Search Results (163)

The alkamide content and specific tissue localization in the cypselae of Heliopsis longipes were investigated using gas chromatography–electron ionization mass spectrometry (GC-EIMS) and multiphoton fluorescence microscopy (MPFM). GC-EIMS analysis identified two olefinic alkamides: affinin (spilanthol) and N-2-methylbutyl-2E,6Z,8E-decatrienamide. Microscopic analysis revealed that alkamides are localized within the cotyledons, and specifically compartmentalized in lipid bodies, highlighting their spatial organization. The linear unmixing of fluorescence emission fingerprints showed that affinin exhibits autofluorescence at 693 nm, corresponding to the red spectral region. This emission is attributed to the conjugated double bonds in its acyl chain. This study is the first to report on the presence and precise localization of alkamides in the cypselae of H. longipes. Full article

We introduce a new model for non-linear endmember extraction and spectral unmixing of hyperspectral imagery called Generative Simplex Mapping (GSM). The model represents endmember mixing using a latent space of points sampled within a $(n-1)$-simplex corresponding to n unique sources. Barycentric coordinates within this simplex are naturally interpreted as relative endmember abundances satisfying both the abundance sum-to-one and abundance non-negativity constraints. Points in this latent space are mapped to reflectance spectra via a flexible function combining linear and non-linear mixing. Due to the probabilistic formulation of the GSM, spectral variability is also estimated by a precision parameter describing the distribution of observed spectra. Model parameters are determined using a generalized expectation-maximization algorithm, which guarantees non-negativity for extracted endmembers. We first compare the GSM against three varieties of non-negative matrix factorization (NMF) on a synthetic data set of linearly mixed spectra from the USGS spectral database. Here, the GSM performed favorably for both endmember accuracy and abundance estimation with all non-linear contributions driven to zero by the fitting procedure. In a second experiment, we apply the GTM to model non-linear mixing in real hyperspectral imagery captured over a pond in North Texas. The model accurately identified spectral signatures corresponding to near-shore algae, water, and rhodamine tracer dye introduced into the pond to simulate water contamination by a localized source. Abundance maps generated using the GSM accurately track the evolution of the dye plume as it mixes into the surrounding water. Full article

The InVEST model, with its ability to perform spatial visualization and quantification, is an important tool for mapping ecosystem services. However, the spatial accuracy and simulating performance of the model are deeply influenced by the land use parameter, which often relies on the accuracy of land use/cover data. To address this issue, we propose a novel method for optimizing the land use parameter of the InVEST model based on the vegetation–impervious surface–soil (V–I–S) model and a machine learning algorithm. The optimized model is called Sub-InVEST, and it improves the performance of assessing ecosystem services on a sub-pixel scale. The conceptual steps are (i) extracting the V–I–S fraction of remote sensing images based on the spectral unmixing method; (ii) determining the mapping relationship of the V–I–S fraction between land use/cover type using a machine learning algorithm and field observation data; (iii) inputting the V–I–S fraction into the original model instead of the land use/cover parameter of the InVEST model. To evaluate the performance and spatial accuracy of the Sub-InVEST model, we employed the habitat quality module of InVEST and multi-source remote sensing data, which were applied to acquire Sub-InVEST and estimate the habitat quality of central Guangzhou city from 2000 to 2020 with the help of the LSMA and ISODATA methods. The experimental results showed that the Sub-InVEST model is robust in assessing ecosystem services in sets of complex ground scenes. The spatial distribution of the habitat quality of both models revealed a consistent increasing trend from the southwest to the northeast. Meanwhile, linear regression analyses observed a robust correlation and consistent linear trends, with R² values of 0.41, 0.35, 0.42, 0.39, and 0.47 for the years 2000, 2005, 2010, 2015, and 2020, respectively. Compared with the original model, Sub-InVEST had a more favorable performance in estimating habitat quality in central Guangzhou. The spatial depictions and numerical distribution of the results of the Sub-InVSET model manifest greater detail and better concordance with remote sensing imagery and show a more seamless density curve and a substantially enhanced probability distribution across interval ranges. Full article

