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Search Results (825)

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Keywords = thermo-electric generator

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12 pages, 5879 KiB  
Article
Advanced Thermoelectric Performance of SWCNT Films by Mixing Two Types of SWCNTs with Different Structural and Thermoelectric Properties
by Yutaro Okano, Hisatoshi Yamamoto, Koki Hoshino, Shugo Miyake and Masayuki Takashiri
Materials 2025, 18(1), 188; https://doi.org/10.3390/ma18010188 - 4 Jan 2025
Viewed by 311
Abstract
Semiconducting single-walled carbon nanotubes (SWCNTs) are significantly attractive for thermoelectric generators (TEGs), which convert thermal energy into electricity via the Seebeck effect. This is because the characteristics of semiconducting SWCNTs are perfectly suited for TEGs as self-contained power sources for sensors on the [...] Read more.
Semiconducting single-walled carbon nanotubes (SWCNTs) are significantly attractive for thermoelectric generators (TEGs), which convert thermal energy into electricity via the Seebeck effect. This is because the characteristics of semiconducting SWCNTs are perfectly suited for TEGs as self-contained power sources for sensors on the Internet of Things (IoT). However, the thermoelectric performances of the SWCNTs should be further improved by using the power sources. The ideal SWCNTs have a high electrical conductivity and Seebeck coefficient while having a low thermal conductivity, but it is challenging to balance everything. In this study, to improve the thermoelectric performance, we combined two types of SWCNTs: one with a high electrical conductivity (Tuball 01RW03, OCSiAl) and the other with a high Seebeck coefficient and low thermal conductivity (ZEONANO SG101, ZEON). The SWCNT inks were prepared by mixing two types of SWCNTs using ultrasonic dispersion while varying the mixing ratios, and p-type SWCNT films were prepared using vacuum filtration. The highest dimensionless figure-of-merit of 1.1 × 10−3 was exhibited at approximately 300 K when the SWCNT film contained the SWCNT 75% of SWCNT (ZEONANO SG101) and 25% of SWCNT (Tuball 01RW03). This simple process will contribute to the prevalent use of SWCNT-TEG as a power source for IoT sensors. Full article
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<p>Manufacturing process of SWCNT inks and films.</p>
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<p>Nanostructure of SWCNTs determined by FE-TEM. (<b>a</b>) SWCNT-SG and (<b>b</b>) SWCNT-Tu.</p>
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<p>Microstructure and surface morphology of SWCNT films with different mixing ratios at SWCNT-Tu/(SWCNT-Tu + SWCNT-SG) of (<b>a</b>) 0%, (<b>b</b>) 25%, (<b>c</b>) 50%, (<b>d</b>) 75%, and (<b>e</b>) 100%.</p>
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<p>(<b>a</b>) Raman spectra of the SWCNT films with different mixing ratios of SWCNTs and (<b>b</b>) the relationship between the Raman intensity ratio (<span class="html-italic">I<sub>G</sub></span>/<span class="html-italic">I<sub>D</sub></span>) of the SWCNT films and the mixing ratio of SWCNTs.</p>
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<p>Thermal and physical properties of SWCNT films with different mixing ratios of SWCNTs. (<b>a</b>) In-plane thermal diffusivity, (<b>b</b>) mass density, (<b>c</b>) specific heat, and (<b>d</b>) in-plane thermal conductivity.</p>
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<p>In-plane thermoelectric properties of SWCNT films with different mixing ratios of SWCNTs. (<b>a</b>) Electrical conductivity, (<b>b</b>) Seebeck coefficient, (<b>c</b>) power factor, and (<b>d</b>) dimensionless figure-of-merit.</p>
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43 pages, 11377 KiB  
Review
Thermoelectric Generators Applied as a Power Source in CubeSats: State of the Art
by Gabriel Brugues Soares, Jorge Javier Gimenez Ledesma, Eder Andrade da Silva and Oswaldo Hideo Ando Junior
Energies 2025, 18(1), 173; https://doi.org/10.3390/en18010173 - 3 Jan 2025
Viewed by 328
Abstract
This systematic review outlines the application of thermoelectric generators (TEGs) as energy sources in CubeSats. While CubeSats currently rely on solar cells with efficiencies between 16.8% and 32.2%, their performance diminishes with increased distance from the Sun. TEGs, although used in radioisotope thermoelectric [...] Read more.
This systematic review outlines the application of thermoelectric generators (TEGs) as energy sources in CubeSats. While CubeSats currently rely on solar cells with efficiencies between 16.8% and 32.2%, their performance diminishes with increased distance from the Sun. TEGs, although used in radioisotope thermoelectric generators (RTGs) for satellites, remain underutilized in CubeSats. A literature review revealed 33 relevant articles, with 21.2% employing simulation software to evaluate thermal behavior. Among 34 patents, only one mentioned micro-TEGs, with most focusing on structural improvements. Patent activity peaked between 2016 and 2020, emphasizing structural and thermal optimization, but no patents addressed TEGs as energy sources for CubeSats, highlighting a significant research gap. TEGs present a viable solution for harnessing residual heat in CubeSats. Full article
(This article belongs to the Special Issue Advanced Research on Heat Exchangers Networks and Heat Recovery)
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<p>Standardized structure of a CubeSat. Adapted from [<a href="#B11-energies-18-00173" class="html-bibr">11</a>].</p>
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<p>Basic process for conducting a systematic review.</p>
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<p>ProKnow-C methodology process.</p>
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<p>Initial filtering process for aligning titles with the proposed theme.</p>
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<p>Process of analyzing Repositories K and P, resulting in Repository C.</p>
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<p>Distribution of (<b>a</b>) articles and (<b>b</b>) citations over the years.</p>
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<p>Distribution of (<b>a</b>) the number of publications per author and (<b>b</b>) the number of citations per author.</p>
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<p>Scientific Relevance of the articles composing the BP and their published journals.</p>
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<p>Representation of the 30 most frequently used KWs in the BP.</p>
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<p>Flowchart representing the filtering of products and patents.</p>
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<p>Number of patents registered by country.</p>
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<p>Number of patents registered per year.</p>
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<p>Number of citations per patent by year of publication. Adapted from [<a href="#B96-energies-18-00173" class="html-bibr">96</a>].</p>
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<p>Number of patents produced by inventor. Adapted from [<a href="#B96-energies-18-00173" class="html-bibr">96</a>].</p>
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<p>Number of documents by (<b>a</b>) institutions and (<b>b</b>) according to CPC classification.</p>
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<p>Drawing of the (<b>a</b>) three-dimensional schematic and (<b>b</b>) layer structure of the invention [<a href="#B97-energies-18-00173" class="html-bibr">97</a>].</p>
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<p>MTG device. Adapted from [<a href="#B62-energies-18-00173" class="html-bibr">62</a>].</p>
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<p>MJPV-NETT device. Adapted from [<a href="#B63-energies-18-00173" class="html-bibr">63</a>].</p>
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<p>Schematic drawing of the thermoelectric device composed of carbon nanotube cores: (<b>a</b>) three-dimensional and (<b>b</b>) two-dimensional [<a href="#B64-energies-18-00173" class="html-bibr">64</a>].</p>
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<p>Number of scientific articles and patents over the years.</p>
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<p>Mapping the existing connections between the inventors.</p>
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<p>Representation of (<b>a</b>) density mapping and (<b>b</b>) the relationship between the number of citations per author and density.</p>
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<p>Mapping the existing connections between the inventors.</p>
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15 pages, 621 KiB  
Article
Image Analysis of the Influence of the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) on the Mars Environmental Dynamics Analyzer at Extremely Low Reynolds Number
by Ángel Antonio Rodríguez-Sevillano, María Jesús Casati-Calzada, Rafael Bardera-Mora, Juan Carlos Matías-García, Estela Barroso-Barderas and Emilio Fernández-Rivero
Appl. Sci. 2025, 15(1), 220; https://doi.org/10.3390/app15010220 - 30 Dec 2024
Viewed by 294
Abstract
This study analyzes the influence of the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) on the Mars Environmental Dynamics Analyzer (MEDA) station located on board the Perseverance rover (Mars 2020). A novel visualization methodology was developed using a hydrodynamic towing tank and 3D-printed models created [...] Read more.
