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15 pages, 257 KiB  
Article
Exploring Transformative Ecotourism Experiences on Italian Pathways Through Online Reviews
by Alessandra Marasco and Valentina Marchi
Sustainability 2025, 17(2), 452; https://doi.org/10.3390/su17020452 - 9 Jan 2025
Viewed by 465
Abstract
Transformative tourism experiences have attracted considerable scholarly interest in the recent past and deserve further attention to advance knowledge on the role of tourism in human transformation. This study aims to advance the understanding of the triggers and dimensions of transformative ecotourism experiences [...] Read more.
Transformative tourism experiences have attracted considerable scholarly interest in the recent past and deserve further attention to advance knowledge on the role of tourism in human transformation. This study aims to advance the understanding of the triggers and dimensions of transformative ecotourism experiences through the analysis of travelers’ online reviews relating to 10 Italian Pathways (Cammini d’Italia). A total of 742 reviews from 2010 to 2022 were collected from TripAdvisor using a web scraping procedure and analyzed by applying text mining techniques. This analysis explored the cognitive, affective, sensory, social and other experiential factors that can trigger tourists’ transformative experiences and their relationship with behavioral, psychological, spiritual and physical dimensions of transformation. The findings provide evidence of the association of cognitive and sensory triggers and the search for unusual, special tourism experiences to transformative experiences, with specific regard to the psychological, spiritual and physical dimensions. Based on the findings, theoretical and managerial implications are provided to improve the understanding and promotion of transformative tourism experiences in this context. Full article
(This article belongs to the Special Issue Sustainable Development of Ecotourism)
28 pages, 212841 KiB  
Article
The Ponte Delle Chianche on the Via Traiana in Buonalbergo (Benevento, Italy): New Data for an Integrated Study
by Ivan Ferrari
Heritage 2025, 8(1), 11; https://doi.org/10.3390/heritage8010011 - 28 Dec 2024
Viewed by 657
Abstract
This article illustrates a systematic and updated study of the Ponte delle Chianche, a Roman bridge on the ancient Via Traiana built at the beginning of the second century AD and located near Buonalbergo (Benevento, Italy). The study aimed to retrieve all information [...] Read more.
This article illustrates a systematic and updated study of the Ponte delle Chianche, a Roman bridge on the ancient Via Traiana built at the beginning of the second century AD and located near Buonalbergo (Benevento, Italy). The study aimed to retrieve all information contained in literary sources and to cross-reference them with new data from research conducted in recent years. Thanks to an instrumental metric survey of the structures, both the construction techniques used and the bridge construction process were better understood, elements that were then incorporated into the development of a 3D reconstruction proposal. At the same time, a close visual analysis of the structures led to the discovery of a large number of brick stamps, also unpublished, which is important for understanding the logistical aspects of the building materials. The results obtained will be used to implement a comprehensive project for the recovery and securing of the property. Full article
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<p>The Ponte delle Chianche: downstream side (2024).</p>
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<p>The stretch of Via Traiana between Forum Novum and Aequum Tuticum where the Ponte delle Chianche is located.</p>
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<p>The path of the Via Traiana in relation to the Via Appia between Beneventum (Benevento) and Brundisium (Brindisi) in southern Italy.</p>
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<p>Flowchart of methods, showing the sequence in which they are applied.</p>
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<p>Metric survey of the bridge using a laser scanner: (<b>a</b>) panoramic shot of the instrument during acquisition on the bridge; (<b>b</b>) close-up shot of the instrument at the end of acquisition.</p>
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<p>The matching of the point clouds in Leica Cyclone FIELD 360 software: screenshot.</p>
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<p>Detail of the central pillar of the Ponte delle Chianche in the 3D model obtained from the point cloud: (<b>a</b>) model of 41,132,100 polygons; (<b>b</b>) model of 4,238,798 polygons.</p>
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<p>Visual surveys of the brick wall structures: (<b>a</b>) the search for brick marks on the arches; (<b>b</b>) the graphic survey of brick marks.</p>
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<p>Modeling of the 3D reconstruction proposal: screenshot.</p>
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<p>The brick stamps discovered by Dressel and published in the <span class="html-italic">CIL</span> [<a href="#B12-heritage-08-00011" class="html-bibr">12</a>]: (<b>a</b>) <span class="html-italic">CIL</span> 1883, IX, 6011; (<b>b</b>) <span class="html-italic">CIL</span> 1883, IX, 6078.123; (<b>c</b>) <span class="html-italic">CIL</span> 1883, IX, 6078.41.</p>
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<p>The Ponte delle Chianche in two shots from the early 1900s: (<b>a</b>) photo by R. Gardner [<a href="#B13-heritage-08-00011" class="html-bibr">13</a>]; (<b>b</b>) photo by E. van Deman [<a href="#B13-heritage-08-00011" class="html-bibr">13</a>].</p>
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<p>The brick stamp reported by T. Ashby and R. Gardner [<a href="#B13-heritage-08-00011" class="html-bibr">13</a>].</p>
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<p>1986 metric survey of the Ponte delle Chianche by Galliazzo [<a href="#B15-heritage-08-00011" class="html-bibr">15</a>].</p>
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<p>Integrative hypothesis of the Ponte delle Chianche by Galliazzo [<a href="#B15-heritage-08-00011" class="html-bibr">15</a>].</p>
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<p>2007 metric survey of the Ponte delle Chianche by Busino [<a href="#B17-heritage-08-00011" class="html-bibr">17</a>].</p>
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<p>The original photo of the Ponte delle Chianche by R. Gardner republished in the exhibition catalogue <span class="html-italic">Lungo l’Appia e la Traiana</span> [<a href="#B18-heritage-08-00011" class="html-bibr">18</a>].</p>
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<p>Early 1900s photo by R. Gardner of the western portion of the Ponte delle Chianche on the upstream side (Photographic Archive of the British School at Rome, Gardner collection, n. 120).</p>
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<p>Metric survey of the Ponte delle Chianche: (<b>a</b>) top and south front orthogonal view of the high resolution polygonal model extracted from laser scanner data; (<b>b</b>) metric data of the plan and south elevation; (<b>c</b>) south front orthogonal view of the 3D reconstructive hypothesis.</p>
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<p>Metric survey of the Ponte delle Chianche: (<b>a</b>) top and south front orthogonal view of the high resolution polygonal model extracted from laser scanner data; (<b>b</b>) metric data of the plan and south elevation; (<b>c</b>) south front orthogonal view of the 3D reconstructive hypothesis.</p>
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<p>Ponte delle Chianche (2024): detail of the downstream side of the first two western arches.</p>
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<p>Ponte delle Chianche (2024): detail of the downstream side of the third arch from the west.</p>
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<p>Ponte delle Chianche (2024): detail of the downstream side of the fourth arch from the west.</p>
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<p>Ponte delle Chianche (2024): detail of the downstream side of the eastern end of the bridge, with the rebuilt sixth arch and the viaduct.</p>
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<p>Ponte delle Chianche (2024), detail of the central tympanum (2024): (<b>a</b>) the downstream side; (<b>b</b>) the upstream side.</p>
