Search Results (20)

Nitrogen foam is a promising enhanced oil recovery (EOR) technique with significant potential for tertiary oil recovery. This improves the efficiency of the oil displacement during the gas drive processes while expanding the swept volume. However, in the high-temperature, high-salinity reservoirs of the Tahe Oilfield, conventional N₂ foam systems show suboptimal performance, as their effectiveness is heavily limited by temperature and salinity. Consequently, enhancing the foam stability under these harsh conditions is crucial for unlocking new opportunities for the development of Tahe fracture-vuggy reservoirs. In this study, the Waring–Blender method was used to prepare weathered coal particles as a foam stabilizer. Compared to conventional foam stabilizers, weathered coal particles were found to enhance the stability of the liquid film under high-temperature and high-salinity conditions. Firstly, the foaming properties of the six foaming agents were comprehensively evaluated and their foaming properties were observed at different concentrations. YL-3J with a mass concentration of 0.7% was selected. The foaming stabilization performance of four types of solid particles was evaluated and weathered coal solid particles with a mass concentration of 15% and particle size of 300 mesh were selected. Therefore, the particle-reinforced foam system was determined to consist of “foaming agent YL-3J (0.7%) + weathered coal (15.0%) + nitrogen”. This system exhibited a foaming volume of 310 mL at 150 °C and salinity of 210,000 mg/L, with a half-life of 1920 s. Finally, through interfacial tension and viscoelastic modulus tests, the synergistic mechanism between weathered coal particles and surfactants was demonstrated. The incorporation of weathered coal particles reduced the interfacial tension of the system. The formation of a skeleton at the foam interface increased the apparent viscosity and viscoelastic modulus, reduced the liquid drainage rate from the foam, and mitigated the disproportionation effect. These effects enhanced the temperature, salinity resistance, and stability of the foam. Consequently, they contributed to the stable flow of foam under high-temperature and high-salinity conditions in the reservoir, thereby improving the oil displacement efficiency of the system. Full article

Following open-pit coal mining in the Powder River Basin, landscape reconstruction includes the construction of backfill aquifers from overburden waste rock. With overburden disaggregation and the re-introduction of groundwater, the weathering of newly available mineral surfaces and mobilization of nanomaterials can impact groundwater quality even when such issues were not previously detected in the overburden’s groundwater. Kinetic columns of Powder River Basin waste rock were used to evaluate backfill construction options—zeolite amendment, and soil amendment, compaction, rinse—that could reduce potential groundwater quality impacts. The leachate from each column was collected twice weekly for 20 weeks. The Eh and pH of the leachate substantially varied during an initial high-weathering period indicative of the traditional weathering of newly exposed mineral surfaces and the weathering and flushing of mobile particles. Correspondingly, select elements, such as arsenic and cadmium, were present in relatively high concentrations during this initial weathering period. Waste rock that was compacted or rinsed produced leachate with less solutes and potential contaminants when compared to the unaltered and zeolite- and soil-amended waste rock. Greater compaction during backfilling is possible but may require additional consideration for connecting the surface drainage network to the surrounding area. Rinsing of the waste rock is a viable construction option because of the temporary storage of the waste rock prior to backfilling but would require leachate collection for contaminant treatment. Full article

Historical coal mining practices have caused various soil and water hazards, particularly through the dumping of mine waste. The primary environmental risk associated with this waste is the leaching of toxic metals from dumps of spoil or refuse into the subsurface soil or into nearby water resources. The extent of metal release is controlled via the oxidative dissolution of pyrite and potential re-sequestration through secondary Fe oxides. The characterization of the dominant Fe-bearing phase and the distribution of trace metals associated with these phases was determined via electron microscopy, synchrotron-based X-ray micro-fluorescence (μ-XRF) element and redox mapping from shallow mine soils from an impacted watershed in Appalachian Ohio. The dominant Fe-bearing phases were: (1) unweathered to partially weathered pyrite; (2) pseudomorphic replacement of pyrite with Fe(III) oxides; (3) fine-grained Fe oxide surface coatings; and (4) discrete Fe(III) oxide grains. Thicker secondary coatings and larger particles were sulfate rich, whereas smaller grains and thinner coatings were sulfate poor. The discrete Fe oxide grains exhibited the highest concentrations of Cr, Mn, Ni, and Cu, and sub-grain-scale concentration trends (Mn > Cr > Ni > Cu) were consistent with bulk soil properties. Predicting future metal transport requires an understanding of metal speciation and distribution from the sub-grain scale to the pedon scale. Full article

