Advanced Processes in Metallurgical Technologies

Cored wire is a widespread technology used for performing additions into liquid metal baths as an alternative to bulk-additions. A laboratory-scale study was performed in which the kinetics of assimilation of cored wire in liquid steel baths were studied. An original dataset of positions of the wire/melt interface of cored wire as a function of the time and steel bath temperature was produced. The dataset was compared against results of simulations made with a transient 1D (radial) thermal model of the assimilation of cored wire, and demonstrated reasonable agreement. Hence, this paper provides a dataset that can be used as a resource for the validation of future developments in the field of modeling cored wire injection into liquid metal baths. Full article

Porous tungsten gradient materials with ordered gradient variations in pore size have significant application value in the field of vacuum electronic devices. This work combines tape casting and dealloying methods to achieve the integrated preparation of porous tungsten gradient materials with a wide range of controllable porosity. The study focused on the phase composition and microstructure evolution during the preparation of porous tungsten gradient materials. The results show that the tape casting process allows for the precise and controllable thickness of each layer of the porous tungsten materials and uniform composition structure, while the stepwise dealloying of Fe and Ti enables a wide range of controllable porosity for the porous tungsten gradient materials. PVB, after thermal decomposition, provides a carbon source for the in situ reaction to form W-Fe-C compounds, and the surface diffusion behavior of W-Fe-C compounds at high temperatures improves the stratification of the porous tungsten gradient materials. This work provides a design concept for the integrated preparation of porous metal gradient materials. Full article

The welding process itself is a non-linear, multivariable, coupled physical metallurgical process that is easily perturbed. Improper welding parameter selection and welding process conditions will interfere with the welding process and affect the final welding quality. This study aims to identify and locate two types of welding interference, insufficient shielding gas and unremoved oxidation film on the base metal surface, during the Pulse Multi-Control Gas Metal Arc Welding (PMC GMAW) process of aluminum alloy. The Characteristic Intrinsic Mode Function (IMF), which is closely related to the short circuit transition process, was obtained by applying the Complementary Ensemble Empirical Mode Decomposition (CEEMD) method to the welding current signal measured during the welding process. Time and frequency domain analysis of the acquired characteristic IMF was then performed. The experimental results demonstrated that for a stable welding process, the frequency of the characteristic IMF is concentrated within a narrow range. The frequency spectrum of the characteristic IMF exhibits distinct variations under different types of welding interference. Based on this, the chronological arrangement of characteristic IMF components’ frequency spectrum allows for locating welding interferences by analyzing their abnormal signals within the reconstructed signal sequence. Full article

High-pressure die casting (HPDC) has been extensively used to manufacture aluminum alloy heat dissipation components in the fields of vehicles, electronics, and communication. With the increasing demand for HPDC heat dissipation components, the thermal conductivity of die-cast aluminum alloys is paid more attention. In this paper, a comprehensive review of the research progress on the thermal conductivity of HPDC aluminum alloys is provided. First of all, we introduce the general heat transport mechanism in aluminum alloys, including electrical transport and phonon transport. Secondly, we summarize several common die-cast aluminum alloy systems utilized for heat dissipation components, such as an Al–Si alloy system and silicon-free aluminum alloy systems, along with the corresponding composition optimizations for these alloy systems. Thirdly, the effect of processing parameters, which are significant for the HPDC process, on the thermal conductivity of HPDC aluminum alloys is discussed. Moreover, some heat treatment strategies for enhancing the thermal conductivity of die-cast aluminum alloys are briefly discussed. Apart from experimental findings, a range of theoretical models used to calculate the thermal conductivity of die-cast aluminum alloys are also summarized. This review aims to guide the development of new high-thermal-conductivity die-cast aluminum alloys. Full article

Tungsten is a high-value resource with a wide range of applications. The tungsten metal is produced via ammonium paratungstate, which is a multi-stage process including leaching, conversion, precipitation, calcination, and reduction. A short process to produce tungsten metal from the electrolysis of molten sodium tungstate has been demonstrated. However, sodium tungstate cannot be directly produced from wolframite in the conventional hydrometallurgical process. There was no information reported in the literature on producing sodium tungstate directly from tungsten concentrates. The present study proposed a simple and low-cost process to produce sodium tungstate by high-temperature processing of wolframite. The mixtures of wolframite, sodium carbonate, and silica were melted in air between 1100 and 1300 °C. High-density sodium tungstate was easily separated from the immiscible slag, which contained all impurities from wolframite, flux, excess sodium oxide, and dissolved tungsten oxide. The slag was further water leached to recover sodium tungstate in the solution. Effects of Na₂CO₃/Ore and SiO₂/Ore ratios, temperature, and reaction time on the recovery of tungstate and the purity of sodium tungstate were systematically studied. Sodium tungstate containing over 78% WO₃ was produced in the smelting process, which is suitable for the electrolysis process. The experimental results will provide a theoretical basis for the direct production of sodium tungstate from wolframite. The compositions of the WO₃-containing slags and sodium tungstate reported in the present study fill the knowledge gap of the tungsten-containing thermodynamic database. Further studies to use complex and low-grade tungsten concentrates to produce sodium tungstate are underway. Full article