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<p>Ponte delle Chianche (2024), the downstream side of the eastern viaduct (2024): (<b>a</b>) the three visible buttresses indicated by the arrows; (<b>b</b>) two distinct levels of the stepped foundations indicated by the arrows.</p>
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<p>Ponte delle Chianche (2024), the upstream side of the western viaduct (2024): (<b>a</b>) the two remaining buttresses indicated by the arrows; (<b>b</b>) arrows indicating the string course of <span class="html-italic">bipedales</span> between the foundation and the wall elevation.</p>
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<p>Ponte delle Chianche (2013), the western top blocks of the fourth pillar: (<b>a</b>) view from the west; (<b>b</b>) detail of the metal clamp holes on the upper surfaces of the blocks near the joints.</p>
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<p>Ponte Santo Spirito (2013), the remains of the pillar and the platform: (<b>a</b>) downstream view; (<b>b</b>) upstream view.</p>
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<p>Ponte delle Chianche (2024): top view, from drone, of the Roman pavement (by G. Ceraudo).</p>
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<p>Ponte delle Chianche (2013): one of the blocks from the crowning frame of the bridge.</p>
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<p>Graphic surveys of the six typologies of brick stamps of the Ponte delle Chianche.</p>
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<p><span class="html-italic">Bipedales</span> of the Ponte delle Chianche with the brick stamp <span class="html-italic">PO<span class="underline">NT</span>V·TRA</span> (2013): (<b>a</b>) brick in storage at the Antiquarium of Casalbore (Bn) with the detail of the brick stamp indicated by the arrow at the bottom; (<b>b</b>) brick located in the fifth arch.</p>
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<p>Ponte delle Chianche, 3D reconstruction: perspective view from the southeast.</p>
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<p>Ponte delle Chianche, 3D elaboration of the original landscape context: (<b>a</b>) view from the southwest; (<b>b</b>) view from the southeast.</p>
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<p>Ponte delle Chianche, 3D elaboration of the construction phases: diversion of the stream useful to the construction of the eastern half of the bridge.</p>
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<p>Ponte delle Chianche, 3D elaboration of the construction phases: cleaning of river debris for direct laying of foundations.</p>
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<p>Ponte delle Chianche, 3D elaboration of the construction phases: construction of the foundations of the pillars, the viaduct and the platform.</p>
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<p>Ponte delle Chianche, 3D elaboration of the construction phases: raising of the pillars and assembly of the wooden centerings.</p>
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<p>Ponte delle Chianche, 3D elaboration of the construction phases: construction of the arches, the tympanums, and the viaduct.</p>
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<p>Ponte delle Chianche, 3D elaboration of the construction phases: completion of the eastern part of the bridge.</p>
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<p>Ponte delle Chianche, 3D elaboration of the construction phases: channeling of the stream under the first arches built.</p>
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<p>Ponte delle Chianche, 3D elaboration of the construction phases: construction of arches, tympanums, and viaduct of the western part of the bridge.</p>
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<p>Ponte delle Chianche, 3D elaboration of the construction phases: completion of the crowning frames, the road, and the parapets.</p>
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20 pages, 14729 KiB  
Article
The Cultural Heritage Framework Programme: Highlighting the Contribution of Marine Cultural Heritage to the UN Decade of Ocean Science for Sustainable Development (2021–2030)
by Jon Henderson, Georgia Holly, Arturo Rey da Silva and Athena Trakadas
Oceans 2025, 6(1), 1; https://doi.org/10.3390/oceans6010001 - 27 Dec 2024
Viewed by 668
Abstract
This paper considers the importance of including Marine Cultural Heritage (MCH) in the UN Decade of Ocean Science for Sustainable Development (2021–2030) in order to fully address the challenges facing the health of our oceans. It outlines the aims and objectives of the [...] Read more.
This paper considers the importance of including Marine Cultural Heritage (MCH) in the UN Decade of Ocean Science for Sustainable Development (2021–2030) in order to fully address the challenges facing the health of our oceans. It outlines the aims and objectives of the Cultural Heritage Framework Programme (CHFP), an official action of the UN Decade of Ocean Science and the only one that specifically deals with cultural heritage. The role of MCH in the Decade is discussed, and its under-appreciation in the UNESCO Cultural Conventions is outlined. The paper then presents the activities of the CHFP, discussing the main themes identified to date, and finishes by outlining the initiative’s next steps. Full article
(This article belongs to the Special Issue Feature Papers of Oceans 2024)
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<p>The primary Cultural Heritage Framework Programme objectives (authors).</p>
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<p>The outputs of the Cultural Heritage Framework Programme (authors).</p>
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<p>The cargo wreck (<span class="html-italic">Pecheur Breton</span>) in Sri Lanka, surveyed as part of the Shipwrecks as Artificial Reef Structures Project. Shipwrecks are not only heritage assets; they can also improve fish biodiversity and enhance marine ecosystem health (photo credit: Ales Reich).</p>
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<p><span class="html-italic">SeaVoice</span> magazine poster, presented at the UNESCO Ocean Decade Conference organised in Barcelona, Spain, 10–12 April 2024 (photo credit: SeaVoice, CHFP/University of Edinburgh).</p>
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<p>Bidii na Kazi women fencing plots for mangrove nurseries as part of the Rising from the Depths project ‘MUCH to Discover in Mida Creek: creating pathways to community resilience and sustainable development through the maritime cultural landscape in Kenya’ (photo credit: Rising from the Depths network).</p>
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<p>School children in Malta experience an immersive 360 virtual dive on a historic wreck surveyed as part of the WreckLife project (photo credit: Heritage Malta).</p>
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<p>Indigenous leaders from Malawig, north of Coron, Palawan in the Philippines, identify illegal fishing hotspots within their ancestral territories during a workshop facilitated by Community Centred Conservation (C3) Philippines, Inc. on 9 September 2024. The threat maps from the workshop guided the Indigenous community in designating Indigenous Marine Managed Areas within their ancestral territory (photo credit: C3 Philippines, Replicating a Successful Model to Develop a Network of Indigenous Marine Managed Areas in the Philippines).</p>
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<p>The primary outcomes of the Cultural Heritage Framework Programme (authors).</p>
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<p>Endorsement Proposal Criteria (Ocean Decade Guidance Notes for Applicants, Accessed 2023).</p>
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20 pages, 5432 KiB  
Article
Prospection of the Red Biological Patinas Influencing the Urban Scenery Architecture in Portuguese Territory
by Fabio Sitzia, Carla Lisci, Luis Dias, Silvia Macedo Arantes and Ana Teresa Caldeira
Heritage 2024, 7(12), 7236-7254; https://doi.org/10.3390/heritage7120334 - 16 Dec 2024
Viewed by 440
Abstract
Portugal’s architecture reflects a rich history influenced by Roman, Moorish, Neoclassical and Romantic styles, with the 20th century marked by Art Deco and colonial influences. Regional styles vary, with white-painted buildings commonly experiencing color changes due to biofilm formation. Visually striking are the [...] Read more.