This study analyzes the influence of the Multi-Mission Radioisotope Thermoelectric Generator (MMRTG) on the Mars Environmental Dynamics Analyzer (MEDA) station located on board the Perseverance rover (Mars 2020). A novel visualization methodology was developed using a hydrodynamic towing tank and 3D-printed models created through additive manufacturing. This experimental approach, not previously applied in this context, proved to be a cost-effective alternative for studying thermal interactions while providing accurate preliminary insights into the behavior of thermal plumes under Martian-like conditions. Key factors such as the extremely low Reynolds number, an increasing temperature of the model, and atmospheric properties similar to those in Mars were incorporated. The findings suggest that the MMRTG’s thermal plume may significantly influence MEDA’s performance due to the plume’s height and its interaction with the surrounding environment. Full article
(This article belongs to the Special Issue Advanced Image Analysis and Processing Technologies and Applications)
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<p>(<b>left</b> (Mast)) Modular mast design with mounting of the booms, TIRS, and rover head. (<b>right</b> (MMRTG)) Modular design of the MMRTG with shell and main module assembly.</p>
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<p>MMRTG cavity (<b>left</b>) in addition to the resistor housing and the presence of the ink holes. MMRTG’s shell (<b>right</b>) with 30° angled brackets.</p>
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<p>MMRTG and mast on the experimental floor: the 200 mm spacing between the mast and the MMRTG can be seen.</p>
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<p>Comparison of laminar length fluxes (marked in a green line) for active and non-active resistor: (<b>a</b>) non-active resistor (289 K); (<b>b</b>) active resistor (301 K).</p>
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<p>Side view flow rate 0.7 [mL/s]—dynamic mast/MMRTG—non-active resistor; in green and blue lines, the thermal plume near the mast and downstream is marked.</p>
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<p>Side view flow rate 0.7 [mL/s]—dynamic mast/MMRTG active resistor; in green and blue lines, the thermal plume near the mast and downstream is marked.</p>
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<p>Zenithal view exit angle flow rate 0.7 [mL/s]—dynamic mast/MMRTG-non-active resistor. Upper images (from 1 to 4) show the ink emission flow evolution; lower image details (green lines) the measurement of the exit angle.</p>
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<p>Zenithal view exit angle flow rate 0.7 [mL/s]—dynamic mast/MMRTG active resistor. Upper images (from 1 to 4) show the ink emission flow evolution; lower image details (green lines) the measurement of the exit angle.</p>
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19 pages, 5615 KiB  
Article
An Approach to Reduce Tuning Sensitivity in the PIC-Based Optoelectronic Oscillator by Controlling the Phase Shift in Its Feedback Loop
by Vladislav Ivanov, Ivan Stepanov, Grigory Voronkov, Ruslan Kutluyarov and Elizaveta Grakhova
Micromachines 2025, 16(1), 32; https://doi.org/10.3390/mi16010032 - 28 Dec 2024
Viewed by 479
Abstract
Radio photonic technologies have emerged as a promising solution for addressing microwave frequency synthesis challenges in current and future communication and sensing systems. One particularly effective approach is the optoelectronic oscillator (OEO), a simple and cost-effective electro-optical system. The OEO can generate microwave [...] Read more.
Radio photonic technologies have emerged as a promising solution for addressing microwave frequency synthesis challenges in current and future communication and sensing systems. One particularly effective approach is the optoelectronic oscillator (OEO), a simple and cost-effective electro-optical system. The OEO can generate microwave signals with low phase noise and high oscillation frequencies, often outperforming traditional electrical methods. However, a notable disadvantage of the OEO compared to conventional signal generation methods is its significant frequency tuning step. This paper presents a novel approach for continuously controlling the output frequency of an optoelectronic oscillator (OEO) based on integrated photonics. This is achieved by tuning an integrated optical delay line within a feedback loop. The analytical model developed in this study calculates the OEO’s output frequency while accounting for nonlinear errors, enabling the consideration of various control schemes. Specifically, this study examines delay lines based on the Mach–Zehnder interferometer and microring resonators, which can be controlled by either the thermo-optic or electro-optic effect. To evaluate the model, we conducted numerical simulations using Ansys Lumerical software. The OEO that utilized an MRR-based electro-optical delay line demonstrated a tuning sensitivity of 174.5 MHz/V. The calculated frequency tuning sensitivity was as low as 6.98 kHz when utilizing the precision digital-to-analog converter with a minimum output voltage step of 40 μV. The proposed approach to controlling the frequency of the OEO can be implemented using discrete optical components; however, this approach restricts the minimum frequency tuning sensitivity. It provides an additional degree of freedom for frequency tuning within the OEO’s operating range, which is ultimately limited by the amplitude-frequency characteristic of the notch filter. Thus, the proposed approach opens up new opportunities for increasing the accuracy and flexibility in generating microwave signals, which can be significant for various communications and radio engineering applications. Full article
(This article belongs to the Special Issue Silicon Photonics–CMOS Integration and Device Applications)
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<p>The circuit diagram of an integrated OEO supplemented with a delay line. Optical signals are displayed in green, while electrical signals are represented in blue.</p>
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<p>A potential implementation of an integrated optical delay line based on the MZI. The waveguides, where the effective refractive index varies, are indicated in red, while the control signal is depicted in blue.</p>
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<p>Microring resonator. Tuning elements are shown in red, and control signals are shown in blue.</p>
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<p>Simulation flow of time delay lines.</p>
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<p>Waveguides used in numerical models (dimensions in micrometers).</p>
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<p>Geometric parameters of a waveguide featuring a heating element (<b>a</b>) and a semiconductor diode (<b>b</b>). The shades of red indicate regions with free carriers of the p-type, while the shades of blue represent n-type regions. All dimensions are measured in µm.</p>
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<p>Relationship between the effective refractive index of the waveguide and the voltage applied to the heater.</p>
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<p>Relationship between the effective refractive index of the waveguide and the voltage applied to the anode.</p>
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<p>Transmission coefficient from a straight waveguide to a ring waveguide vs. the wavelength.</p>
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<p>Relationship between the time delay and the applied voltage for a thermo-optical MZI at sampling frequencies of 1.8 THz (<b>a</b>) and 50 THz (<b>b</b>) and for an electro-optical MZI at frequencies of 1.8 THz (<b>c</b>) and 50 THz (<b>d</b>).</p>
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<p>Coupling ratio of tunable couplers against the voltage applied to the tuning contact for thermo-optical (<b>a</b>) and electro-optical (<b>b</b>) MZIs.</p>
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<p>Introduced time delays against the voltage applied to the tuning contact for thermo-optical (<b>a</b>) and electro-optical (<b>b</b>) MZIs.</p>
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<p>Introduced time delays against the voltage applied to the tuning contact for thermo-optical (<b>a</b>) and electro-optical (<b>b</b>) MRRs. A wavelength of 1550.4 nm was used for the calculation.</p>
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<p>OEO’s output frequency against the introduced time delay (<b>a</b>) and comparison of the results obtained from analytical calculations and simulations (<b>b</b>). The green dashed line represents a section of the frequency curve within the 2π phase incursion.</p>
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<p>Temperature compensation scheme. The red line represents heating, and the blue one represents cooling.</p>
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17 pages, 6346 KiB  
Article
Improving Efficiency of AB-Class Audio Power Amplifier Using Thermoelectric Generators
by Ivan Marinović and Ivan Škalic
Electronics 2025, 14(1), 34; https://doi.org/10.3390/electronics14010034 - 25 Dec 2024
Viewed by 289
Abstract
Since circuit-based solutions for increasing the efficiency of Class AB audio amplifiers have reached their peak, this article presents a non-circuit-based approach for the same purpose. The output transistors of this class of amplifiers dissipate a significant amount of thermal energy, resulting in [...] Read more.
