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Search Results (43,062)

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23 pages, 1583 KiB  
Article
Mitigating Randomness Leakage in SM2 White-Box Implementations via Trusted Execution Environments
by Hongyu Zhu, Yubo Song, Yang Li, Weiqiang Luo, Jianwei Tian, Fangliao Yang, Wenchang Liu, Yi Gong and Ding Li
Electronics 2025, 14(2), 301; https://doi.org/10.3390/electronics14020301 - 13 Jan 2025
Abstract
White-box cryptography plays a vital role in untrusted environments where attackers can fully access the execution process and potentially expose cryptographic keys. It secures keys by embedding them within complex and obfuscated transformations, such as lookup tables and algebraic manipulations. However, existing white-box [...] Read more.
White-box cryptography plays a vital role in untrusted environments where attackers can fully access the execution process and potentially expose cryptographic keys. It secures keys by embedding them within complex and obfuscated transformations, such as lookup tables and algebraic manipulations. However, existing white-box protection schemes for SM2 signatures face vulnerabilities, notably random number leakage, which compromises key security and diminishes overall effectiveness. This paper proposes an improved white-box implementation of the SM2 signature computation leveraging a Trusted Execution Environment (TEE) architecture. The scheme employs three substitution tables for SM2 key generation and signature processes, orchestrated by a random bit string k. The k value and lookup operations are securely isolated within the TEE, effectively mitigating the risk of k leakage and enhancing overall security. Experimental results show our scheme enhances security, reduces storage, and improves performance over standard SM2 signature processing, validating its efficacy with TEE and substitution tables in untrusted environments. Full article
(This article belongs to the Section Artificial Intelligence)
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Figure 1
<p>An elliptic curve equation.</p>
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<p>TEE in a computing device.</p>
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<p>Overall design of the SM2 white-box implementation.</p>
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<p>TEE-based page table protection flowchart.</p>
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<p>White-box diversity and ambiguity for different λ values.</p>
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<p>Performance comparison of SM2 white-box methods.</p>
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20 pages, 2844 KiB  
Article
Rheology and Stability of Hydrocarbon-Based Gelled Fuels for Airbreathing Applications
by Simone Dell’Acqua, Francesco Morando, Stefania Carlotti and Filippo Maggi
Aerospace 2025, 12(1), 49; https://doi.org/10.3390/aerospace12010049 - 13 Jan 2025
Abstract
Gelled fuels are rheologically complex, non-Newtonian fluids. They combine the benefits of both liquid and solid states, reducing risks of leakage, spilling, and sloshing during storage while maintaining the ability to be sprayed inside a combustion chamber. Additionally, suspending energetic particles, such as [...] Read more.
Gelled fuels are rheologically complex, non-Newtonian fluids. They combine the benefits of both liquid and solid states, reducing risks of leakage, spilling, and sloshing during storage while maintaining the ability to be sprayed inside a combustion chamber. Additionally, suspending energetic particles, such as metal powders of aluminum and boron, can significantly enhance their energy density compared to conventional liquid fuels. In this study, several kerosene-based and ethanol-based formulations were experimentally investigated, using both organic and inorganic gelling agents. The compositions were optimized in terms of the gellant amount and manufacturing process. Some of the most promising gellants for kerosene include fatty acids, such as Thixcin® R or THIXATROL® ST, and metallic soaps, such as aluminum stearate and zinc stearate. The effects of various co-solvents were assessed, including ketones (methyl isoamyl ketone, methyl ethyl ketone, and acetone) and alcohols (ethanol and octadecanol). Sugar polymers like hydroxypropyl cellulose were tested as gelling agents for ethanol. A preliminary rheological analysis was conducted to characterize their behavior at rest and under shear stress. Finally, a novel approach was introduced to study the stability of the gels under vibration, which was derived from a realistic mission profile of a ramjet. Finally, the ideal gravimetric specific impulse was evaluated through ideal thermochemical computations. The results showed that promising formulations can be found in both kerosene-based and ethanol-based gels. Such compositions are of interest in practical airbreathing applications as they have demonstrated excellent stability under vibration, ideal combustion properties, and pronounced shear-thinning behavior. Full article
13 pages, 3391 KiB  
Article
Preparation of a Silicon/MXene Composite Electrode by a High-Pressure Forming Method and Its Application in Li+-Ion Storage
by Yonghao Liu, Dawei Zhao, Lujia Cong, Yanfeng Han, Mingdi Fu, Xiaoxin Wu and Junkai Zhang
Molecules 2025, 30(2), 297; https://doi.org/10.3390/molecules30020297 - 13 Jan 2025
Abstract
The main component of high-capacity silicon-based electrodes is silicon powder, which necessitates intricate processing to minimize volume growth and powder separation while guaranteeing the ideal Si content. This work uses the an situ high-pressure forming approach to create an MXene/m-Si/MXene composite [...] Read more.