Portugal’s architecture reflects a rich history influenced by Roman, Moorish, Neoclassical and Romantic styles, with the 20th century marked by Art Deco and colonial influences. Regional styles vary, with white-painted buildings commonly experiencing color changes due to biofilm formation. Visually striking are the red-colored biological patinascommon in the coastal areas. A survey of 120 historical buildings affected by bio-colonization helps to understand the reasons for the patinas’ growing, which beyond natural factors, is often linked to construction defects. A characterization of four samples utilizes Next-Generation Sequencing (NGS) to identify the microorganisms composing the red biofilm, while the SEM-EDS, FTIR-ATR and XRD techniques provide further insights into the biofilm and substrate features. The comprehensive data of biochemical characterization indicate a wide variety of microorganisms, including bacteria and fungi, some of which exhibit potential as producers of a UV-tolerant red/yellow pigment (carotenoid) responsible for the macroscopic coloration of bio-colonization. Full article
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<p>The four buildings affected by biological patina and the objects of this study: (<b>a</b>,<b>b</b>) Ancient train station (<span class="html-italic">Montijo</span>, Portugal) and red patina affecting the building. (<b>c</b>,<b>d</b>) Old grinding factory and red patina affecting the building (<span class="html-italic">Arraiolos</span>, Portugal). (<b>e</b>,<b>f</b>) Snapshots of red biological patina affecting an ancient private house in <span class="html-italic">Alcochete</span> (Portugal). The building is not shown for privacy reasons, (<b>g</b>,<b>h</b>) Ancient aqueduct (<span class="html-italic">Évora</span>, Portugal) and relative red patina.</p>
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<p>(<b>a</b>) Cardinal exposition of the wall stained by the red patina. A total of 120 buildings located in the villages of <span class="html-italic">Sesimbra</span>, <span class="html-italic">Alcochete</span>, <span class="html-italic">Montijo</span>, <span class="html-italic">Alcacer do Sal</span>, <span class="html-italic">Setubal</span>, <span class="html-italic">Fatima</span>, <span class="html-italic">Caldas da Rainha</span>, <span class="html-italic">Évora</span> and <span class="html-italic">Arraiolos</span> were considered for the observations; (<b>b</b>) direction and frequency of the winds in the study areas.</p>
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<p>Practical cases of bio-colonization as markers of building pathologies: (<b>a</b>,<b>c</b>,<b>d</b>) private houses, (<b>b</b>) old grinding factory (<span class="html-italic">Arraiolos</span>), sampling location of the specimen L2.</p>
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<p>Practical case of bio-colonization as markers of building pathologies: (<b>a</b>,<b>b</b>) private buildings, (<b>c</b>) colonnade at Fatima’s sanctuary.</p>
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<p>FTIR-ATR survey on biofilms from <span class="html-italic">Montijo</span> and <span class="html-italic">Alcochete</span>.</p>
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<p>FTIR-ATR survey on biofilms from <span class="html-italic">Arraiolos</span> and <span class="html-italic">Évora</span>.</p>
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<p>Relative abundance (%) of the majority genera present in the Procaryotic population.</p>
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<p>Heatmap analysis of the genera’s relative abundance of every genus level based on the bacterial community 16s rDNA sequence, according to the average frequency of samples L1 (<span class="html-italic">Montijo</span>), L2 (<span class="html-italic">Arraiolos</span>), L3 (<span class="html-italic">Alcochete</span>) and L4 (<span class="html-italic">Évora</span>). Red and blue colors show the high and low enrichment of a genus, respectively. The scale represents normalized abundance values, where positive values indicate abundances above the mean and negative values indicate abundances below the mean relative to the dataset. These differences are visually represented by the color intensity on the heatmap.</p>
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<p>Relative abundance (%) of the majority phyla present in the eukaryotic population.</p>
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<p>Heatmap analysis of the species relative abundance of every genus level based on the eucarya community ITS2 sequence, according to the average frequency of samples L1 (<span class="html-italic">Montijo</span>), L2 (<span class="html-italic">Arraiolos</span>), L3 (<span class="html-italic">Alcochete</span>), and L4 (<span class="html-italic">Évora</span>). Red and blue colors show the high and low enrichment of a genus, respectively. The scale represents normalized abundance values, where positive values indicate abundances above the mean and negative values indicate abundances below the mean relative to the dataset. These differences are visually represented by the color intensity on the heatmap.</p>
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20 pages, 19114 KiB  
Article
The Role of Bacteria in Pink Stone Discoloration: Insights from Batalha Monastery
by Inês Silva, Cátia Salvador, Ana Z. Miller, António Candeias and Ana Teresa Caldeira
Micro 2024, 4(4), 778-797; https://doi.org/10.3390/micro4040048 - 14 Dec 2024
Viewed by 768
Abstract
The colonization of historical buildings and monuments by fungi, algae, and bacteria is a common phenomenon. This often leads to deterioration processes that cause either visual or structural harm. The Batalha Monastery in Portugal, a UNESCO World Heritage Site, currently shows significant surface [...] Read more.
The colonization of historical buildings and monuments by fungi, algae, and bacteria is a common phenomenon. This often leads to deterioration processes that cause either visual or structural harm. The Batalha Monastery in Portugal, a UNESCO World Heritage Site, currently shows significant surface changes to the stone architectural elements within both the Founder’s Chapel and the church, including a widespread pink discoloration on the walls and columns. The main goal of this study was to analyze the biological colonization and assess the influence of bacterial communities on the biodeterioration of Ançã limestone, providing valuable insights to help conservators and restorers select the best preservation strategies for the monastery. The prokaryote population was characterized using both high-throughput DNA sequencing and culture-dependent methods and several orange-pink pigment-producing bacteria were identified, for example, Bacillus, Gordonia, Serratia and Methylobacterium, as well as Halalkalicoccus, an abundant archaeal genus. The pink discoloration observed could be due to biofilms created by bacteria that produce pigments, namely carotenoids. Biocolonization tests were performed using stone mock-ups, which were prepared and inoculated with the bacteria isolated in this study. These tests were designed to replicate the natural conditions of the monastery and monitor the colonization process to understand the discoloration phenomenon. Full article
(This article belongs to the Section Microscale Biology and Medicines)
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<p>Surface alterations of the stone architectural elements both inside (<b>a</b>,<b>b</b>) the church and (<b>c</b>) the Founder’s Chapel at Batalha Monastery.</p>
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<p>Predominant prokaryote (<b>a</b>) phyla and (<b>b</b>) families on the pink biofilms.</p>
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<p>Predominant prokaryote genera on the pink biofilms; the symbol (*) represents the samples collected in the monastery church.</p>
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<p>Formation of biofilms on microplates by the bacterial isolate Gordonia.</p>
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<p>Determination of biofilm formation capacity. The values shown are the mean ± standard deviation of 16 replicates. Different letters (a or b) indicate different levels of significance.</p>
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<p>Production of pigments in the stone mock-up by isolate CCLBMBatB3 (<b>a</b>) kept in the dark and (<b>b</b>) exposed to sunlight.</p>
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<p>CIELAB color spectrum and color representation of colored stones and control.</p>
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<p>Raman spectrum of in vitro bacterial isolate CCLBMBatB3.</p>
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<p>In situ Raman spectra of the stone kept in the dark considering the scales (<b>a</b>) 930–1270 cm<sup>−1</sup> and (<b>b</b>) 1160–1560 cm<sup>−1</sup>. The connotation (*) represents peaks corresponding to calcite.</p>
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<p>In situ Raman spectra of the stone exposed to the sunlight. The connotation (*) represents peaks corresponding to calcite.</p>
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<p>Cleaning test on stone (in conditions of darkness) stained by bacterial biofilms: (<b>a</b>) before and (<b>b</b>) after the cleaning process.</p>
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<p>Measurement of reflectance (%) for the cleaning solutions (stone kept in the dark).</p>
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<p>Cleaning test on stone (in bright conditions) stained by bacterial biofilms: (<b>a</b>) before and (<b>b</b>) after the cleaning process.</p>
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<p>Measurement of reflectance (%) for the cleaning solutions (stone exposed to the sunlight).</p>
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17 pages, 1652 KiB  
Article
A Fistful of Mars Exploring the Role of Martian Meteorites in Cultural Heritage and Scientific Inquiry
by Annarita Franza, Xhonatan Shehaj and Giovanni Pratesi
Heritage 2024, 7(12), 6981-6997; https://doi.org/10.3390/heritage7120323 - 10 Dec 2024
Viewed by 657
Abstract
Meteorites have intrigued humanity for centuries, representing our enduring pursuit of knowledge and exploration of the cosmos’ enigmas. These celestial objects have not only influenced artistic expression and the formation of myths but have also fostered scientific inquiry. In this regard, meteorites are [...] Read more.
Meteorites have intrigued humanity for centuries, representing our enduring pursuit of knowledge and exploration of the cosmos’ enigmas. These celestial objects have not only influenced artistic expression and the formation of myths but have also fostered scientific inquiry. In this regard, meteorites are crucial to space research, offering valuable information about the early solar system, the formation of planets, and the development of organic compounds. Their analysis aids in deciphering cosmic processes and identifying resources that may support future space missions, making them essential for advancing planetary sciences. Meteorites are also cultural heritage items, with most known samples preserved in natural history museums. This paper deals with the Martian meteorites collected to date, focusing on NWA 16788, the largest individual Martian meteorite recovered so far. Full article
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<p>The number of Martian meteorites recovered from 1815 to 2023. Data source: Meteoritical Bulletin Database.</p>
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<p>Classification of the Martian meteorites according to the Meteoritical Bulletin Database.</p>
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<p>NWA 16788 is the largest individual Martian meteorite recovered thus far (ca. 24.6 kg). The sample is kept at a private gallery in Arezzo. Two slices are preserved at the University of Firenze.</p>
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<p>The exhibition of the NWA 16788 meteorite sample at the Italian Space Agency (Rome) during the 2024 European Researchers’ Night.</p>
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27 pages, 1175 KiB  
Review
Recent Developments in Materials Science for the Conservation and Restoration of Historic Artifacts
by Mihaela Doni, Irina Fierascu and Radu Claudiu Fierascu
Appl. Sci. 2024, 14(23), 11363; https://doi.org/10.3390/app142311363 - 5 Dec 2024
Viewed by 1342
Abstract
The preservation of cultural heritage artifacts presents complex challenges that require innovative solutions to prevent deterioration and extend the lifespan of priceless historical objects. Advances in materials science are revolutionizing the field of cultural heritage conservation and restoration, offering new techniques and materials [...] Read more.
