Journal of the Serbian Chemical Society 2023 Volume 88, Issue 12, Pages: 1237-1252
https://doi.org/10.2298/JSC230702062B
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Spectroscopic and structural characterization of hexaamminecobalt(III) dibromide permanganate
Barta Holló Berta 
(Department of Chemistry, Biochemistry and Environmental Protection, Faculty of Sciences, University of Novi Sad, Novi Sad, Serbia)
Bayat Niloofar (Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Budapest, Hungary + Department of Inorganic and Analytical Chemistry, Budapest University of Technology and Economics, Budapest, Hungary)
Bereczki Laura (Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Budapest, Hungary + Centre for Structural Science, Research Centre for Natural Sciences, Budapest, Hungary)
Petruševski Vladimir M. (Faculty of Natural Sciences and Mathematics, Ss. Cyril and Methodius University, Skopje, North Macedonia)
Béres Kende Attila (Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Budapest, Hungary + György Hevesy PhD School of Chemistry, Institute of Chemistry, ELTE Eötvös Loránd University, Budapest, Hungary)
Farkas Attila (Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary)
Szilágyi Imre Miklós (Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Budapest, Hungary)
Kótai László (Institute of Materials and Environmental Chemistry, Research Centre for Natural Sciences, Budapest, Hungary + Deuton-X Ltd., Érd, Hungary), kotai.laszlo@ttk.hu
Structural and spectroscopic characterization (SXRD, IR, liq. N2 temperature Raman, UV) of hexaamminecobalt(III) dibromide permanganate, [Co(NH3)6]Br2(MnO4) (compound 1), are described. There is a 3D hydrogen bond network including N–H···O–Mn and N–H···Br interactions, which could serve as potential reaction centres for solid-phase redox reactions between the ammonia ligands and/or bromide ions as reductants and permanganate ions as oxidant agents. The effect of the nature of halogen ions on the structural and spectroscopic properties of [Co(NH3)6]Br2(MnO4) and the analogous chloride compound, [Co(NH3)6]Cl2(MnO4) (compound 2), are discussed in detail.
Keywords: permanganate, ammine, cobalt(III), IR and Raman spectroscopy, solid-phase quasi-intramolecular redox reaction.
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