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Search Results (1,074)

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19 pages, 3364 KiB  
Article
Research on Increasing the Building’s Energy Efficiency by Using the Ground Beneath It for Thermo-Accumulation
by Tadas Zdankus, Sandeep Bandarwadkar, Juozas Vaiciunas, Gediminas Stelmokaitis and Arnas Vaicaitis
Sustainability 2025, 17(1), 262; https://doi.org/10.3390/su17010262 - 2 Jan 2025
Viewed by 261
Abstract
A whole series of factors influence the temperature of the soil surface and surface layers. The soil surface is heated by solar radiation during the day. It radiates some of the obtained heat at night. The heat exchange between the soil and the [...] Read more.
A whole series of factors influence the temperature of the soil surface and surface layers. The soil surface is heated by solar radiation during the day. It radiates some of the obtained heat at night. The heat exchange between the soil and the atmosphere depends on the air and soil temperatures and the speed of air movement. Precipitation may also affect surface soil layers, but this was not considered in this study. In the mentioned interaction, a specific temperature field of the surface layers of the soil is established. To increase the building’s energy efficiency, the aim is to optimize the operation of its heating and cooling systems and to reduce heat loss to the environment as much as possible. Heat loss through the floor of the building or the walls of the recessed part into the ground changes the established temperature field of the ground. The heat spreads in the soil and is given to the atmospheric air. During the research, to validate the numerical model, the heat flow density was analysed to determine how it changes while maintaining a constant temperature of the heating surface at a certain depth of the soil. It was found that the new thermodynamic equilibrium, depending on the seasonality, can be reached in a time interval of up to a week. The temperature change in the artificially limited volume of the ground under the building or next to it can be treated as the work of the ground thermo-accumulator: its charge or discharge by heat. This makes it possible to reduce the annual energy costs of the building by more than ten percent. Full article
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<p>Experimental setup.</p>
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<p>Scheme of the building with a semi-basement for numerical simulation. The external surface of the building floor is at a depth of 1 m—Case 2. Building with sand filler layer separated from the surrounding environment—Case 3.</p>
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<p>Comparison of the air temperatures measured in the period from 2022 to 2023 with average monthly temperature values given in documents of the construction climatology [<a href="#B34-sustainability-17-00262" class="html-bibr">34</a>,<a href="#B35-sustainability-17-00262" class="html-bibr">35</a>].</p>
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<p>Change in air temperature over the year, starting from January, going to July and returning to January.</p>
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<p>Change in soil temperature at different depths during the year.</p>
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<p>Change in monthly ground temperature at different depths over the year, starting from January to July and returning to January.</p>
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<p>Change in monthly ground temperature at the depths: <span class="html-italic">h</span> = −1.0 m and <span class="html-italic">h</span> = −1.5 m, over the year, starting from February to August and returning to February.</p>
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<p>Change in soil temperature distribution at depths <span class="html-italic">h</span> = −1.0 m, −1.25 m and −1.5 m one week after the heating device was turned on.</p>
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<p>Change in the heat flux density generated by the heated surface over time. Note: data are presented starting from the second hour.</p>
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<p>Change in heat flux density from the heated surface of the constant temperature to the ground from December to July.</p>
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<p>The temperature profile of the ground after 168 h (one week) of operation of the heating device placed at <span class="html-italic">h</span> = −1 m.</p>
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<p>The temperature profile of the ground after one week in Case 2.</p>
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<p>The temperature profile of the ground after three weeks in Case 3.</p>
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21 pages, 7742 KiB  
Article
The Impact of Building and Green Space Combination on Urban Thermal Environment Based on Three-Dimensional Landscape Index
by Ying Wang, Yin Ren, Xiaoman Zheng and Zhifeng Wu
Sustainability 2025, 17(1), 241; https://doi.org/10.3390/su17010241 - 31 Dec 2024
Viewed by 323
Abstract
Urbanization transforms landscapes from natural ecosystems to configurations of impervious surfaces and green spaces, leading to urban heat island effects that impact health and ecosystem sustainability. This study in Xiamen City, China, categorizes urban areas into functional zones, employs Random Forest and Stepwise [...] Read more.
Urbanization transforms landscapes from natural ecosystems to configurations of impervious surfaces and green spaces, leading to urban heat island effects that impact health and ecosystem sustainability. This study in Xiamen City, China, categorizes urban areas into functional zones, employs Random Forest and Stepwise Regression models to assess thermal differences, and proposes optimization measures for the building–green space landscape. The optimization involves altering the characterization of the building–green space landscape pattern. Results indicate: (1) due to the spatial heterogeneity of the building–green space landscape pattern in different functional zones, the surface temperature also shows strong spatial heterogeneity in different functional zones; (2) different optimization measures for the building–green space pattern are needed for different functional zones; taking the urban residential zone as an example, the Normalized Difference Vegetation Index (NDVI) in the hot spot area can be adjusted according to the value range of the cold spot area; (3) considering the solar radiation process, Sun View Factor (SunVF) plays an important role in indicating the change in surface temperature in the commercial service area, and as SunVF increases, the surface temperature of the functional zone tends to rise. This research offers insights into urban thermal environment improvement and landscape pattern optimization. Full article
(This article belongs to the Special Issue Sustainability in Urban Climate Change and Ecosystem Services)
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<p>Map of the study area. (<b>a</b>) the location of Xiamen in Fujian Province; (<b>b</b>) the study area of Xiamen.</p>
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<p>Spatial distribution of the Landscape Pattern Index. (<b>a</b>) Normalized Difference Vegetation Index (NDVI); (<b>b</b>): Normalized Difference Building Index (NDBI); (<b>c</b>): Building coverage ratio (BCR); (<b>d</b>): Floor Area Ratio (FAR); (<b>e</b>): Sun View Factor (SunVF); (<b>f</b>): Sky View Factor (SkyVF).</p>
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<p>The spatial distribution of LST (<b>a</b>) and cold/hot spots (<b>b</b>).</p>
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<p>Proportion of hot and cold spots in functional urban areas.</p>
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<p>Pearson correlation coefficients for cold spot (<b>a</b>) and hot spot (<b>b</b>), ** indicates <span class="html-italic">p</span> &lt; 0.01, * indicates <span class="html-italic">p</span> &lt; 0.05.</p>
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<p>Comparison of shared parameters for 4 UFZs.</p>
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<p>Comparison of variable importance scores in RF models for all UFZs in cold spot (<b>a</b>) and hot spot (<b>b</b>).</p>
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<p>Comparison of important predictors of variations in LST relative to temperature classes by UFZ.</p>
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34 pages, 7261 KiB  
Article
Performance Evaluation of Photovoltaic Panels in Extreme Environments: A Machine Learning Approach on Horseshoe Island, Antarctica
by Mehmet Das, Erhan Arslan, Sule Kaya, Bilal Alatas, Ebru Akpinar and Burcu Özsoy
Sustainability 2025, 17(1), 174; https://doi.org/10.3390/su17010174 - 29 Dec 2024
Viewed by 423
Abstract
Due to the supply problems of fossil-based energy sources, the tendency towards alternative energy sources is relatively high. For this reason, the use of solar energy systems is increasing today. This study combines experimental data and machine learning algorithms to evaluate the energy [...] Read more.