Hot stamping (or press hardening) is a new technology that is widely used in the production of advanced high-strength steel parts for automotive applications. Electrochemical measurements, including potentiodynamic polarization and electrochemical impedance spectroscopy (EIS), and accelerated corrosion tests (the neutral salt spray test and periodic immersion test) were conducted on press-hardened samples produced from uncoated (cold-rolled and cold strip production (CSP) hot-rolled) and Al–Si-coated press-hardened steels to elucidate their distinct anti-corrosion mechanisms. The cross-sectional micromorphology and element distribution of three types of press-hardened steels after a neutral salt spray test were observed using scanning electron microscopy (SEM) and energy-dispersive X-ray analysis (EDAX). The corrosion resistance of Al–Si-coated press-hardened steel was found to be significantly diminished following the hot stamping process due to the presence of microcracks and elevated iron content in the coating subsequent to austenitizing heat treatment. On the other hand, the corrosion resistance of uncoated press-hardened sheets produced from cold-rolled and CSP hot-rolled press-hardened steel was found to be proximal due to their nearly identical composition and microstructure (fully martensite) after the hot stamping process. Considering the high efficiency and energy-saving properties of hot-rolled press-hardened steel, it holds the potential to replace cold-rolled and even aluminum–silicon-coated press-hardened steel in automobile manufacturing. Full article

In this work, the microstructure and texture of Mg-1.0Al-xZn-0.2Mn-0.5Ca (wt.%, x = 0, 1) alloys, which were produced via conventional casting or twin roll casting (TRC), were investigated, and their relation to the mechanical properties of the sheets at the final gage was analyzed. In the Zn-containing AZMX1100 alloy sheets, the amount and size of the secondary phases were significantly reduced, in comparison to the Zn-free AMX100 alloy sheet. The TRC sheet shows a smaller grain structure and fine secondary phases in comparison to the sheets produced via the conventional casting process. The texture of the AMX100 sheet is characterized by the basal poles tilted in the sheet rolling direction (RD). In the AZMX1100 sheets, the texture with the tilted basal poles towards the RD and transverse direction (TD) was developed after recrystallization annealing, while the tilting angle of the basal pole in the TD is larger than in the RD. There is no significant difference in the texture between the sheets produced by the casting and TRC process. The highest yield strength was obtained in the AZMX1100 sheet produced by the TRC process, and all examined sheets showed the mechanical anisotropy in accordance with their textures. Full article

This work investigates the dissolution of CaO into three different compositions of SiO₂-CaO-Al₂O₃ slag similar to those found in industrial Si furnaces. It was found that CaO dissolution into the slag is fast. During the dissolution process, a layer containing 35–42% CaO was formed between the CaO particle and the slag, which corresponded to the phases CaO·Al₂O₃·2SiO₂ or 2CaO·Al₂O₃·SiO₂ in this study. Two models were investigated to determine the dissolution rate of the three slags. In the first model, the CaO particle is assumed to be a smooth shrinking sphere, and the rate controlled by the chemical reaction rate. The second model assumes that the rate is controlled by mass transport and depends on the diffusion rate of CaO through a boundary layer on the surface of the CaO. Both models gave similar accuracy to the experimental values, and a proportional relationship between the rate constants and the viscosities was obtained. At 1500 °C, the diffusion coefficients were found to be in the order of 10⁻⁶ cm²/s. Full article

Experiments were conducted to pilot the initial reduction in chromium raw materials using the innovative Hoganas technology in a tunnel furnace. To simulate the process, a gas-fired bogie hearth furnace was employed. Technological containers made of silicon carbide crucibles were utilized. Sixteen different combinations of ore and coal mixtures were employed for the initial reduction process. Their total mass was more than 20 tons. Their heat treatment was performed at different temperatures and durations. During the pilot tests, the possibility of achieving chromium metallization was confirmed. Thus, it explains the application of a pre-reduction instead of the sintering or charge heating before the ferrochromium melting, i.e., the power consumption is minimized during the final remelting of the product in DC furnaces. The pilot melting of three batches of the pre-reduced chromium raw materials with various chromium metallization degrees has been tested in the ore-smelting furnace at Zh. Abishev Chemical–Metallurgical Institute (Karaganda). The capacity was 0.2 MVA. To evaluate the technical and economic efficiency of remelting pre-reduced chromium raw materials in commercial DC furnaces, a specific batch of primary ingredients for producing high-carbon ferrochromium, including chromite ore, coke, and quartz flux, was successfully melted in a segregated phase. As a result of the study, it was found that the specific energy consumption for melting high-carbon ferrochromium in the pilot furnace depends on the chromium metallization degree. The researchers tested a range of chromium metallization degrees from 0 to 65% and determined the corresponding specific energy consumption for each degree. Using the data obtained from the study, the researchers were able to assess the melting indexes of high-carbon ferrochromium in a larger 72 MW furnace. They found that by using a pre-reduced product with a chromium metallization degree of 65%, it was possible to reduce the specific energy consumption by half, to around 3.4 MW·h per ton of chromium. Overall, this study highlights the importance of considering the chromium metallization degree when determining the specific energy consumption for melting high-carbon ferrochromium. By optimizing the metallization degree, significant energy savings can be achieved, leading to more efficient and sustainable production processes. Full article

This study focuses on the thermodynamic modeling of the crystallization by the drowning process for two lithium salts: lithium hydroxide (LiOH) and lithium formate (CHLiO₂). The modeling involves utilizing thermodynamic properties, such as the activity, osmotic, and solubility coefficients, within the ternary systems of LiOH + cosolvent + water and CHLiO₂ + cosolvent + water, as well as their respective binary constituent systems. Ethanol is chosen as the cosolvent for both salts, facilitating a comparative analysis. Given the limited availability of thermodynamic data for lithium formate with different cosolvents, the study aims to address this gap. The modified Pitzer model was employed for the modeling process, where the parameters were successfully obtained for both systems, with a deviation of less than 1%. Additionally, the mass and energy balance for the drowning-out crystallization process of both salts was performed. Full article