The main component of high-capacity silicon-based electrodes is silicon powder, which necessitates intricate processing to minimize volume growth and powder separation while guaranteeing the ideal Si content. This work uses the an situ high-pressure forming approach to create an MXene/m-Si/MXene composite electrode, where MXene refers to Ti3C2TX, and m-Si denotes two-phase mixed nano-Si particles. The sandwich shape promotes silicon’s volume growth and stops active particles from spreading. The conductive structure of Ti3C2TX MXene increases the efficiency of charge transfer while reducing internal resistance. After 100 cycles, the composite electrode’s original capacity of 1310.9 mAh g−1 at a current density of 0.5 A g−1 is maintained at 781.0 mAh g−1. These findings lay the foundation for further investigations into Si matrix composite electrodes. Full article
(This article belongs to the Special Issue The Way Forward in MXenes Materials)
46 pages, 8792 KiB  
Review
Polysaccharides: The Sustainable Foreground in Energy Storage Systems
by Sharin Maria Thomas, Pedro Gómez-Romero and Rosa M. González-Gil
Polysaccharides 2025, 6(1), 5; https://doi.org/10.3390/polysaccharides6010005 - 13 Jan 2025
Abstract
Polysaccharides offer a perfect option as raw materials for the development of a new generation of sustainable batteries and supercapacitors. This is due to their abundance and inherent structural characteristics. Polysaccharides can be chemically functionalized and engineered, offering a wide range of possibilities [...] Read more.
Polysaccharides offer a perfect option as raw materials for the development of a new generation of sustainable batteries and supercapacitors. This is due to their abundance and inherent structural characteristics. Polysaccharides can be chemically functionalized and engineered, offering a wide range of possibilities as electrode materials (as precursors of porous nanocarbons), binders and separators. Their hierarchical morphology also enables their exploitation as aerogel and hydrogel structures for quasi-solid and solid polymer electrolytes with high conductivity and wide voltage stability windows. In this review, we discuss how different polysaccharides, such as lignocellulosic biomass, starch, chitosan, natural gums, sugars and marine polysaccharides, can be applied in different components of energy storage systems (ESSs). An overview of the recent research work adhering to each functionality of different polysaccharides in various storage systems is provided. Full article
(This article belongs to the Collection Current Opinion in Polysaccharides)
14 pages, 1066 KiB  
Article
Comparison of Molten Salts and Thermal Oil in Parabolic Trough Power Plants for Different Sites and Different Storage Capacities
by Jürgen Dersch, Michael Karl Wittmann and Tobias Hirsch
Energies 2025, 18(2), 326; https://doi.org/10.3390/en18020326 - 13 Jan 2025
Abstract
This study compares the levelized cost of energy (LCOE) of parabolic trough solar power plants using thermal oil or two different molten salt mixtures located at three different sites and with different thermal storage capacities. The necessity of using appropriate model approaches for [...] Read more.
This study compares the levelized cost of energy (LCOE) of parabolic trough solar power plants using thermal oil or two different molten salt mixtures located at three different sites and with different thermal storage capacities. The necessity of using appropriate model approaches for the temperatures along a loop of the solar field is discussed, as well as the utilization of heat from thermal storage for freeze protection of the molten salt plants. The ternary salt mixture with a lower temperature limit of 170 °C and an upper temperature limit of 500 °C shows the lowest LCOE for all sites and almost all investigated storage capacities. Molten salts as heat transfer fluids are particularly favorable for sites with high irradiation and plants with large storage capacities of more than six full load hours. Full article
(This article belongs to the Special Issue Solar Energy and Resource Utilization)
34 pages, 8302 KiB  
Review
Native Cyclodextrin-Based Metal–Organic Frameworks (MOFs): Synthesis, Characterization, and Potential Applications in Food Industry
by Siddanth Saxena and Manuel J. Lis
Molecules 2025, 30(2), 293; https://doi.org/10.3390/molecules30020293 - 13 Jan 2025
Abstract
Metal–organic frameworks (MOFs) have become a highly usable system in various sectors because of their highly ordered structure and high porosity providing them with high storage capacity. However, their use is sometimes forbidden in the food industry due to the presence of some [...] Read more.
Metal–organic frameworks (MOFs) have become a highly usable system in various sectors because of their highly ordered structure and high porosity providing them with high storage capacity. However, their use is sometimes forbidden in the food industry due to the presence of some organic compounds which have undesirable effects. Cyclodextrins, which are considered GRAS (Generally Recognized as Safe) by the FDA, comes as a very good alternative to previously used compounds for the development of the MOFs to be used in the food packaging industry, especially in the packaging sector. The cyclodextrin MOF does possess edible, biocompatible, as well as biodegradable characteristics and due to these reasons, they have gained attention from researchers in the food industry. In this review, we focus on the recent advancements in the field of CD MOFs. We have emphasized the synthesis of these MOFs through different techniques, formations of their inclusion complex with bioactive compounds, and their characterization. Finally, we discussed the use of CD MOFs as carriers for various highly volatile bioactive compounds and their ability to increase the solubility and stability of these bioactive compounds. Full article
(This article belongs to the Special Issue Metal Organic Frameworks: Synthesis and Application, 3rd Edition)
15 pages, 461 KiB  
Article
Characteristics of Soft Wheat and Tiger Nut (Cyperus esculentus) Composite Flour Bread
by Svitlana Nedviha and Joanna Harasym
Foods 2025, 14(2), 229; https://doi.org/10.3390/foods14020229 - 13 Jan 2025
Abstract
This study investigated the effects of tiger nut flour (TNF) incorporation (5–25%) on wheat-based bread characteristics. Dough rheology analysis revealed optimal gas retention at 10% TNF addition, while higher concentrations decreased dough stability. Physical analysis demonstrated that 10% TNF substitution yielded the highest [...] Read more.