The preservation of cultural heritage artifacts presents complex challenges that require innovative solutions to prevent deterioration and extend the lifespan of priceless historical objects. Advances in materials science are revolutionizing the field of cultural heritage conservation and restoration, offering new techniques and materials that enhance the protection, stability, and aesthetic integrity of artifacts. This review explores cutting-edge technologies and materials developed for the conservation and restoration of heritage artifacts, including nanomaterials, smart materials, and bio-inspired polymers. Case studies highlight successful applications of these technologies on various artifacts, from ancient manuscripts to architectural heritage. This review also addresses the challenges associated with integrating modern materials into conservation practices, including compatibility, reversibility, and long-term effects. By synthesizing current research and technological advancements, this review aims to provide a comprehensive understanding of how advanced materials are transforming the conservation and restoration of cultural heritage, ensuring the preservation of human history for future generations. Full article
(This article belongs to the Special Issue Advanced Technologies in Cultural Heritage)
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<p>Graphical representation of the aspects presented in the following sections.</p>
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18 pages, 31699 KiB  
Article
The Megafauna3D Educational Environment: Harnessing the Combination of New and Traditional Technologies to Improve Geoscience Education and Outreach
by Luciano Varela, Martín Batallés, P. Sebastián Tambusso, Gabriela Costoya and Richard A. Fariña
Geosciences 2024, 14(12), 321; https://doi.org/10.3390/geosciences14120321 - 26 Nov 2024
Viewed by 491
Abstract
The Megafauna3D project integrates advanced 3D scanning technologies and paleontological research to bring the extinct megafauna of Uruguay to formal and informal educational settings. Through the use of digitized fossil models, interactive education materials, and a web platform, the project engages the public [...] Read more.
The Megafauna3D project integrates advanced 3D scanning technologies and paleontological research to bring the extinct megafauna of Uruguay to formal and informal educational settings. Through the use of digitized fossil models, interactive education materials, and a web platform, the project engages the public and educational institutions in understanding the country’s paleontological heritage. This manuscript presents Megafauna3D’s multidisciplinary approach, its outreach initiatives, and the educational resources developed, such as 3D models and printed replicas, a book integrated with augmented reality, fanzines, and a teaching box. With a focus on open science, inclusivity, and accessibility, the project fosters public engagement with paleontological content and promotes fossil heritage conservation. Full article
(This article belongs to the Section Geoheritage, Geoparks and Geotourism)
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<p>Flowchart depicting how the objectives, data acquisition, methods, results, and impacts are interconnected in the project.</p>
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<p>(<b>A</b>) Three-dimensional digitizing using the structured light method during the first step of surface acquisition. (<b>B</b>) Three-dimensional digitizing using the structured light method during surface alignment to complete the 3D model. (<b>C</b>) A render of the 3D model of a skull of the ground sloth <span class="html-italic">Lestodon armatus</span>.</p>
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<p>(<b>A</b>) Web platform at <a href="http://megafauna3d.org" target="_blank">megafauna3d.org</a> (accessed on 19 November 2024) showing 3D model metadata (including physical object data) and the interactive visualizer. (<b>B</b>) Augmented reality incorporated in the Megafauna3D book, running as a web-app without the need to install specific software. (<b>C</b>) Virtual visit to a fossil excavation site in Uruguay developed in Sketchfab, including interest points and site information.</p>
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<p>(<b>A</b>) Minecraft Education world developed for use alongside the other educational resources in primary school settings. (<b>B</b>) Sign language videos focused on increasing the accessibility of the project. (<b>C</b>) NetLogo web agent-based model simulating a Late Pleistocene ecosystem with different species and their interactions, showing ecosystem stability and the impact of different perturbations and extinction cascades.</p>
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<p>(<b>A</b>,<b>B</b>) Paleoartistic representations of the Late Pleistocene megafauna of Uruguay. (<b>C</b>) Fanzines developed during the project and openly distributed via the Megafauna3D website. (<b>D</b>) The physical book “Megafauna3D: un libro de huesos”, merging traditional media with new technologies.</p>
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<p>(<b>A</b>) The educational kit developed for the Megafauna3D project. (<b>B</b>) An active learning workshop with primary school children in the context of the science outreach activities carried out during the project. (<b>C</b>) The presentation of the project and its educational resources at a public school in Uruguay.</p>
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22 pages, 5504 KiB  
Article
Investigation on Tattoo Ink (Hexadecachlorinate Copper Phthalocyanine) Removal: Novel Chemical and Biological Approach
by Giancarlo Ranalli, Alessia Andreotti, Maria Perla Colombini, Cristina Corti, Debora Paris, Laura Rampazzi, Gabriella Saviano, Ramona Vecchio and Claudio Caprari
Molecules 2024, 29(23), 5543; https://doi.org/10.3390/molecules29235543 - 24 Nov 2024
Viewed by 877
Abstract
Tattoos have been a ubiquitous phenomenon throughout history. Now, the demand for tattoo removal for aesthetic or practical reasons is growing rapidly. This study outlines the results of field investigations into the chemical and biological removal of tattoo inks (Hexadecachlorinate copper phthalocyanine—C32 [...] Read more.
Tattoos have been a ubiquitous phenomenon throughout history. Now, the demand for tattoo removal for aesthetic or practical reasons is growing rapidly. This study outlines the results of field investigations into the chemical and biological removal of tattoo inks (Hexadecachlorinate copper phthalocyanine—C32Cl16CuN8—CAS no° 1328-53-6). FTIR, Py-GC/MS, and NMR analyses yielded intriguing profiles pertaining to the primary chemical constituents, along with others of an ambiguous nature. A bioremoval protocol was developed on a pork rind surface to simulate human tattooing. Two previously studied microbial strains were included in this analysis: (i) a bacterial culture of Pseudomonas stutzeri 5190 DSMZ viable cells and (ii) a fungal culture of Alternaria infectoria strain NIS4, the latter already isolated and identified. A combination of physical, chemical, and microbiological analyses, along with microscopic observations, was conducted. In our experimental conditions, inocula from environmental samples (soil and compost) were capable of inducing changes in even trace organic matter (glycerin and additives in pigments) used as a binder in emulsifiers in tattoo inks. Furthermore, the two microbial strains demonstrated promising potential for removing green tattoo ink. Finally, wastewater effluents containing green ink were recovered via electrochemical treatment, and the environmental impact in terms of the CO2 equivalent of our experiments was assessed. The results are promising and warrant further investigation into the innovative biological and chemical removal of tattoo inks from human skin and wastewater, respectively. Full article
(This article belongs to the Section Cross-Field Chemistry)
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<p>Chemical structure of Cyanine Green G related to the green ink tattoo in this study [<a href="#B46-molecules-29-05543" class="html-bibr">46</a>].</p>