The paper presents the possibility of recovering metals from printed circuit boards (PCBs) of spent mobile phones using the hydrometallurgical method. Two-stage leaching of Cu(II), Fe(III), Sn(IV), Zn(II), Ni(II) and Pb(II) with H₂SO₄ (2 and 5 M) and HNO₃ (2 M) with the addition of H₂O₂ (10 and 30%) and O₃ (9 or 15 g/h) was conducted at various process conditions (temperature—313, 333 and 353 K, time—60, 120, 240, 300 min, type and concentration of leaching agent, type and concentration of oxidant, solid–liquid ratio (S/L)), allowing for a high or total metals leaching rate. The use of two leaching stages allows for the preservation of selectivity, separation and recovery of metals: in the first stage of Fe(III), Sn(IV) and in the second stage of the remaining tested metal ions, i.e., Cu(II), Zn(II), Ni(II) and Pb(II). Removing Fe from the tested PCBs’ material at the beginning of the process eliminates the need to use magnetic methods, the purpose of which is to separate magnetic metal particles (ferrous) from non-magnetic (non-ferrous) particles; these procedures involve high operating costs. Since the leaching of Cu(II) ions with sulfuric(VI) acid practically does not occur (less than 1%), this allows for almost complete transfer of these ions into the solution in the second stage of leaching. Moreover, to speed up the process and not generate too many waste solutions, oxidants in the form of hydrogen peroxide and ozone were used. The best degree of leaching of all tested metal ions was obtained when 2 M sulfuric(VI) acid at 353 K was used in the 1st research stage, and 2 M nitric(V) acid and 9 g/h O₃ at 298 K in the 2nd stage of leaching, which allowed it to be totally leached 100% of Fe(III), Cu(II), Sn(IV), Zn(II), Ni(II) and 90% Pb(II). Full article

In this paper, the properties, mineral magnetic modification, and beneficiation of tailings from the central mining and processing plant in Kryvyi Rih, Ukraine, have been studied. Samples were investigated by X-ray diffraction, X-ray fluorescence, microscopy, and magnetization measurements. The beneficiation was conducted using magnetizing roasting with carbon monoxide followed by dry low-intensity magnetic separation. The effects of chemical, mineral, and granulometric composition on the processing of fine tailings of different sizes sampled at different points of the tailings pond were investigated. Additionally, we proposed a new approach for magnetic separation of fine magnetically modified tailings based on the combination of permanent and alternating magnetic fields. Magnetizing roasting resulted in an enhancement in mass magnetization to 11–62 Am²/kg in comparison with initial values of 0.3–1.5 Am²/kg. After magnetic separation, the magnetic concentrates consisted almost completely of magnetite (with the magnetization of 75–88 Am²/kg) and non-magnetic residues contained major quartz. The content of iron in magnetic concentrates reached 68.5–70.2 wt.% and iron recovery 77–96 wt.%, depending on size fraction. We could conclude that the tailings are represented by fine-grained liberated material that can be effectively upgraded using magnetizing roasting and magnetic separation into two valuable products, such as iron concentrate and quartz powder. Full article

In this study, two typical commercially used CaO-SiO₂-CaF₂-based mold fluxes with different basicities were adopted. Solid slag films of the two mold fluxes were obtained by immersing an improved water-cooled copper probe in the molten fluxes for different probe immersion times and molten slag temperatures. The film thickness, closed porosity, and roughness of the film surfaces in contact with the copper probe were measured. The heat flux through the solidified films and the comprehensive thermal conductivity of the films were both calculated. The results indicated that compared with the heat flux through high-basicity films, the heat flux through low-basicity films exhibited high fluctuation due to the evolution of fusion cracks within the glass layer. High-basicity mold fluxes resulted in higher thickness, growth velocity, surface roughness, and devitrification velocity of the films. With the growth and crystallization of the slag films, the comprehensive thermal conductivity of the high-basicity films increased significantly. For the low-basicity films, their comprehensive thermal conductivity first decreased and then increased after the solidification time exceeded 30 s. The comprehensive thermal conductivity of the high- and low-basicity films ranged from 0.63 to 0.91 and 0.62 to 0.81 W/(m·K), respectively. The results provide a novel method for analyzing the potential effect of the structural factors of slag films on heat transfer control and controlling the heat transfer behavior of slag films. Full article

In the application of Ti-6Al-4V to aerospace structural components, when welding thick plates similar of the thickness of the components, microstructure and hardness gradients emerge between the base material (BM) and the joint. This leads to the issue of significant stress concentration in the BM under tensile stress. To address this problem through post-welding heat treatment, this study conducted heat treatments at temperatures both below (mill annealing, MA) and above the beta-transus temperature (beta annealing, BA) on electron-beam weldments of 18 mm thickness Ti-6Al-4V plates. Subsequently, microstructures and hardness were analyzed at different depths from the upper surface and areas (fusion zone (FZ), heat-affected zone (HAZ), and BM), and tensile properties were measured at various depths. The results indicated that α′ observed in FZ and HAZ was resolved through both MA and BA. Particularly after BA, the microstructural gradient that persisted even after MA completely disappeared, resulting in the homogenization of widmanstätten α + β. Consequently, after BA, the hardness gradient in each zone also disappeared, and the tensile strength was higher than in just-welded and MA heat-treated plates. Full article