This study investigated the effects of tiger nut flour (TNF) incorporation (5–25%) on wheat-based bread characteristics. Dough rheology analysis revealed optimal gas retention at 10% TNF addition, while higher concentrations decreased dough stability. Physical analysis demonstrated that 10% TNF substitution yielded the highest specific volume (2.4 mL/g) and porosity (67.0%), with significant textural changes observed at higher concentrations. Bioactive compound analysis showed progressive increases in the total polyphenol content and antioxidant activity with increasing TNF levels, particularly in 25% TNF bread (111.31 mg TE/g dm in crumb). Storage studies over 7 days indicated that TNF incorporation affected bread staling characteristics, with 10–15% substitution levels maintaining better textural properties. The results suggest that TNF incorporation up to 15% can enhance bread’s nutritional value, while maintaining acceptable technological properties, with 10% substitution showing an optimal balance between functional benefits and bread quality. Full article
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<p>Whitening index (WI) and browning index (BI) of the samples on the day of baking and after 7 days of storage.</p>
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24 pages, 529 KiB  
Article
Analysis and Evaluation of Intel Software Guard Extension-Based Trusted Execution Environment Usage in Edge Intelligence and Internet of Things Scenarios
by Zhiyuan Wang and Yuezhi Zhou
Future Internet 2025, 17(1), 32; https://doi.org/10.3390/fi17010032 (registering DOI) - 13 Jan 2025
Abstract
With the extensive deployment and application of the Internet of Things (IoT), 5G and 6G technologies and edge intelligence, the volume of data generated by IoT and the number of intelligence applications derived from these data are rapidly growing. However, the absence of [...] Read more.
With the extensive deployment and application of the Internet of Things (IoT), 5G and 6G technologies and edge intelligence, the volume of data generated by IoT and the number of intelligence applications derived from these data are rapidly growing. However, the absence of effective mechanisms to safeguard the vast data generated by IoT, along with the security and privacy of edge intelligence applications, hinders their further development and adoption. In recent years, Trusted Execution Environment (TEE) has emerged as a promising technology for securing cloud data storage and cloud processing, demonstrating significant potential for ensuring data and application confidentiality in more scenarios. Nevertheless, applying TEE technology to enhance security in IoT and edge intelligence scenarios still presents several challenges. This paper investigates the technical challenges faced by current TEE solutions, such as performance overhead and I/O security issues, in the context of the resource constraints and data mobility that are inherent to IoT and edge intelligence applications. Using Intel Software Guard Extensions (SGX) technology as a case study, this paper validates these challenges through extensive experiments. The results provide critical assessments and analyses essential for advancing the development and usage of TEE in IoT and edge intelligence scenarios. Full article
(This article belongs to the Special Issue Edge Intelligence: Edge Computing for 5G and the Internet of Things)
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<p>Different SGX implementations. (<b>a</b>) SGX SDK-based. (<b>b</b>) LibOS-based.</p>
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<p>CPU-intensive workload.</p>
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<p>Sequential read/write performance. (<b>a</b>) Sequential read. (<b>b</b>) Sequential write.</p>
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<p>Random read/write performance. (<b>a</b>) Random read. (<b>b</b>) Random write.</p>
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<p>Impact of concurrency on throughput.</p>
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<p>Comparison on CPU usage.</p>
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<p>Impact of file size on latency.</p>
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<p>Process creation latency.</p>
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<p>Inter-process communication.</p>
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<p>Throughput versus latency of Memcached.</p>
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13 pages, 5486 KiB  
Article
Development of Gelatin/Zein Electrospun Nanofiber Films Containing Purple Sweet Potato Anthocyanin for Real-Time Freshness Monitoring of Aquatic Products
by Chenyu Wang, Aixia Huang, Jiaxuan Fang, Shuangdie Li, Siyu Wu, Di Sun, Qingbao Ma, Zhongjie Yu, Yu Liu and Wei Jiang
Coatings 2025, 15(1), 79; https://doi.org/10.3390/coatings15010079 - 13 Jan 2025
Abstract
In the present study, an electrospinning freshness monitoring film prepared by gelatin/zein loading with purple sweet potato anthocyanins (PSPA) was produced to track the freshness state of Penaeus vannamei. The electrospun nanofiber films with the gelatin and zein weight ratio of 1:0, [...] Read more.