Due to the supply problems of fossil-based energy sources, the tendency towards alternative energy sources is relatively high. For this reason, the use of solar energy systems is increasing today. This study combines experimental data and machine learning algorithms to evaluate the energy performance of four different photovoltaic (PV) panel designs (monocrystalline, polycrystalline, flexible, and transparent) under harsh environmental conditions on Horseshoe Island (Antarctica). In this research, the effects of environmental factors, such as solar radiation, temperature, humidity, and wind speed, on the panels were analyzed. Electrical power output of the PV panels are analyzed using six machine learning models. Random forest (RF) and CatBoost (CB) models showed the highest accuracy and reliability among these models. According to the experimental results, Monocrystalline PV provided the highest electrical power (20.5 Watts on average), and Flexible PV provided the highest energy efficiency (19.67%). However, Flexible PV was observed to have higher surface temperatures compared to the other panel types. Furthermore, using Monocrystalline PV resulted in an average reduction of 4.1 tons of CO2 emissions per year, demonstrating the positive environmental impact of renewable energy systems. Thanks to this study, renewable energy research for temporary stations in Antarctica will focus on explainable and interpretable artificial intelligence models that will provide an understanding of the factors affecting the energy performance of PV panels. The research results will be an important guide for optimizing energy consumption, management, and demand forecasting in temporary research stations in Antarctica. Full article
(This article belongs to the Section Energy Sustainability)
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<p>Regional view of the project and the TARS (<b>A</b>), the TARS and the experimental set (<b>B</b>).</p>
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<p>(<b>A</b>) Experiments were conducted in the open area behind the container temporarily located at the TARS. (<b>B</b>) Experimental setup and measurement equipment were as follows: 1. Solar meter, 2. Infrared temperature, 3. Temperature and Humidity sensor, 4. Wind speed sensor, 5. Two batteries, 6. Dummy loads.</p>
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<p>Data Processing and Machine Learning Model Evaluation Workflow for Photovoltaic Panel Performance Prediction.</p>
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<p>Variation of ambient temperature and wind speed values according to time.</p>
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<p>Solar radiation and relative humidity values change with time during the experiment.</p>
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<p>Surface temperature changes of photovoltaic solar panels.</p>
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<p>Variation of power values of photovoltaic solar panels according to time.</p>
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<p>Changes in energy efficiency values of photovoltaic solar panels during the experiment.</p>
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<p>Comparison of Model Performance Metrics Across Different Photovoltaic Panels.</p>
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<p>Comparison of Actual and Predicted Power Output for Poly PV.</p>
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<p>Comparison of Actual and Predicted Power Output for Flexible PV.</p>
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<p>Comparison of Actual and Predicted Power Output for Mono PV.</p>
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<p>Comparison of Actual and Predicted Power Output for Transparent PV.</p>
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28 pages, 17955 KiB  
Article
Development of a Method for Evaluating the Influence of Building Facade Form on Its Potential for Solar Radiation Acquisition
by Shangkai Hao, Yu Liu, Xiaojing Yang and Jie Song
Energies 2024, 17(24), 6394; https://doi.org/10.3390/en17246394 - 19 Dec 2024
Viewed by 361
Abstract
Studying the potential of buildings for utilizing solar radiation would be helpful to decrease the energy consumption of buildings. The solar radiation acquisition (SRA) potential of building facades can be used to characterize the building’s SRA potential. A review of the existing literature [...] Read more.
Studying the potential of buildings for utilizing solar radiation would be helpful to decrease the energy consumption of buildings. The solar radiation acquisition (SRA) potential of building facades can be used to characterize the building’s SRA potential. A review of the existing literature shows that few performance indicators have been established to specifically evaluate and guide the design of the building facade form from the perspective of SRA potential. This study explores how to evaluate the form of building facades to affect their SRA potential. Two new indicators (ρ value—the surface density of solar radiation received by the facades—and α value—the correction coefficient for receiving solar radiation in the concave part of the facade) and one new path were constructed to evaluate the SRA potential of building facades. It was found that the ρ values can reflect the upper limit of solar radiation in the region itself and serve as a basis for measuring the building’s SRA potential in the region. It is only related to the shapes of buildings and not to their sizes, and the larger the ρ value of a building, the stronger its facade’s potential to receive solar radiation. The α values can intuitively show the discount of the SRA potential when adding a concave part into the architectural design. At the same time, the extent of the discount due to the elements of the concave part can be elucidated, which can help minimize the loss of solar radiation when designing the concave part in the architectural design process. It is only related to the shapes of building plans (which directly relate to the building facade) but not their sizes. The larger the α value of the concave part of the building facade, the stronger its potential to receive solar radiation. The method for identifying the proper range of ρ values and calculating the standard ρ values was proposed and utilized in Lanzhou city as an example. It reveals that, for Lanzhou city, the maximum ρ value (ρmax) is 670.98 kwh/m2 and the average value of ρ value (ρave) is 592.47 kwh, which reflect the basic situation of buildings’ SRA potentials in this city. For the concave parts of the triangular facades in this specific region, the concave offset has almost no effect on their α value. When the concave part of the building facade is triangular, the further south the concave part (rectangular is up to 30° southwest), the smaller the CCS, the higher the concave HWR, the larger the correction coefficient, and the greater the SRA potential of the buildings’ facades. Full article
(This article belongs to the Special Issue Green Energy Integrated Building Application)
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<p>(<b>a</b>) Schematic diagram of a convex polygon; (<b>b</b>) Schematic diagram of a concave polygon.</p>
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<p>Schematic diagram of the concept related to the correction coefficient α for the concave part of the building form.</p>
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<p>Research workflow.</p>
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<p>Schematic diagram of the concept of surface density (<span class="html-italic">ρ</span>) of solar radiation received by building facades.</p>
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<p>Schematic diagram of concave plane scaling.</p>
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<p>Diagram of the relationship between the correction factor α, CSR, and concave HWR in a triangular concave facade.</p>
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<p>Relationship diagram for the correction factor α, CSR, and CCS in a triangular concave facade.</p>
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<p>Relationship diagram for the correction factor α, CSR, and concave HWR in a rectangular concave facade.</p>
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<p>Relationship diagram for the correction factor α, CSR, and CCS in a rectangular concave facade.</p>
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<p>Diagonal diagram of a rectangular flat building.</p>
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<p>Relationship between the <span class="html-italic">ρ</span> value, direction, and LWR of rectangular flat buildings.</p>
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<p>Schematic diagram of factors affecting the correction coefficient α of concave parts (triangular concave type).</p>
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<p>Relationship diagram for α, concave HWR, CDI, and COF in a triangular concave structure (CCS = 0.25). (<b>a</b>) HWR = 0.5; (<b>b</b>) HWR = 1; (<b>c</b>) HWR = 1.5; (<b>d</b>) HWR = 2; (<b>e</b>) HWR = 2.5; (<b>f</b>) HWR = 3; (<b>g</b>) HWR = 3.5; (<b>h</b>) HWR = 4; (<b>i</b>) HWR = 4.5; (<b>j</b>) HWR = 5.</p>
Full article ">Figure 13 Cont.
<p>Relationship diagram for α, concave HWR, CDI, and COF in a triangular concave structure (CCS = 0.25). (<b>a</b>) HWR = 0.5; (<b>b</b>) HWR = 1; (<b>c</b>) HWR = 1.5; (<b>d</b>) HWR = 2; (<b>e</b>) HWR = 2.5; (<b>f</b>) HWR = 3; (<b>g</b>) HWR = 3.5; (<b>h</b>) HWR = 4; (<b>i</b>) HWR = 4.5; (<b>j</b>) HWR = 5.</p>
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<p>Relationship diagram for α, concave HWR, CDI, and COF in a triangular concave structure (CCS = 0.5). (<b>a</b>) HWR = 0.5; (<b>b</b>) HWR = 1; (<b>c</b>) HWR = 1.5; (<b>d</b>) HWR = 2; (<b>e</b>) HWR = 2.5; (<b>f</b>) HWR = 3; (<b>g</b>) HWR = 3.5; (<b>h</b>) HWR = 4; (<b>i</b>) HWR = 4.5; (<b>j</b>) HWR = 5.</p>
Full article ">Figure 14 Cont.
<p>Relationship diagram for α, concave HWR, CDI, and COF in a triangular concave structure (CCS = 0.5). (<b>a</b>) HWR = 0.5; (<b>b</b>) HWR = 1; (<b>c</b>) HWR = 1.5; (<b>d</b>) HWR = 2; (<b>e</b>) HWR = 2.5; (<b>f</b>) HWR = 3; (<b>g</b>) HWR = 3.5; (<b>h</b>) HWR = 4; (<b>i</b>) HWR = 4.5; (<b>j</b>) HWR = 5.</p>
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<p>Relationship diagram for α, concave HWR, CDI, and COF in a triangular concave structure (CCS = 0.75). (<b>a</b>) HWR = 0.5; (<b>b</b>) HWR = 1; (<b>c</b>) HWR = 1.5; (<b>d</b>) HWR = 2; (<b>e</b>) HWR = 2.5; (<b>f</b>) HWR = 3; (<b>g</b>) HWR = 3.5; (<b>h</b>) HWR = 4; (<b>i</b>) HWR = 4.5; (<b>j</b>) HWR = 5.</p>
Full article ">Figure 15 Cont.