In this study, titanium (Ti) and manganese (Mn) element powders in determined amounts (0.35–0.75 and 1.5 wt %) were added into the 316 L stainless steel matrix by means of powder metallurgy (PM) technology, either individually or in pairs, and the desired composition was obtained as a powder mixture. The powders used in the study were cold-pressed tensile sample molds prepared in ASTM E8M standards, unidirectionally cold-pressed under 750 MPa compression pressure and formed into blocks. After pressing, the raw strength samples were sintered in an atmosphere-controlled tube furnace at 1250 °C for two hours in an argon atmosphere. The microstructure and mechanical properties of the produced PM steels were characterized using an optical microscope, SEM, EDS, tensile test, and hardness test. The results showed that the stainless steel samples with 0.35 (Ti and Mn) added to 316 L stainless steel had the highest yield strength, tensile strengths, and hardness strengths. However, with the addition of 0.75–1.5 Ti, 0.75–1.5 Mn and 0.75–1.5 (Ti and Mn) to 316 L stainless steel, a decrease was observed in the mechanical properties. Moreover, the stainless steel sample with 0.35 (Ti and Mn) added to 316 L stainless steel is better than other samples in terms of surface quality. Full article

This study focuses on the analyses of nano-twinned copper (Cu) films deposited through magnetron sputtering on silicon carbide (SiC) chips. The investigation encompasses the utilization of a chromium (Cr) adhesive layer coupled with varying voltage bias conditions. The goal is to comprehensively examine the influence of the adhesive layer and negative bias voltages, contributing to an enhanced understanding of materials engineering and bonding technologies for advanced applications. The formation of a nano-twinned structure and (111) surface orientation can be properly controlled by applied substrate bias. High-density nanotwinned structures were introduced into Cu films sputtered on SiC substrates with 82.3% of (111) orientation proportion at −150 V, much higher than the Cu film sputtered with another substrate bias. It is concluded that the sputtered Cu nanotwinned film formed with −150 V bias voltage has the potential to be employed as the interlayer for low-temperature direct bonding. Full article

Sinter sensible heat recovery via a vertical cooling furnace is a new type of waste heat recovery process proposed based on coke dry quenching. However, the segregation of the burden in a vertical cooling furnace is serious, resulting in a large amount of cooling gas escaping from the short-circuit channel of the vertical cooling furnace, which seriously affects the uniform gas–solid heat transfer in the furnace. To improve the burden distribution and gas flow in such a furnace, this paper proposes a Venturi-type vertical cooling furnace. Based on the single silo of a vertical cooling furnace in Meishan Steel, a slot model was established, and the improvement effect of the Venturi furnace structure on the burden distribution and gas flow was studied using the DEM–CFD coupling method. The results show that compared with the existing furnace type, the inclined wall of the Venturi furnace changed the direction of the high D_nv (average diameter) channel from vertical to inclined-vertical and reduced the D_nv from >0.033 m to 0.028~0.03 m in the vertical part of the variable-diameter section, thus reducing the influence area of the high D_nv channel. The minimum and average values of the voidage in the contraction part of the variable-diameter section increased from 0.28 and 0.315 to 0.31 and 0.33, respectively, which caused the voidage distribution to change from U-shaped to W-shaped along the longitudinal direction while simultaneously reducing the longitudinal fluctuation range of the voidage from 0.28~0.39 to 0.298~0.37. The gas flow direction changed from vertical-upward to vertical-inclined-upward, which increased the gas–solid contact. The gas velocity increased significantly. In the vertical section, the average gas velocity was 2.34 m/s, which was 30.73% higher than the velocity of 1.79 m/s of the existing furnace type. In the variable-diameter section, the average gas velocity was 3.52 m/s, which was 72.55% higher than the velocity of 2.04 m/s of the existing furnace type. The high-speed gas channel basically only existed in the sidewall area and the center area of the vertical section, and the length was reduced from 3.11 m to 2.52 m, which reduced the influence area. In the variable-diameter section, the high-speed gas channel disappeared, and the uniformity of the gas velocity distribution was greatly improved. The gas pressure drop increased from 4140 Pa to 6410 Pa, with an increase of 54.83%. Therefore, when designing the Venturi furnace type, it was necessary to take into consideration the improvement in the gas velocity distribution and the increase in the pressure drop. The research results of this paper can provide guidance for the structure optimization of the sinter vertical cooling furnace. Full article

In metallurgical converter processes, numerical modeling is a useful tool for understanding the complexity of the systems. In this paper, we present a practical model that couples fluid dynamics and chemical reactions to explore the impact of mixing time on decarburization. Using computational fluid dynamics (CFD), in this study, we investigate an arbitrary metallurgical reactor with continuous oxygen supply, focusing on the Fe–C–O system. The model employs local equilibrium, a turbulence limiter, and finite volume method for mass, momentum, and energy transfer. Tracer injection points in the gas plume’s rising region exhibit faster mixing, and a comparison of reaction cases reveals distinct decarburization rates based on oxygen injection distribution and the influence of turbulence on reactions. Overall, while mixing time matters, the results show that this system is primarily governed by thermodynamics and oxygen supply, and a 270% increase in mixing time increase had a small impact on the end carbon content. Full article