In the present study, an electrospinning freshness monitoring film prepared by gelatin/zein loading with purple sweet potato anthocyanins (PSPA) was produced to track the freshness state of Penaeus vannamei. The electrospun nanofiber films with the gelatin and zein weight ratio of 1:0, 3:1, 2:1, and 1:1 were named GA, GZA 3:1, GZA 2:1, and GZA 1:1, respectively. The impacts of zein concentration on the electrospun nanofiber film properties were investigated. SEM results showed that a smooth surface was observed for the electrospun nanofiber films. As the zein content increased, the average diameter decreased. No new characteristic peaks were shown by FTIR and XRD, indicating the good compatibility between gelatin, zein, and PSPA. The incorporation of zein decreased the swelling ratio (from completely dissolved to 100.7%) and water solubility (from 100% to 30%) and increased the water contact angle (from 0° to 113.3°). The GA, GZA 3:1, GZA 2:1, and GZA 1:1 had apparent color changes to NH3 and demonstrated good stability and reversibility. Furthermore, the freshness states (fresh, sub-fresh, and spoiled) of Penaeus vannamei storage at 4 °C could be effectively distinguished by GZA 3:1 by showing different colors (from pink to grayish purple to blue). Consequently, GZA3:1 exhibited improved hydrophobicity and pH sensitivity and has great potential in real-time monitoring of aquatic product quality. Full article
(This article belongs to the Special Issue New Advance in Nanoparticles, Fiber, and Coatings)
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Figure 1
<p>SEM images and diameter distribution of (<b>a</b>) GA, (<b>b</b>) GZA 3:1, (<b>c</b>) GZA 2:1, and (<b>d</b>) GZA 1:1.</p>
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<p>(<b>a</b>) FTIR spectra, (<b>b</b>) XRD patterns, (<b>c</b>) thermogravimetric, and (<b>d</b>) differential thermal of electrospun nanofiber films.</p>
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<p>(<b>a</b>) Color change of films to volatile ammonia (0.8 mol/L) for 1 min; (<b>b</b>) ΔE of films in the ammonia-air circulation.</p>
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<p>ΔE values of GA, GZA 3:1, GZA 2:1, and GZA 1:1 during storage at (<b>a</b>) 4 °C and (<b>b</b>) 25 °C for 20 days; (<b>c</b>) Color response and (<b>d</b>) ΔE values of electrospun nanofiber films to ammonia. GA, GZA 3:1, GZA 2:1, and GZA 1:1 indicate freshly prepared films. 4 °C GA, 4 °C GZA 3:1, 4 °C GZA 2:1 and 4 °C GZA 1:1 indicate films stored at 4 °C for 20 days. 25 °C GA, 25 °C GZA 3:1, 25 °C GZA 2:1 and 25 °C GZA 1:1 indicate films stored at 25 °C for 20 days.</p>
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<p>(<b>a</b>) The application photos of the experiments; (<b>b</b>) Colors of films; (<b>c</b>) pH values, (<b>d</b>) TVB-N contents and (<b>e</b>) TVC values of <span class="html-italic">Penaeus vannamei</span> during storage; (<b>f</b>) ∆E values of GA, GZA 3:1, GZA 2:1 and GZA 1:1 for freshness monitoring of <span class="html-italic">Penaeus vannamei</span>; The cluster analysis diagrams of freshness discrimination by ∆E values of (<b>g</b>) GA, (<b>h</b>) GZA 3:1, (<b>i</b>) GZA 2:1 and (<b>j</b>) GZA 1:1.</p>
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<p>(<b>a</b>) The application photos of the experiments; (<b>b</b>) Colors of films; (<b>c</b>) pH values, (<b>d</b>) TVB-N contents and (<b>e</b>) TVC values of <span class="html-italic">Penaeus vannamei</span> during storage; (<b>f</b>) ∆E values of GA, GZA 3:1, GZA 2:1 and GZA 1:1 for freshness monitoring of <span class="html-italic">Penaeus vannamei</span>; The cluster analysis diagrams of freshness discrimination by ∆E values of (<b>g</b>) GA, (<b>h</b>) GZA 3:1, (<b>i</b>) GZA 2:1 and (<b>j</b>) GZA 1:1.</p>
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16 pages, 6236 KiB  
Article
Hybrid Analysis of Biochar Production from Pyrolysis of Agriculture Waste Using Statistical and Artificial Intelligent-Based Modeling Techniques
by Hani Hussain Sait, Ramesh Kanthasamy and Bamidele Victor Ayodele
Agronomy 2025, 15(1), 181; https://doi.org/10.3390/agronomy15010181 - 13 Jan 2025
Abstract
Biochar is gaining recognition as a sustainable material, with several applications in soil amendment, carbon sequestration, nutrient dynamics, the remediation of organic contaminants from soil, and water filtration. However, understanding its characteristics is limited due to its intricate structure. This study used response [...] Read more.