<p>Relationship diagram for α, concave HWR, CDI, and COF in a triangular concave structure (CCS = 0.75). (<b>a</b>) HWR = 0.5; (<b>b</b>) HWR = 1; (<b>c</b>) HWR = 1.5; (<b>d</b>) HWR = 2; (<b>e</b>) HWR = 2.5; (<b>f</b>) HWR = 3; (<b>g</b>) HWR = 3.5; (<b>h</b>) HWR = 4; (<b>i</b>) HWR = 4.5; (<b>j</b>) HWR = 5.</p>
Full article ">Figure 15 Cont.
<p>Relationship diagram for α, concave HWR, CDI, and COF in a triangular concave structure (CCS = 0.75). (<b>a</b>) HWR = 0.5; (<b>b</b>) HWR = 1; (<b>c</b>) HWR = 1.5; (<b>d</b>) HWR = 2; (<b>e</b>) HWR = 2.5; (<b>f</b>) HWR = 3; (<b>g</b>) HWR = 3.5; (<b>h</b>) HWR = 4; (<b>i</b>) HWR = 4.5; (<b>j</b>) HWR = 5.</p>
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<p>Relationship diagram for α, concave HWR, CDI, and COF in a triangular concave structure (CCS = 1). (<b>a</b>) HWR = 0.5; (<b>b</b>) HWR = 1; (<b>c</b>) HWR = 1.5; (<b>d</b>) HWR = 2; (<b>e</b>) HWR = 2.5; (<b>f</b>) HWR = 3; (<b>g</b>) HWR = 3.5; (<b>h</b>) HWR = 4; (<b>i</b>) HWR = 4.5; (<b>j</b>) HWR = 5.</p>
Full article ">Figure 16 Cont.
<p>Relationship diagram for α, concave HWR, CDI, and COF in a triangular concave structure (CCS = 1). (<b>a</b>) HWR = 0.5; (<b>b</b>) HWR = 1; (<b>c</b>) HWR = 1.5; (<b>d</b>) HWR = 2; (<b>e</b>) HWR = 2.5; (<b>f</b>) HWR = 3; (<b>g</b>) HWR = 3.5; (<b>h</b>) HWR = 4; (<b>i</b>) HWR = 4.5; (<b>j</b>) HWR = 5.</p>
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<p>Relationship diagram for α, concave HWR, CDI, and CCS in a triangular concave structure. (<b>a</b>) CCS = 0.25; (<b>b</b>) CCS = 0.5; (<b>c</b>) CCS = 0.75; (<b>d</b>) CCS = 1.</p>
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<p>Relationship diagram for α, CCS, CDI, and concave HWR in a rectangular concave part. (<b>a</b>) CDI = 0°; (<b>b</b>) CDI = 30°; (<b>c</b>) CDI = 60°; (<b>d</b>) CDI = 90°; (<b>e</b>) CDI = 120°; (<b>f</b>) CDI = 150°; (<b>g</b>) CDI = 180°; (<b>h</b>) CDI = 210°; (<b>i</b>) CDI = 240°; (<b>j</b>) CDI = 270°; (<b>k</b>) CDI = 300°; (<b>l</b>) CDI = 330°.</p>
Full article ">Figure 18 Cont.
<p>Relationship diagram for α, CCS, CDI, and concave HWR in a rectangular concave part. (<b>a</b>) CDI = 0°; (<b>b</b>) CDI = 30°; (<b>c</b>) CDI = 60°; (<b>d</b>) CDI = 90°; (<b>e</b>) CDI = 120°; (<b>f</b>) CDI = 150°; (<b>g</b>) CDI = 180°; (<b>h</b>) CDI = 210°; (<b>i</b>) CDI = 240°; (<b>j</b>) CDI = 270°; (<b>k</b>) CDI = 300°; (<b>l</b>) CDI = 330°.</p>
Full article ">Figure 18 Cont.
<p>Relationship diagram for α, CCS, CDI, and concave HWR in a rectangular concave part. (<b>a</b>) CDI = 0°; (<b>b</b>) CDI = 30°; (<b>c</b>) CDI = 60°; (<b>d</b>) CDI = 90°; (<b>e</b>) CDI = 120°; (<b>f</b>) CDI = 150°; (<b>g</b>) CDI = 180°; (<b>h</b>) CDI = 210°; (<b>i</b>) CDI = 240°; (<b>j</b>) CDI = 270°; (<b>k</b>) CDI = 300°; (<b>l</b>) CDI = 330°.</p>
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22 pages, 8876 KiB  
Article
Sorption of Platinum and Palladium on Polyethylene Microplastics in Natural Water
by Sylwia Sajkowska and Barbara Leśniewska
Molecules 2024, 29(24), 5987; https://doi.org/10.3390/molecules29245987 - 19 Dec 2024
Viewed by 315
Abstract
In this work, for the first time, the sorption behaviour of platinum and palladium on polyethylene microplastics (PE-MP) was studied. To simulate natural conditions, part of PE-MP was subjected to the ageing process in lake water under the influence of solar radiation. The [...] Read more.
In this work, for the first time, the sorption behaviour of platinum and palladium on polyethylene microplastics (PE-MP) was studied. To simulate natural conditions, part of PE-MP was subjected to the ageing process in lake water under the influence of solar radiation. The original and aged PE-MP was characterised using elemental analysis, FT-IR, SEM-EDX, and nitrogen porosimetry methods. The studies on Pt and Pd sorption on PE-MP were carried out in batch mode in natural lake water at pH 7.6. It was found that the ageing process led to the degradation of the surface of the PE-MP and the formation of a biofilm. The sorption process of Pt and Pd on PE-MP particles proceeds according to pseudo-second-order kinetics. A good fit of the experimental data to the Freundlich and Langmuir isotherm model indicates the mixed nature of Pt and Pd sorption on PE-MP. It was clearly indicated that Pt and Pd sorption from natural waters can occur on the surface of inert polyethylene particles, which can lead to the preconcentration of these elements, even from waters with a very low content, and transferring them over longer distances. This poses a threat to the health of living organisms and humans. Full article
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<p>FT-IR spectrum of PE microplastic: original, aged in Milli-Q water, and aged in lake water.</p>
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<p>SEM images of MP surface: (<b>a</b>) original, (<b>b</b>) aged in Milli-Q water, (<b>c</b>) aged in lake water (particle size 500–1000 µm).</p>
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<p>SEM–EDX spectra of PE microplastic (500–1000 µm): (<b>a</b>) original, (<b>b</b>) aged in Milli-Q water, (<b>c</b>) aged in lake water—white particle on its surface.</p>
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<p>SEM–EDX spectra of PE microplastic (500–1000 µm): (<b>a</b>) original, (<b>b</b>) aged in Milli-Q water, (<b>c</b>) aged in lake water—white particle on its surface.</p>
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<p>The effect of the pH value of the sample solution on the sorption of Pt(IV) and Pd(II) on the original PE-MP (value ± standard deviation, <span class="html-italic">n</span> = 3).</p>
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<p>The effect of the mass of original PE-MP on the sorption of Pt(IV) and Pd(II) from solution at pH 8 (value ± standard deviation, <span class="html-italic">n</span> = 3).</p>
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<p>Sorption kinetics of Pt(IV) and Pd(II) onto original and aged microplastics in Milli-Q and lake water: (<b>a</b>) pseudo-first-order model, (<b>b</b>) pseudo-second-order model, (<b>c</b>) intra-particle diffusion model, (<b>d</b>) Elovich model.</p>
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<p>Sorption isotherms of Pt(IV) and Pd(II) onto original and aged microplastics in Milli-Q and lake water: (<b>a</b>) Langmuir model, (<b>b</b>) Freundlich model, (<b>c</b>) Temkin model.</p>
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18 pages, 2829 KiB  
Article
Deep FS: A Deep Learning Approach for Surface Solar Radiation
by Fatih Kihtir and Kasim Oztoprak
Sensors 2024, 24(24), 8059; https://doi.org/10.3390/s24248059 - 18 Dec 2024
Viewed by 468
Abstract
Contemporary environmental challenges are increasingly significant. The primary cause is the drastic changes in climates. The prediction of solar radiation is a crucial aspect of solar energy applications and meteorological forecasting. The amount of solar radiation reaching Earth’s surface (Global Horizontal Irradiance, GHI) [...] Read more.