As various regions around the world implement carbon taxes, we assert that the competitiveness of steel products in the marketplace will shift according to individual manufacturers’ ability to reduce CO₂ emissions as measured by cradle-to-gate Life Cycle Analysis (LCA). This study was performed by using LCA and cost estimate research to compare the CO₂ emissions and the additional cost applied to the production of various decarbonized materials used in sheet for automotive industry applications using the bending stiffness-based weight reduction factor. The pre-pandemic year 2019 was used as a baseline for cost estimates. This paper discusses the future cost scenarios based on carbon taxes and hydrogen cost. The pathways to decarbonize steel and alternative materials such as aluminum and reinforced polymer composites were evaluated. Normalized global warming potential (nGWP) estimates were calculated assuming inputs from the current USA electricity grid, and a hypothetical renewables-based grid. For a current electricity grid mix in the US (with 61% fossil fuels, 19% nuclear, 20% renewables), the lowest nGWP was found to be secondary aluminum and 100% recycled scrap melting of steel. This is followed by the natural gas Direct Reduced Iron–Electric Arc Furnace (DRI-EAF) route with carbon capture and the Blast Furnace-Basic Oxygen Furnace (BF-BOF) route with carbon capture. From the cost point of view, the current cheapest decarbonized production route is natural gas DRI-EAF with Carbon Capture and Storage (CCS). For a renewable electricity grid (50% solar photovoltaic and 50% wind), the lowest GWP was found to be 100% recycled scrap melting of steel and secondary aluminum. This is followed by the hydrogen-based DRI-EAF route and natural gas DRI-EAF with carbon capture. The results indicate that, when applying technologies available today, decarbonized steel will remain competitive, at least in the context of automotive sheet selection compared to aluminum and composites. Full article

To control well the surface fluctuation of liquid metal in a slab mold, a new type of combined permanent magnets braking system, namely a permanent magnet flow control mold (PMFC-Mold) is proposed by our research group, of which its main feature is that the device can control the flow of molten steel in the mold without additional energy. To observe the fluctuation state of the alloy with the PMFC-Mold, instantaneous surface fluctuations were recorded by a laser level meter and camera. To study the effect of various casting speeds and permanent magnet placement on surface fluctuations, the three measurement points, which were 7, 18, and 36 mm away from the narrow surface of the mold, were selected to record the trend of level fluctuation. Three types of permanent magnet placement were designed by setting the differences between the height center of the permanent magnet and the free surface in the slab mold, which were H₁ = 0 mm, H₂ = −25 mm, and H₃ = −75 mm. The experimental results indicated that with the acceleration of the casting speed, the average height and standard deviation of surface fluctuation at the measurement point increased, but the surface fluctuation pattern remained. When the permanent magnets were arranged at H₁ = 0 mm and H₂ = −25 mm, the position of the magnetic field was reasonable and the surface fluctuation could be effectively suppressed. In contrast, when the permanent magnets were arranged at H₃ = −75 mm, the level fluctuation was intensified. Full article

In order to ensure the stable operation of blast furnace production, it is necessary to keep abreast of the trends in the gas permeability index of the blast furnace. As one of the key parameters to be monitored in the process of blast furnace smelting, the gas permeability index directly reflects the performance of the blast furnace in the actual production of the furnace. Continuous monitoring of the permeability index is required in the actual production of the blast furnace in order to effectively guarantee the stable and smooth operation of the blast furnace. The aim of this study is to accurately predict the trend in the blast furnace gas permeability index by constructing an intelligent prediction model and utilizing a data-driven approach to monitor the gas permeability index and ensure the stable operation of the blast furnace. First, based on the actual production data of a #2 blast furnace of an iron and steel enterprise, an isolated forest algorithm is applied to detect and eliminate the outliers in the original data, and then a data driver set is constructed after normalization of the deviation. Second, by analyzing the coupling mechanism between the blast furnace permeability and gas flow, as well as Spearman correlation analysis and MIC maximum information coefficient (MIC) analysis, key parameters are screened out as feature variables from the data-driven set. Finally, a wavelet neural network algorithm is used to construct an intelligent prediction model of the blast furnace gas permeability index. Compared with a BP neural network (BP), a particle swarm-optimized BP neural network (PSO-BP), and XGBoost, the wavelet neural network shows obvious advantages when the error is controlled in the range of ±0.1, and the prediction accuracy can reach 95.71%. The model is applied to the actual production of a #2 blast furnace of an iron and steel enterprise, and the results show that the predicted value of the blast furnace permeability index is highly consistent with the actual value of real-time blast furnace production, which verifies its excellent characteristics. Full article

In the investment casting process, the pattern made of wax is obtained in a die for further formation of a shell mold. The problem of die-filling by pattern wax is significant because it influences the quality of the final casting. This work investigates three commercial pattern waxes’ fluidity with a newly developed injection fluidity test. It was shown that the fluidity of waxes increased with increasing injection temperature and pressure, and the simultaneous increase in temperature and pressure gives a much more significant enhancement of fluidity than an increase in temperature or pressure separately. The rheological behavior of the waxes was also investigated at different temperatures using a rotational viscosimeter, and temperature dependences of waxes’ dynamic viscosity were determined. It was shown that wax viscosity is increased more than ten times with decreasing temperature from 90 to 60 °C. A good correlation between wax fluidity and its viscosity is observed, which is different from metallic alloys, where the solidification behavior is more critical. The difference in wax flow behavior in comparison with metallic melts is associated with the difference in dynamic viscosity, which for investigated waxes and metallic melts is 3000–27,000 mPa·s and 0.5–6.5 mPa·s, respectively. The difference in investigated filled waxes’ fluidity is observed, which can be associated with the type and amount of filler. The twice-increasing fraction of cross-linked polystyrene decreases fluidity twice. At the same time, terephthalic acid has a minor influence on wax fluidity. Full article