Biochar is gaining recognition as a sustainable material, with several applications in soil amendment, carbon sequestration, nutrient dynamics, the remediation of organic contaminants from soil, and water filtration. However, understanding its characteristics is limited due to its intricate structure. This study used response surface methodology (RSM) and artificial neural networks (ANNs) to optimize and predict the production of biochar from the pyrolysis of palm kernel shells. To determine how residence time, nitrogen flow rate, and pyrolysis temperature affected biochar production, a Box–Behnken experimental design was employed. The prediction of the biochar yield was modeled using four different models of ANNs: narrow, medium, wide, and optimum. The physicochemical properties of the biochar produced at pyrolysis temperatures ranging from 400 to 800 °C were determined using X-ray diffraction (XRD), energy dispersive X-ray spectroscopy (EDX), nitrogen (N2) physisorption analysis, and field emission scanning electron microscopy (FESEM). With a p-value significantly lower than 0.05, the response surface quadratic model was found to be the most suitable to optimize the biochar yield obtained from the PKS pyrolysis. Biochar production was very sensitive to the three operating parameters: pyrolysis temperature, nitrogen flow rate, and pyrolysis time. With a coefficient of determination (R2) of 0.900, root mean square error (RMSE) of 0.936, and mean absolute error (MAE) of 0.743, the optimized ANN outperformed the other three ANN models tested. When compared to the optimized ANN, the response surface quadratic model with an R2 of 0.989 had better prediction of biochar yield. At optimized experimental conditions for nitrogen flow rate (150.01 mL/min), temperature (799.71 °C), and pyrolysis time (107.61 min), a biochar yield of 37.87% was obtained at a desirability function of 1. Full article
(This article belongs to the Section Soil and Plant Nutrition)
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<p>Schematic representation of the ANN architecture.</p>
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<p>Effect of (<b>a</b>) pyrolysis temperature and flow rate of N<sub>2</sub>, (<b>b</b>) pyrolysis temperature and time on stream, and (<b>c</b>) flow rate of N<sub>2</sub> and time on stream on biochar yield.</p>
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<p>The two most significant factors as a function of the desirability function.</p>
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<p>Feature analysis.</p>
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<p>Morphology of the biochar pyrolyzed at 400 °C: (<b>a</b>) 10 K and (<b>b</b>) 30 K magnifications; (<b>c</b>) EDX micrograph of the biochar pyrolyzed at 400 °C.</p>
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<p>Morphology of the biochar pyrolyzed at 600 °C: (<b>a</b>) 10 K and (<b>b</b>) 30 K magnifications; (<b>c</b>) EDX micrograph of the biochar pyrolyzed at 600 °C.</p>
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<p>Morphology of the biochar pyrolyzed at 800 °C: (<b>a</b>) 10 K and (<b>b</b>) 30 K magnifications; (<b>c</b>) EDX micrograph of the biochar pyrolyzed at 400 °C.</p>
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<p>XRD pattern of the biochar pyrolyzed at 400–800 °C.</p>
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<p>N<sub>2</sub> adsorption isotherm of the biochar pyrolyzed at 400–800 °C.</p>
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26 pages, 4478 KiB  
Article
A Two-Stage Robust Optimization Strategy for Long-Term Energy Storage and Cascaded Utilization of Cold and Heat Energy in Peer-to-Peer Electricity Energy Trading
by Yun Chen, Yunhao Zhao, Xinghao Zhang, Ying Wang, Rongyao Mi, Junxiao Song, Zhiguo Hao and Chuanbo Xu
Energies 2025, 18(2), 323; https://doi.org/10.3390/en18020323 - 13 Jan 2025
Abstract
This study addresses the optimization of urban integrated energy systems (UIESs) under uncertainty in peer-to-peer (P2P) electricity trading by introducing a two-stage robust optimization strategy. The strategy includes a UIES model with a photovoltaic (PV)–green roof, hydrogen storage, and cascading cold/heat energy subsystems. [...] Read more.