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<p>FTIR-ATR spectra of green ink “Azayaka True Green dispersion”, PG7 “Kremer 23000 Phthalo Green dark” and PY1 “Zecchi Primary Hansa Yellow”. Diagnostic peaks are reported on the spectra.</p>
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<p>Example of enrichment test cultures performed on green (<b>a</b>) and black (<b>b</b>) ink tattoos.</p>
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<p>Pyrogram of sample S (soil) compared with control peaks (raw green ink).</p>
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<p>Pyrogram of sample S (SOIL) and C (COMPOST) compared with control peaks (green ink). Label with asterisk (*) belongs to byproducts of the derivatizing agent (HMDS). 1: chloro pentylphenol; 2: aniline; 3: glycerol (2TMS); 4: glycerol (3TMS); 5: quinolinamine; 6: phenylacetamide; 7,8: methyl nitro-benzenamines; 9: benzonitrile.</p>
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<p>Comparison between 1D NMR experiments of raw green ink (<b>top</b>), soil after treatment with green ink (<b>middle</b>), and compost after treatment with green ink (<b>bottom</b>).</p>
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<p>Comparison between 1D-<sup>13</sup>C NMR experiments of raw green ink (<b>top</b>), soil after treatment with green ink (<b>middle</b>), and compost after treatment with green ink (<b>bottom</b>).</p>
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<p>FTIR-ATR spectra on raw green ink (control), compared on soil and compost samples after separate addition of inocula.</p>
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<p>Microbial growths of <span class="html-italic">P. stutzeri</span> 5190 (<b>a</b>) and <span class="html-italic">A. infectoria</span> NIS4 (<b>b</b>) on PCA and PDA media with the addition of tattoo carbon black and green inks, respectively.</p>
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<p>In vitro bioremoval ink tattoo on pork rind, with carbon black (<b>a</b>) and green (<b>b</b>) ink addition, in Petri dishes, in duplicate test.</p>
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<p>Viable cell bioactivity (activated biogel) of <span class="html-italic">P. stutzeri</span> DSMZ 5190 strain at 7th day on green tattooed pork rind (<b>a</b>); green ink tattoo removal by cotton swab (<b>b</b>); stereomicroscope surface observations after biogel removal (<b>c</b>).</p>
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<p>Electrochemical trials carried out on green ink tattoo in wastewater solution; (<b>a</b>) reference coin without current; (<b>b</b>) coin electrode under power working phase; (<b>c</b>) comparison view between two coins at end of trial.</p>
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<p>Schematic diagram of experimental design.</p>
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<p>Tattoo machine and needles used in this work (<b>a</b>); tattooing pork rind (<b>b</b>).</p>
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<p>Colorimeter adopted in all the trials (<b>a</b>), working on tattooed pork rind (<b>b</b>).</p>
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17 pages, 1884 KiB  
Article
Indoor Air Quality in a Museum Storage Room: Conservation Issues Induced in Plastic Objects
by Maria Catrambone, Marianna Cappellina, Francesca Olivini, Elena Possenti, Ilaria Saccani and Antonio Sansonetti
Atmosphere 2024, 15(12), 1409; https://doi.org/10.3390/atmos15121409 - 23 Nov 2024
Viewed by 514
Abstract
This study focuses on assessing the indoor air quality in a storage room (SR) belonging to Museo Nazionale Scienza e Tecnologia Leonardo da Vinci in Milan (MUST), covering pollutants originating from outdoor sources and emissions from historical plastic objects made from cellulose acetate [...] Read more.
This study focuses on assessing the indoor air quality in a storage room (SR) belonging to Museo Nazionale Scienza e Tecnologia Leonardo da Vinci in Milan (MUST), covering pollutants originating from outdoor sources and emissions from historical plastic objects made from cellulose acetate (CA), cellulose nitrate (CN), and urea–formaldehyde (UF) stored in metal cabinets. The concentrations of SO2 (sulphur dioxide), NO2 (nitrogen dioxide), NOx (nitrogen oxides), HONO (nitrous acid), HNO3 (nitric acid), O3 (ozone), NH3 (ammonia), CH3COOH (acetic acid), and HCOOH (formic acid) were determined. The concentrations of SO2, O3, and NOx measured inside the metal cabinets were consistently lower compared to the other sampling sites. This result was expected due to their reactivity and the lack of internal sources. The SR and metal cabinets showed similar concentrations of NO and NO2, except for CA, where a high NO concentration was detected. The interaction between the CA surfaces and NO2 altered the distribution of NO and NO2, leading to a significant increase in NO. The presence of HNO3 potentially led to the formation of ammonium nitrate, as confirmed by ER-FTIR measurements. High levels of HONO and HNO3 in CN and NH3 in the UF indicate object deterioration, while elevated concentrations of CH3COOH in CA and HCOOH in the SR suggest specific degradation pathways for cellulose acetate and other organic materials, respectively. These results could direct conservators towards the most appropriate practical actions. Full article
(This article belongs to the Section Air Quality)
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<p>Metal cabinet containing object in cellulose acetate (<b>a</b>) and storage room (<b>b</b>); the arrow indicates the position of diffusive samplers.</p>
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<p>Average concentrations of (<b>a</b>) SO<sub>2</sub>, (<b>b</b>) NO<sub>2,</sub> (<b>c</b>) NO<sub>x</sub>, (<b>d</b>) O<sub>3</sub>, (<b>e</b>) NO, (<b>f</b>) HONO, (<b>g</b>) HNO<sub>3,</sub> (<b>h</b>) NH<sub>3</sub>, (<b>i</b>) CH<sub>3</sub>COOH, (<b>j</b>) HCOOH measured in the three metal cabinets (MCA, MCN, and MUF) and in the two rooms (SR and OSR) (see <a href="#atmosphere-15-01409-t001" class="html-table">Table 1</a>).</p>
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<p>Average concentrations of (<b>a</b>) SO<sub>2</sub>, (<b>b</b>) NO<sub>2,</sub> (<b>c</b>) NO<sub>x</sub>, (<b>d</b>) O<sub>3</sub>, (<b>e</b>) NO, (<b>f</b>) HONO, (<b>g</b>) HNO<sub>3,</sub> (<b>h</b>) NH<sub>3</sub>, (<b>i</b>) CH<sub>3</sub>COOH, (<b>j</b>) HCOOH measured in the three metal cabinets (MCA, MCN, and MUF) and in the two rooms (SR and OSR) (see <a href="#atmosphere-15-01409-t001" class="html-table">Table 1</a>).</p>
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<p>Average concentrations of (<b>a</b>) SO<sub>2</sub>, (<b>b</b>) NO<sub>2,</sub> (<b>c</b>) NO<sub>x</sub>, (<b>d</b>) O<sub>3</sub>, (<b>e</b>) NO, (<b>f</b>) HONO, (<b>g</b>) HNO<sub>3,</sub> (<b>h</b>) NH<sub>3</sub>, (<b>i</b>) CH<sub>3</sub>COOH, (<b>j</b>) HCOOH measured in the three metal cabinets (MCA, MCN, and MUF) and in the two rooms (SR and OSR) (see <a href="#atmosphere-15-01409-t001" class="html-table">Table 1</a>).</p>
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<p>ER-FTIR spectrum collected on the body of the bag (in red, where the plastic material appears sound), in comparison to the ER-FTIR spectrum of cellulose acetate (in black).</p>
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<p>ER-FTIR spectrum collected on the cellulose acetate bag in correspondence of those parts where the surface appears decayed and covered by white crystals (in red), in comparison to the ER-FTIR spectrum of cellulose nitrate (in black).</p>
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23 pages, 16528 KiB  
Article
Mortars in the Archaeological Site of Hierapolis of Phrygia (Denizli, Turkey) from Imperial to Byzantine Age
by Matteo Maria Niccolò Franceschini, Sara Calandra, Silvia Vettori, Tommaso Ismaelli, Giuseppe Scardozzi, Maria Piera Caggia and Emma Cantisani
Minerals 2024, 14(11), 1143; https://doi.org/10.3390/min14111143 - 11 Nov 2024
Viewed by 844
Abstract
Hierapolis of Phrygia, an archaeological site in southwestern Turkey, has been a UNESCO World Heritage Site since 1988. During archaeological campaigns, 71 mortar samples from public buildings were collected, dating from the Julio-Claudian to the Middle Byzantine period. The samples were analyzed using [...] Read more.
