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Oxalate sulfate

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From Wikipedia, the free encyclopedia

Oxalate sulfates are mixed anion compounds containing oxalate and sulfate. They are mostly transparent, and any colour comes from the cations.

Related compounds include the sulfite oxalates[1] and oxalate selenates.[2]

Production

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Oxalate sulfates may be deposited from a solution in water of the metal anions and sulfate with oxalic acid when evaporated. Crystals formed this way may be hydrates.[3]

Properties

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Many crystal forms are non-centrosymmetric and have non-linear optical properties.[3]

When heated, oxalate sulfates will first dehydrate, and then give off carbon dioxide.[3]

List

[edit]
name formula system space group unit cell Å volume density comment ref
lithium sulfate monohydrate oxalate ? triclinic P1 a = 3.4014 b = 5.0397 c = 6.120 α = 78.62° β= 84.95°

γ = 81.14°

101.45 band gap 4.57 eV

dielectric constant 29.7 stable below 83°C piezoelectric coefficient 6pC/N

[3]
homopiperazinium dimagnesium dioxalate sulfate dihydrate C5H14N2•Mg2•[C2O4]2•SO4•2H2O monoclinic Ia a=11.5673 b=27.3352 c=16.6097 β=95.255° Z=12 5229.8 1.749 colourless [4]
piperazinium magnesium oxalate sulfate hydrate C4H12N2•Mg•[C2O4]•SO4•H2O monoclinic P21/c a=12.7330 b=8.9240 c=11.8172 β=115.502° Z=4 1211.95 1.724 colourless [4]
potassium sulphato oxalate ? triclinic a = 6.37 b = 7.03 c = 10.61 α = 93.96 ̊ β = 101.37 ̊ γ = 100.1 ̊ colourless > 300nm; SHG 1.6×KDP [5]
bapp = 1,4-bis(3-aminopropyl)piperazine (H4bapp)0.5·VO(SO4)(C2O4) triclinic P1 a=6.2031 b=8.6599 c=12.1853 α=77.130° β=76.207° γ=82.987° [6]
bipy=4,4′-bipyridine; (μ2-Oxalato-O,O',O'',O''')-tetrakis(2,2'-bipyridine)-di-chromium(iii) disulfate 2,2'-bipyridine solvate monohydrate [Cr2(bipy)4(C2O4)](SO4)·(bipy)0.5·H2O triclinic P1 a=11.610 b=12.668 c=17.155 α=77.297° β=83.957° γ=85.458° [7]
depa = 3-(diethylamino)propylamine H2depa⋅Mn2(SO4)(C2O4)2(H2O)⋅H2O orthorhombic Pbca a=14.6293 b=15.6671 c=17.3579 [6]
hpip = homopiperazine H2hpip·Mn2(SO4)(C2O4)2(H2O) orthorhombic P212121 a=9.9066 b=12.4496 c=13.6640 [8]
pip = piperazine; piperazinediium (μ-oxalato)-bis(μ-sulfato)-diaqua-di-manganese(ii) dihydrate H2pip·Mn2(SO4)2(C2O4)(H2O)4 triclinic P1 a 6.6501(4)Å b 7.7034(4)Å c 9.6810(5)Å, α 69.850(4)° β 70.553(5)° γ 83.921(4)° [9]
ipa = 3,3′-iminobis(N,N-dimethylpropylamine) bis(3-dimethylammoniopropyl)ammonium pentakis(μ-oxalato)-bis(μ-sulfato)-tetra-manganese(ii) dihydrate H3ipa⋅Mn2(SO4)(C2O4)2.5·H2O triclinic P1 a 9.9379(6)Å b 11.2423(6)Å c 11.6390(7)Å, α 86.793(5)° β 81.644(5)° γ 74.481(5)° [9]
dpta = dipropylenetriamine; bis(3-ammoniopropyl)ammonium tris(μ-oxalato)-bis(μ-sulfato)-bis(sulfato)-hexa-aqua-tetra-manganese(ii) H3dpta⋅Mn2(SO4)2(C2O4)1.5(H2O)3 triclinic P1 a 8.6819(3)Å b 10.1689(3)Å c 13.7456(5)Å, α 70.197(3)° β 73.406(3)° γ 87.636(3)° [9]