Since circuit-based solutions for increasing the efficiency of Class AB audio amplifiers have reached their peak, this article presents a non-circuit-based approach for the same purpose. The output transistors of this class of amplifiers dissipate a significant amount of thermal energy, resulting in relatively low amplifier efficiency and requiring the transistors to be mounted on large heatsinks. This study was conducted with the aim of capturing the waste heat energy dissipated by the output transistors and converting it into electrical energy using thermoelectric generators (TEGs), which can then be used to increase the efficiency of the amplifier system. In addition to improving efficiency, this study aims to determine the extent to which heatsinks with smaller dimensions can be used in combination with the amplifier through the use of TEGs, potentially leading to a wider commercial application of Class AB audio amplifiers. The experimental results show that the thermoelectric conversion efficiency of TEGs reached 1.097% in the best case, indicating a potential increase of 0.275% in the overall efficiency of the amplifier system. These results show that the low thermoelectric efficiency of TEGs is a limiting factor that prevents a breakthrough in improving the efficiency of the power amplifier system with the proposed non-circuit-based approach. Full article
(This article belongs to the Section Semiconductor Devices)
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<p>Assembly diagram: 1. Power amplifier output transistors. 2. Silicone mica sheets. 3. Heat spreader. 4. Thermoelectric generator. 5. Heatsink.</p>
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<p>Practically implemented setup for thermoelectric conversion.</p>
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<p>Individually connected TEG during a 10 min operation of the amplifier: (<b>a</b>) Hot side temperature. (<b>b</b>) Generated power (energy) at the TEG load.</p>
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<p>Thermal series connection of TEGs during a 10 min operation of the amplifier: (<b>a</b>) Hot side temperature. (<b>b</b>) Total generated power (energy) at the TEG loads.</p>
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<p>Individually connected TEG in single-ended mode of TEG operation: (<b>a</b>) Hot side temperature. (<b>b</b>) Temperature difference.</p>
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<p>Thermal series connection of TEGs in single-ended mode of TEG operations: (<b>a</b>) Hot side temperature. (<b>b</b>) Temperature difference.</p>
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<p>Total generated power (energy) in single-ended mode of TEG operation(s) for different switching times, continuous (blue), 30 s (black), 60 s (red), and 120 s (green): (<b>a</b>) Individually connected TEG. (<b>b</b>) Thermal series connection of TEGs.</p>
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<p>Total generated power (energy) in push–pull mode of TEG(s) operation for different switching times, continuous (blue), 30 s (black), 60 s (red), and 120 s (green): (<b>a</b>) Individually connected TEG. (<b>b</b>) Thermal series connection of TEGs.</p>
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<p>Heatsinks used in measurements, labeled as heatsink #1, heatsink #2, and heatsink #3.</p>
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<p>Total generated energy in the push–pull mode of TEG(s) operation for 30 s switching: (<b>a</b>) Individually connected TEG. (<b>b</b>) Thermal series connection of TEGs.</p>
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<p>Total generated energy in the push–pull mode of TEG(s) operation for 60 s switching: (<b>a</b>) Individually connected TEG. (<b>b</b>) Thermal series connection of TEGs.</p>
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<p>Total generated energy in the push–pull mode of TEG(s) operation for 120 s switching: (<b>a</b>) Individually connected TEG. (<b>b</b>) Thermal series connection of TEGs.</p>
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<p>Total generated energy in the push–pull mode of TEG(s) operation in continuous mode: (<b>a</b>) Individually connected TEG. (<b>b</b>) Thermal series connection of TEGs.</p>
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14 pages, 2267 KiB  
Article
Pressure-Induced Assembly of Organic Phase-Change Materials Hybridized with Expanded Graphite and Carbon Nanotubes for Direct Solar Thermal Harvesting and Thermoelectric Conversion
by Jie Ji, Yizhe Liu, Xiaoxiang Li, Yangzhe Xu, Ting Hu, Zhengzheng Li, Peng Tao and Tao Deng
Nanomaterials 2024, 14(24), 2047; https://doi.org/10.3390/nano14242047 - 21 Dec 2024
Viewed by 469
Abstract
Direct harvesting of abundant solar thermal energy within organic phase-change materials (PCMs) has emerged as a promising way to overcome the intermittency of renewable solar energy and pursue high-efficiency heating-related applications. Organic PCMs, however, generally suffer from several common shortcomings including melting-induced leakage, [...] Read more.
