[go: up one dir, main page]
More Web Proxy on the site http://driver.im/ Skip to main content
Springer Nature Link
Log in

The role of crosslinking on the physical properties of gelatin based films

  • Original Contribution
  • Published:
Colloid and Polymer Science Aims and scope Submit manuscript

Abstract

The crosslinking of gelatin using crosslinking agents based on condensation of the aldehyde groups and ε-amine groups present in lysine and hydroxylysine rests is a very attractive method reported recently. The present work deals with different films prepared from commercial gelatin of type B and animal origin, aiming at an improvement of physical properties. These films were modified by two plasticizing agents (glycerol, GLY, and poly (vinyl alcohol), PVA) and/or crosslinked by glutaraldehyde (GTA). The number of ε-amino groups present in the gelatin chains, before and after modification, was determined by the method of protein dosage using 2,4,6-trinitro benzene sulfonic acid (TNBS). The addition of the plasticizing and/or crosslinking agents induced a decrease in the number of ε-amino-groups due to the fact that these groups are involved in the physical and/or chemical crosslinking reactions occurring among the different components. The variation of the crosslinking ratio was studied as a function of formulation type, crosslinking nature and GTA concentration. The use of microhardness (H) in this study emphasizes the effect of the crosslinking on the improvement of the micromechanical properties. The study of differential scanning calorimetry reveals that crosslinking induces a drastic decrease of crystallinity in the samples.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
£29.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price includes VAT (United Kingdom)

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1:
Fig. 2:
Fig. 3:
Fig. 4:
Fig. 5:
Fig. 6:
Fig. 7.

Similar content being viewed by others

Explore related subjects

Discover the latest articles, news and stories from top researchers in related subjects.

References

  1. Chiellini E, Cinelli P, Grillo Fernandes E, Kenawy ES, Lazzeri A (2001) Biomacromolecules 2:806

    Article  CAS  Google Scholar 

  2. Ulubayram K, Cakar AN, Korkusuz P, Ertan C, Hasirci N (2001) Biomaterials 22:1345

    Article  CAS  Google Scholar 

  3. Prasad MP, Kalyanasundaram M (1993) J Appl Polym Sci 49:2075

    Article  CAS  Google Scholar 

  4. Tan H, Marra KG (2010) Materials 3:1746

    Article  CAS  Google Scholar 

  5. Xiao W, He J, Nichol JW, Wang L, Hutson CB, Wang B, Du Y, Fan H, Khademhosseini A (2011) Acta Biomater 7:2384

    Article  CAS  Google Scholar 

  6. Benbettaieb N, Kurek M, Bornaz S, Debeaufort F (2014) J Sci Food Agric 94:2409

    Article  CAS  Google Scholar 

  7. Andreuccetti C, Carvalho RA, Galicia-García T, Martínez-Bustos F, Grosso CRF (2011) J Food Eng 103:129

    Article  CAS  Google Scholar 

  8. Schacht E, Bogdanov B, Van Den Bulcke A, De Rooze N (1997) React Funct Polym 33:109

    Article  CAS  Google Scholar 

  9. Migneault I, Dartiguenave C, Bertrand MJ, Waldron KC (2004) Biotechniques 37:790

    CAS  Google Scholar 

  10. Kim, J-Y.; Yoon, J. H; Kim, D-H.; Kim, S. B. Korean J Chem Eng 2012, 29, 503.

    Article  CAS  Google Scholar 

  11. Bigi A, Cojazzi G, Panzavolta S, Rubini K, Roveri N (2001) Biomaterials 22:763

    Article  CAS  Google Scholar 

  12. Biscarat J, Charmette C, Sánchez J, Pochat-Bohatier C (2015) Can J Chem Eng 93:176

    Article  CAS  Google Scholar 

  13. Cui, L.; Wang, Q.; Wang, P.; Huan, Q.; Fan, X. J Appl Polym Sci, 2009, 113, 2598.

    Article  CAS  Google Scholar 

  14. Zhu DY, Jin LQ, Wang L, Ren HX (2013) Ad Mater Res 335–336, 1391.

  15. Zaman HU, Khan MA, Khan RA (2013) J Thermoplast Compos Mater 26:795

    Article  CAS  Google Scholar 

  16. Said M, Arab H (2013) J Nucl Sci Appl 46:70

    Google Scholar 

  17. Baltá Calleja FJ, Fakirov S (2000) Microhardness of polymers. (Solid State Science Series). Cambridge University Press, Cambridge, p. 11