Hierapolis of Phrygia, an archaeological site in southwestern Turkey, has been a UNESCO World Heritage Site since 1988. During archaeological campaigns, 71 mortar samples from public buildings were collected, dating from the Julio-Claudian to the Middle Byzantine period. The samples were analyzed using a multi-analytical approach including polarized optical microscopy (POM), digital image analysis (DIA), X-ray powder diffraction (XRPD) and SEM–EDS to trace the raw materials and understand the evolution of mortar composition and technology over time. During the Roman period, travertine and marble were commonly used in binder production, while marble dominated in the Byzantine period. The aggregates come mainly from sands of the Lycian Nappe and Menderes Massif, with carbonate and silicate rock fragments. Variations in composition, average size and circularity suggest changes in raw material sources in both Roman and Byzantine periods. Cocciopesto mortar was used in water-related structures from the Flavian to the Severan period, but, in the Byzantine period, it also appeared in non-hydraulic contexts. Straw became a common organic additive in Byzantine renders, marking a shift from the exclusively inorganic aggregates of Roman renders. This study illustrates the evolving construction technologies and material sources used throughout the city’s history. Full article
(This article belongs to the Special Issue The Significance of Applied Mineralogy in Archaeometry)
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<p>Plan of the ancient city of Hierapolis.</p>
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<p>(<b>a</b>) Tectonic map of western Anatolia (A: Gediz or Alaşehir Graben, B: Küçük Menderes Graben and C: Büyük Menderes Graben), modified from [<a href="#B44-minerals-14-01143" class="html-bibr">44</a>]; (<b>b</b>) geological map of the Denizli Basin (modified from [<a href="#B45-minerals-14-01143" class="html-bibr">45</a>]).</p>
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<p>Some of the main monuments of Hierapolis: (<b>a</b>) The Apollo Sanctuary, Building A; (<b>b</b>) the Stoa of the Springs; (<b>c</b>) Nymphaeum of the Tritons; (<b>d</b>) the Theatre; (<b>e</b>) the Ploutonion; and (<b>f</b>) Church of St. Philip.</p>
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<p>Some examples of (<b>a</b>) bedding mortar (SP5 sample—Church of St. Philip); (<b>b</b>) grouting mortar (NT4 sample—Nymphaeum of the Tritons); (<b>c</b>) coating mortar (SS5—Stoa of the Springs); and (<b>d</b>) concrete fill (P7 sample—Ploutonion).</p>
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<p>Microphotographs of main aspects of binder and lumps in analyzed mortars (cross polarized nicols): (<b>a</b>) SA-C1 homogeneous micritic binder; (<b>b</b>) SS7 non-homogeneous binder; (<b>c</b>) NA3 binder with recrystallization; (<b>d</b>) P2 binder heterogeneous from micritic to sparitic; (<b>e</b>) P2 travertine underburned fragment; (<b>f</b>) GB2 travertine underburned fragment; (<b>g</b>) P1 marble underburned fragment; (<b>h</b>) SP29 marble underburned fragment.</p>
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<p>Microphotographs of most common aggregate in analyzed mortars (crossed polarized nicols): (<b>a</b>) TH2 gneiss; (<b>b</b>) SS7 meta-sandstone and schist; (<b>c</b>) SS6 calc-schist and quartzite; (<b>d</b>) SA-C1 amphibolite; (<b>e</b>) TH2 breccias; (<b>f</b>) P6 fossiliferous limestone; (<b>g</b>) P1 on the left micritic limestone and on the right travertine; (<b>h</b>) SS5 crushed ceramic fragment; (<b>i</b>) SA-A2 gabbro-like igneous rock; (<b>j</b>) SA-A1 serpentine fragment; (<b>k</b>) SS6 marble on the left and schist on the right; (<b>l</b>) P6 phyllite with schists.</p>
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<p>Microphotographs of sample; (<b>a</b>) SA-C1 bedding mortar; (<b>b</b>) NT1 bedding mortar; (<b>c</b>) SP11, render mortar; (<b>d</b>) SS7 render mortar; (<b>e</b>) SP30 render mortar; (<b>f</b>) SP29 render mortar; (<b>g</b>) SP36 opus sectile bedding mortar; (<b>h</b>) NT4 grouting mortar.</p>
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<p>Backscattered SEM image of binder: (<b>a</b>,<b>c</b>) reaction rim between binder and ceramic fragment (NT2 and SS5, respectively); (<b>b</b>,<b>d</b>) air lime binder (P7 and SA-A1, respectively); (<b>e</b>) HI calculated on selected samples using microchemical SEM–EDS data of binders and lumps. All the acquired data are presented in <a href="#app1-minerals-14-01143" class="html-app">Table S4</a>.</p>
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45 pages, 24880 KiB  
Article
Future Low-Cost Urban Air Quality Monitoring Networks: Insights from the EU’s AirHeritage Project
by Saverio De Vito, Antonio Del Giudice, Gerardo D’Elia, Elena Esposito, Grazia Fattoruso, Sergio Ferlito, Fabrizio Formisano, Giuseppe Loffredo, Ettore Massera, Paolo D’Auria and Girolamo Di Francia
Atmosphere 2024, 15(11), 1351; https://doi.org/10.3390/atmos15111351 - 10 Nov 2024
Viewed by 1312
Abstract
The last decade has seen a significant growth in the adoption of low-cost air quality monitoring systems (LCAQMSs), mostly driven by the need to overcome the spatial density limitations of traditional regulatory grade networks. However, urban air quality monitoring scenarios have proved extremely [...] Read more.
The last decade has seen a significant growth in the adoption of low-cost air quality monitoring systems (LCAQMSs), mostly driven by the need to overcome the spatial density limitations of traditional regulatory grade networks. However, urban air quality monitoring scenarios have proved extremely challenging for their operative deployment. In fact, these scenarios need pervasive, accurate, personalized monitoring solutions along with powerful data management technologies and targeted communications tools; otherwise, these scenarios can lead to a lack of stakeholder trust, awareness, and, consequently, environmental inequalities. The AirHeritage project, funded by the EU’s Urban Innovative Action (UIA) program, addressed these issues by integrating intelligent LCAQMSs with conventional monitoring systems and engaging the local community in multi-year measurement strategies. Its implementation allowed us to explore the benefits and limitations of citizen science approaches, the logistic and functional impacts of IoT infrastructures and calibration methodologies, and the integration of AI and geostatistical sensor fusion algorithms for mobile and opportunistic air quality measurements and reporting. Similar research or operative projects have been implemented in the recent past, often focusing on a limited set of the involved challenges. Unfortunately, detailed reports as well as recorded and/or cured data are often not publicly available, thus limiting the development of the field. This work openly reports on the lessons learned and experiences from the AirHeritage project, including device accuracy variance, field recording assessments, and high-resolution mapping outcomes, aiming to guide future implementations in similar contexts and support repeatability as well as further research by delivering an open datalake. By sharing these insights along with the gathered datalake, we aim to inform stakeholders, including researchers, citizens, public authorities, and agencies, about effective strategies for deploying and utilizing LCAQMSs to enhance air quality monitoring and public awareness on this challenging urban environment issue. Full article
(This article belongs to the Special Issue Air Quality and Energy Transition: Interactions and Impacts)
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<p>The path from the goals to the selection of architectural design and technology for LCAQMS network deployment projects; connections illustrate possible routes throughout the project design choices.</p>
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<p>MONICA<sup>TM</sup> node diagram.</p>
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<p>Front and back picture of the MONICA node.</p>
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<p>Synthetic schema of complete software architecture for AirHeritage project.</p>
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<p>Status of air quality from fixed stations.</p>
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<p>Interactive map for a MONICA registered session. Mobility paths are highlighted using a color code base on the European Air Quality Index (EAQI).</p>
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<p>The position of the three co-location campaigns on a map performed in the AirHeritage project and details of the assembly and USB based on the multiple device power supply unit.</p>
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<p>Scheme of IoT architecture in stationary setup.</p>
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<p>The 7 fixed stations as deployed nearby the reference mobile station during calibration data gathering (co-location periods).</p>
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<p>Lognormal fitted pollutant concentrations as recorded in the first co-location period by mobile ARPAC air quality monitoring laboratory reporting reference values for data-driven calibration.</p>
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<p>Lognormal fitted concentrations of CO as recorded during the first co-location period by mobile ARPAC air quality monitoring laboratory reporting reference values for data-driven calibration.</p>
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<p>Distribution, across the 30 MONICA™ devices, of R<sup>2</sup> (first coloumn) and MAE (second column) short-term performance values for NO<sub>2</sub> (first row), O<sub>3</sub> (second row). and CO (third row), as estimated by MLR-based data-driven calibration in deployment period 1. The distributions appear to be skewed by a few outliers. Performed checks show that anomalous low performance is due to transients in raw sensor responses when they were first switched on.</p>