Direct harvesting of abundant solar thermal energy within organic phase-change materials (PCMs) has emerged as a promising way to overcome the intermittency of renewable solar energy and pursue high-efficiency heating-related applications. Organic PCMs, however, generally suffer from several common shortcomings including melting-induced leakage, poor solar absorption, and low thermal conductivity. Compounding organic PCMs with single-component carbon materials faces the difficulty in achieving optimized comprehensive performance enhancement. Herein, this work reports the employment of hybrid expanded graphite (EG) and carbon nanotubes (CNTs) to simultaneously realize leakage-proofness, high solar absorptance, high thermal conductivity, and large latent heat storage capacity. The PCM composites were prepared by directly mixing commercial high-temperature paraffin (HPA) powders, EG, and CNTs, followed by subsequent mechanical compression molding. The HPA-EG composites loaded with 20 wt% of EG could effectively suppress melting-induced leakage. After further compounding with 1 wt% of CNTs, the form-stable HPA-EG20-CNT1 composites achieved an axial and in-plane thermal conductivity of 4.15 W/m K and 18.22 W/m K, and a melting enthalpy of 165.4 J/g, respectively. Through increasing the loading of CNTs to 10 wt% in the top thin layer, we further prepared double-layer HPA-EG-CNT composites, which have a high surface solar absorptance of 92.9% for the direct conversion of concentrated solar illumination into storable latent heat. The charged composites could be combined with a thermoelectric generator to release the stored latent heat and generate electricity, which could power up small electric devices such as light-emitting diodes. This work demonstrates the potential for employing hybrid fillers to optimize the thermophysical properties and solar thermal harvesting performances of organic PCMs. Full article
(This article belongs to the Special Issue Nano-Based Advanced Thermoelectric Design)
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<p>Pressure-induced assembly of organic PCM hybridized with EG and CNT for high-performance direct solar thermal energy harvesting and thermoelectric conversion.</p>
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<p>(<b>a</b>) Schematic showing the preparation process of PCM composites through pressure-induced assembly. (<b>b</b>) Schematic structure of PCM composites. (<b>c</b>,<b>d</b>) SEM images of EG at low and high magnification. (<b>e</b>) SEM image showing adsorption of 20 wt% of HPA within EG after heating treatment. (<b>f</b>,<b>g</b>) SEM image of HPA-EG20-CNT1 composites at low and high magnification. (<b>h</b>) SEM image showing agglomeration of CNTs within the HPA-EG20-CNT2 composites.</p>
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<p>(<b>a</b>) Photographs comparing anti-leakage performance of HPA and HPA-EG composites with different loadings of EG. (<b>b</b>) Mass retention rate of HPA-EG composites during leakage tests. (<b>c</b>) Photographs showing leakage-proofness of HPA-EG20-CNT composites. (<b>d</b>) Axial and in-plane thermal conductivity of HPA-EG and HPA-EG-CNT composites. (<b>e</b>) Schematic showing enhancement of heat conduction of HPA-EG composites through further compounding with CNTs.</p>
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<p>(<b>a</b>) Endothermic DSC curves of HPA, HPA-EG20, and HPA-EG20-CNT composites. (<b>b</b>) Peak, onset, and offset melting temperature of HPA, HPA-EG20, and HPA-EG20-CNT composites. (<b>c</b>) Melting enthalpy of HPA, HPA-EG20, and HPA-EG20-CNT composites. (<b>d</b>) DSC curves of HPA-EG20-CNT1 composites before and after cycled melting/solidification.</p>
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<p>(<b>a</b>) Photograph of HPA-EG20 composites showing gray surfaces. (<b>b</b>) Photograph of double-layer structure HPA-EG20-CNT1-D composites. (<b>c</b>) Schematic structure of HPA-EG20-CNT1-D composites. (<b>d</b>) Optical absorption spectra of HPA-EG and HPA-EG-CNT composites. (<b>e</b>) Schematics comparing solar absorption by HPA, HPA-EG20, and HPA-EG20-CNT1-D composites.</p>
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<p>(<b>a</b>) Schematic of experimental setup for evaluating direct solar thermal harvesting performance. (<b>b</b>) Time-sequential infrared images showing charging process of HPA, HPA-EG20, and HPA-EG20-CNT composites. (<b>c</b>) Temperature evolution profiles during solar thermal charging and natural cooling discharging processes.</p>
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<p>(<b>a</b>) Schematic experimental setup for releasing solar thermal energy stored within HPA-EG20-CNT1-D composites and thermoelectric conversion. (<b>b</b>) Temperature evolution profile and corresponding output voltage during discharging. (<b>c</b>) Time-sequential photographs showing lighting up an LED bulb with generated electrical output.</p>
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19 pages, 8661 KiB  
Article
Thermoelectric Generator-Powered Long-Range Wireless Real-Time Steam Leak Detection in Steam Traps
by Raúl Aragonés, Joan Oliver and Carles Ferrer
Future Internet 2024, 16(12), 474; https://doi.org/10.3390/fi16120474 - 19 Dec 2024
Viewed by 314
Abstract
This paper introduces a novel thermoelectric generator (TEG)-powered Industrial Internet of Things (IIoT) device that addresses key limitations in the detection of steam leaks in industrial steam pipelines, particularly in steam traps. Existing solutions often rely on battery-powered or wired sensors, which are [...] Read more.
This paper introduces a novel thermoelectric generator (TEG)-powered Industrial Internet of Things (IIoT) device that addresses key limitations in the detection of steam leaks in industrial steam pipelines, particularly in steam traps. Existing solutions often rely on battery-powered or wired sensors, which are limited by high maintenance costs, short lifespans, or significant infrastructure investments. The proposed device operates without batteries, using waste heat to provide continuous power, and leverages LoRaWAN for long-range wireless communication, minimizing reliance on costly internal infrastructure. Additionally, the device integrates temperature differential (ΔT) and ultrasonic sensors with edge computing capabilities to enhance real-time leak detection and reduce dependency on cloud computing. By enabling precise, low-maintenance monitoring of steam systems in energy-intensive industries (e.g., petrochemical, pharmaceutical), this technology can significantly reduce energy losses, operational costs, and greenhouse gas emissions. Initial testing demonstrates the device’s ability to detect leaks accurately under varying industrial conditions, offering a robust, scalable solution for Industry 4.0 applications. Full article
(This article belongs to the Special Issue Wireless Sensor Networks in the IoT)
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<p>Arctic ice melting according to citizenship.</p>
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<p>Steam circuit composed of the boiler, steam pipeline, and steam trap.</p>
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<p>Napier’s equation representing steam loss in Kg per hour.</p>
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<p>Proposed scenario from the heat-powered IoT device to the cloud platform.</p>
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<p>The heat-powered IIoT device is composed of three modules; rendered (<b>a</b>) and real (<b>b</b>).</p>
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<p>Thermoelectric Peltier housing for the pipeline (<b>a</b>) and radiator (<b>b</b>) to increase the ΔT.</p>
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<p>Heat propagation considering 150 °C of heat in the pipeline.</p>
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<p>DC/DC up-converter model to stabilize the output voltage at 3.3 V.</p>
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<p>(<b>a</b>) Main board location. (<b>b</b>) Main board diagram.</p>
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<p>Main board with the data processing and communication subsystem (<b>top figure</b>) and the DC/DC conversion and TEG power maximization (<b>below figure</b>).</p>
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<p>The main board is soldered with all components ready for testing.</p>
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<p>Main algorithm.</p>
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<p>(<b>a</b>) The test bench. (<b>b</b>) Device under test.</p>
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<p>Open-circuit voltage characteristics with a set of hot and cold surface temperatures.</p>
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<p>Power generation characteristics with a set of hot and cold surface temperatures.</p>
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<p>(<b>a</b>) Test of buoy steam trap. (<b>b</b>) The gateway. (<b>c</b>) Test of the thermodynamic steam trap.</p>
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<p>Steam leak detection using delta temperatures between inlet and outlet.</p>
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<p>Steam leak frequencies between 30 kHz and 40 kHz.</p>
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<p>Steam leak frequencies between 10 kHz and 40 kHz.</p>
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11 pages, 1197 KiB  
Article
Ab Initio Investigation of the Mechanics and Thermodynamics of the Cubic EuAlO3 and GdAlO3 Perovskites for Optoelectronic Applications
by Adel Bandar Alruqi and Nicholas O. Ongwen
Crystals 2024, 14(12), 1084; https://doi.org/10.3390/cryst14121084 - 16 Dec 2024
Viewed by 567
Abstract
Perovskites are currently becoming common in the field of optoelectronics, owing to their promising properties such as electrical, optical, thermoelectric, and electronic. Although mechanical and thermal properties also play a crucial part in the functioning of the optoelectronic devices, they have scarcely been [...] Read more.