This study addresses the optimization of urban integrated energy systems (UIESs) under uncertainty in peer-to-peer (P2P) electricity trading by introducing a two-stage robust optimization strategy. The strategy includes a UIES model with a photovoltaic (PV)–green roof, hydrogen storage, and cascading cold/heat energy subsystems. The first stage optimizes energy trading volume to maximize social welfare, while the second stage maximizes operational profit, considering uncertainties in PV generation and power prices. The Nested Column and Constraint Generation (NC&CG) algorithm enhances privacy and solution precision. Case studies with three UIESs show that the model improves economic performance, energy efficiency, and sustainability, increasing profits by 1.5% over non-P2P scenarios. Adjusting the robustness and deviation factors significantly impacts P2P transaction volumes and profits, allowing system operators to optimize profits and make risk-aligned decisions. Full article
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Graphical abstract

Graphical abstract
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<p>Market framework for P2P electricity energy trading.</p>
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<p>Flowchart of the NC&amp;CG algorithm.</p>
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<p>Upper and lower bounds for outer and inner iteration: (<b>a</b>) upper and lower bounds for outer iteration; (<b>b</b>) upper and lower bounds for inner iteration.</p>
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<p>Energy flow map for UIESs.</p>
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<p>Flow diagrams for individual equipment units: (<b>a</b>) UIES1 energy transmission volumes by moment; (<b>b</b>) UIES2 energy transmission volumes by moment; (<b>c</b>) UIES3 energy transmission volumes by moment; (<b>d</b>) Total energy transmission volumes of three UIESs.</p>
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<p>Flow diagrams for individual equipment units: (<b>a</b>) UIES1 energy transmission volumes by moment; (<b>b</b>) UIES2 energy transmission volumes by moment; (<b>c</b>) UIES3 energy transmission volumes by moment; (<b>d</b>) Total energy transmission volumes of three UIESs.</p>
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<p>Comparison of UIES2 energy output in P2P and non-P2P transactions.</p>
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<p>Comparison of profits and trading volumes under different robust factors and maximum deviation factors: (<b>a</b>) comparison of profits under different robust factors and maximum deviation factors; (<b>b</b>) comparison of trading volumes under different robust factors and maximum deviation factors.</p>
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<p>Comparison of profits and trading volumes under different robust factors and maximum deviation factors: (<b>a</b>) comparison of profits under different robust factors and maximum deviation factors; (<b>b</b>) comparison of trading volumes under different robust factors and maximum deviation factors.</p>
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19 pages, 7230 KiB  
Article
Conservation Analysis and Colorimetric Characterization of Betalain Extracts from the Peel of Red Beetroot, Golden Beetroot, and Prickly Pear Applied to Cottage Cheese
by Elizabeth López-Solórzano, Claudia Muro, Yolanda Alvarado Perez, Andrea Y. Guadarrama-Lezama, Elsa Gutiérrez-Cortez and Juan Manuel Urrieta
Foods 2025, 14(2), 228; https://doi.org/10.3390/foods14020228 - 13 Jan 2025
Abstract
The maintenance of betalains and the color of extracts from the peel of red beetroot (RBAC), golden beetroot (YBAC), and purple prickly pear (PBAC) were evaluated, describing the capacity of their use as natural pigments and in the formulation of attractive and functional [...] Read more.
The maintenance of betalains and the color of extracts from the peel of red beetroot (RBAC), golden beetroot (YBAC), and purple prickly pear (PBAC) were evaluated, describing the capacity of their use as natural pigments and in the formulation of attractive and functional foods. Betalain extracts were prepared as juices from frozen and dehydrated peel, adding organic acids and concentrating for water reduction. Extracts were evaluated and applied on cottage cheese, measuring the capacity of betalains retention and pigmentation, during 10 days of storage of closed and opened products. Extracts of RBAC showed the highest betacyanin concentration, followed by YBAC with betaxanthins and PBAC with less betacyanin content. The pH stability for the extracts was pH4–7; RBAC and PBAC were stables at <90 °C, whereas YBAC exposed >125 °C. Extracts were constant during 10 days under oxygen and light exposure; however, YBAC exhibited low resistance in this environment. With cottage cheese, extracts exposed no changes in betalains and color on closed products (10 days of storage at 4 °C). In opened products, PBAC maintained the maximum betalains and color at 90%, PBAC at 75%, and YBAC at 60%. The obtained data contributed to use of agro-industrial residues, betalain extraction and conservation, and their potential use in food coloration and stabilization. Full article
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<p>Uv-vis spectra and images of betalain extracts from red beetroot, golden beetroot, and purple prickly pear from samples of RBAC, YBAC and PBAC.</p>
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<p>The color characteristics Chroma* and Hue° of the betalain extracts of RB, RBA, RBC RBAC, YB, YBA, YBC, YBAC, PB, PBA, PBC, and PBAC.</p>
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<p>Kinetics of betalains maintenance in extracts RBAC, YBAC, and PBAC.</p>
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<p>Luminosity L* and color difference ΔE from samples of cottage cheese with betalain extracts; conforming samples CCH + PBAC, CCH + RBAC and CCH-YBAC for closed products (above) and opened products (below).</p>
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22 pages, 4457 KiB  
Article
Sensitivity Analysis and Application of the Shanghai Model in Ultra-Deep Excavation Engineering
by Aoyang Ma, Weiyi Wang, Wenxuan Zhu, Zhonghua Xu and Guanlin Ye
Geotechnics 2025, 5(1), 6; https://doi.org/10.3390/geotechnics5010006 - 13 Jan 2025
Abstract
In deep foundation pit engineering, the soil undergoes a complex stress path, encompassing both loading and unloading phases. The Shanghai model, an advanced constitutive model, effectively accounts for the soil’s deformation characteristics under these varied stress paths, which is essential for accurately predicting [...] Read more.
