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On the way to high-conductivity single lithium-ion conductors

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Abstract

Solid electrolytes can potentially address three key limitations of the organic electrolytes used in today’s lithium-ion batteries, namely, their flammability, limited electrochemical stability and low cationic transference number. The pioneering works of Wright and Armand, suggesting the use of solid poly(ethylene oxide)-based polymer electrolytes (PE) for lithium batteries, paved the way to the development of solid-state batteries based on PEs. Yet, low cationic mobility–low Li+ transference number in polymer materials coupled with sufficiently high room-temperature conductivity remains inaccessible. The current strategies employed for the production of single-ion polymer conductors include designing new lithium salts, bonding of anions with the main polyether chain or incorporating them into the side chains of comb-branched polymers, plasticizing, adding inorganic fillers and anion receptors. Glass and crystalline superionic solids are classical single-ion-conducting electrolytes. However, because of grain boundaries and poor electrode/electrolyte interfacial contacts, achieving electrochemical performance in solid-state batteries comprising polycrystalline inorganic electrolytes, comparable to the existing batteries with liquid electrolytes, is particularly challenging. Quasi-elastic polymer-in-ceramic electrolytes provide good alternatives to the traditional lithium-ion-battery electrolytes and are believed to be the subject of extensive current research. This review provides an account of the advances over the past decade in the development of single-ion-conducting electrolytes and offers some directions and references that may be useful for further investigations.

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  1. Ministry of Science and Technology, Jerusalem, Israel

    E. Strauss

  2. School of Chemistry, Tel Aviv University, Tel Aviv, 69978, Israel

    S. Menkin & D. Golodnitsky

  3. Applied Materials Research Center, Tel Aviv University, Tel Aviv, 69978, Israel

    D. Golodnitsky

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Strauss, E., Menkin, S. & Golodnitsky, D. On the way to high-conductivity single lithium-ion conductors. J Solid State Electrochem 21, 1879–1905 (2017). https://doi.org/10.1007/s10008-017-3638-8

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