dmen = N,N-dimethylethylenediamine H2dmen·Mn(SO4)(C2O4) monoclinic P21/n a=9.8603 b=12.6525 c=10.0837 β=113.002° [10]
bis(N,N-dimethylpropane-1,3-diaminium) bis(μ-oxalato)-bis(μ-sulfato)-di-manganese triclinic P1 a=8.5307 b=9.0432 c=9.6913 α=69.632° β=64.639° γ=88.148° [11]
butane-1,4-diaminium bis(μ-oxalato)-(μ-sulfato)-aqua-di-manganese triclinic P1 a=8.5468 b=10.0050 c=10.6532 α=75.445° β=79.787° γ=71.848° [11]
Na2Fe(C2O4)SO4⋅H2O orange; most air sensitive [12]
(μ-oxalato)-(μ-sulfato)-iron-di-potassium K2[Fe(C2O4)(SO4)] monoclinic P21/c a=5.8735 b=10.2169 c=13.1491 β=91.226° [13]
tris(μ-oxalato)-bis(μ-sulfato)-tri-iron-tetra-potassium K4[Fe3(C2O4)3(SO4)2] monoclinic P21/c a 13.739 b 5.496 c 12.774 β 97.677° [13]
acid oxalo-bisulfate of roseocobalt ?? Co2(HN3)10(C2O4)(SO4)2 ·H2O·H2C2O4 speculative [14]
[Co(NH3)4(C2O4)]2SO4·2H2O [15]
[Co(NH3)4(C2O4)]2S2O6 [15]
tris(μ-aqua)-tris(μ-oxalato)-tris(μ-sulfato)-tri-cobalt-hexa-sodium Na2[Co(C2O4)(SO4)]·H2O hexagonal P62m a=10.2322 c=6.4774 [13]
tris(μ-oxalato)-bis(μ-sulfato)-bis(2-((2-aminoethyl)amino)ethanaminium)-tetraaqua-tetra-cobalt triclinic P1 a=8.6065 b=9.5595 c=9.5987 α=77.884° β=82.744° γ=87.356° [16]
bis(μ-oxalato)-bis(μ-sulfato)-bis(4-(2-aminoethyl)piperazin-1-ium)-tri-cobalt triclinic P1 a=8.4331 b=9.4691 c=9.5144 α=71.522° β=64.356° γ=89.622° [16]
1,4-dimethylpiperazinedi-ium bis(μ-oxalato)-hepta-aqua-tri-cobalt bis(sulfate) (H2dmp)(SO4)3Co3(C2O4)2(H2O)7 orthorhombic Pnma a=11.1050 b=16.4221 c=13.9815 violet [17]
Bis[tris(oxamide dioxime-2N,N')cobalt(III)] oxalate bis(sulfate) dodecahydrate [Co(C2H6N4O2)3]2(C2O4)(SO4)212H2O triclinic P1 a = 9.430 b = 11.782 c = 12.812 α = 65.494° β = 83.088° γ = 86.735° Z=1 1285.7 1.698 at 193K; red [18]
homopiperazinium dizinc dioxalate sulfate hydrate C5H14N2•Zn2•[C2O4]2•SO4•H2O monoclinic P21 a=15.8356 b=13.5022 c=15.9578 β=109.075° Z=8 3224.7 2.154 colourless [4]
homopiperazinium dizinc dioxalate sulfate dihydrate C5H14N2•Zn2•[C2O4]2•SO4•2H2O monoclinic Ia a=11.5681 b=27.1755 c=16.5979 β=94.946° Z=12 5198.4 2.074 colourless [4]
bis(4-(2-aminoethyl)piperazin-1-ium)-bis(μ-oxalato)-bis(μ-sulfato)-tri-zinc triclinic P1 a=8.407 b=9.523 c=9.543 α=108.39° β=115.52° γ=90.17° [11]
1,4-dimethylpiperazinedi-ium bis(sulfate) bis(μ-oxalato)-hepta-aqua-tri-zinc (H2dmp)(SO4)3Zn3(C2O4)2(H2O)7 orthorhombic Pnma a 11.1058 b 16.3449 c 14.0064 colourless [17]
(Hgly)2·Zn(SO4)(C2O4) monoclinic C2 a 19.1509 b 5.4000 c 12.8206 β 102.878° [19]
RbFe(SO4)(C2O4)0.5·H2O monoclinic P21/c a = 7.9193, b = 9.4907, c = 8.8090, β = 95.180°, Z = 4 [20]
bis(μ3-sulfato)-bis(μ2-oxalato)-diaqua-di-yttrium diammonium [NH4][Y(H2O)(SO4)(C2O4)] monoclinic P21/n a=6.534 b=8.527 c=13.745 β=92.87° [21]
bis(μ3-Sulfato-O,O,O',O'',O''')-(μ2-oxalato-O,O',O'',O''')-(μ2-piperazine-diium-1,4-diacetato-O,O')-diaqua-di-yttrium(iii) Y2(H2pda)(C2O4)(SO4)2(H2O)2] monoclinic C2/c a 19.392 b 6.2757 c 16.999 β 108.279° [22]
levinsonite-(Y) (Y,Nd,Ce)Al(SO4)2(C2O4) · 12H2O monoclinic P2/n a = 10.289 Å, b = 9.234, c = 11.015