In deep foundation pit engineering, the soil undergoes a complex stress path, encompassing both loading and unloading phases. The Shanghai model, an advanced constitutive model, effectively accounts for the soil’s deformation characteristics under these varied stress paths, which is essential for accurately predicting the horizontal displacement and surface settlement of the foundation pit’s enclosure structure. This model comprises eight material parameters, three initial state parameters, and one small-strain parameter. Despite its sophistication, there is a scarcity of numerical studies exploring the correlation between these parameters and the deformation patterns in foundation pit engineering. This paper initially establishes the superiority of the Shanghai model in ultra-deep circular vertical shaft foundation pit engineering by examining a case study of a nursery circular ultra-deep vertical shaft foundation pit, which is part of the Suzhou River section’s deep drainage and storage pipeline system pilot project in Shanghai. Subsequently, utilizing an idealized foundation pit engineering model, a comprehensive sensitivity analysis of the Shanghai model’s multi-parameter values across their full range was performed using orthogonal experiments. The findings revealed that the parameter most sensitive to the lateral displacement of the underground continuous wall was κ, with an increase in κ leading to a corresponding increase in displacement. Similarly, the parameter most sensitive to surface subsidence outside the pit was λ, with an increase in λ resulting in greater subsidence. Lastly, the parameter most sensitive to soil uplift at the bottom of the pit was also κ, with an increase in κ leading to more significant uplift. Full article
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<p>Numerical research path of deep excavation engineering based on Shanghai model.</p>
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<p>Superloading surface, normal yield surface, and subloading surface of soil.</p>
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<p>Introduction to constitutive parameters of Shanghai model.</p>
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<p>Layout of measurement points and structural parameters for deep foundation pit engineering in Miaopu.</p>
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<p>Three-dimensional finite element calculation model of Miaopu foundation pit.</p>
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<p>Finite element results of lateral displacement of underground continuous wall upon completion of foundation pit construction. (<b>a</b>) X-directional displacement of underground continuous wall (east side); (<b>b</b>) Y-direction displacement of underground continuous wall (north side); (<b>c</b>) total displacement of underground continuous wall.</p>
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<p>Comparison between the calculation results and actual measurements of the lateral displacement of the underground continuous wall at each stage.</p>
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<p>Comparison between the calculation results and actual measurements of the lateral displacement of the underground continuous wall at each stage.</p>
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<p>Finite element results of surface settlement outside the pit.</p>
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<p>Comparison between the calculated and measured settlement results of the surface soil outside the pit.</p>
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<p>Sensitivity study model of excavation engineering parameters.</p>
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<p>Orthogonal experimental research results.</p>
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16 pages, 7637 KiB  
Article
The Preparation of C-S-H Powder Seeds and Their Effect on the Early Hydration Performance of Cement Paste
by Chunlong Huang, Yiren Wang, Zhongyuan Wei and Yong Yu
Crystals 2025, 15(1), 73; https://doi.org/10.3390/cryst15010073 - 13 Jan 2025
Abstract
C-S-H/PCE suspension can boost the hydration degree and strength of cement composite binding. However, the suspension will inevitably precipitate after a period of time, which is not conducive to its preservation, and its low solid content increases transportation costs in practical applications. In [...] Read more.
C-S-H/PCE suspension can boost the hydration degree and strength of cement composite binding. However, the suspension will inevitably precipitate after a period of time, which is not conducive to its preservation, and its low solid content increases transportation costs in practical applications. In this study, utilizing synthetic PCE as a template, C-S-H/PCE suspension was synthesized using a co-precipitation method. Subsequently, powder seeds were produced via the spray-drying technique, and these prepared powder seeds were analyzed via microscopic characterization. The impact of these powder nucleating agents on cement hydration kinetics was evaluated through hydration heat measurements and hydration degree, fluidity, and compressive strength testing. The results indicated that these powder seeds exhibited a nano-film morphology. Their nucleation effect significantly enhanced the cement hydration rate, increased the degree of hydration, and improved strength. The hydration kinetics showed that the hydration of cement mixed with nucleating agents was not governed by a single reaction mechanism, but rather constitutes a complex, multi-component reaction process. As the content of nucleating agents increased, higher dosages of nucleating agents accelerated the production of more products within a short period, causing the system to rapidly transition to phase boundary reaction control. When the dosage of nucleating agents reached 2%, the cement hydration process bypassed the phase boundary reaction control stage and transitioned directly from the crystallization nucleation and crystal growth control process to the diffusion-controlled phase. Although the influence of powder seeds on the enhancement of the early-stage strength of mortar was slightly lower than that of the suspension, the powder was beneficial to its storage and transportation. Therefore, it has the potential to replace the suspension. Full article
(This article belongs to the Section Inorganic Crystalline Materials)
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<p>Preparation mechanism diagram of the PCE template and powder seeds.</p>
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<p>FTIR spectra of the PCE template.</p>
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<p>Size distribution of the PCE template.</p>
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<p>FTIR spectra of powder seeds.</p>
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<p>Particle size distribution of powder seeds.</p>
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<p>TEM images of powder seeds.</p>
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<p>XRD (<b>a</b>) and SEM with EDS (<b>b</b>) of powder seeds. Figure (<b>a</b>) shows the XRD pattern of the powder seeds, and Figure (<b>b</b>) shows the SEM image and EDS pattern of the powder seeds. The EDS pattern is from the blue area of synthetic powder seeds.</p>
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<p>Exothermic rate curves of fresh pastes with powder seeds.</p>
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<p>Cumulative heat curves of fresh pastes with powder seeds.</p>
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<p>Fitting curves of the material reaction rates of pastes with different amounts of powder seeds.</p>
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<p>Hydration degree of cement paste with 0.2% powder seeds. The black arrow represents the TG curve, and the red arrow represents the DTG curve.</p>
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<p>(<b>a</b>): Effect of different dosages of powder seeds on the fluidity of fresh cement pastes. (<b>b</b>): The numbers in Figure (<b>b</b>) represent the concentration of the powder nucleating agent, and the bleeding phenomenon occurs with 0.8% powder seeds.</p>
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<p>Compressive strengths of cement mortar at various curing ages.</p>
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33 pages, 4698 KiB  
Article
Experimental Characterization of Reversible Oil-Flooded Twin-Screw Compressor/Dry Expander for a Micro-Scale Compressed Air Energy Storage System
by Marco Francesconi, Arianna Baldinelli, Luca Sani and Marco Antonelli
Energies 2025, 18(2), 320; https://doi.org/10.3390/en18020320 - 13 Jan 2025
Viewed by 65
Abstract
The reversible use of a volumetric machine as a compressor and expander shows potential for micro-scale compressed air energy storage systems because of lower investment costs and higher operational flexibility. This paper investigates experimentally the reversible use of a 3 kW oil-flooded twin-screw [...] Read more.