Surface water fraction mapping is an essential preprocessing step for the subpixel mapping (SPM) of surface water, providing valuable prior knowledge about surface water distribution at the subpixel level. In recent years, spectral mixture analysis (SMA) has been extensively applied to estimate surface water fractions in multispectral images by decomposing each mixed pixel into endmembers and their corresponding fractions using linear or nonlinear spectral mixture models. However, challenges emerge when introducing existing surface water fraction mapping methods to hyperspectral images (HSIs) due to insufficient exploration of spectral information. Additionally, inaccurate extraction of endmembers can result in unsatisfactory water fraction estimations. To address these issues, this paper proposes an adaptive unmixing method based on iterative multi-objective optimization for surface water fraction mapping (IMOSWFM) using Zhuhai-1 HSIs. In IMOSWFM, a modified normalized difference water fraction index (MNDWFI) was developed to fully exploit the spectral information. Furthermore, an iterative unmixing framework was adopted to dynamically extract high-quality endmembers and estimate their corresponding water fractions. Experimental results on the Zhuhai-1 HSIs from three test sites around Nanyi Lake indicate that water fraction maps obtained by IMOSWFM are closest to the reference maps compared with the other three SMA-based surface water fraction estimation methods, with the highest overall accuracy (OA) of 91.74%, 93.12%, and 89.73% in terms of pure water extraction and the lowest root-mean-square errors (RMSE) of 0.2506, 0.2403, and 0.2265 in terms of water fraction estimation. This research provides a reference for adapting existing surface water fraction mapping methods to HSIs. Full article

Baiyangdian Lake, recognized as the largest freshwater body in northern China, plays a vital role in maintaining the regional eco-environment. Prior studies have pointed out the contamination of sediments with heavy metals, raising concerns about eco-environmental challenges. Therefore, it is imperative to evaluate the current pollution levels and ecological threats related to heavy metals found in the sediments of Baiyangdian Lake as well as in its inflow rivers. In May 2022, surface sediments with a depth of less than 20 cm were analyzed for Cu, Zn, Pb, Cr, Ni, As, Cd, and Hg to determine the pollution status, identify sources of pollution, and evaluate potential ecological risks. A range of evaluation methods used by predecessors such as geo-accumulation index (I_geo), enrichment factor (EF), ecological risk index (RI), sediment quality guidelines (SQGs), positive matrix factorization (PMF), absolute principal component score-multiple linear regression model (APCS-MLR), chemical mass balance (CMB), and UNMIX model were analyzed. After comparison, multi-methods including the geo-accumulation index (Igeo), absolute principal component score-multiple linear regression model (APCS-MLR), ecological risk index (RI), and sediment quality guidelines (SQGs) were utilized this time, leading to a better result. Findings reveal that pollution levels are generally low or non-existent, with only 1.64% of sampling sites showing close to moderate pollution levels for Cu, Pb, and Zn, and 4.92% and 1.64% of sites exhibiting close to moderate and moderate pollution levels for Cd, respectively. The main contributors to heavy metal presence are pinpointed as industrial wastewater discharge, particularly Cu, Zn, Pb, Cd, and Hg. The ecological risks are also relatively low, with 4.92%, 1.64%, and 1.64% of sampling sites demonstrating close to moderate, moderate, and strong risks in the inflow rivers, respectively. Additionally, only one site shows moderate potential biological toxicity, while the rest display non-toxicity. These findings will update our cognition and offer a scientific basis for pollution treatment and ecosystem enhancement for government management. Full article

The composition of clay minerals in soils, and more particularly the presence of montmorillonite (as part of the smectite family), is a key factor in soil swell–shrinking as well as off–road vehicle mobility. Detecting these topsoil clay minerals and quantifying the montmorillonite abundance are a challenge since they are usually intimately mixed with other minerals, soil organic carbon and soil moisture content. Imaging spectroscopy coupled with unmixing methods can address these issues, but the quality of the estimation degrades the coarser the spatial resolution is due to pixel heterogeneity. With the advent of UAV-borne and proximal hyperspectral acquisitions, it is now possible to acquire images at a centimeter scale. Thus, the objective of this paper is to evaluate the accuracy and limitations of unmixing methods to retrieve montmorillonite abundance from very-high-resolution hyperspectral images (1.5 cm) acquired from a camera installed on top of a bucket truck over three different agricultural fields, in Loiret department, France. Two automatic endmember detection methods based on the assumption that materials are linearly mixed, namely the Simplex Identification via Split Augmented Lagrangian (SISAL) and the Minimum Volume Constrained Non-negative Matrix Factorization (MVC-NMF), were tested prior to unmixing. Then, two linear unmixing methods, the fully constrained least square method (FCLS) and the multiple endmember spectral mixture analysis (MESMA), and two nonlinear unmixing ones, the generalized bilinear method (GBM) and the multi-linear model (MLM), were performed on the images. In addition, several spectral preprocessings coupled with these unmixing methods were applied in order to improve the performances. Results showed that our selected automatic endmember detection methods were not suitable in this context. However, unmixing methods with endmembers taken from available spectral libraries performed successfully. The nonlinear method, MLM, without prior spectral preprocessing or with the application of the first Savitzky–Golay derivative, gave the best accuracies for montmorillonite abundance estimation using the USGS library (RMSE between 2.2–13.3% and 1.4–19.7%). Furthermore, a significant impact on the abundance estimations at this scale was in majority due to (i) the high variability of the soil composition, (ii) the soil roughness inducing large variations of the illumination conditions and multiple surface scatterings and (iii) multiple volume scatterings coming from the intimate mixture. Finally, these results offer a new opportunity for mapping expansive soils from imaging spectroscopy at very high spatial resolution. Full article