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<p>R<sup>2</sup> (1st coloumn) and MAE (2nd coloumn) and short-term performance for PM<sub>2.5</sub> (first row) and PM<sub>10</sub> (second row) as estimated by MLR-based data-driven calibration in deployment period 1, across the 30 MONICA devices.</p>
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<p>Histogram of PM<sub>2.5</sub> R<sup>2</sup> accuracy index; (violet) along with gaussian distribution fit (blue) 3 different device performance clusters are observable, each one corresponding to a co-location batch.</p>
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<p>Time series of PM<sub>10</sub> and PM<sub>2.5</sub> concentrations, as measured by the mobile laboratory, during the initial co-location period.</p>
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<p>Trend in the measured hourly mean NO<sub>2</sub> concentrations.</p>
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<p>The hourly mean concentration of ozone (O<sub>3</sub>) (black line) and the 8 h moving average (yellow line) are reported.</p>
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<p>Hourly average carbon monoxide CO concentration time series.</p>
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<p>The time series of PM<sub>10</sub> and PM2<sub>.5</sub> concentrations, as measured by the mobile laboratory, during the 2nd co-location period.</p>
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<p>Trend in the measured hourly mean NO<sub>2</sub> concentrations during the 2nd co-location.</p>
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<p>The hourly mean concentration of ozone (O3) (black line) and the 8 h moving average (yellow line) are presented along with the daily average temperature graph.</p>
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<p>Hourly average carbon monoxide CO concentration time series in 2nd co-location.</p>
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<p>The time series of PM<sub>10</sub> and PM<sub>2.5</sub> concentrations, as measured by the mobile laboratory, during the 3rd co-location period.</p>
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<p>NO<sub>2</sub> hourly average concentrations during the 3rd co-location.</p>
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<p>Hourly average concentration of ozone (O<sub>3</sub>) (black line) and the 8 h moving average (yellow line) are shown (<b>top</b>) with the daily average temperature plot (<b>bottom</b>).</p>
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<p>CO hourly average concentrations recorded by the mobile station during the 3rd co-location period.</p>
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<p>(<b>a</b>) An illustrative example of a user session as displayed on the webpage, accompanied by an indication of the location and the level of pollutants. (<b>b</b>) An illustrative example of a user session as displayed on the MONICA app.</p>
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<p>A schematic representation of the data flow in a mobile application scenario.</p>
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<p>The workflow performed in the Air-Heritage project.</p>
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<p>Site suitability map for networks of low-cost traffic-orientated stations for air pollutant monitoring across the city of Portici.</p>
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<p>Map of one of the optimal locations (red triangle within the red circle), with the related geographical coordinates (marked in red in the table) and the image of the mounted pole where NOx and PM<sub>2.5</sub> sensors have to be installed.</p>
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<p>Maps of the mobile monitoring campaigns along the selected monitoring route.</p>
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<p>Comparison between MONICA (blue line) and SIRANE (orange line), for CO pollutant on 5 and 21 June. Triangles are street canyons and circles are open roads. The ID receptors are grouped by monitoring road segments. The graphs (<b>a</b>,<b>c</b>,<b>e</b>) show the comparisons at 9 a.m., 1 p.m. and 5 p.m. on 5 June while the graphs (<b>b</b>,<b>d</b>,<b>f</b>) show the comparison at 9 a.m., 1 p.m. and 5 p.m. on 21 June.</p>
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<p>Maps of the PM<sub>2.5</sub> measurement density for each 25 m bin in summer (<b>a</b>) and winter campaigns (<b>b</b>).</p>
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<p>Maps of the distribution (median value) of the recorded PM<sub>2.5</sub> concentrations within the 25 m bins in summer (<b>a</b>) and winter campaigns (<b>b</b>).</p>
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21 pages, 26323 KiB  
Article
The Use of Phosphonates to Inhibit Salt Crystallization: A Laboratory Study for the Sustainable Conservation of Mural Paintings in the Hypogea Context
by Giulia Simonelli, Giancarlo Sidoti, Ludovica Ruggiero, Angela Calia, Giovanni Quarta, Fabio Aramini and Paola Mezzadri
Sustainability 2024, 16(22), 9745; https://doi.org/10.3390/su16229745 - 8 Nov 2024
Viewed by 884
Abstract
This research is focused on the laboratory study of salt crystallization inhibitor products as new materials for conservation treatments which can be applied to mortars and painted plasters; as is well known, salt crystallization is one of the most frequent causes of decay [...] Read more.
This research is focused on the laboratory study of salt crystallization inhibitor products as new materials for conservation treatments which can be applied to mortars and painted plasters; as is well known, salt crystallization is one of the most frequent causes of decay processes on decorated architectural surfaces in a wide range of environments. Specifically, the study targets the field of the preventive conservation of mural paintings within rupestrian heritage sites. For the first time, systematic investigations were performed on mock-ups made of plaster painted with two different pigments: yellow ochre and carbon black. Two types of phosphonate inhibitors, PBTC (2-phosphonobutane-1,2,4-tricarboxylic acid) and ATMP (aminotris (methylene phosphonic acid)), were chosen and applied at two different concentrations. Given the limited literature available, and the presence of pigments potentially sensitive to treatment with salt inhibitors, preliminary tests were required. Their effects on the chromatic features of the pigments were evaluated visually and using colorimetry. The changes in the behaviour of water circulation in the mortar resulting from the treatments were evaluated through water vapour permeability and absorption tests. Accelerated crystallization experiments were carried out to assess how inhibitors could influence the growth of salts and the resulting material damage. The latter was carried out by employing sodium sulphate and calcium sulphate solutions, quantifying the damage to the specimens through material loss in weight and the percentage of painted surface loss. Based on the overall results, the product with the best performance was identified was ATMP 0.1% (by volume) in deionized water. The obtained results show that salt inhibitor treatments are promising for in situ application and could represent an innovative approach to promote the sustainable conservation of mural painting, particularly those located in hypogeal contexts, where the salt supply cannot be removed and slowing the growth of salts and/or changing their crystalline habitus may be effective in limiting their damage. Full article
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<p>Saint Agustine in Saint Canione’ s chapel pictorial cycle in the rupestrian church of S. Pietro Barisano (Matera, Southern Italy): the painting before the conservation treatment.</p>
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<p>Mean values of the water vapour resistance coefficient (µ) obtained for the two products at the two concentrations and for the samples before the treatments.</p>
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<p>Amounts of water absorbed by contact sponge test in the samples before (BT) and after (AT) the treatment with the salt inhibitors.</p>
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<p>∆<span class="html-italic">E*</span><sub>00</sub> values measured on the surfaces of yellow ochre and carbon black specimens after the treatments. ∆<span class="html-italic">E</span>*<sub>00</sub> meaning: the International Commission on Illumination (CIE) calls their distance metric Δ<span class="html-italic">E</span>* (also inaccurately called dE*, dE, or “Delta E”) where delta is a Greek letter often used to denote difference, and E stands for Empfindung; German for “sensation”.</p>
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<p>∆<span class="html-italic">E*</span><sub>00</sub> values measured on the surfaces of yellow ochre and carbon black specimens after the treatments. ∆<span class="html-italic">E</span>*<sub>00</sub> meaning: the International Commission on Illumination (CIE) calls their distance metric Δ<span class="html-italic">E</span>* (also inaccurately called dE*, dE, or “Delta E”) where delta is a Greek letter often used to denote difference, and E stands for Empfindung; German for “sensation”.</p>
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<p>Weight changes in treated and untreated samples of plaster with yellow ochre and carbon black paint layers during the Na<sub>2</sub>SO<sub>4</sub> crystallization test.</p>
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<p>Weight changes in treated and untreated samples of plaster with yellow ochre and carbon black paint layers during the Na<sub>2</sub>SO<sub>4</sub> crystallization test.</p>
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<p>Visual appearance of the yellow ochre and black carbon triple specimens treated with ATMP (INA) and PBTC (INB) products compared to untreated ones, at the end of the Na<sub>2</sub>SO<sub>4</sub> crystallization test (7th week).</p>