β = 108.50°

992.4 2.181 Biaxial (+) Refractive index:

nα = 1.480 nβ = 1.490 nγ = 1.550

[23][24]
thfa = tetrahydrofurfurylamine; bis(tetrahydrofurfurylammonium) tris(μ-oxalato)-(μ-sulfato)-di-indium(iii) dihydrate (Hthfa)2·In2(SO4)(C2O4)3·2H2O monoclinic P21/c a=10.7581 b=12.9985 c=19.9093 β=92.876° [8]
bapp = N,N′-bis(3-aminopropyl)piperazine H4bapp·[In2(SO4)3(C2O4)2(H2O)2]·H2O monoclinic I2/a a=13.8931 b=14.6792 c=15.2418 β=111.153° [10]
bis(1-ethylpiperazinedi-ium) tris(μ-oxalato)-bis(sulfato)-di-indium H2epip·[In2(SO4)2(C2O4)3] tetragonal I41/a a=26.0767 c=8.9467 colourless [17]
Piperazinediium bis(μ2-oxalato-O,O',O'',O''')-bis(μ2-sulfato-O,O')-diaqua-di-indium dihydrate [C4N2H12]0.5InSO4C2O4·2H2O monoclinic P21/c a=6.478 b=11.067 c=14.317 β=100.302° [25]
Hgly·In(SO4)(C2O4)(gly) monoclinic P21 a 6.5179(2)Å b 10.9928(3)Å c 18.0301(6)Å, α 90° β 93.9700(10)° [19]
CsMn(SO4)(C2O4)0.5·H2O monoclinic P21/c a = 8.065, b = 9.610, c = 9.219, β = 94.564°, Z = 4 [20]
CsFe(SO4)(C2O4)0.5·H2O monoclinic P21/c a = 7.9377, b = 9.5757, c = 9.1474, β = 96.104°, Z = 4 [20]
La2(C2O4)(SO4)2(H2O)3 monoclinic P21/n a=9.838 b=9.817 c=13.111 β=104.258° [26]
bis(μ3-sulfato)-bis(μ2-oxalato)-diaqua-di-lanthanum diammonium [NH4][La(H2O)(SO4)(C2O4)] monoclinic P21/n a=6.629 b=8.673 c=13.867 β=93.35° [21]
(μ4-Piperazine-diium-1,4-diacetato-O,O',O'',O''')-bis(μ3-sulfato-O,O',O'')-(μ2-oxalato-O,O',O'',O''')-diaqua-di-cerium(iii) dihydrate Ce2(H2pda)(C2O4)(SO4)2(H2O)2 · 2H2O monoclinic C2/c a 19.353 b 6.836 c 16.400 β 94.312° [22]
coskrenite-(Ce) (Ce,Nd,La)2(C2O4)(SO4)2 · 12H2O triclinic a = 6.007(1) Å, b = 8.368(2) Å, c = 9.189(2) Å