Hyperspectral unmixing (HU) aims to decompose mixed pixels into a set of endmembers and corresponding abundances. Deep learning-based HU methods are currently a hot research topic, but most existing unmixing methods still rely on per-pixel training or employ convolutional neural networks (CNNs), which overlook the non-local correlations of materials and spectral characteristics. Furthermore, current research mainly focuses on linear mixing models, which limits the feature extraction capability of deep encoders and further improvement in unmixing accuracy. In this paper, we propose a nonlinear unmixing network capable of extracting global spatial-spectral features. The network is designed based on an autoencoder architecture, where a dual-stream CNNs is employed in the encoder to separately extract spectral and local spatial information. The extracted features are then fused together to form a more complete representation of the input data. Subsequently, a linear projection-based multi-head self-attention mechanism is applied to capture global contextual information, allowing for comprehensive spatial information extraction while maintaining lightweight computation. To achieve better reconstruction performance, a model-free nonlinear mixing approach is adopted to enhance the model’s universality, with the mixing model learned entirely from the data. Additionally, an initialization method based on endmember bundles is utilized to reduce interference from outliers and noise. Comparative results on real datasets against several state-of-the-art unmixing methods demonstrate the superior of the proposed approach. Full article

Establishing a quantitative relationship between Synthetic Aperture Radar (SAR) data and optical data can facilitate the fusion of these two data sources, enhancing the time-series monitoring capabilities for remote sensing of a land surface. In this study, we analyzed the Normalized Difference Vegetation Index (NDVI) and Shortwave Infrared Transformed Reflectance (STR) with the backscatter coefficients in vertical polarization VV (σ⁰VV) and cross polarization VH (σ⁰VH) across different seasons. We used optical and microwave satellite data spanning from the southern Gobi Desert region to the steppe region in northern Mongolia. The results indicate a relatively high correlation between the NDVI derived from Sentinel-2 and σ⁰VH (R_VH = 0.29, R_VH = 0.44, p < 0.001) and a low correlation between the NDVI and σ⁰VV (R_VH = 0.06, R_VH = 0.14, p < 0.01) in the Gobi Desert region during summer and fall. STR showed a positive correlation with both σ⁰VH and σ⁰VV except in spring, with the highest correlation coefficients observed in summer (R_VV = 0.45, R_VV = 0.44, p < 0.001). In the steppe region, significant seasonal variations in the NDVI and σ⁰VH were noted, with a strong positive correlation peaking in summer (R_VH = 0.71, p < 0.001) and an inverse correlation with σ⁰VV except in summer (R_VV = −0.43, R_VV = −0.34, R_VV = −0.13, p < 0.001). Additionally, STR showed a positive correlation with σ⁰VH and σ0VV in summer (R_VH = 0.40, R_VV = 0.39, p < 0.001) and fall (R_VH = 0.38, R_VV = 0.09, p < 0.01), as well as an inverse correlation in spring (R_VH= −0.17, R_VV= −0.38, p < 0.001) and winter (R_VH = −0.21, R_VV = −0.06, p < 0.001). The correlations between the NDVI, STR, σ⁰VH, and σ⁰VV were shown to vary by season and region. In the Gobi Desert region, perennial shrubs are not photosynthetic in spring and winter, and they affect backscatter due to surface roughness. In the steppe region, annual shrubs were found to be the dominant species and were found to photosynthesize in spring, but not enough to affect the backscatter due to surface roughness. Full article