Contemporary environmental challenges are increasingly significant. The primary cause is the drastic changes in climates. The prediction of solar radiation is a crucial aspect of solar energy applications and meteorological forecasting. The amount of solar radiation reaching Earth’s surface (Global Horizontal Irradiance, GHI) varies with atmospheric conditions, geographical location, and temporal factors. This paper presents a novel methodology for estimating surface sun exposure using advanced deep learning techniques. The proposed method is tested and validated using the data obtained from NASA’s Goddard Earth Sciences Data and Information Services Centre (GES DISC) named the SORCE (Solar Radiation and Climate Experiment) dataset. For analyzing and predicting accurate data, features are extracted using a deep learning method, Deep-FS. The method extracted and provided the selected features that are most appropriate for predicting the surface exposure. Time series analysis was conducted using Convolutional Neural Networks (CNNs), with results demonstrating superior performance compared to traditional methodologies across standard performance metrics. The proposed Deep-FS model is validated and compared with the traditional approaches and models through the standard performance metrics. The experimental results concluded that the proposed model outperforms the traditional models. Full article
(This article belongs to the Special Issue AI-Based Security and Privacy for IoT Applications)
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<p>Proposed Model.</p>
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<p>Time series analysis for a specific time.</p>
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<p>Spectral analysis.</p>
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<p>Regression analysis.</p>
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<p>Time series visualization for different timestamps.</p>
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<p>Surface exposure prediction using CNN-LSTM models.</p>
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<p>Surface exposure prediction using different models.</p>
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<p>The CNN-GRU model’s time series visualization for different timestamps.</p>
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<p>The CNN-LSTM model’s time series visualization for different timestamps.</p>
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<p>The CNN-LSTM model’s training history and prediction success.</p>
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<p>CNN-GRU model’s training history and prediction success.</p>
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<p>CNN-GRU and CNN-LSTM ROC curves.</p>
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11 pages, 7797 KiB  
Article
Comparative Analysis of the Effects of Additives of Nanostructured Functional Ceramics on the Properties of Welding Electrodes
by Saidov Rustam Mannapovitch, Rakhimov Rustam Khalidov and Kamel Touileb
Crystals 2024, 14(12), 1082; https://doi.org/10.3390/cryst14121082 - 16 Dec 2024
Viewed by 434
Abstract
The synthesis of special photocatalysts of nanostructured functional ceramics (PNFC) under the ZKHM brand under the influence of concentrated solar radiation showed the effectiveness of these ceramic materials in multifunctional use, in particular as additives for coatings of welding electrodes. However, problems with [...] Read more.
The synthesis of special photocatalysts of nanostructured functional ceramics (PNFC) under the ZKHM brand under the influence of concentrated solar radiation showed the effectiveness of these ceramic materials in multifunctional use, in particular as additives for coatings of welding electrodes. However, problems with producing these materials in solar ovens on an industrial scale did not allow the widespread use of this method. This problem was solved using the technique of PNFC synthesis, followed by activation by pulsed radiation generated by functional ceramics. The ceramic material obtained by this method under the brand name ZB-1 also showed its effectiveness when used as an additive in welding electrode coatings. A comparative analysis of the effectiveness of the actions of additives from the ZKHM and ZB-1 brands on the welding and technological properties of welding electrodes from the MR-3 brand was carried out. Comparative results for the formation of weld beads showed that beads with high-quality formation without external defects were achieved when surfaced with electrodes with additives from both brands at concentrations up to 1%. Also, at concentrations up to 1%, these additives increased the breaking length of the arc and the stability of arc welding. The different effects of these additives were observed in a comparative analysis of their impacts on the size of the visor at the end of the electrode, the coefficients of melting and surfacing, and the loss factor for fumes and splashing of electrode metal. Full article
(This article belongs to the Special Issue Ceramics: Processes, Microstructures, and Properties)
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<p>Electrode preparation steps.</p>
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<p>The installation for the determination of the breaking length of the arc (“Lbla”).</p>
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<p>The visor at the end of the electrode (“hk”).</p>
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<p>The dependence of the arc breaking length (“L<sub>bla</sub>”) on the contents of the ZKHM and ZB-1 additives in the MR-3 electrode coating.</p>
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<p>The dependence of the “h<sub>k</sub>” indicator on the proportion of the ZKHM and ZB-1 additives in the MR-3 electrode coating.</p>
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<p>The dependence of the melting coefficient (“α<sub>p</sub>”) on the proportions of the ZKHM and ZB-1 additives in the MR-3 electrode coating.</p>
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<p>The dependence of the surfacing coefficient (“α<sub>H</sub>”) on the proportions of the ZKHM and ZB-1 additives in the MR-3 electrode coating.</p>
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<p>The effect of the ZKHM and ZB-1 proportions in the MR-3 electrode coating on the “ψ” indicator.</p>
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17 pages, 6521 KiB  
Article
Rational Fabrication of Ag2S/g-C3N4 Heterojunction for Photocatalytic Degradation of Rhodamine B Dye Under Natural Solar Radiation
by Ali Alsalme, Ahmed Najm, Nagy N. Mohammed, M. F. Abdel Messih, Ayman Sultan and Mohamed Abdelhay Ahmed
Catalysts 2024, 14(12), 914; https://doi.org/10.3390/catal14120914 - 11 Dec 2024
Viewed by 660
Abstract
Near-infrared light-triggered photocatalytic water treatment has attracted significant attention in recent years. In this novel research, rational sonochemical fabrication of Ag2S/g-C3N4 nanocomposites with various compositions of Ag2S (0–25) wt% was carried out to eliminate hazardous rhodamine [...] Read more.