    Book  Google Scholar 

  18. Michler GH, Baltá Calleja FJ (2012) Nano- and micromechanics of polymers: structure modification and improvement of properties. Carl Hanser Verlag, München, pp. 1–563

    Book  Google Scholar 

  19. Flores A, Ania F, Baltá Calleja FJ (2009) Polymer 50:729–746

    Article  CAS  Google Scholar 

  20. Fakirov S, Cagiao ME, Baltá Calleja FJ, Sapundjieva D, Vassileva E (1999) Int J Polym Mater 43:195–206

    Article  CAS  Google Scholar 

  21. Vassileva E, Baltá Calleja FJ, Cagiao ME, Fakirov S (1998) Macromol Rapid Commun 19:451–454

    Article  CAS  Google Scholar 

  22. Fakirov S, Baltá Calleja FJ, Krumova MA (1999) Journal of Polym Sci Part B: Polymer Physics 37:1413–1419

    Article  CAS  Google Scholar 

  23. Fakirov S, Sarac Z, Anbar T, Boz B, Bahar B, Evstatiev M, Apostolov AA, Mark JE, Kloczkowski A (1996) Colloid Polym Sci 274:334–341

    Article  CAS  Google Scholar 

  24. Fakirov S, Sarac Z, Anbar T, Boz B, Bahar B, Evstatiev M, Apostolov AA, Mark JE, Kloczkowski A (1997) Colloid Polym Sci 275:307–314

    Article  CAS  Google Scholar 

  25. Chaibi S (2003) Préparation et Caractérisation de films à Base de Gélatine réticulée par du Glutaraldehyde et/ou modifiée par du Glycérol/Polyvinylalcool. Université Ferhat-Abbas, Sétif, Algeria, Magister Thesis

    Google Scholar 

  26. Maria TMC, De Carvalho RA, Sobral PJA, Habitante AMBQ, Solorza-Feria J (2008) J Food Eng 87:191

    Article  CAS  Google Scholar 

  27. Mendieta-Taboada O, Sobral PJA, De Carvalho RA, Habitante AMBQ (2008) Food Hydrocoll 22:1485

    Article  CAS  Google Scholar 

  28. Bubnis WA, Ofner III CM (1992) Anal Biochem 207:129

    Article  CAS  Google Scholar 

  29. Choi YS, Hong SR, Lee YM, Song KW, Park MH, Nam YS (1999) Biomaterials 20:409

    Article  CAS  Google Scholar 

  30. Borchard W, Bremer W, Keese A (1980) Colloid Polym Sci 258:516–526

    Article  CAS  Google Scholar 

  31. Wu J, Chiu SC, Pearce EM, Kwei TK (2001) J Polym Sci: Part A: Polymer Chemistry 39:224

    Article  CAS  Google Scholar 

  32. Bajpai AK, Saini R (2005) Polym Int 54:1233

    Article  CAS  Google Scholar 

  33. Christova D, Ivanova S, Trzebicka B, Walach W, Velichkova R, Dworak A (2003) E-Polymers 3(1):565

    Article  Google Scholar 

  34. Ikada,Y.; Shalaby, W. S.; Langer, R.; Williams, J.; (1994) Polymers of biological and biomedical significance. Symposium by the Division of Polymer Chemistry of American Chemical Society Inc., Washington, D.C., pp 24–28.

  35. Bellamy LJ (1984) The infrared spectra of complex molecules. John Wiley and Sons, New York

    Google Scholar 

Download references

Acknowledgments

FJBC gratefully acknowledges the MINECO, Spain (grant MAT 2013–47898-C2-1-R) for the generous support of this work.

Author information

Authors and Affiliations

  1. Laboratoire des Matériaux Polymères Multiphasiques (LMPMP), Faculté de Technologie, Université Ferhat ABBAS Sétif, 19000, Sétif, Algeria

    Samira Chaibi, Djafer Benachour & Meriem Merbah

  2. Department of Macromolecular Physics, Instituto de Estructura de la Materia, CSIC, 28006, Madrid, Spain

    M. Esperanza Cagiao & Francisco J. Baltá Calleja

Authors
  1. Samira Chaibi
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Djafer Benachour
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Meriem Merbah
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. M. Esperanza Cagiao
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Francisco J. Baltá Calleja
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Djafer Benachour.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chaibi, S., Benachour, D., Merbah, M. et al. The role of crosslinking on the physical properties of gelatin based films. Colloid Polym Sci 293, 2741–2752 (2015). https://doi.org/10.1007/s00396-015-3660-2

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s00396-015-3660-2

Keywords

Search

Navigation