Hot isostatic pressing (HIP) technology can directly produce nearly clean shaped workpieces that meet the requirements while ensuring machining accuracy and surface quality. Usually, people use numerical simulation methods to reduce experimental costs. Generally, a uniform powder relative density distribution of about 65% is used in the simulation. However, in practical engineering, we found that even with additional tools such as vibration tables, the powder filling is not uniform. The non-uniform distribution causes uneven shrinkage of the powder and capsule after HIP. In this paper, a numerical model for HIPing of Ti-6Al-4V powder is developed to improve the prediction by comparing the uniform and non-uniform initial powder distribution. The results show that different initial relative density distributions affect the powder densification process and further affect the deformation of the capsule. It also leads to non-uniform stress distribution after HIP, which increases the risk of capsule rupture. The analysis of the numerical simulation results and the comparison with the experimental results highlights that taking into account the non-uniform powder distribution inside the capsule is vital to improve numerical results and produce near-net shape components. The maximum error of the simulation with the usual initial relative density setting of 65% is 4.2%. However, considering the uneven distribution of initial powder, the maximum error is reduced to 3.16%, and the average error is also less than 2%. Full article

Centrifugal atomization is a rapid solidification technique involving fast cooling rates to produce high-quality powders. The final microstructure of the atomized particles is closely linked with the thermal history and cooling rates experienced during the atomization process. However, there is insufficient research on the temperature evolution of metal particles produced by this technique, and most works evaluate the thermal history of the droplet through semi-empirical correlations that lie outside the conditions where they were derived. In this work, the cooling rate of centrifugally atomized Al-4%Cu was studied via mathematical modelling and experimental validation. A heat transfer model was implemented, and the value of the convective heat transfer coefficient was obtained from the Whitaker semi-empirical correlation considering three cases of study for the thermophysical properties of the gas. The validity of the Whitaker correlation was experimentally evaluated by means of cooling rates based on the Secondary Dendrite Arm Spacing (SDAS) technique. The Whitaker correlation with the Reynolds and Prandtl numbers evaluated at the ambient temperature and the gas conductivity evaluated at the film temperature gave the best agreement with the experimental results, with cooling rates in the order of 10⁵ Ks⁻¹ for <32.5 µm powders atomized in He atmosphere. Full article

Fundamental studies have been carried out experimentally and theoretically on the magnesiothermic reduction of silica with different Mg/SiO₂ molar ratios (1–4) in the temperature range of 1073 to 1373 K with different reaction times (10–240 min). Due to the kinetic barriers occurring in metallothermic reductions, the equilibrium relations calculated by the well-known thermochemical software FactSage (version 8.2) and its databanks are not adequate to describe the experimental observations. The unreacted silica core encapsulated by the reduction products can be found in some parts of laboratory samples. However, other parts of samples show that the metallothermic reduction disappears almost completely. Some quartz particles are broken into fine pieces and form many tiny cracks. Magnesium reactants are able to infiltrate the core of silica particles via tiny fracture pathways, thereby enabling the reaction to occur almost completely. The traditional unreacted core model is thus inadequate to represent such complicated reaction schemes. In the present work, an attempt is made to apply a machine learning approach using hybrid datasets in order to describe complex magnesiothermic reductions. In addition to the experimental laboratory data, equilibrium relations calculated by the thermochemical database are also introduced as boundary conditions for the magnesiothermic reductions, assuming a sufficiently long reaction time. The physics-informed Gaussian process machine (GPM) is then developed and used to describe hybrid data, given its advantages when describing small datasets. A composite kernel for the GPM is specifically developed to mitigate the overfitting problems commonly encountered when using generic kernels. Training the physics-informed Gaussian process machine (GPM) with the hybrid dataset results in a regression score of 0.9665. The trained GPM is thus used to predict the effects of Mg-SiO₂ mixtures, temperatures, and reaction times on the products of a magnesiothermic reduction, that have not been covered by experiments. Additional experimental validation indicates that the GPM works well for the interpolates of the observations. Full article

The focus of this work is to analyze the sintering kinetics of Ti12.5Ta12.5Nb alloy by dilatometry. The mixture of powders was achieved by mixing individual powders of Ti, Ta and Nb, which were then axially pressed. Sintering was performed at 1260 °C using different heating rates. The microstructure was determined by X-ray diffraction and scanning electron microscopy. Results show that densification is achieved by solid state diffusion and that the relative density increased as the heating rate was slow. Due to the full solubility of Ta and Nb in Ti, the relative density reached was up to 93% for all samples. Activation energy was estimated from the densification rate and it was determined that two main diffusion mechanisms were predominant: grain boundary and lattice self-diffusion. This suggests that Ta and Nb diffusion did not affect the atomic diffusion to form the necks between particles. The microstructure shows a combination of α, β and α′, and α″ martensitic phases as a result of the diffusion of Ta and Nb into the Ti unit cell. It was concluded that the heating rate plays a major role in the diffusion of Ta and Nb during sintering, which affects the resulting microstructure. Full article

Electrical resistivity was used in this test methodology to estimate the relative precipitate density in AA7075. Various electrical test parameters were explored to determine the difference between pulsed and DC-type currents. No difference between these test conditions could be distinguished. Furthermore, an electroplastic effect was not needed to explain these results and the effects are likely to be caused by purely joule heating. Full article