Perovskites are currently becoming common in the field of optoelectronics, owing to their promising properties such as electrical, optical, thermoelectric, and electronic. Although mechanical and thermal properties also play a crucial part in the functioning of the optoelectronic devices, they have scarcely been explored. The present work performed an ab initio study of the mechanical and thermal properties of the cubic EuAlO3 and GdAlO3 perovskites for the first time using density functional theory. Quantum Espresso and Themo_pw codes were utilized by employing the generalized gradient approximation. Although the results showed that both materials have good mechanical and thermal properties that are ideal for the above–mentioned applications, EuAlO3 possessed better structural and thermal stability, bulk modulus, Poisson ratio, thermal expansion coefficient, and thermal stress; while GdAlO3 possessed better Young’s modulus and shear modulus. Moreover, the mechanical properties of the two materials turned out to be much better than those of the common materials for optoelectronic applications, while their thermal properties were comparable to that of sapphire glass. Since this study was computational, an experimental verification of the computed properties of the two materials needs to be carried out before they can be commercialized. Full article
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<p>The 3D structures of <b>(a)</b> EuAlO<sub>3</sub> and <b>(b)</b> GdAlO<sub>3</sub>.</p>
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<p>Total energy per atom against unit cell volumes for both EuAlO<sub>3</sub> and GdAlO<sub>3</sub>.</p>
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<p>Elastic constants of EuAlO<sub>3</sub> and GdAlO<sub>3</sub> as functions of temperature.</p>
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<p>Thermal expansion coefficients of EuAlO<sub>3</sub> and GdAlO<sub>3</sub> as a function of temperature.</p>
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<p>Thermal stress of EuAlO<sub>3</sub> and GdAlO<sub>3</sub> as a function of temperature.</p>
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20 pages, 5421 KiB  
Article
A Miniaturized and Ultra-Low-Power Wireless Multi-Parameter Monitoring System with Self-Powered Ability for Aircraft Smart Skin
by Chongqi Wang, Yu Wang, Wei Pu and Lei Qiu
Sensors 2024, 24(24), 7993; https://doi.org/10.3390/s24247993 - 14 Dec 2024
Viewed by 376
Abstract
The aircraft smart skin (ASS) with structural health monitoring capabilities is a promising technology. It enables the real-time acquisition of the aircraft’s structural health status and service environment, thereby improving the performance of the aircraft and ensuring the safety of its operation, which [...] Read more.
The aircraft smart skin (ASS) with structural health monitoring capabilities is a promising technology. It enables the real-time acquisition of the aircraft’s structural health status and service environment, thereby improving the performance of the aircraft and ensuring the safety of its operation, which in turn reduces maintenance costs. In this paper, a miniaturized and ultra-low-power wireless multi-parameter monitoring system (WMPMS) for ASS is developed, which is capable of monitoring multiple parameters of an aircraft, including random impact events, vibration, temperature, humidity, and air pressure. The system adopts an all-digital monitoring method and a low-power operating mechanism, and it is integrated into a low-power hardware design. In addition, considering the airborne resources limitations, an energy self-supply module based on a thermoelectric generator (TEG) is developed to continuously power the system during flight. Based on the above design, the system has a size of only 45 mm × 50 mm × 30 mm and an average power consumption of just 7.59 mW. Through experimental validation, the system has excellent performance in multi-parameter monitoring and operating power consumption, and it can realize the self-supply of energy. Full article
(This article belongs to the Section Fault Diagnosis & Sensors)
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<p>Architecture of ASS-based multi-parameter monitoring of an aircraft.</p>
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<p>Basic principle of the digital sequence-based impact region localization method.</p>
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<p>Overall hardware architecture of the WMPMS.</p>
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<p>The developed WMPMS.</p>
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<p>Software architecture of the system.</p>
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<p>The thermoelectric conversion unit.</p>
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<p>Experimental setup of impact monitoring.</p>
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<p>Example of impact monitoring: (<b>a</b>) impact occurring in region 1; (<b>b</b>) digital sequences.</p>
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<p>Experimental setup of environmental monitoring verification.</p>
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<p>Vibration monitoring results: (<b>a</b>) WMPMS; (<b>b</b>) accelerometer.</p>
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<p>Temperature monitoring results.</p>
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<p>Humidity monitoring results.</p>
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<p>Air pressure monitoring results.</p>
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<p>Schematic diagram of the energy self-supply verification setup.</p>
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<p>Physical diagram of the energy self-supply verification setup.</p>
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<p>Verification results of the thermoelectric generator.</p>
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<p>Energy recovery results.</p>
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<p>Multi-parameter monitoring of the composite UAV wing.</p>
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<p>PZT placement on the impact monitoring regions.</p>
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22 pages, 3843 KiB  
Article
Performance Improvement of the LNG Regasification Process Based on Geothermal Energy Using a Thermoelectric Generator and Energy and Exergy Analyses
by Amin Mohammadi and Akbar Maleki
Sustainability 2024, 16(24), 10881; https://doi.org/10.3390/su162410881 - 12 Dec 2024
Viewed by 498
Abstract
In this paper, a new approach is proposed to improve the performance of the LNG regasification process in a geothermal-transcritical CO2–LNG cycle by using thermoelectric generators. Energy and exergy analyses were applied to the proposed system and the plant’s performance is [...] Read more.