Restoration of open-pit mines may utilize waste rock for landscape reconstruction, which can include the construction of backfill aquifers. Weathering and contaminant transport may be different in backfill aquifers compared to the surrounding aquifer because of newly available mineral surfaces and transportable nano- to micro-scale particles generated during mining. Waste rock from the Cordero Rojo open-pit coal mine in the Powder River Basin was exposed to benchtop leachate experiments for 20 weeks at temperatures of 5 °C and 20 °C. Collected leachate was analyzed for Eh, pH, specific conductance, alkalinity, and cation and anion concentrations as unfiltered and 0.45-μm and 0.2-μm filtered concentrations. During the experiment, leachate Eh and pH substantially varied during the first 55 days, which corresponds to a period of high specific conductance (>1000 µS/cm) and alkalinity (>200 mg/L). Correspondingly, anion and cation concentrations were the largest during this early weathering stage, and the filter fractions indicated multiple forms of transported elements. After this early weathering stage, column leachate evolved towards a weathering equilibrium of neutral, oxidizing, and low solute conditions indicated by positive Eh values, pH near 7, and specific conductance <500 μS/cm. This evolution was reflected in the decline and stabilization or non-detection of metal(loid) concentrations reflective of a shift to primarily bulk aluminosilicate weathering when coal- and salt-associated elements, such as arsenic, cadmium, and selenium, were not detected or at minimal concentrations. Over the course of the experiment, the solute trend of certain elements indicated particular weathering processes—cadmium and nanoparticle transport, selenium and salt dissolution, and arsenic and pyrite oxidation. The mining of overburden formations and use of the waste rock for backfill aquifers as part of landscape reconstruction will create newly available mineral surfaces and nanoparticles that will weather to produce solute concentrations not typically found in groundwater associated with the original overburden. Full article

Environmental pollution has been widely considered by researchers, especially the heavy metals damage to the human and ecological environment is irreversible. Adsorption is an important method to remove heavy metal ions from the environment. In this paper, humic acid (HA) was functionalized by the improved Hummers method, and its adsorption capacity for Pb(II) was studied. The results of scanning electron microscope (SEM), X-ray diffraction (XRD), Roman, and Brunauer-Emmett-Teller (BET) showed that the thickness of irregular particles decreases to a layered structure during the transformation process. In addition, X-ray photoelectron spectroscopic (XPS) and Fourier transform infrared spectra (FT-IR) spectra showed that the surface of oxidized-biochar (OBC) was rich in reactive oxygen species, which was conducive to the formation of coordination bonds with Pb(II). Further adsorption experiments showed that it was a spontaneous monolayer chemisorption. The results of the DFT calculation showed that -COOH had the lowest adsorption energy for Pb(II), and it was easier to form stable chemical bonds than -OH, -C=O, and -C-O-C-. Because those oxygen-containing functional groups not only can promote electrostatic attraction but also are more favorable for forming a covalent bond with Pb(II). This study had guiding significance for the deep modification and application of weathered coal as a heavy metal ion adsorbent or cation exchanger. Full article