Near-infrared light-triggered photocatalytic water treatment has attracted significant attention in recent years. In this novel research, rational sonochemical fabrication of Ag2S/g-C3N4 nanocomposites with various compositions of Ag2S (0–25) wt% was carried out to eliminate hazardous rhodamine B dye in a cationic organic pollutant model. g-C3N4 sheets were synthesized via controlled thermal annealing of microcrystalline urea. However, black Ag2S nanoparticles were synthesized through a precipitation-assisted sonochemical route. The chemical interactions between various compositions of Ag2S and g-C3N4 were carried out in an ultrasonic bath with a power of 300 W. XRD, PL, DRS, SEM, HRTEM, mapping, BET, and SAED analysis were used to estimate the crystalline, optical, nanostructure, and textural properties of the solid specimens. The coexistence of the diffraction peaks of g-C3N4 and Ag2S implied the successful production of Ag2S/g-C3N4 heterojunctions. The band gap energy of g-C3N4 was exceptionally reduced from 2.81 to 1.5 eV with the introduction of 25 wt% of Ag2S nanoparticles, implying the strong absorbability of the nanocomposites to natural solar radiation. The PL signal intensity of Ag2S/g-C3N4 was reduced by 40% compared with pristine g-C3N4, implying that Ag2S enhanced the electron–hole transportation and separation. The rate of the photocatalytic degradation of rhodamine B molecules was gradually increased with the introduction of Ag2S on the g-C3N4 surface and reached a maximum for nanocomposites containing 25 wt% Ag2S. The radical trapping experiments demonstrated the principal importance of reactive oxygen species and hot holes in destroying rhodamine B under natural solar radiation. The charge transportation between Ag2S and g-C3N4 semiconductors proceeded through the type I straddling scheme. The enriched photocatalytic activity of Ag2S/g-C3N4 nanocomposites resulted from an exceptional reduction in band gap energy and controlling the electron–hole separation rate with the introduction of Ag2S as an efficient photothermal photocatalyst. The novel as-synthesized nanocomposites are considered a promising photocatalyst for destroying various types of organic pollutants under low-cost sunlight radiation. Full article
(This article belongs to the Section Photocatalysis)
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<p>XRD of g-C<sub>3</sub>N<sub>4</sub>, Ag<sub>2</sub>S, and CNAgS25 nanocomposites.</p>
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<p>N<sub>2</sub>-adsorption isotherm of (<b>a</b>) g-C<sub>3</sub>N<sub>4</sub> and (<b>b</b>) CNAgS25.</p>
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<p>(<b>a</b>) SEM of CNAgS25, (<b>b</b>) mapping of CNAgS25, (<b>c</b>) mapping of C, (<b>d</b>) mapping of (N), (<b>e</b>) mapping of Ag, (<b>f</b>) mapping of S, (<b>g</b>) EDX of CNAgS25.</p>
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<p>(<b>a</b>) TEM of CNAgS25, (<b>b</b>) HRTEM of CNAgS25 and (<b>c</b>) SAED of CNAgS25.</p>
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<p>(<b>a</b>) TEM of CNAgS25, (<b>b</b>) HRTEM of CNAgS25 and (<b>c</b>) SAED of CNAgS25.</p>
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<p>(<b>a</b>) DRS of g-C<sub>3</sub>N<sub>4</sub>, Ag<sub>2</sub>S, CNAgS15, and CNAgS25. (<b>b</b>) Tauc plot of g-C<sub>3</sub>N<sub>4</sub>, Ag2S, CNAgS15, and CNAgS25.</p>
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<p>PL analysis of g-C<sub>3</sub>N<sub>4</sub>, NAgS15, and CNAgS25.</p>
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<p>The absorption spectrum for photocatalytic degradation of rhodamine B over the surfaces of g-C3N4, CNAg10, CNAg15, and CNAg25.</p>
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<p>(<b>a</b>) The variations in the amount of RhB removed (%) under dark and light reactions with the illumination time over the surfaces of g-C<sub>3</sub>N<sub>4</sub>, CNAg10, CNAg15, and CNAg25. (<b>b</b>) The kinetic first-order plot for photocatalytic degradation of RhB dye over the surfaces of g-C<sub>3</sub>N<sub>4</sub>, CNAg10, CNAg15, and CNAg25.</p>
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<p>Photocatalytic degradation of rhodamine B (2 × 10<sup>−5</sup> M) over CNAgS25 nanocomposite in the presence of 2 × 10<sup>−5</sup> M of the following scavengers: (<b>a</b>) benzoquinone, (<b>b</b>) ammonium oxalate, and (<b>c</b>) isopropanol. (<b>d</b>) PL spectrum of terephthalic acid 2 × 10<sup>−4</sup> M over CNAgS25 nanocomposite at 325 nm excitation wavelength.</p>
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<p>Photocatalytic degradation of rhodamine B (2 × 10<sup>−5</sup> M) over CNAgS25 nanocomposite in the presence of 2 × 10<sup>−5</sup> M of the following scavengers: (<b>a</b>) benzoquinone, (<b>b</b>) ammonium oxalate, and (<b>c</b>) isopropanol. (<b>d</b>) PL spectrum of terephthalic acid 2 × 10<sup>−4</sup> M over CNAgS25 nanocomposite at 325 nm excitation wavelength.</p>
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<p>Regeneration of CNAgS25 for five consecutive cycles for removal of RhB dye over CNAgS25 nanocomposite.</p>
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<p>A scheme for electron transportation between g-C<sub>3</sub>N<sub>4</sub> and Ag<sub>2</sub>S semiconductors.</p>
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<p>Scheme for synthesis of (<b>a</b>) g-C<sub>3</sub>N<sub>4</sub>, (<b>b</b>) Ag<sub>2</sub>S and (<b>c</b>) Ag<sub>2</sub>S/g-C<sub>3</sub>N<sub>4</sub> heterojunction.</p>
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22 pages, 7583 KiB  
Article
The Evapotranspiration Characteristics and Evaporative Cooling Effects of Different Vegetation Types on an Intensive Green Roof: Dynamic Performance Under Different Weather Conditions
by Haishun Xu, Huiying Chen, Chen Qian and Jining Li
Sustainability 2024, 16(24), 10812; https://doi.org/10.3390/su162410812 - 10 Dec 2024
Viewed by 605
Abstract
Previous research has demonstrated that the multiple environmental benefits of green roofs are primarily associated with their evaporative cooling effect. However, current studies on green roof evapotranspiration (ET) mainly focus on extensive green roofs, and the evaporative cooling effect of intensive green roofs [...] Read more.
Previous research has demonstrated that the multiple environmental benefits of green roofs are primarily associated with their evaporative cooling effect. However, current studies on green roof evapotranspiration (ET) mainly focus on extensive green roofs, and the evaporative cooling effect of intensive green roofs is still unclear. Using the intensive green roof of AQUA City in Nanjing as a case study, this research employs the three-temperature (3T) model combined with high-resolution thermal infrared imagery obtained via an unmanned aerial vehicle (UAV) to estimate the ET of different vegetation types. The study aims to explore the spatiotemporal variations in surface temperature, evapotranspiration (ET) rate, and evaporative cooling rate for various vegetation types under typical seasonal (summer and winter) and weather conditions (sunny, cloudy, and rainy before and after rainy days). The results showed that: (1) the ET rates and evaporative cooling effects of different types of vegetation differed significantly, with shrubs having the fastest ET rates, followed by arbors, and grasslands having relatively low ET rates. (2) Solar radiation and air temperature are the most crucial meteorological parameters for inducing ET on green roofs. In this study, the evaporative cooling performance showed the patterns of summer > winter and sunny > cloudy > rainy days. (3) In the spatial distribution of tree and irrigation plant groups, some low-temperature diffusion phenomena to the adjacent small microenvironments were evident, while the diffusion effect in winter is smaller and mainly shows the opposite warming characteristics. This study offers a valuable reference for quantifying the ET and evaporative cooling effects of various vegetation types on intensive green roofs, facilitating the optimization of vegetation configuration and supporting sustainable urban development. Full article
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<p>The location of the green roof of AQUA City shopping mall. (<b>a</b>) A map of the climatic zones of Chinese buildings. (<b>b</b>) The high-density neighborhood in which the building is located. (<b>c</b>) Information on the periphery of the site.</p>
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<p>Details of the green roof of AQUA City Shopping Mall; (<b>a</b>) an aerial floor plan and live view; (<b>b</b>) the classification of the site’s underlying surface.</p>
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<p>Comparison of estimation results by UAV thermal infrared remote sensing 3T model and Bowen’s ratio method.</p>
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<p>Daily trends in roof surface temperature and air temperature under three weather conditions: (<b>a</b>) summer, (<b>b</b>) winter.</p>
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<p>Spatial distribution of surface temperature of vegetation at typical moments under three weather conditions: (<b>a</b>) summer, (<b>b</b>) winter.</p>
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<p>Daily trends in the ET rate of different vegetation types under three weather conditions: (<b>a</b>) summer, (<b>b</b>) winter.</p>
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<p>Spatial distribution of ET rate of vegetation at typical moments under three weather conditions: (<b>a</b>) summer, (<b>b</b>) winter.</p>
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<p>Daily trends in evaporative cooling rate of different vegetation types under three weather conditions: (<b>a</b>) summer, (<b>b</b>) winter.</p>
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<p>Spatial distribution of evaporative cooling rate of vegetation at typical moments under three weather conditions: (<b>a</b>) summer, (<b>b</b>) winter.</p>
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18 pages, 10821 KiB  
Article
Thermal-Management Performance of Phase-Change Material on PV Modules in Different Climate Zones
by Liang Tang, Yong Luo, Linlin Yin, Jinwei Li and Xiaoling Cao
Energies 2024, 17(23), 6200; https://doi.org/10.3390/en17236200 - 9 Dec 2024
Viewed by 535
Abstract
Phase-change material (PCM) can enhance the efficiency of photovoltaic (PV) modules by reducing their temperature and is widely studied for thermal management. However, their performance varies due to differences in local solar radiation and climate conditions. Previous studies have mainly focused on the [...] Read more.