The Multisensor Multiresolution Technique (MMT) is applied to unmixed thermal images from ASTER (90 m), using 30 m resolution images from Landsat 8-9 reflective channels. The technique allows for the retrieval of thermal radiance values of the features identified in the high-resolution reflective images and the generation of a high-resolution radiance image. Different alternatives of application of MMT are evaluated in order to determine the optimal methodology design: performance of the Iterative Self-Organizing Data Analysis Technique (ISODATA) and K-means classification algorithms, with different initiation numbers of clusters, and computation of contributions of each cluster using moving windows with different sizes and with and without weight coefficients. Results show the K-means classification algorithm with five clusters, without matrix weighting, and utilizing a 5 × 5 pixel window for synthetic high-resolution image reconstruction. This approach obtained a maximum R² of 0.846 and an average R² of 0.815 across all cases, calculated through the validation of the synthetic high-resolution TIR image generated against a real Landsat 8-9 TIR image from the same area, same date, and co-registered. These values imply a 0.89% improvement regarding the second-best methodology design (K-means with five starting clusters with 7 × 7 moving window) and a 410.25% improvement regarding the worst alternative (K-means with nine initial clusters, weighting, and 3 × 3 moving window). Full article

Analyzing the impacts of urban landscape patterns on the thermal environment has become one of the key research areas in addressing urban heat islands (UHIs) and improving the living environment. A case study was carried out in Fuzhou, Fujian Province of China, and bi-temporal Landsat imagery was selected to calculate land surface temperature (LST), percent impervious surface area (ISA), and fractional vegetation cover (FVC). The urban area was further divided into three concentric urban zones, ranging from the city center to the urban periphery, based on urban development densities. The spatial pattern of LST and its variance were analyzed and compared between different zones and different dates. The thermal environment contribution of different zones was also quantified to indicate the change in urban landscape patterns resulting from urban expansion in different zones. Furthermore, Geodetector was used to explore the single factors and interaction factors controlling the spatial patterns of LST in each zone. The results showed that (i) urban expansion primarily increased in Zone 2 and Zone 3, and the areal proportion of high and sub-high LST areas increased from 56.11% and 21.08% to 62.03% and 32.49% in Zone 2 and Zone 3, respectively, from 2004 to 2021; (ii) the heat effect contribution of Zones 2 and 3 reached from 75.16% in 2004 to 89.40% in 2021, indicating that the increase in ISA with >LST_mean was more pronounced in Zone 3 and Zone 2 during the period; (iii) the driving factors of LST spatial distribution were regionally different because of the different landscape patterns, and the explanatory power for the heterogeneity of LST in Zone 1 was weaker than in Zone 2 and Zone 3 in the study area; (iv) the interaction of different factors had a higher explanatory power in the spatial distribution of LST than a single factor in each zone because the distributions of land cover types are heterogeneous in urban areas. The results of this study can be used to improve urban planning for urban ecology and UHI mitigation. Full article

This study introduces a novel method utilizing hyperspectral imaging for instantaneous ore-waste analysis of drill cuttings. To implement this technique, we collected samples of drill cuttings at regular depth intervals from five blast holes in an open pit gold mine and subjected them to scanning using a hyperspectral imaging system. Subsequently, we employed two distinct methods for processing the hyperspectral images. A knowledge-based method was used to estimate ore grade within each sampled interval, and a data-driven technique was employed to distinguish the ore and waste for each sample interval. Firstly, leveraging the mixed mineralogical composition of the samples, the Linear Spectral Unmixing (LSU) technique was utilized to predict ore grade for each sample. Additionally, the Gradient Boosting Classifier (GBC) was used as an efficient data-driven approach to classify ore-waste samples. Both methods rendered accurate results when they were compared with results obtained through laboratory X-ray diffraction (XRD) analysis and gold assay analysis for the same sample intervals. Adopting the proposed methodology in open pit mine operations can significantly enhance the process of grade control during blast hole drilling. This includes reducing costs, saving time, minimizing uncertainty in ore grade estimation, and establishing more precise ore-waste boundaries in resource block models. Full article

The new generation of satellite hyperspectral (HS) sensors provides remarkable potential for regional-scale mineralogical mapping. However, as with any satellite sensor, mapping results are dependent on a typically complex correction procedure needed to remove atmospheric, topographic and geometric distortions before accurate reflectance spectra can be retrieved. These are typically applied by the satellite operators but use different approaches that can yield different results. In this study, we conduct a comparative analysis of PRISMA, EnMAP, and EMIT hyperspectral satellite data, alongside airborne data acquired by the HyMap sensor, to investigate the consistency between these datasets and their suitability for geological mapping. Two sites in Namibia were selected for this comparison, the Marinkas-Quellen and Epembe carbonatite complexes, based on their geological significance, relatively good exposure, arid climate and data availability. We conducted qualitative and three different quantitative comparisons of the hyperspectral data from these sites. These included correlative comparisons of (1) the reflectance values across the visible-near infrared (VNIR) to shortwave infrared (SWIR) spectral ranges, (2) established spectral indices sensitive to minerals we expect in each of the scenes, and (3) spectral abundances estimated using linear unmixing. The results highlighted a notable shift in inter-sensor consistency between the VNIR and SWIR spectral ranges, with the VNIR range being more similar between the compared sensors than the SWIR. Our qualitative comparisons suggest that the SWIR spectra from the EnMAP and EMIT sensors are the most interpretable (show the most distinct absorption features) but that latent features (i.e., endmember abundances) from the HyMap and PRISMA sensors are consistent with geological variations. We conclude that our results reinforce the need for accurate radiometric and topographic corrections, especially for the SWIR range most commonly used for geological mapping. Full article