In this paper, a new approach is proposed to improve the performance of the LNG regasification process in a geothermal-transcritical CO2–LNG cycle by using thermoelectric generators. Energy and exergy analyses were applied to the proposed system and the plant’s performance is compared with the conventional CO2–LNG cycle. To achieve the optimal solution for the system, a multi-objective optimization technique based on a genetic algorithm is used. This study’s findings revealed that in the conventional CO2–LNG cycle, the highest exergy destruction occurs in the preheater. However, integrating a thermoelectric generator allows a portion of this destroyed exergy to be converted into power. The proposed system demonstrated 2% less exergy destruction compared to the conventional system. Moreover, the TEG contributes additional power, increasing the net output power of the system by 24%. This improvement ultimately enhances the overall exergy efficiency of the system. The analysis also concluded that, although a lower LNG mass flow rate reduces the system’s net power output, it improves the exergy efficiency. Overall, the proposed system exhibits an 8.37% higher exergy efficiency and a 24.22% greater net output power compared to the conventional CO2–LNG cycle. Full article
(This article belongs to the Section Energy Sustainability)
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<p>Conventional integration of the transcritical CO<sub>2</sub> cycle and LNG.</p>
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<p>Schematic diagram of the new system proposed.</p>
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<p>The EDR of different equipment in conventional systems and the proposed system.</p>
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<p>Comparison of the share of each equipment in the total exergy destruction of conventional systems and the proposed system.</p>
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<p>Total exergy efficiency and NOP vs. CO<sub>2</sub> TIT.</p>
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<p>Generated power vs. inlet temperature of the CO<sub>2</sub> turbine.</p>
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<p>Exergy efficiency and NOP vs. the inlet pressure of the CO<sub>2</sub> turbine.</p>
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<p>Scheme performance vs. condenser pressure.</p>
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<p>Power production vs. condenser pressure.</p>
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<p>System performance vs. the minimum temperature difference in the condenser.</p>
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<p>Mass flow rate variation and power generation vs. the minimum temperature difference in the condenser.</p>
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<p>System performance vs. the TEG outlet temperature.</p>
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<p>System performance vs. the minimum temperature difference in the preheater.</p>
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<p>Pareto front for the new proposed system.</p>
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15 pages, 5160 KiB  
Article
Powering Agriculture IoT Sensors Using Natural Temperature Differences Between Air and Soil: Measurement and Evaluation
by Kamil Bancik, Jaromir Konecny, Jiri Konecny, Miroslav Mikus, Jan Choutka, Radim Hercik, Jiri Koziorek, Dangirutis Navikas, Darius Andriukaitis and Michal Prauzek
Sensors 2024, 24(23), 7687; https://doi.org/10.3390/s24237687 - 30 Nov 2024
Viewed by 916
Abstract
As the need to monitor agriculture parameters intensifies, the development of new sensor nodes for data collection is crucial. These sensor types naturally require power for operation, but conventional battery-based power solutions have certain limitations. This study investigates the potential of harnessing the [...] Read more.
As the need to monitor agriculture parameters intensifies, the development of new sensor nodes for data collection is crucial. These sensor types naturally require power for operation, but conventional battery-based power solutions have certain limitations. This study investigates the potential of harnessing the natural temperature gradient between soil and air to power wireless sensor nodes deployed in environments such as agricultural areas or remote off-grid locations where the use of batteries as a power source is impractical. We evaluated existing devices that exploit similar energy sources and applied the results to develop a state-of-the-art device for extensive testing over a 12-month period. Our main objective was to precisely measure the temperature on a thermoelectric generator (TEG) (a Peltier cell, in particular) and assess the device’s energy yield. The device harvested 7852.2 J of electrical energy during the testing period. The experiment highlights the viability of using environmental temperature differences to power wireless sensor nodes in off-grid and battery-constrained applications. The results indicate significant potential for the device as a sustainable energy solution in agricultural monitoring scenarios. Full article
(This article belongs to the Special Issue Energy Harvesting and Machine Learning in IoT Sensors)
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<p>Concept of an energy-harvesting IoT sensor powered by the natural temperature differences between air and soil. Batteryless sensors are powered with harvested energy, and measurement data are transmitted to the cloud.</p>
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<p>The principle of converting the heat flux generated by the temperature difference between the ground and the ambient air using a TEG.</p>
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<p>Prototype of energy-harvesting device: (<b>a</b>) photograph in profile (<b>b</b>) cross-sectional drawing.</p>
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<p>Measurement setup block diagram depicting the data acquisition unit and NI components for collecting temperature data from the prototype.</p>
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<p>Sensor calibration in a climate chamber to improve temperature measurement accuracy.</p>
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<p>The energy-harvesting device deployed at the experiment site. The upper part of the prototype is shown, with a heat sink and its ambient temperature sensor equipped with a radiation shield.</p>
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<p>Day temperature curves from T1–T7 PT100 sensors.</p>
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<p>Daily average of the absolute temperature difference and power output on the TEG during the measurement period.</p>
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<p>Monthly distribution of energy harvested by the TEG, categorized according to the direction of heat flow through the energy-harvesting device prototype.</p>
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<p>Simulated quantity of energy after conversion by the LTC3109 DC/DC converter according to its efficiency curve, divided by the monthly contributions and heat flow direction through the energy-harvesting device prototype.</p>
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21 pages, 6506 KiB  
Article
Performance and Reliability of Thermoelectric Conversion Using a Crooked Thermosyphon to Enhance Heat Transfer from Coal Fires
by Qingfeng Bao, Xiuting Guo, Bo Li, Wuyi Chen, Zhenping Wang and Yang Xiao
Processes 2024, 12(12), 2692; https://doi.org/10.3390/pr12122692 - 29 Nov 2024
Viewed by 546
Abstract
A large amount of energy can accumulate and be stored during underground coal fires. As thermal energy cannot be easily removed using the traditional technologies of fire prevention and extinguishment, there is a potential benefit to collecting and utilizing thermal energy from coal [...] Read more.
A large amount of energy can accumulate and be stored during underground coal fires. As thermal energy cannot be easily removed using the traditional technologies of fire prevention and extinguishment, there is a potential benefit to collecting and utilizing thermal energy from coal fires and converting it to electrical energy. Thus, this work proposes a thermoelectric generator as a solution to convert thermal energy from coal fires to electrical energy. To improve the thermal energy conversion efficiency, an experimental test system was established using a thermosyphon, an electric heating module, a cooling circulation module, a thermoelectric module, and a data acquisition module. Under the condition of ensuring the same input heat and cooling boundary conditions, the influence of three factors, namely the cooling method, the connection method, and the coverage rate of thermoelectric devices, on the performance of the coal fire waste heat conversion system was studied. The results show that, compared with air cooling, water cooling provides a greater temperature difference for the thermoelectric module, and the maximum temperature difference can reach 65.90 °C. Series connection between thermoelectric devices will generate a higher open-circuit voltage and output voltage. The maximum horizontal open-circuit voltage value can reach 3.34 V, and the maximum output voltage is 2.61 V. Compared with the coverage rates of thermoelectric devices of 15.0% and 30.0%, the output power under the coverage rate of 22.5% is the largest at 0.35 W, and its thermoelectric conversion efficiency is also the largest at 0.35%. The optimal combination of thermoelectric modules obtained from the research results can provide ideas for the application of in situ coal fire prevention and control. Full article
(This article belongs to the Special Issue Advances in Coal Processing, Utilization, and Process Safety)
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<p>Physical picture of thermoelectric performance test system of coal fire waste heat conversion system.</p>
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<p>Physical picture of the sleeve-type heat-conducting copper block.</p>
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<p>The physical pictures of the heating wire and the power regulator. (<b>a</b>) The heating wire. (<b>b</b>) The power regulator.</p>
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<p>The data acquisition device Keysight DAQ970A.</p>
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<p>Schematic diagram of the thermoelectric device coverages. (<b>a</b>) 15.0% coverage rate. (<b>b</b>) 22.5% coverage rate. (<b>c</b>) 30.0% coverage rate.</p>
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<p>Schematic diagram of thermoelectric performance test system of coal fire waste heat conversion system.</p>
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<p>Variation in wall temperature in the condensing section and the thermoelectric device’s hot end temperature. (<b>a</b>) Air-cooled mode and (<b>b</b>) water-cooled mode.</p>
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<p>Variation in wall temperature in the condensing section and the thermoelectric device’s hot end temperature. (<b>a</b>) Air-cooled mode and (<b>b</b>) water-cooled mode.</p>
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<p>Temperature difference diagram of thermoelectric module with (<b>a</b>) air-cooled and (<b>b</b>) water-cooled modes.</p>
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<p>Open-circuit voltage under different thermoelectric device coverage rates. (<b>a</b>) 15.0% coverage rate. (<b>b</b>) 22.5% coverage rate. (<b>c</b>) 30.0% coverage rate.</p>
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<p>Output voltage at different levels under (<b>a</b>) series connection and (<b>b</b>) parallel connection.</p>
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<p>Nominal power at different levels under (<b>a</b>) series connection and (<b>b</b>) parallel connection.</p>
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<p>Temperature distribution of components of coal fire waste heat conversion system.</p>
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<p>Heat transfer resistance distribution of coal fire waste heat conversion system.</p>
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<p>Open-circuit voltage of thermoelectric module.</p>
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<p>System’s output voltage and nominal power with different coverage rates. (<b>a</b>) Output voltage, and (<b>b</b>) output power.</p>
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19 pages, 3804 KiB  
Article
Assessment of Wind Energy Potential Generated by Vehicles: A Case Study in Mexico
by Luis Alfonso Moreno-Pacheco, Leopoldo José Luis Sánchez-Hueto, Juan Gabriel Barbosa-Saldaña, José Martínez-Trinidad, Miguel Toledo-Velázquez and Ricardo Andrés García-León
Designs 2024, 8(6), 126; https://doi.org/10.3390/designs8060126 - 26 Nov 2024
Viewed by 676
Abstract
This research focuses on analyzing the aerodynamic characteristics of residual air currents generated by vehicle movement and evaluating their feasibility for energy generation, then designing a vertical axis wind turbine. The parameters assessed include the characteristic velocity profile, the average and maximum velocities, [...] Read more.