α = 99.90(2)°, β = 105.55(2)°, γ = 107.71(2)°

2.881 Biaxial (-) refractive indices: nα = 1.544 nβ = 1.578 nγ = 1.602; Birefringence: δ = 0.058 [27][28]
zugshunstite-(Ce) (Ce,Nd,La)Al(SO4)2(C2O4) · 12H2O Monoclinic C2/c a = 8.718 b = 18.313 c = 13.128

β = 93.90°

2091 2.121 Large REE; pink in incandescent light; blue in fluorescent light; Biaxial (+) refractive index: nα = 1.455 nβ = 1.485 nγ = 1.528; [29][24]
(μ4-Piperazine-diium-1,4-diacetato-O,O',O'',O''')-bis(μ3-sulfato-O,O',O'')-(μ2-oxalato-O,O',O'',O''')-diaqua-di-praseodymium(iii) dihydrate Pr2(H2pda)(C2O4)(SO4)2(H2O)2 · 2H2O monoclinic C2/c a 19.295 b 6.8100 c 16.377 β 94.369° [22]
heptakis(μ-oxalato)-bis(μ-sulfato)-tetradecaaqua-hexa-neodymium dihydrate Nd6(SO4)2(C2O4)7(H2O)14·H2O triclinic P1 a=6.0817 b=11.8807 c=16.0749 α=73.230° β=80.873° γ=88.976° [30]
N,N'-dimethylethane-1,2-diaminium tetrakis(μ-sulfato)-tris(μ-oxalato)-octaaqua-tetra-neodymium [C4H14N2]·Nd4(SO4)4(C2O4)3(H2O)8 triclinic P1 a=7.0649 b=11.2771 c=11.8318 α=67.370° β=80.035° γ=82.821° [30]
bis(μ3-Sulfato-O,O,O',O'',O''')-(μ2-oxalato-O,O',O'',O''')-(μ2-piperazine-diium-1,4-diacetato-O,O')-diaqua-di-neodymium(iii) Nd2(H2pda)(C2O4)(SO4)2(H2O)2] monoclinic C2/c a=19.702 b=6.348 c=17.352 β=109.973° [22]
bis(1,4-Diazoniabicyclo[2.2.2]octane) tetrakis(μ2-oxalato-O,O',O'',O''')-tetrakis(μ2-sulfato-O,O',O'')-octa-aqua-tetra-neodymium(iii) dihydrate [C6N2H14][Nd2(C2O4)2(SO4)2(H2O)4]·H2O monoclinic P21/c a=8.523 b=28.628 c=9.306 β=96.497° [31]
(μ4-Piperazine-diium-1,4-diacetato-O,O',O'',O''')-bis(μ3-sulfato-O,O',O'')-(μ2-oxalato-O,O',O'',O''')-diaqua-di-europium(iii) dihydrate Eu2(H2pda)(C2O4)(SO4)2(H2O)2 · 2H2O monoclinic C2/c a=19.143 b=6.722 c=16.323 β=94.58° [22]
(μ5-Oxalato)-(μ3-sulfato)-(μ2-aqua)-aqua-europium-silver AgEu(μ5-C2O4)(SO4)(H2O)2 monoclinic P21/c a=6.627 b=13.848 c=8.983 β=96.985° [32]
tetrakis(μ2-oxalato)-bis(μ2-sulfato)-dodeca-aqua-tetra-erbium monohydrate Er4(SO4)2(C2O4)4(H2O)12·H2O monoclinic P21/c a=10.5598 b=12.8404 c=12.0835 β=93.327° [30]