The coupling effects of sandstorm and dust from coal bases themselves can have a major impact on the atmospheric environment as well as on human health. The typical coal resource city of Wuhai in Inner Mongolia was selected in order to study these impacts during a severe sandstorm event in March 2021. Particulate matter (PM₁, PM_2.5 and PM₁₀) and total suspended particulate matter (TSP) samples were collected during the sandstorm event of 15–19 March 2021 and non-sandstorm weather (11–13 March 2021) and analyzed for their chemical composition. The concentrations of PM₁, PM_2.5, PM₁₀ and TSP in Wuhai city during the sandstorm were 2.2, 2.6, 4.8 and 6.0 times higher than during non-sandstorm days, respectively. Trace metals concentrations in particles of different sizes generally increased during the sandstorm, while water-soluble ions decreased. Positive matrix fraction (PMF) results showed that the main sources of particles during both sandstorm and non-sandstorm days were industrial emissions, traffic emissions, combustion sources and dust. The proportion of industrial emissions and combustion sources increased compared with non-sandstorm days, while traffic emissions and dust decreased. The backward trajectory analysis results showed that airflows were mainly transported over short distances during non-sandstorm days, and high concentration contribution source areas were from southern Ningxia, southeast Gansu and western Shaanxi. The airflow was mainly transported over long distances during the sandstorm event, and high concentration contribution source areas were from northwestern Inner Mongolia, southern Russia, northern and southwestern Mongolia, and northern Xinjiang. A health risk analysis showed that the risk to human health during sandstorm days related to the chemical composition of particles was generally 1.2–13.1 times higher than during non-sandstorm days. Children were more susceptible to health risks, about 2–6.3 times more vulnerable than adults to the risks from heavy metals in the particles under both weather conditions. Full article

Alkyl polycyclic aromatic hydrocarbons (APAHs) are more toxic and persistent than their parent compounds. Here, the concentrations, composition profiles, and spatial distribution of polycyclic aromatic compounds (PACs) in 127 topsoil samples from Huaibei coalfield were analyzed. The PAC concentrations in different functional areas were significantly different: mining area > industrial area > residential area > agricultural area. APAHs were the major contributors to PACs, accounting for 71–83% of total PACs. Alkylnaphthalenes and alkylphenanthrenes were the primary APAH components, accounting for 83–87% of APAHs. Principal component analysis showed that petrogenic source, coal and biomass combustion, and vehicle emissions were the primary sources of PACs. By comparing the fingerprint information of soil, coal, and coal gangue, it was hypothesized that the petrogenic source of PAC pollution in typical mining areas and surrounding areas are coal particle scattering and coal gangue weathering. Some coal mining and industrial areas potentially pose risks to children, whereas others do not. There are limited evaluation criteria for alkyl PAHs; hence, the estimated risk is likely lower than the actual risk. In addition to the conventional 16 PAHs, it is critical to consider a broader range of PACs, especially APAHs. Full article

The aims of this study were to determine the concentrations and elemental composition of PM10 in the village of Kotórz Mały (Poland), to analyse their seasonal variability, to determine the sources of pollutant emissions and to compare the consistency of the results obtained using different methods. Sampling and weather condition measurements were carried out in the winter (January–February) and spring (April) of 2019. Two combinations of different techniques were used to examine PM10 concentrations and their chemical composition: gravimetric method + atomic absorption spectrometry (GM+AAS) and continuous particle monitor + energy dispersive X-ray fluorescence (CPM+EDXRF). In winter, the average concentrations of PM10 measured by the GM and CPM were similar (GM 44.3 µg/m³; CPM 34.0 µg/m³), while in spring they were clearly different (GM 49.5 µg/m³; CPM 29.8 µg/m³). Both AAS and EDXRF proved that in both seasons, Ca, K and Fe had the highest shares in the PM10 mass. In the case of the lowest shares, the indications of the two methods were slightly different. Factor analysis indicated that air quality in the receptor was determined by soil erosion, coal and burning biomass, and the combustion of fuels in car engines; in the spring, air quality was also affected by gardening activities. Full article

Numerous researchers have described the correlation between the short-term contact of nano-particulate (NP) matter in diverse coal phases and amplified death or hospitalizations for breathing disorders in humans. However, few reports have examined the short-term consequences of source-specific nanoparticles (NPs) on coal mining areas. Advanced microscopic techniques can detect the ultra-fine particles (UFPs) and nanoparticles that contain potential hazardous elements (PHEs) generated in coal mining areas. Secondary aerosols that cause multiple and complex groups of particulate matter (PM₁₀, PM_2.5, PM₁) can be collected on dry deposition. In this study, scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HR-TEM) were employed to detect and define the magnitude of particulate matters on restaurants walls at coal mines due to weathering interactions. The low cost self-made passive sampler (SMPS) documented several minerals and amorphous phases. The results showed that most of the detected coal minerals exist in combined form as numerous complexes comprising significant elements (e.g., Al, C, Fe, K, Mg, S, and Ti), whereas others exist as amorphous or organic compounds. Based on the analytical approach, the study findings present a comprehensive understanding of existing potential hazardous elements in the nanoparticles and ultrafine particles from coal mining areas in Brazil. Full article

