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Coordination compounds of nickel with trithiocyanuric acid. Part IV. Structure of [Ni(pmdien)(ttcH)] (pmdien = N,N,N′,N′,N′′-pentamethyldiethylenetriamine, ttcH3 = trithiocyanuric acid)

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Abstract

NiII mixed-ligand complexes of compositions [Ni(pmdien)(ttcH)] (1), [Ni(baphen)2(ttcH)] · 4H2O (2), [Ni-(dpa)(ttcH)(H2O)] (3), [Ni(cyclam)(ttcH)] · 2H2O (4), [Ni(hexaa)](ttcH) (5) and [Ni(hexab)(ttcH)] · 2H2O (6), (baphen = 4,7-diphenyl-1,10-phenanthroline, dpa = 2,2′-dipyridylamine, cyclam = 1,4,8,11-tetraazacyclotetradecane, hexaa = 1,3,6,9,11,14-hexaazatricyclo[12.2.1.16,9]-octadecane, hexab = 1,8-dimethyl-1,3,6,8,10,13-hexaazacyclotetradecane) have been prepared and characterized by means of i.r., u.v.–vis. spectroscopies and magnetochemical measurements. The redox properties of the complexes were studied by cyclic voltammetry. The crystal and molecular structure of [Ni(pmdien)(ttcH)] was determined. The nickel atom is penta-coordinated by three N atoms of pmdien, and by S and N atoms of trithiocyanurate(2−) anion.

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Authors and Affiliations

  1. Department of Inorganic and Physical Chemistry, Palacký University, Křížkovského 10, 771 47, Olomouc, Czech Republic

    Pavel Kopel, Zdeněk Trávníček, Libor Kvítek, Martin Biler, Marek Pavlíček & Zdeněk Šindelář

  2. X-Ray Laboratory of Department of Inorganic Chemistry & Laboratory of Biomolecular Structure and Dynamics, Masaryk University, Kotlářská 2, 611 37, Brno, Czech Republic

    Jaromír Marek

Authors
  1. Pavel Kopel
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  2. Zdeněk Trávníček
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  3. Libor Kvítek
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  4. Martin Biler
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  5. Marek Pavlíček
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  6. Zdeněk Šindelář
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  7. Jaromír Marek
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Kopel, P., Trávníček, Z., Kvítek, L. et al. Coordination compounds of nickel with trithiocyanuric acid. Part IV. Structure of [Ni(pmdien)(ttcH)] (pmdien = N,N,N′,N′,N′′-pentamethyldiethylenetriamine, ttcH3 = trithiocyanuric acid). Transition Metal Chemistry 26, 282–286 (2001). https://doi.org/10.1023/A:1007129711379

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