This research focuses on analyzing the aerodynamic characteristics of residual air currents generated by vehicle movement and evaluating their feasibility for energy generation, then designing a vertical axis wind turbine. The parameters assessed include the characteristic velocity profile, the average and maximum velocities, disturbance lifetimes, as well as the frequency and probability of recurrence of these disturbances. Using the data, projections are made on the electrical energy amount that can be produced by a wind turbine operating under such wind conditions. Measurements were taken at four locations: three within Mexico City (CDMX) and one on the outskirts. The measurement station, consisting of a 2.35 m vertical tower equipped with eight vertically aligned thermos-resistive anemometers, is installed on medians less than 0.50 m from moving vehicles. The data from within CDMX show maximum wind velocities ranging from 6 to 8 m/s at ground level, while measurements on the outskirts record velocities of up to 19.5 m/s. A probabilistic analysis reveals that usable air currents could be present 58% of the time. Based on electrical production calculations, it is estimated that harnessing this residual energy could power approximately 4500 homes, considering the national cost per kWh and the average electricity consumption of a four-person household. Full article
(This article belongs to the Topic Building Energy and Environment, 2nd Edition)
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<p>(<b>a</b>) Measuring device system at different locations and environmental conditions. Own image. Side photographs: Calle Miguel Bernard; central: Av. Ribera de San Cosme. (<b>b</b>) Data acquisition system.</p>
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<p>Primary velocity fluctuation mapping. (<b>a</b>) August 15–14:10 h—Av. Ribera de San Cosme, 24 °C, RH 53%, 1009 hPa—maximum velocity 11.856 m/s—average velocity 2.49 m/s; (<b>b</b>) August 16–20:45 h—Av. Ribera de San Cosme, 20 °C, RH 65%, 1008 hPa—maximum velocity 8.977 m/s—average velocity 1.32 m/s; (<b>c</b>) August 17–14:00 h—Av. Ribera de San Cosme, 26 °C, RH 49%, 1009 hPa—maximum velocity 7.733 m/s—average velocity 1.91 m/s.</p>
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<p>Velocity profiles taken randomly from the sampling carried out on the CDMX-QRO highway. Measurement of the median strip on the side adjacent to the high-velocity lane.</p>
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<p>Visualization of pulsating flow patterns.</p>
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<p>Visualization of pulsating wake-type flow patterns.</p>
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<p>Visualization of intense pulsating flow patterns, without apparent wake.</p>
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<p>Velocity profile referring to the measurement section considering the actual positions of the measurement points (1.75 m).</p>
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<p>Relative frequency distribution with a splice of Weibull frequency distribution plot.</p>
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<p>Power curves developed considering a vertical axis wind turbine.</p>
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<p>Helical Savonius rotor model.</p>
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<p>Process of visualization of modification of a Savonius helical rotor.</p>
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<p>Representation of the modified 2- and 3-blade rotors. (<b>a</b>) Isometric view, (<b>b</b>) lateral view, and (<b>c</b>) top and bottom views.</p>
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11 pages, 10254 KiB  
Article
Modulation of BixSb2−xTe3 Alloy Application Temperature via Optimizing Material Composition
by Shifang Ma, Jianan Li, Daming Du, Xuefeng Ruan, Ming Cao, Ming Lin, Qiongxin Hua, Qi Luo, Ping Tang, Jinzhao Guan and Jian Yu
Materials 2024, 17(23), 5751; https://doi.org/10.3390/ma17235751 - 24 Nov 2024
Viewed by 624
Abstract
Bi2Te3-based alloys are representatively commercialized thermoelectric materials for refrigeration and power generation. Refrigeration mainly utilizes thermoelectric properties near room temperature, while the power generation temperature is relatively high. However, it is difficult for bismuth telluride to maintain good thermoelectric [...] Read more.