Phase-change material (PCM) can enhance the efficiency of photovoltaic (PV) modules by reducing their temperature and is widely studied for thermal management. However, their performance varies due to differences in local solar radiation and climate conditions. Previous studies have mainly focused on the thermal properties of PCM, but practical evaluation should consider specific local conditions. To investigate the thermal-management performance of PCMs in different zones and obtain optimal design parameters, this study investigated the temperature-control effect of PCMs on PV systems across different regions through experiments. The results revealed that the temperature-control performance of PCM was limited in cold regions. Furthermore, the study developed a PCM-PV model and employed response surface methodology along with an NSGA-II to analyze the temperature-control effectiveness of the PCM-PV system in nine regions of China. Pareto solutions were obtained for nine regions in China, balancing annual power generation and system costs. PCM effectiveness is limited in colder regions like Naqu, where it increases power generation by only 0.5%, while in other regions, it improves annual power generation by 1.4% to 3%, especially in areas with high temperatures and abundant solar resources. However, when considering life-cycle gains and initial investment, PCM technology may not always be economically efficient, highlighting the need for region-specific evaluations. Full article
(This article belongs to the Section A: Sustainable Energy)
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<p>Schematic drawing of two modules: (<b>a</b>) PV-ref and (<b>b</b>) PV-PCM.</p>
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<p>Real products of two modules.</p>
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<p>Preparation process of paraffin/expanded graphite composite phase-change materials.</p>
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<p>The PV temperature and power output in Jinan on 11 October 2022.</p>
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<p>The PV temperature and power output in Shangri-La on 11 November 2022.</p>
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<p>The PV temperature and power output in Ganzi on 17 November 2022.</p>
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<p>Heat transfer schematic diagram of the PV-PCM system. (<b>a</b>) heat transfer in the daytime (<b>b</b>) heat transfer at the nighttime.</p>
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<p>Annual daily hourly solar radiation and temperature of the nine selected cities: (<b>a</b>) solar radiation, (<b>b</b>) temperature.</p>
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<p>Thermal-management performance on a typical day of winter. (<b>a</b>) Solar radiation (<b>b</b>) Air temperature. (<b>c</b>) Temperature of PV panel (<b>d</b>) Liquid fraction of PCM.</p>
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<p>Thermal-management performance on a typical day of winter. (<b>a</b>) Solar radiation (<b>b</b>) Air temperature. (<b>c</b>) Temperature of PV panel (<b>d</b>) Liquid fraction of PCM.</p>
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<p>Thermal-management performance on a typical day of Summer. (<b>a</b>) Solar radiation (<b>b</b>) Air temperature. (<b>c</b>) Temperature of PV panel (<b>d</b>) Liquid fraction of PCM.</p>
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<p>Power generation in different regions.</p>
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16 pages, 4275 KiB  
Article
Improving Irrigation Water Use Efficiency and Maximizing Vegetable Yields with Drip Irrigation and Poly-Mulching: A Climate-Smart Approach
by Denis Bwire, Fumio Watanabe, Shinji Suzuki and Kana Suzuki
Water 2024, 16(23), 3458; https://doi.org/10.3390/w16233458 - 1 Dec 2024
Viewed by 1018
Abstract
Water management is a significant aspect of sustainable vegetable farming, especially in water-scarce regions. This, in addition to weed infestations, limits vegetable yields, which negatively affect food security in developing regions, particularly East Africa, where livelihoods chiefly depend on rain-fed agriculture. Vegetable farming, [...] Read more.
Water management is a significant aspect of sustainable vegetable farming, especially in water-scarce regions. This, in addition to weed infestations, limits vegetable yields, which negatively affect food security in developing regions, particularly East Africa, where livelihoods chiefly depend on rain-fed agriculture. Vegetable farming, especially tomato cultivation, requires more water. By promoting mulching, a soil water conservation tool, we can control surface evaporation (E), which, together with irrigation, enhances effective water use and vegetable yields. The experiments for this study were conducted at the Tokyo University of Agriculture, Japan, to evaluate the influences of different irrigation conditions and poly-mulching on weed control, tomato yields, and water use efficiency. The study was conducted from May to September 2018 on a 30 m2 plot in an open-ended greenhouse using drip irrigation for tomato cultivation. Three predetermined irrigation conditions of 4, 3, and 2 mm/day were applied on black poly-mulched and bare ridges. Data on soil conditions—soil temperature, as well as meteorological variables, including solar radiation and temperature—were measured using thermocouple sensors and micro-hobo weather stations, respectively, during the tomato cultivation, while yield components—growth, yield, water productivity, and sugar content—were determined after harvest. The results of a two-way ANOVA show that irrigation conditions with poly-mulching reduced the weed biomass significantly, and improved yields and water use efficiency compared to the irrigation conditions on bare ridges. The application of 4, 3, and 2 mm/day irrigation with poly-mulching significantly reduced the weed biomass by 5% compared to the same irrigation conditions on bare ridges. Similarly, 4 and 3 mm/day irrigation conditions with poly-mulching significantly increased the tomato yield by 5% compared to 2 mm/day on bare ridges. The bigger roots were concentrated and widely distributed at the shallow soil depth (0–20 cm) of the ridges with high irrigation amounts, while the small and thin roots were in deeper soil layers (30–45 cm). This study provides scientific knowledge on the application of predetermined irrigation conditions that can be (i) integrated into irrigation scheduling and (ii) adopted for regions facing water scarcity and limited or no in situ meteorological data, to improve water use efficiency for vegetable cultivation. Full article
(This article belongs to the Special Issue Advances in Agricultural Irrigation Management and Technology)
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<p>Schematic experimental design and tomato cultivation with poly-mulch in an open-ended greenhouse. 1, NPC (low pressure) drip lines; <span class="html-fig-inline" id="water-16-03458-i001"><img alt="Water 16 03458 i001" src="/water/water-16-03458/article_deploy/html/images/water-16-03458-i001.png"/></span>, location of tensiometers and thermocouple sensors; 2, 3 and 4 are the main field, ridges and trenches, respectively; <span class="html-fig-inline" id="water-16-03458-i002"><img alt="Water 16 03458 i002" src="/water/water-16-03458/article_deploy/html/images/water-16-03458-i002.png"/></span> denotes the thermocouple data lodgers, while gold and dark colors represent bare and mulched ridges.</p>
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<p>Schematic illustration of the installed sensors (<b>a</b>) and photo of the thermal couples (<b>b</b>).</p>
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<p>Average diurnal temperature variation and relative humidity as measured by the thermo recorder-TR-72U for a given tomato cultivation period.</p>
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<p>The effect of black poly-mulch on soil temperature measured at a 10 cm soil depth.</p>
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<p>Effects of irrigation conditions and poly-mulching on tomato growth. M is poly-mulch and NM is bare ridges, and * indicates a significant difference at <span class="html-italic">p</span> &lt; 0.05.</p>
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<p>Influence of irrigation conditions on (<b>a</b>) chlorophyll content and (<b>b</b>) tomato sugar content. Here, M is poly-mulch and NM is bare ridges, with significant difference at <span class="html-italic">p</span> &lt; 0.05.</p>
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<p>Influence of irrigation conditions and poly-mulch on tomato yield components. M is poly-mulch, and NM is bare ridges, with yield in kg (<b>a</b>) and fruit number (<b>b</b>) at <span class="html-italic">p</span> &lt; 0.05.</p>
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<p>Root distribution, where (<b>a</b>) mulch is poly-mulch and (<b>b</b>) no-mulch is bare soil ridges under different irrigation conditions.</p>
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<p>Root length density (RLD) under different irrigation conditions, (<b>a</b>) poly-mulched and (<b>b</b>) bare soil ridges.</p>
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<p>Comparison of irrigation conditions and tomato crop water needs (ET<sub>C</sub>) during tomato cultivation.</p>
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34 pages, 37752 KiB  
Article
Improving Solar Radiation Prediction in China: A Stacking Model Approach with Categorical Boosting Feature Selection
by Yuehua Ding, Yuhang Wang, Zhe Li, Long Zhao, Yi Shi, Xuguang Xing and Shuangchen Chen
Atmosphere 2024, 15(12), 1436; https://doi.org/10.3390/atmos15121436 - 29 Nov 2024
Viewed by 423
Abstract
Solar radiation is an important energy source, and accurately predicting it [daily global and diffuse solar radiation (Rs and Rd)] is essential for research on surface energy exchange, hydrologic systems, and agricultural production. However, Rs and Rd estimation [...] Read more.