The reversible use of a volumetric machine as a compressor and expander shows potential for micro-scale compressed air energy storage systems because of lower investment costs and higher operational flexibility. This paper investigates experimentally the reversible use of a 3 kW oil-flooded twin-screw compressor as an expander for a micro-scale compressed air energy storage system to assess its operation while minimizing operating costs and the need for adjustments. As a result, the oil injection was only implemented in the compressor operation since the oil takes part in the compression process, while its use appears optional in expander operation. The results indicate that the compressor exhibited an efficiency in the range of 0.57–0.80 and required an input power from 1 kW up to 3 kW. These values decreased for the expander, whose efficiency was in the range of 0.24–0.38 and the delivered power between 300 and 1600 W. The experimental data allow assessing the operation of such machine in a hypothetical micro-scale compressed air energy storage. The calculation revealed that this machine may operate in this energy storage asset and deliver up to 90% of the power recovered in the charging process when the temperature of the stored air is 80 °C. Full article
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<p>Architecture of a conventional CAES power plant.</p>
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<p>View of the rotors and their profiles of the oil-flooded twin-screw compressor investigated in the tests.</p>
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<p>Schematic diagram of the experimental test-rig developed to investigate the reversible use of the twin-screw device as a compressor (<b>a</b>) and as an expander (<b>b</b>). Solid lines represent air streams, dashed lines represent lubricant oil streams. The arrows give the flow direction.</p>
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<p>Operating maps of the device tested as an oil-flooded twin-screw compressor in terms of processed air mass flow rate and compression ratio.</p>
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<p>Trend of the oil-to-air mass flow rate ratio detected in the compressor operating mode as a function of the rotating speed and compression ratio.</p>
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<p>Temperature of the oil and air at the inlet of the compressor and temperature of the oil–air mixture acquired downstream of the discharge port of the compressor. The data are reported in terms of the compression ratio and rotating speed.</p>
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<p>Mechanical power requested at shaft by the device in the compressor operating mode.</p>
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<p>Trend of dissipative effects due to frictions and turbulence obtained from the experimental data of the compressor operating mode for different compression ratios and rotating speeds.</p>
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<p>Trend of the overall compression efficiency evaluated in the compressor operating mode in terms of the pressure ratio and rotating speed.</p>
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<p>Volumetric efficiency calculated in the compressor operating mode as a function of the pressure ratio and rotating speed.</p>
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<p>Displacement fraction of the device in the compressor operating mode to compress the air under a given compression ratio.</p>
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<p>Thermal losses through the housing of the device in the compressor operating mode as a function of the pressure ratio and rotating speed.</p>
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<p>Operating maps of the device tested as a dry-running twin-screw expander in terms of the delivered air mass flow rate and expansion ratio.</p>
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<p>Experimental discharge temperatures of the air downstream of the discharge port of the expander in terms of the expansion ratio and rotating speed.</p>
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<p>Mechanical power delivered at shaft by the device in the expander operating mode in terms of the expansion ratio and rotating speed.</p>
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<p>Trend of dissipations due to frictions and turbulence detected in the expander operating mode for different expansion ratios and rotating speeds.</p>
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<p>Thermal losses through the machine housing in the expander operating mode as a function of the expansion ratio and rotating speed.</p>
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<p>Trend of the overall expander efficiency in the expander operating mode as a function of the pressure ratio and rotating speed.</p>
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<p>Trend of the filling factor of the expander represented in terms of the expansion ratio and rotating speed.</p>
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<p>Maps of the unitary round-trip efficiency of the hypothetic CAES system evaluated for three different pressure ratios: (<b>a</b>) pressure ratio 5, (<b>b</b>) pressure ratio 7, and (<b>c</b>) pressure ratio 9.</p>
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<p>Maps of the power ratio of the hypothetic CAES system evaluated for three different pressure ratios: (<b>a</b>) pressure ratio 5, (<b>b</b>) pressure ratio 7, and (<b>c</b>) pressure ratio 9.</p>
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