Bi2Te3-based alloys are representatively commercialized thermoelectric materials for refrigeration and power generation. Refrigeration mainly utilizes thermoelectric properties near room temperature, while the power generation temperature is relatively high. However, it is difficult for bismuth telluride to maintain good thermoelectric properties throughout the entire temperature range of 300–500 K. Herein, a series of BixSb2−xTe3 alloys with different Bi contents were prepared by a simple preparation method and systematically investigated, and their best application temperature range was found. The Bi content can modulate carrier concentration and band gap, and the maximum dimensionless figure of merit (ZT) value of BixSb2−xTe3 can be achieved in the corresponding application temperature range. The maximum ZT of Bi0.3Sb1.7Te3 with a Bi content equal to 0.3 reaches 1.14 at 400 K, and the average ZT is 1.06 in the range of 300–500 K, which is suitable for both power generation and refrigeration. Therefore, power generation technologies with higher application temperatures should be selected from BixSb2−xTe3 materials with Bi content less than 0.3, and refrigeration technologies with lower application temperatures should be selected with Bi content greater than 0.3. This work provides experimental guidance for finding the composition of Bi2Te3-based alloys in scientific research and practical applications. Full article
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<p>(<b>a</b>) XRD patterns of sintered Bi<span class="html-italic"><sub>x</sub></span>Sb<sub>2−<span class="html-italic">x</span></sub>Te<sub>3</sub> materials. (<b>b</b>) The expanded view of XRD in the range of 45–60°. (<b>c</b>) Lattice parameters of sintered Bi<span class="html-italic"><sub>x</sub></span>Sb<sub>2−<span class="html-italic">x</span></sub>Te<sub>3</sub> materials.</p>
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<p>(<b>a</b>) Backscattered electron image of Bi<sub>0.4</sub>Sb<sub>1.6</sub>Te<sub>3</sub>. (<b>b</b>–<b>d</b>) WDS elemental mapping of Bi, Sb, and Te elements, respectively.</p>
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<p>(<b>a</b>–<b>e</b>) Backscattered electron images of Bi<span class="html-italic"><sub>x</sub></span>Sb<sub>2−<span class="html-italic">x</span></sub>Te<sub>3</sub> materials. (<b>f</b>) Density of Bi<span class="html-italic"><sub>x</sub></span>Sb<sub>2−<span class="html-italic">x</span></sub>Te<sub>3</sub> materials.</p>
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<p>Temperature dependencies of (<b>a</b>) electrical conductivity, (<b>b</b>) carrier concentration, (<b>c</b>) Hall mobility, (<b>d</b>) Seebeck coefficient, (<b>e</b>) Hall coefficient, and (<b>f</b>) a power factor for Bi<span class="html-italic"><sub>x</sub></span>Sb<sub>2−<span class="html-italic">x</span></sub>Te<sub>3</sub> materials. The inset in (<b>c</b>) is log(<span class="html-italic">μ</span><sub>H</sub>) versus log(T).</p>
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<p>Temperature dependence of (<b>a</b>) thermal conductivity, (<b>b</b>) carrier thermal conductivity, (<b>c</b>) lattice thermal conductivity, and (<b>d</b>) <span class="html-italic">ZT</span> for Bi<span class="html-italic"><sub>x</sub></span>Sb<sub>2−<span class="html-italic">x</span></sub>Te<sub>3</sub> materials.</p>
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18 pages, 2873 KiB  
Article
Improving Resistive Heating, Electrical and Thermal Properties of Graphene-Based Poly(Vinylidene Fluoride) Nanocomposites by Controlled 3D Printing
by Rumiana Kotsilkova, Vladimir Georgiev, Mariya Aleksandrova, Todor Batakliev, Evgeni Ivanov, Giovanni Spinelli, Rade Tomov and Tsvetozar Tsanev
Nanomaterials 2024, 14(22), 1840; https://doi.org/10.3390/nano14221840 - 17 Nov 2024
Viewed by 977
Abstract
This study developed a novel 3D-printable poly(vinylidene fluoride) (PVDF)-based nanocomposite incorporating 6 wt% graphene nanoplatelets (GNPs) with programmable characteristics for resistive heating applications. The results highlighted the significant effect of a controlled printing direction (longitudinal, diagonal, and transverse) on the electrical, thermal, Joule [...] Read more.
This study developed a novel 3D-printable poly(vinylidene fluoride) (PVDF)-based nanocomposite incorporating 6 wt% graphene nanoplatelets (GNPs) with programmable characteristics for resistive heating applications. The results highlighted the significant effect of a controlled printing direction (longitudinal, diagonal, and transverse) on the electrical, thermal, Joule heating, and thermo-resistive properties of the printed structures. The 6 wt% GNP/PVDF nanocomposite exhibited a high electrical conductivity of 112 S·m−1 when printed in a longitudinal direction, which decreased significantly in other directions. The Joule heating tests confirmed the material’s efficiency in resistive heating, with the maximum temperature reaching up to 65 °C under an applied low voltage of 2 V at a raster angle of printing of 0°, while the heating Tmax decreased stepwise with 10 °C at the 45° and the 90° printing directions. The repeatability of the Joule heating performance was verified through multiple heating and cooling cycles, demonstrating consistent maximum temperatures across several tests. The effect of sample thickness, controlled by the number of printed layers, was investigated, and the results underscore the advantages of programmable 3D printing orientation in thin layers for enhanced thermal stability, tailored electrical conductivity, and efficient Joule heating capabilities of 6 wt% GNP/PVDF composites, positioning them as promising candidates for next-generation 3D-printed electronic devices and self-heating applications. Full article
(This article belongs to the Special Issue Hybrid Nano Polymer Composites (2nd Edition))
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<p>TEM images: (<b>a</b>) GNP filler surfaces with SEAD pattern (inset); (<b>b</b>) high-resolution TEM image of the GNP thickness showing the multi-layered structure of oriented graphene monolayers; and (<b>c</b>) exfoliated GNP nanostructures dispersed in the PVDF matrix. Arrows show the thickness of the exfoliated GNPs.</p>
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<p>Thermal properties of PVDF and 6 wt% GNP/PVDF: DSC thermograms of heat flow vs. temperature at a scan rate of 10 °C/min, showing the first heating run (<b>a</b>), cooling cycle (<b>b</b>), and second heating run (<b>c</b>). The dash lines point the thermal transitions of the neat PVDF. In (<b>d</b>), the TGA/DTG thermograms of mass loss vs. temperature for the polymer and the nanocomposite are plotted, while the GNP thermogram is presented in the inset figure.</p>
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<p>SEM micrographs of the cut surface of samples with different deposition directions: (<b>a</b>) longitudinal (3DP 0°); (<b>b</b>) diagonal (3DP 45°); (<b>c</b>) transverse (3DP 90°); and (<b>d</b>) voltage vs. current dependence, varying the printing directions. The magnification bar is 1 mm. The arrows show the current flow direction.</p>
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<p>Comparison of (<b>a</b>) temperature vs. time and (<b>b</b>) temperature increase and heat vs. electrical conductivity of 6 wt% GNP/PVDF, varying the 3D printing directions—3DP 0°, 3DP 45°, and 3DP 90°—for 2 mm thick samples at an applied voltage of 2 V.</p>
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<p>Temperature vs. time for four-cycle heating–cooling test of 6 wt% GNP/PVDF samples at an applied voltage of 2 V with various printing directions: (<b>a</b>) longitudinal 3DP 0°, (<b>b</b>) diagonal 3DP 45°, and (<b>c</b>) transverse 3DP 90°. (<b>d</b>) Repeatability of the maximal temperature and current in the four heating–cooling cycles for the three printing directions.</p>
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<p>Temperature and current vs. time for 6 wt% GNP/PVDF, for the diagonally printed samples (3DP 45°) with (<b>a</b>) 4 printed layers (0.8 mm thick) and (<b>b</b>) 10 printed layers (2 mm thick), varying the applied voltage.</p>
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<p>Comparison of (<b>a</b>) maximum heating temperature and current vs. applied voltage and (<b>b</b>) generated heat and heating efficiency vs. power for the 3DP45° samples of the 6 wt% GNP/PVDF nanocomposite, with a controlled number of printed layers (4 layers, 0.8 mm thick; and 10 layers, 2 mm thick).</p>
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<p>Resistance vs. temperature of the 6 wt% GNP/PVDF composites with various printing directions of 3DP 0°, 3DP 45°, and 3DP 90°.</p>
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<p>Thermal diffusivity and conductivity of the 3DP samples of 6 wt% GNP/PVDF vs. temperature, with various printing directions.</p>
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