Solar radiation is an important energy source, and accurately predicting it [daily global and diffuse solar radiation (Rs and Rd)] is essential for research on surface energy exchange, hydrologic systems, and agricultural production. However, Rs and Rd estimation relies on meteorological data and related model parameters, which leads to inaccuracy in some regions. To improve the estimation accuracy and generalization ability of the Rs and Rd models, 17 representative radiation stations in China were selected. The categorical boosting (CatBoost) feature selection algorithm was utilized to construct a novel stacking model from sample and parameter diversity perspectives. The results revealed that the characteristics related to sunshine duration (n) and ozone (O3) significantly affect solar radiation prediction. The proposed new ensemble model framework had better accuracy than base models in root mean square error (RMSE), coefficient of determination (R2), mean absolute error (MAE), and global performance index (GPI). The solar radiation prediction model is more applicable to coastal areas, such as Shanghai and Guangzhou, than to inland regions of China. The range and mean of RMSE, MAE, and R2 for Rs prediction are 1.5737–3.7482 (1.9318), 1.1773–2.6814 (1.4336), and 0.7597–0.9655 (0.9226), respectively; for Rd prediction, they are 1.2589–2.9038 (1.8201), 0.9811–2.1024 (1.3493), and 0.5153–0.9217 (0.7248), respectively. The results of this study can provide a reference for Rs and Rd estimation and related applications in China. Full article
(This article belongs to the Section Atmospheric Techniques, Instruments, and Modeling)
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<p>Distribution map of solar radiation stations.</p>
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<p>Correlation analysis of the prediction error of a single ML model.</p>
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<p>Schematics of the stacking model.</p>
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<p>Feature importance results of the CatBoost feature selection algorithm: (<b>a</b>) (R<sub>s</sub>); (<b>b</b>) (R<sub>d</sub>).</p>
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<p>Mean absolute SHAP value of the stacking model in Beijing: (<b>a</b>) (R<sub>s</sub>); (<b>b</b>) (R<sub>d</sub>).</p>
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<p>The SHAP value of input features in Beijing: (<b>a</b>) (R<sub>s</sub>); (<b>b</b>) (R<sub>d</sub>). Note: Red indicates high eigenvalues, and blue indicates low eigenvalues. A SHAP value greater than 0 indicates that the feature has a positive impact on radiation, and a SHAP value less than 0 indicates that the feature has a negative impact on radiation.</p>
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<p>Daily R<sub>s</sub> evaluation metrics for 17 stations predicted by various ML models during the testing phase.</p>
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<p>Daily R<sub>d</sub> evaluation metrics for 17 stations predicted by various ML models during the testing phase.</p>
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<p>R<sub>s</sub> scatter density diagrams for different models at Beijing station.</p>
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<p>R<sub>d</sub> scatter density diagrams for different models at Beijing station.</p>
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<p>Box diagram of evaluation indexes of various ML models in the R<sub>s</sub> test stage.</p>
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<p>Box diagram of evaluation indexes of various ML models in the R<sub>d</sub> test stage.</p>
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<p>Taylor diagram of Beijing application model to predict R<sub>s</sub>.</p>
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<p>Taylor diagram of Beijing application model to predict R<sub>d</sub>.</p>
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<p>The mean absolute SHAP value of the stacking model in estimating R<sub>s</sub>.</p>
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<p>The mean absolute SHAP value of the stacking model in estimating R<sub>d</sub>.</p>
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<p>The input feature SHAP value of stacking when estimating R<sub>s</sub>.</p>
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<p>The input feature SHAP value of stacking when estimating R<sub>d</sub>.</p>
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<p>Scatter density plot of different models in estimating R<sub>s</sub>.</p>
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<p>Scatter density plot of different models in estimating R<sub>s</sub>.</p>
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<p>Scatter density plot of different models in estimating R<sub>s</sub>.</p>
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<p>Scatter density plot of different models in estimating R<sub>d</sub>.</p>
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<p>Scatter density plot of different models in estimating R<sub>d</sub>.</p>
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<p>Scatter density plot of different models in estimating R<sub>d</sub>.</p>
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<p>Taylor plots of different models when estimating R<sub>s</sub>.</p>
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<p>Taylor plots of different models when estimating R<sub>d</sub>.</p>
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15 pages, 12141 KiB  
Article
Black Body-Inspired Chemically Oxidized Nanostructures with Varied Perforations: A New Frontier in Solar Desalination
by Ajay Kumar Kaviti, Shaik Afzal Mohiuddin and Vineet Singh Sikarwar
Water 2024, 16(23), 3444; https://doi.org/10.3390/w16233444 - 29 Nov 2024
Viewed by 528
Abstract
Ideal black bodies absorb all electromagnetic energy without reflecting it. As it does not reflect or transmit light, it appears black when cold. Heated black bodies emit black body radiation, a temperature-dependent spectrum. This idea helps scientists and engineers comprehend heat radiation and [...] Read more.
Ideal black bodies absorb all electromagnetic energy without reflecting it. As it does not reflect or transmit light, it appears black when cold. Heated black bodies emit black body radiation, a temperature-dependent spectrum. This idea helps scientists and engineers comprehend heat radiation and design efficient solar desalination absorbers. This work uses the black body concept to create three non-contact nanostructured single-slope solar stills (NCNSSSs) with varied perforation diameters (2.4 mm, 3.2 mm, and 3.8 mm). The chemical oxidation of mirror-polished perforated stainless steel 304 sheets resulted in highly absorptive top surfaces with 90% absorptivity. The structures’ bottom surfaces were coated with a commercial high-emissivity coating to make them 85% emissive. The developed non-contact nanostructures absorbed maximum solar light and converted it into infrared radiation using a highly emissive bottom coating and a very absorptive top coating. Water, an excellent absorber of infrared (IR) radiation, readily absorbs the IR radiations and evaporates through the perforations, thus producing a desalination effect. Experiments were conducted parallelly in three NCNSSSs under the same weather conditions at three water depths. It was observed that non-contact nanostructure perforation diameters affected solar still performance. The NCNSSS-3 (3.8 mm) achieved a 9.89% and 13.47% higher productivity than the NCNSSS-2 (3.2 mm) and NCNSSS-1 (2.4 mm) at a 5 mm water depth. Additionally, fouling studies, expedited corrosion studies, and water quality assessments (TDS, salinity, fluoride, chlorides, nitrates, sodium) were performed. Water eminence examinations confirmed that the collected freshwater was bacteria-free and safe to drink. Full article
(This article belongs to the Special Issue Water Treatment Technology for Emerging Contaminants)
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<p>High absorption nanocoating on perforated stainless steel sheet: graphical illustration of its evolution [<a href="#B4-water-16-03444" class="html-bibr">4</a>].</p>
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<p>The steps employed to make a high-emissivity layer for the back of the perforated SS304 sheet.</p>
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<p>(<b>a</b>) Nanocoating with high absorption (upper surfaces) and (<b>b</b>) coating with high emissivity (lower surfaces) on three perforated sheets with diameters of 2.4 mm, 3.2 mm, and 3.8 mm, and constant pitch of 8 mm.</p>
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<p>Non-contact nanostructure operation principle. (<b>a</b>) Solar and infrared photon penetration depth into water is shown in picture at bottom, while flux spectra of sources of solar radiation and black bodies are shown in picture at top. (<b>b</b>) Water in contact with solar-absorbing material, in which thermal conduction carries heat to water (right side/upper figure), and (<b>c</b>) heat transfer through thermal radiation to water by NCNS at specific distance from water surface (right side/lower figure).</p>
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<p>Photographs taken from the inside of the NCNSSS with two views: (<b>a</b>) before the NCNS was placed; (<b>b</b>) after the NCNS was placed.</p>
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<p>(<b>a</b>) Digital image of NCNSSS experimental arrangement, (<b>b</b>) schematic representation of NCNSSSs with different perforation diameters.</p>
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<p>Fluctuation in (<b>a</b>) solar intensity and (<b>b</b>) atmospheric temperature.</p>
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<p>Changes in water temperature at different depths.</p>
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<p>Fluctuation in glass temperature over time.</p>
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<p>Fluctuation in emitter temperature over time.</p>
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<p>Fluctuation in vapor temperature over time.</p>
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<p>The variation in the wind speed vs. time.</p>
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<p>Variation in hourly productivity vs. time.</p>
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<p>(<b>a</b>) Cumulative yield over time, (<b>b</b>) cumulative yield against water depth.</p>
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10 pages, 3781 KiB  
Article
The Photothermal Synergistic Mechanism of Rock Varnish Photoconductance Under Laser Irradiation
by Xinyang Miao, Tiantian An, Lijun Wang, Shujie Xiong, Huanxi Zhang, Jiahao Yi, Bingbing Zhao and Kun Zhao
Materials 2024, 17(23), 5841; https://doi.org/10.3390/ma17235841 - 28 Nov 2024
Viewed by 408
Abstract
Rock varnishes, complex structures formed by long-term deposition on rocks, exhibit unique light absorption characteristics and are widely distributed across arid environments on Earth’s surface. The varnishes possess the ability to absorb and convert photons from solar radiation into electrons, which represents a [...] Read more.