In order to ascertain the kaolinite crystallinity of Carboniferous Permian coal-measure kaolinite rocks, seven groups of fresh samples were collected from below the ground in the Xiaoyu mine, Datong coalfield. Microscopy, X-ray diffraction (XRD), differential thermal analysis (DTA), infrared (IR) spectroscopy and X-ray fluorescence (XRF) spectrometry methods were applied to the samples. The petrographic analysis results show that the kaolinite rocks are characterized as compact, phaneritic, clastic, sand-bearing, sandy and silty types; the kaolinite content in the Shanxi formation and upper Taiyuan formations was more than 95%, while it was 60–90% in the middle and lower Taiyuan formations. Based on the Hinckley index and the features of XRD, DTA and IR of kaolinites, crystallinity was classified as having three grades: ordered, slightly disordered and disordered. The kaolinites’ SiO₂/Al₂O₃ molar ratio was about 1.9–5.7, with a chemical index of alteration (CIA) of about 95.4–99.5. This research suggests that the kaolinite crystallinity correlates positively to its clay mineral content, purity and particle size, which are also related to the SiO₂/Al₂O₃ molar ratio and CIA. The original sedimentary environment and weathering have a direct influence on kaolinite crystallinity, and the existence of organic matter is conducive to the stable existence of kaolinite. The study results have significance for the extraction and utilization of coal-measure kaolinite and the development of kaolinite crystallography and mineralogy. Full article

Air pollutants have been investigated in many studies, but the variations of atmospheric pollutants and their relationship with rainwater chemistry are not well studied. In the present study, the criteria atmospheric pollutants in nine monitoring stations and rainwater chemistry were analyzed in karst Guiyang city, since the time when the Chinese Ambient Air Quality Standards (CAAQS, third revision) were published. Based on the three-year daily concentration dataset of SO₂, NO₂, CO, PM₁₀ and PM_2.5, although most of air pollutant concentrations were within the limit of CAAQS III-Grade II standard, the significant spatial variations and relatively heavy pollution were found in downtown Guiyang. Temporally, the average concentrations of almost all air pollutants (except for CO) decreased during three years at all stations. Ratios of PM_2.5/PM₁₀ in non- and episode days reflected the different contributions of fine and coarse particles on particulate matter in Guiyang, which was influenced by the potential meteorological factors and source variations. According to the individual air quality index (IAQI), the seasonal variations of air quality level were observed, that is, IAQI values of air pollutants were higher in winter (worst air quality) and lower in summer (best air quality) due to seasonal variations in emission sources. The unique IAQI variations were found during the Chinese Spring Festival. Air pollutant concentrations are also influenced by meteorological parameters, in particular, the rainfall amount. The air pollutants are well scoured by the rainfall process and can significantly affect rainwater chemistry, such as SO₄²⁻, NO₃⁻, Mg²⁺, and Ca²⁺, which further alters the acidification/alkalization trend of rainwater. The equivalent ratios of rainwater SO₄²⁻/NO₃⁻ and Mg²⁺/Ca²⁺ indicated the significant contribution of fixed emission sources (e.g., coal combustion) and carbonate weathering-influenced particulate matter on rainwater chemistry. These findings provide scientific support for air pollution management and rainwater chemistry-related environmental issues. Full article