This paper describes research on the influence the technology of zinc-coated steel wire manufacturing has on the energy and force parameters of the drawing process, energy consumption and zinc expenditure. In the theoretical part of the paper, the theoretical work and drawing power were calculated. Calculations of the electric energy consumption have shown that usage of the optimal wire drawing technology results in a 37% drop in energy consumption, which in the course of a single year translates to savings equal to 13 TJ. This, in turn, results in the decrease of CO₂ emissions by tons and a total decrease of the eco-costs by approximately EUR 0.5 mln. Drawing technology also influences the losses of the zinc coating and CO₂ emissions. Properly adjusted parameters of the wire drawing technology allow obtaining a zinc-coating that is 100% thicker, translating to 265 tons of zinc, whose production generates 900 tons of CO₂ and incurs eco-costs equal to EUR 0.6 mln. Optimal parameters for drawing, from the perspective of decreased CO₂ emissions during the zinc-coated steel wire manufacturing, are as follows: usage of the hydrodynamic drawing dies, angle of the die reducing zone α = 5°, and drawing speed of 15 m/s. Full article

The aim of this research was to determine the factors affecting the metallurgical quality of cast iron during serial production of castings using a campaign cupola and a holding furnace. The problem to be solved, which was to obtain cast iron with the required mechanical properties while reducing the internal porosity, results from the foundry’s need to increase the metallurgical quality of the alloy. The increasing difficulty and complicated constructions of castings, for which it is not possible to introduce risers at the stage of technological design, make the stage of proper preparation of cast iron the only way to obtain castings without shrinkage defects. The article presents the results of the study of physicochemical and mechanical properties, microstructure and shrinkage tendency of ductile iron depending on the charge materials used, the amount of Mg used during spheroidization and the type of final inoculants. Step castings and wedge tests were produced on a vertical molding line. The spheroidization was carried out by injecting a core wire containing Mg alloy into the cast iron. The final inoculation of 0.2% was performed using a pneumatic dispenser equipped with a vision system to control the effectiveness of the inoculation. The ITACA Meltdeck thermal analysis system was used to study the physicochemical properties of the initial cast iron, and the ITACA X system to analyze the state of the final cast iron on the molding line. Mechanical tests were performed on samples cut from a stepped casting, and microstructure tests were carried out using a light microscope and a scanning electron microscope. The results of thermal analyses show that increasing the share of pig iron at the expense of steel increases the minimum solidification temperature of eutectic, and thus, increases the potential for graphite nucleation in cast iron. Increasing the nucleation potential can be obtained by adding anthracite, FeSi and SiC. A very important factor in obtaining cast iron of high metallurgical quality is the possible limitation during spheroidization of the length of the core wire containing Mg, which is a carbide-forming element. The lower the initial sulfur level, the greater the possibility of reducing the amount of cored wire. The inoculants containing Ce and Bi were the most advantageous final inoculants from the point of view of obtaining the best microstructure parameters and plastic properties of cast iron. Full article

Powder metallurgy is a popular method of making raw powders into specific shaped samples. However, the pressure distribution and the microhardness difference within the sample are nonnegligible and unclear when the sample is long or exceeds a specific size. In this study, the long magnesium blocks, with a ratio of about 2.8 between the sample height and the sample side length, are successfully synthesized under three uniaxial and two biaxial conditions. Then, the sample hardness values on the outer surface and the center plane are tested to study the microhardness distribution. The modified analytical expression indicates that the normal pressure exponentially decreases along the compression direction, which is consistent with the hardness distribution trend. Because higher pressure leads to a more compact arrangement of the powders, more metal bonds are formed after sintering. During the first pressing, the sidewall pressure makes the surface hardness higher. The secondary reverse compression mainly improves the bottom and core hardness due to the re-orientation and re-location of the powders. The obtained relationship between the applied pressure and the hardness distribution is instructive in predicting and improving the sample quality. Full article

The paper shows the use of novel modelling techniques adapted from ironmaking in the pyrometallurgical process of zinc production. Firstly, regarding the purpose to determine the boundary conditions of reduction processes taking part in the working volume of an Imperial Smelting Furnace (ISF), a deep thermochemical analysis was conducted. On this basis and using Ramm’s principles of direct and indirect reduction optimal share, the fuel rate minimization model was built. The model’s leading role is minimizing coke consumption in the ISF while maintaining the thermal state of the furnace at the correct level. In addition, the proposed presentation of the ISF thermal state shows in a unified way all the shortcomings in the correct process operation. Verification in real conditions on the ISF in Miasteczko Śląskie shows that model implementation can bring tangible benefits. Coke savings can reach over 30 kg per tonne of raw zinc. Full article

In powder metallurgy (PM), the compaction step is fundamental to determining the final properties of the sintered components. The deformation and defectiveness introduced in the powder material during uniaxial die compaction can be correlated to the activation and enhancement of the dislocation pipe diffusion, a lattice diffusion mechanism during the sintering process. Its coefficient depends on the dislocation density. The powder particles are mostly deformed along the direction of the compaction (longitudinal direction) rather than along the compaction plane; consequently, the contact areas perpendicular to the direction of the compaction present a higher density of dislocations and lattice defects. This high density intensifies the shrinkage along the direction of compaction. To demonstrate the influence of uniaxial cold compaction on the material’s stress state the powder particles and their contacts were modeled using spheres made of pure copper. These spheres are compacted in a die at different pressures to better analyze the system’s response at the grade of deformation and the consequent influence on the material’s behavior during the sintering. In the different zones of the sphere, the micro-hardness was measured and correlated to the concentration of dislocations using the model for indentation size effect (ISE). After the compaction, the spheres were more deformed along the longitudinal than the transversal direction. The results obtained using hardness indentation show differences in the dislocation density between the undeformed and deformed spheres and, in the case of the compacted sphere, between the contact area along the longitudinal and the transversal direction. Full article