Vegetation coverage is a crucial parameter in agriculture, as it offers essential insight into crop growth and health conditions. The spatial resolution of spaceborne sensors is limited, hindering the precise measurement of vegetation coverage. Consequently, fine-resolution ground observation data are indispensable for establishing correlations between remotely sensed reflectance and plant coverage. We estimated rice plant coverage per pixel using time-series Sentinel-2 Multispectral Instrument (MSI) data, enabling the monitoring of rice growth conditions over a wide area. Coverage was calculated using unmanned aerial vehicle (UAV) data with a spatial resolution of 3 cm with the spectral unmixing method. Coverage maps were generated every 2–3 weeks throughout the rice-growing season. Subsequently, crop growth was estimated at 10 m resolution through multiple linear regression utilizing Sentinel-2 MSI reflectance data and coverage maps. In this process, a geometric registration of MSI and UAV data was conducted to improve their spatial agreement. The coefficients of determination (R²) of the multiple linear regression models were 0.92 and 0.94 for the Level-1C and Level-2A products of Sentinel-2 MSI, respectively. The root mean square errors of estimated rice plant coverage were 10.77% and 9.34%, respectively. This study highlights the promise of satellite time-series models for accurate estimation of rice plant coverage. Full article

Accurately mapping urban above-ground vegetation carbon density presents challenges due to fragmented landscapes, mixed pixels, and shadows induced by buildings and mountains. To address these issues, a novel methodological framework is introduced, utilizing a linear spectral unmixing analysis (LSUA) for shadow removal and vegetation information extraction from mixed pixels. Parametric and nonparametric models, incorporating LSUA-derived vegetation fraction, are compared, including linear stepwise regression, logistic model-based stepwise regression, k-Nearest Neighbors, Decision Trees, and Random Forests. Applied in Shenzhen, China, the framework integrates Landsat 8, Pleiades 1A & 1B, DEM, and field measurements. Among the key findings, the shadow removal algorithm is effective in mountainous areas, while LSUA-enhanced models improve urban vegetation carbon density mapping, albeit with marginal gains. Integrating kNN and RF with LSUA reduces errors, and Decision Trees, especially when integrated with LSUA, outperform other models. This study underscores the potential of the proposed framework, particularly the integration of Decision Trees with LSUA, for advancing the accuracy of urban vegetation carbon density mapping. Full article

The thermal band of a satellite platform enables the measurement of land surface temperature (LST), which captures the spatial-temporal distribution of energy exchange between the Earth and the atmosphere. LST plays a critical role in simulation models, enhancing our understanding of physical and biochemical processes in nature. However, the limitations in swath width and orbit altitude prevent a single sensor from providing LST data with both high spatial and high temporal resolution. To tackle this challenge, the unmixing-based spatiotemporal fusion model (STFM) offers a promising solution by integrating data from multiple sensors. In these models, the surface reflectance is decomposed from coarse pixels to fine pixels using the linear unmixing function combined with fractional coverage. However, when downsizing LST through STFM, the linear mixing hypothesis fails to adequately represent the nonlinear energy mixing process of LST. Additionally, the original weighting function is sensitive to noise, leading to unreliable predictions of the final LST due to small errors in the unmixing function. To overcome these issues, we selected the U-STFM as the baseline model and introduced an updated version called the nonlinear U-STFM. This new model incorporates two deep learning components: the Dynamic Net (DyNet) and the Chang Ratio Net (RatioNet). The utilization of these components enables easy training with a small dataset while maintaining a high generalization capability over time. The MODIS Terra daytime LST products were employed to downscale from 1000 m to 30 m, in comparison with the Landsat7 LST products. Our results demonstrate that the new model surpasses STARFM, ESTARFM, and the original U-STFM in terms of prediction accuracy and anti-noise capability. To further enhance other STFMs, these two deep-learning components can replace the linear unmixing and weighting functions with minor modifications. As a deep learning-based model, it can be pretrained and deployed for online prediction. Full article