Over the course of history, the development of human societies implied the exploitation of mineral resources which generated huge amounts of mining wastes leading to substantial environmental contamination by various metal(loid)s. This is especially the case of coal mine tailings which, subjected to weathering reactions, produce acid mine drainage (AMD), a recurring ecological issue related to current and past mining activities. In this study, we aimed to determine the origin, the fate and the ecotoxicity of metal(loid)s leached from a historical coal tailing heap to the Beuveroux river (Franche-Comté, France) using a combination of mineralogical, chemical and biological approaches. In the constitutive materials of the tailings, we identified galena, tetrahedrite and bournonite as metal-rich minerals and their weathering has led to massive contamination of the water and suspended particles of the river bordering the heap. The ecotoxicity of the AMD has been assessed using Chironomus riparius larvae encaged in the field during a one-month biomonitoring campaign. The larvae showed lethal and sub-lethal (growth and emergence inhibition and delay) impairments at the AMD tributary and near downstream stations. Metal bioaccumulation and subcellular fractionation in the larvae tissues revealed a strong bioavailability of, notably, As, Pb and Tl explaining the observed biological responses. Thus, more than 70 years after the end of mining operations, the coal tailings remain a chronic source of contamination and environmental risks in AMD effluent receiving waters. Full article

The primary sources and the conditions for the formation of the Paleogene–Neogene coal-bearing deposits in the Zeya–Bureya sedimentary basin were identified and studied with the help of paleogeographic reconstructions and geochemical analyses. Based on the results obtained, we suggest a new basic model of element transfer into the coal, involving two mutually complementary processes to account for the introduction and concentration of gold and other trace elements in the sequences investigated. The first process reflects the system in which peatlands were concentrated along the basin’s junction zone and the passive internal residual mountain ranges. The second reflects the junction’s contrast-type (sharp-type) forms conditions along the external mobile mountain-fold frame. The eroded gold particles were transported over 10–20 km as complex compounds, colloids, dispersed particles, and nanoparticles, and remobilized into clastogenic and dissolved forms along the first few kilometers. The release of gold in the primary sources occurred due to weathering of gold-bearing ore zones, followed by transportation of gold by minor rivers to the areas of peat accumulation. This study considered the probability of the accumulation of high concentrations of gold and rare earth elements (REE) in coal due to the introduction of organic and inorganic materials during floods, with episodes of catastrophic events, and volcano–hydrothermal activities. Full article

Across the world, ballasted railway tracks are utilised extensively due to their cost efficiency, ease of drainage, and capacity to withstand cyclic imposed loadings from heavy trains. In spite of these benefits, the ballast is often considered as a flexible medium; as such, its continuous deterioration is largely disregarded. Geotechnical challenges such as ballast contamination in the form of particle fragmentation, deposition of weathered materials, upward pumping of clay and fines from underlayers, and coal intrusion have led to differential settlements and reduced drainability of tracks, thereby exacerbating track maintenance costs. This study reviews existing works of literature to expound on the mechanisms for ballast contamination and to highlight the fundamental parameters that guide the characterisation and performance evaluation of railway ballasts. The study shows that ballast fragmentation accounts for about 76% of commonly recorded contaminations, while it is also observed as the most critical to track stability. As such, a variety of indices and specifications for ballast gradation have been established worldwide to guide practice in ballast characterisation and performance evaluation. However, the mechanisms of ballast fragmentation and deterioration require further research to guide the improvement of contemporary guidelines, and mitigate the risk of abrupt track failures, especially in developing countries. Full article

This paper deals with the potential reuse of coal mine waste rocks (CMWR) as an alternative material for road construction to conserve the natural resources and sustainable management of mining waste. The investigation was conducted through the determination of the chemical, mineralogical, geotechnical properties, and acid mine drainage formulation of CMWR as well as economic feasibility. This waste was used either alone for embankments and mixed with stabilizing agents fly ash (FA) and hydraulic road binder (HRB) for pavement applications. The experimental results confirmed that weathered CMWR can be successfully used alone as a sustainable alternative material for the embankment. Furthermore, the use of stabilizing agents in the following ratio CMWR:FA:HRB = 80:20:5 allow the use of CMWR in road sub-base layers for high-traffic pavements. Also, the environmental investigations showed that CMWR does not present any potential contaminating risk on the surrounding environment and most of the pyrite particles were already oxidized. Therefore, the environmental impact of acid mine drainage produced by pyritic waste throughout its life cycle can be neglected. Finally, an economic case study confirmed the workability of CMWR reuse in a radius of 29 km around their dumps by resulting in a lower cost compared with conventional materials. Full article