bis(μ3-sulfato)-bis(μ2-oxalato)-diaqua-di-samarium diammonium [NH4][Sm(H2O)(SO4)(C2O4)] monoclinic P21/n a=6.619 b=8.660 c=13.853 β=93.30° [21]
(μ5-Oxalato)-(μ3-sulfato)-(μ2-aqua)-aqua-samarium-silver AgSm(μ5-C2O4)(SO4)(H2O)2 monoclinic P21/c a=6.630 b=13.829 c=9.001 β=97.128° [32]
(NH4)[Gd(C2O4)(SO4)(H2O)] large magnetocaloric effect [33]
K[Gd(C2O4)(SO4)(H2O)] monoclinic P21/c a = 6.5849 b = 8.5660 c = 14.7660(2) Å, β = 112.470° Z=4 769.66 3.439 colourless [34]
potassium aquaterbium(III) oxalate sulfate KTb(C2O4)(SO4)(H2O) monoclinic a = 6.527 b = 8.507 c = 14.591 β = 112.65° Z=4 747.7 at 113K; colourless [35]
(μ6-Oxalato)-(μ4-oxalato)-bis(μ3-sulfato)-diaqua-di-silver-di-terbium AgTb(μ4-C2O4)0.5(μ6-C2O4)0.5(SO4)(H2O) monoclinic C2/m a=13.693 b=6.889 c=9.0885 β=116.73° [32]
(μ6-Oxalato)-(μ4-oxalato)-bis(μ3-sulfato)-diaqua-di-dysprosium-di-silver AgDy(μ4-C2O4)0.5(μ6-C2O4)0.5(SO4)(H2O) monoclinic C2/m a=13.683 b=6.881 c=9.080 β=116.731° [32]
bis(1-ethyl-3-methyl-1H-imidazol-3-ium) (μ-oxalato)-bis(μ-sulfato)-tetraoxo-di-uranium monohydrate monoclinic P21/c a=11.579 b=17.312 c=13.694 β=108.178° yellow [36]
(NH4)4[(UO2)2(C2O4)(SO4)2(NCS)2]⋅6H2O orthorhombic Pbam a = 12.0177 b = 18.6182 c = 6.757 Z=2 [37]
Tetrapotassium bis(μ2-oxalato)-tetraoxo-bis(sulfato)-di-uranium(vi) hexahydrate K2[UO2(C2O4)SO4] · 3H2O triclinic P1 a=5.743 b=9.544 c=11.845 α=89.49° β=84.95° γ=83.01° [38]
K4[(UO2)2C2O4(SO4)2(NCS)2] orthorhombic Pbam a = 11.5548 b = 7.0847 c = 13.5172 β = 93.130° Z=2 1104.90 [39]
Di-rubidium dioxo-(oxalato-O,O')-(μ3-sulfato)-uranium monohydrate Rb2[UO2SO4(C2O4)] · H2O orthorhombic Pna21 a=9.720 b=17.037 c=6.852 [38][40]
Rb4[(UO2)2C2O4(SO4)2(NCS)2] orthorhombic Pbam a = 11.5854 b = 7.3841 c = 13.9072 β = 95.754 V = Z=2 1183.7 [39]
Cs4[(UO2)2(C2O4)(SO4)2(NCS)2] · 4H2O orthorhombic Pbam a = 11.6539 b = 18.379 c = 6.7216 Z=2 [37]
Tetracesium dioxo-bis(oxalato-O,O')-(sulfato-O)-uranium(vi) hydrate Cs4[UO2(C2O4)2SO4] · 2.7H2O orthorhombic Pbca a=9.546 b=21.119 c=21.499 [38]

References

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