is called nemalite. It occurs in fibers or laths, usually elongated along [1010], but sometimes [1120] crystalline directions.
Occurrence
editA notable location in the US is Wood's Chrome Mine, Cedar Hill Quarry, Lancaster County, Pennsylvania. Yellow, white and blue brucite with a botryoidal habit was discovered in Qila Saifullah District of Province Baluchistan, Pakistan. In a later discovery, brucite also occurred in the Bela Ophiolite of Wadh, Khuzdar District, Province Baluchistan, Pakistan. Brucite has also occurred from South Africa, Italy, Russia, Canada, and other localities as well, but the most notable discoveries are the US, Russian and Pakistani examples.[citation needed]
Industrial applications
editSynthetic brucite is mainly consumed as a precursor to magnesia (MgO), a useful refractory and thermal insulator. It finds some use as a flame retardant because it thermally decomposes to release water in a similar way to aluminium hydroxide (Al(OH)3) and mixtures of huntite (Mg3Ca(CO3)4) and hydromagnesite (Mg5(CO3)4(OH)2·4H2O).[7][8] It also constitutes a significant source of magnesium for industry. Although generally deemed safe, brucite can be contaminated with naturally occurring asbestos fibers.[9]
Magnesium attack of cement and concrete
editWhen cement or concrete are exposed to Mg2+, the neoformation of brucite, an expansive material, may induce mechanical stress in the hardened cement paste or may clog the porous network creating a buffering effect[clarification needed] and delaying the alteration/transformation of the C-S-H phase (the "glue" phase in the hardened cement paste) into M-S-H phase (a non-cohesive mineral phase). The exact magnitude of impact that brucite has on cement paste is still debatable. Prolonged contact between sea water or brines and concrete may induce durability issues for regularly immersed concrete components or structures.
The use of dolomite as aggregate in concrete can also cause magnesium attack and should be avoided.[10]
Gallery
edit-
Yellow brucite from Balochistan, Pakistan
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Nemalite
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Brucite crystals from the Sverdlovsk Region, Urals, Russia (size: 10.5 x 7.8 x 7.4 cm)
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Structure of Mg(OH)2
See also
edit- List of minerals
- List of minerals named after people
- Portlandite, Ca(OH)2
- Cookeite, LiAl4(Si3Al)O10(OH)8
References
edit- ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
- ^ Brucite on Mindat.org
- ^ Handbook of Mineralogy
- ^ Brucite on Webmineral
- ^ Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN 978-0-08-037941-8.
- ^ "Blog | GeoRarities". 2021-01-13. Retrieved 2021-06-02.
- ^ Hollingbery, LA; Hull TR (2010). "The Thermal Decomposition of Huntite and Hydromagnesite - A Review". Thermochimica Acta. 509 (1–2): 1–11. doi:10.1016/j.tca.2010.06.012.
- ^ Hollingbery, LA; Hull TR (2010). "The Fire Retardant Behaviour of Huntite and Hydromagnesite - A Review". Polymer Degradation and Stability. 95 (12): 2213–2225. doi:10.1016/j.polymdegradstab.2010.08.019.
- ^ Malferrari, Daniele; Di Guisseppe, Dario; Scognamiglio, Valentina; Gualtieri, Alessandro F. (2021). "Commercial brucite, a worldwide used raw material deemed safe, can be contaminated by asbestos". Periodico di Mineralogia. 90 (3): 317–324. doi:10.13133/2239-1002/17384.
- ^ Lee, Hyomin; Cody, Robert D.; Cody, Anita M.; Spry, Paul G. (1 May 2002). "Observations on brucite formation and the role of brucite in Iowa highway concrete deterioration". Environmental and Engineering Geoscience. 8 (2): 137–145. Bibcode:2002EEGeo...8..137L. doi:10.2113/gseegeosci.8.2.137. ISSN 1078-7275.
Further reading
edit- Lee, Hyomin; Robert D. Cody; Anita M. Cody; Paul G. Spry (2000). "Effects of various deicing chemicals on pavement concrete deterioration" (PDF). Mid-Continent Transportation Symposium 2000 Proceedings. Archived from the original (PDF) on March 20, 2009. Retrieved 2009-09-10.
- Lee, Hyomin; Robert D. Cody; Anita M. Cody; Paul G. Spry (2002). "Observations on brucite formation and the role of brucite in Iowa highway concrete deterioration". Environmental and Engineering Geoscience. 8 (2): 137–145. Bibcode:2002EEGeo...8..137L. doi:10.2113/gseegeosci.8.2.137. Retrieved 2009-09-10.
- Wies aw, W; Kurdowski (September 2004). "The protective layer and decalcification of C-S-H in the mechanism of chloride corrosion of cement paste". Cement and Concrete Research. 34 (9): 1555–1559. doi:10.1016/j.cemconres.2004.03.023.
- Biricik, Hasan; Fevziye Aköz; Fikret Türker; Ilhan Berktay (2000). "Resistance to magnesium sulfate and sodium sulfate attack of mortars containing wheat straw ash". Cement and Concrete Research. 30 (8): 1189–1197. doi:10.1016/S0008-8846(00)00314-8.