In this study, the authors explored the issues of the Soderbergh electrolysis cell’s increase in economic efficiency. This result was achieved by analyzing the temperature fields of the electrolysis cell in order to determine the overheating points. As a result, it led to the determination of the points of the hearth bottom’s subsequent breakdown, causing the failure of the electrolysis cell. In this paper, the mathematical modeling of the temperature fields using a spatially distributed mathematical model and conducted experimental studies were carried out. The mathematical model also provides the opportunity to measure the temperature field in the hearth bottom (at the bottom) of the OA-300M electrolysis cell. The results of the given research can be used to solve the experimental determination of the hearth bottom internal defect problem. Full article

The application of Ce oxides in oxide metallurgy has received extensive attention, but until now, the direct adding of CeO₂ into molten steel to generate Ce oxides has not occurred. In this paper, a mixture of CeO₂ and Si nanoparticles were added into molten steel. The resultant formation of micrometer scale Ce-bearing oxides confirmed its adding validity. This behavior may be interpreted as the reactivity between CeO₂ and [Al], and the improved wettability between CeO₂ and molten steel with the assistance of Si powder. Thus, when the quantity of CeO₂ is kept constant, its added yield should increase when increasing the added quantity of Si. This was verified by the larger percentage of Ce-bearing oxides of the total oxides and the greater average content of Ce in Ce-bearing oxides after normalization. Moreover, compared with the blank sample, statistical results indicated that the oxides in CeO₂-modified samples were refined, and their dispersion homogeneity was enhanced. This comparison indicates the effectiveness of the external adding method in oxide metallurgy. Full article

In metallurgical processes, coke is used, among other materials, in order to implement the process of removing zinc from waste by reduction and evaporation. Due to the implemented de-carbonization policy, we are dealing with an increase in costs and decreasing availability of coke, which leads to an intensive search for other possibilities for conducting the process, which may generate a fire and explosion hazard in the technological process. This article analyzes the possibility of using soot in the process of reducing the zinc content in deposited metallurgical waste, taking into account the issue of fire and explosion safety. The results of the research proved the possibility of the safe use of the reductor, which is soot and anthracite, as a material replacing coke in pyrometallurgical processes. Full article

In view of the problem that the enrichment and migration law of the Ti element in the slag of vanadium-titanium magnetite during the melting process is not clear, the phase transformation is not clear and the enrichment effect is not obvious, the single factor experiment and orthogonal experiment are used to optimize the melting conditions of Ti enrichment. Through XRD, SEM and EDS analysis, the effects of melting temperature, alkalinity and carbon content on the Ti phase in the slag are studied, and the occurrence form and migration law of the Ti element in the slag system under different melting conditions are clarified. The results demonstrate that increasing the basicity and melting temperature is beneficial to the enrichment of Ti, but it is too high it will lead to the formation of pyroxene, diopside and magnesia-alumina spinel, affecting the enrichment of Ti. The increase in carbon content can make Ti occur in slag in the form of titanium oxides such as TiO, TiO₂, Ti₂O₃ and Ti₃O₅, but excessive carbon content leads to the excessive reduction of Ti compounds to TiCN and TiC. After optimization, under the melting conditions of alkalinity 1.2, the melting temperature 1500 °C and carbon content 15%, the content of Ti in slag can reach 18.84%, and the recovery rate is 93.54%. By detecting the content of Fe and V in molten iron, the recovery rates are 99.86% and 95.64%, respectively. Full article

The high cooling rate and temperature gradient caused by the rapid heating and cooling characteristics of laser welding (LW) leads to excessive thermal stress and even cracks in welded joints. In order to solve these problems, a dynamic preheating method that uses hybrid laser arc welding to add an auxiliary heat source (arc) to LW was proposed. The finite element model was deployed to investigate the effect of dynamic preheating on the thermal behavior of LW. The accuracy of the heat transfer model was verified experimentally. Hardness and tensile testing of the welded joint were conducted. The results show that using the appropriate current leads to a significantly reduced cooling rate and temperature gradient, which are conducive to improving the hardness and mechanical properties of welded joints. The yield strength of welded joints with a 20 A current for dynamic preheating is increased from 477.0 to 564.3 MPa compared with that of LW. Therefore, the use of dynamic preheating to reduce the temperature gradient is helpful in reducing thermal stress and improving the tensile properties of the joint. These results can provide new ideas for welding processes. Full article

In this study, transient liquid-phase (TLP) bonding was adopted to obtain a reliable reduced-activation ferritic/martensitic (RAFM) steel joint with Fe-Si-B amorphous foil. The aging tests and creep tests of the TLP joints were carried out at 550 °C to study the microstructural evolution in the service process. The effect of stress loading on the microstructural evolution of the TLP joint was investigated. The results show that creep fractures in the TLP joints occur in the base material. The main factors affecting the creep performance of TLP joints are the recovery of substructures and the coarsening and deformation of martensitic laths. In addition, the M₂₃C₆ carbides in the base material were coarser than in the weld zone. Compared with aging samples and creep samples undergoing the same test temperature, the dislocation density in the isothermal solidification zone (ISZ) increased significantly with increases in the stress level. Furthermore, it is worth noting that the microstructure of the weld zone changed from large-sized ferrite to a mixed, fine microstructure of ferrite and martensite, which increases the heat resistance of the TLP joints, and thus results in creep fractures in the base metal. Full article