Rock varnishes, complex structures formed by long-term deposition on rocks, exhibit unique light absorption characteristics and are widely distributed across arid environments on Earth’s surface. The varnishes possess the ability to absorb and convert photons from solar radiation into electrons, which represents a newly discovered fundamental energy form in nature, with further elucidation required regarding the underlying mechanism of how semiconductor minerals respond to light radiation. The regulations governing the photoconductive responses of samples from the Alashan region in Gobi, China, and the mechanisms exhibited by rock rock varnishes under various bias voltages and irradiation wavelengths (532 nm, 808 nm, and 1064 nm) were studied. The photoconductivity response is positively correlated with the applied external bias, and the response caused by shorter wavelengths is larger. The synergistic effect was quantitatively assessed by monitoring and fitting the correlation between photoconductivity, temperature, and time during laser irradiation. As an effective method to study the fundamental physical properties of semiconductor minerals, the photoconductivity testing will help to establish a fundamental framework for investigating the intrinsic physical characteristics of natural rock varnishes. Full article
(This article belongs to the Special Issue Advances in Plasma and Laser Engineering (Second Edition))
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<p>Basic characterization of rock varnish sample cutting. (<b>a</b>) SEM topography of the interface between the rock varnish layer and the rock basement; (<b>b</b>) locally enlarged topography; EDS spectra of the rock varnish layer (<b>c</b>) region A and (<b>d</b>) region B. (<b>e</b>) Distribution of elements in region A and inner region B, including mass percentage and atomic percentage. (<b>f</b>) XRD results for both the rock varnish layer and rock basement.</p>
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<p>(<b>a</b>) Schematic diagram of laser irradiation test device for rock varnish. The relationship of (<b>b</b>) current and (<b>c</b>) temperature of S1 and S2 samples with time under laser irradiation; 532 nm laser turned on at 100 s and turned off at 200 s.</p>
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<p>(<b>a</b>) Photoconductivity waveform and (<b>b</b>) temperature–time curve of rock varnish samples irradiated by 532 nm laser at different bias pressures. The relationship between bias and (<b>c</b>) Δ<span class="html-italic">I</span> and (<b>d</b>) Δ<span class="html-italic">T</span> under different laser irradiation.</p>
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<p>Exponential fitting of (<b>a</b>) photoconductive response rise process and (<b>b</b>) temperature change rise process of rock varnish samples irradiated by laser at different wavelengths. The fitting parameters under different wavelength laser irradiation include (<b>c</b>) coefficients <span class="html-italic">A</span><sub>1</sub>, <span class="html-italic">A</span><sub>2</sub> and (<b>d</b>) time constants <span class="html-italic">τ</span><sub>1</sub> and <span class="html-italic">τ</span><sub>2</sub>.</p>
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<p>Exponential fitting of (<b>a</b>) photoconductive response decline process and (<b>b</b>) temperature drop process of the sample after laser irradiation is stopped. The fitting parameters under different wavelength laser irradiation include (<b>c</b>) coefficients <span class="html-italic">A</span><sub>3</sub>, <span class="html-italic">A</span><sub>4</sub> and (<b>d</b>) time constants <span class="html-italic">τ</span><sub>3</sub> and <span class="html-italic">τ</span><sub>4</sub>.</p>
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<p>The relationship between Δ<span class="html-italic">I</span> and Δ<span class="html-italic">T</span> at different laser wavelengths.</p>
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11 pages, 3987 KiB  
Article
A Rectangular Spiral Inward–Outward Alternating-Flow Polymer Thermal Collector for a Solar Water Heating System—A Preliminary Investigation in the Climate of Seri Iskandar, Malaysia
by Taib Iskandar Mohamad and Mohammad Danish Shareeman Mohd Shaifudeen
Appl. Sci. 2024, 14(23), 11045; https://doi.org/10.3390/app142311045 - 27 Nov 2024
Viewed by 596
Abstract
A flat-plate unglazed solar water heater (SWH) with a polymer thermal absorber was developed and experimented with. Polymer thermal absorbers could be a viable alternative to metal thermal absorbers for SWH systems. The performance of this polymer SWH system was measured based on [...] Read more.
A flat-plate unglazed solar water heater (SWH) with a polymer thermal absorber was developed and experimented with. Polymer thermal absorbers could be a viable alternative to metal thermal absorbers for SWH systems. The performance of this polymer SWH system was measured based on inlet and outlet water temperature, water flow rate, ambient air temperature and solar irradiance. The polymer thermal absorbers were hollow Polyvinyl Chloride (PVC) tubes with a 20 mm external diameter and 3 mm thickness and were painted black to enhance radiation absorption. The pipes are arranged in a rectangular spiral inward–outward alternating-flow (RSioaf) pattern. The collector pipes were placed in a 1 m × 1 m enclosure with bottom insulation and a reflective surface for maximized radiation absorption. Water circulated through a closed loop with an uninsulated 16 L storage tank, driven by a pump and controlled by two valves to maintain a mass flow rate of 0.0031 to 0.0034 kg·s−1. The test was conducted under a partially clouded sky from 9 a.m. to 5 p.m., with solar irradiance between 105 and 1003 W·m−2 and an ambient air temperature of 27–36 °C. This SWH system produced outlet hot water at 65 °C by midday and maintained the storage temperature at 63 °C until the end of the test period. Photothermal energy conversion was recorded, showing a maximum value of 23%. Results indicate that a flat-plate solar water heater with a polymer thermal absorber in an RSioaf design can be an effective alternative to an SWH with a metal thermal absorber. Its performance can be improved with glazing and optimized tube sizing. Full article
(This article belongs to the Special Issue Advanced Solar Energy Materials: Methods and Applications)
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<p>Two-dimensional drawing of the RSioaf design with the water flow direction.</p>
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<p>RSioaf polymer tube thermal collector components.</p>
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<p>Schematic diagram of the experimental setup.</p>
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<p>Physical setup of the system.</p>
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<p>Solar irradiance and ambient air temperature plotted against time.</p>
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<p>Hourly recorded inlet and outlet water temperature.</p>
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<p>Water mass flow rate through thermal collector tubes.</p>
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<p>Hourly photothermal conversion efficiency with respect to solar irradiance.</p>
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<p>Performance characteristic of the polymer SWHS with an RSioaf collector tube design.</p>
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