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<p>Visual appearance of samples treated with INA2 (5th week) in raking light macrophotographs: (<b>a</b>) efflorescences and sub-effloresecences on a carbon black specimen; (<b>b</b>) detail of the sub-efflorescences causing the lifting of the surface layers; (<b>c</b>) sub-efflorescences and thick encrustations on a yellow ochre specimen; (<b>d</b>) detail of the encrustation (portable microscope, microphotograph, 50×).</p>
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<p>Visual appearance of the yellow ochre and black carbon specimens treated with ATMP 0.1% (INA1) products compared to the untreated ones during the test, showing the lower extents of the efflorescences in the presence of the treatments.</p>
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<p>Fifth week: (<b>a</b>) efflorescences showing a crater morphology on a yellow ochre sample treated with INA1 (raking light macrophotograph); (<b>b</b>) macrograph detail of the crater morphology; (<b>c</b>) distribution of the sub-efflorescences on an untreated black carbon sample (raking light macrophotograph); (<b>d</b>) a detailed side-view photograph revealing the efflorescence’s lifting effect on the plaster and black paint film.</p>
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<p>Fifth week: (<b>a</b>) efflorescences showing a crater morphology on a yellow ochre sample treated with INA1 (raking light macrophotograph); (<b>b</b>) macrograph detail of the crater morphology; (<b>c</b>) distribution of the sub-efflorescences on an untreated black carbon sample (raking light macrophotograph); (<b>d</b>) a detailed side-view photograph revealing the efflorescence’s lifting effect on the plaster and black paint film.</p>
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<p>Weight changes for treated and untreated samples of plaster with yellow ochre and carbon black paint layers during the CaSO<sub>4</sub> crystallization test.</p>
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<p>Visual appearance of the specimens before and at the end of the salt crystallization test with CaSO<sub>4</sub> (7th week), showing a more evident whitening on the black samples compared to the yellow ones.</p>
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<p>Details of some globular salt aggregates (portable microscope, microphotograph, 50×) on the surface of yellow (<b>a</b>) and black (<b>b</b>) untreated samples during Ca<sub>2</sub>SO<sub>4</sub> salt crystallization test (2nd week).</p>
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<p>Appearance of demineralized water droplets on yellow (<b>a</b>) and black (<b>b</b>) untreated specimens, with measured contact angle values of 75° and 130°, respectively.</p>
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21 pages, 1513 KiB  
Review
From Ecology to Humanities: A Review, Insights, and Recommendations on National Marine Parks
by Qiuhua Li
Sustainability 2024, 16(22), 9734; https://doi.org/10.3390/su16229734 - 8 Nov 2024
Viewed by 1034
Abstract
National marine parks (NMPs) represent a category within the marine protected area (MPA) framework, and nearly all countries worldwide have implemented marine protected area or national marine park initiatives. Correspondingly, research on this topic has gradually emerged. Given that existing research tends to [...] Read more.
National marine parks (NMPs) represent a category within the marine protected area (MPA) framework, and nearly all countries worldwide have implemented marine protected area or national marine park initiatives. Correspondingly, research on this topic has gradually emerged. Given that existing research tends to focus too much on the perspective of natural sciences such as ecology, this article specifically focuses on humanities research. The relevant literature on national marine parks is organized using a literature review method and mainly analyzed through content analysis. It is summarized into five research areas: park creation research, ecological and economic impact assessment, park community management research, park marine cultural heritage, and new park-planning methods. Through this review, it is found that the research content exhibits characteristics of being “ecology-heavy but humanities-light, impact-heavy but strategy-light, conservation-heavy but development-light, and qualitative-heavy but interdisciplinary-light”. In response to these trends, this paper suggests adopting new planning approaches, implementing participatory management strategies, enhancing community policy guidance, and promoting education on sustainable development. Furthermore, it proposes establishing NMPs focused on marine cultural heritage, creating authoritative park evaluation criteria and research methods, and strengthening diachronic studies, quantitative analysis, and interdisciplinary methods in the humanities. Full article
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<p>The top ten disciplines in all results of the topic search.</p>
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<p>The co-occurrence of keywords in the field of humanities.</p>
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<p>Annual publication frequency of selected literature.</p>
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17 pages, 2432 KiB  
Article
Non-Destructive Estimation of Paper Fiber Using Macro Images: A Comparative Evaluation of Network Architectures and Patch Sizes for Patch-Based Classification
by Naoki Kamiya, Kosuke Ashino, Yasuhiro Sakai, Yexin Zhou, Yoichi Ohyanagi and Koji Shibazaki
NDT 2024, 2(4), 487-503; https://doi.org/10.3390/ndt2040030 - 7 Nov 2024
Viewed by 539
Abstract
Over the years, research in the field of cultural heritage preservation and document analysis has exponentially grown. In this study, we propose an advanced approach for non-destructive estimation of paper fibers using macro images. Expanding on studies that implemented EfficientNet-B0, we explore the [...] Read more.
Over the years, research in the field of cultural heritage preservation and document analysis has exponentially grown. In this study, we propose an advanced approach for non-destructive estimation of paper fibers using macro images. Expanding on studies that implemented EfficientNet-B0, we explore the effectiveness of six other deep learning networks, including DenseNet-201, DarkNet-53, Inception-v3, Xception, Inception-ResNet-v2, and NASNet-Large, in conjunction with enlarged patch sizes. We experimentally classified three types of paper fibers, namely, kozo, mitsumata, and gampi. During the experiments, patch sizes of 500, 750, and 1000 pixels were evaluated and their impact on classification accuracy was analyzed. The experiments demonstrated that Inception-ResNet-v2 with 1000-pixel patches achieved the highest patch classification accuracy of 82.7%, whereas Xception with 750-pixel patches exhibited the best macro-image-based fiber estimation performance at 84.9%. Additionally, we assessed the efficacy of the method for images containing text, observing consistent improvements in the case of larger patch sizes. However, limitations exist in background patch availability for text-heavy images. This comprehensive evaluation of network architectures and patch sizes can significantly advance the field of non-destructive paper analysis, offering valuable insights into future developments in historical document examination and conservation science. Full article
(This article belongs to the Special Issue Advances in Imaging-Based NDT Methods)
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<p>Overview of the proposed paper fiber estimation method. The process begins with a macro image (4000 × 3000 pixels) of paper, which is divided into patches of various sizes (500 × 500, 750 × 750, and 1000 × 1000 pixels). These patches are fed into different pretrained deep convolutional neural networks (DCNNs) for classification. Finally, the results are aggregated to estimate the fiber type of the entire macro image.</p>
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<p>Macro image fiber estimation results based on patch classification using Inception-ResNet-v2 across three patch sizes (500 × 500, 750 × 750, and 1000 × 1000 pixels) for a macro image of mitsumata fiber. The colored areas represent the classification results, with green, blue, and red corresponding to kozo, mitsumata, and gampi, respectively. The gray areas in the 750 × 750 patch size image indicate regions at the edges of the original macro image where patches could not be extracted completely, and thus, no classification was performed. This visualization demonstrates the impact of increasing patch size on classification accuracy and consistency. As the patch size increases from left to right, a clear improvement is observed in the correct classification of mitsumata fibers (blue areas). The larger patch sizes (750 × 750 and 1000 × 1000) exhibit significantly fewer misclassifications, particularly reducing the instances of kozo (green) misclassification. This improvement suggests that larger patches capture more comprehensive fiber structures and patterns, resulting in more accurate and stable classifications. The progression also highlights the trade-off between classification detail and the number of available patches for voting in macro image estimation.</p>
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<p>Macro image fiber estimation results based on patch classification using Inception-ResNet-v2 across three patch sizes (500 × 500, 750 × 750, and 1000 × 1000 pixels) for a kozo fiber sample containing text. The colored areas represent patch-level classification results, with green, blue, and red corresponding to kozo, mitsumata, and gampi, respectively. The gray areas in the 750 × 750 patch size image indicate regions at the edges of the original macro image where patches could not be fully extracted, and thus, no classification was performed. Additionally, in all patch sizes, gray areas represent regions where patches contained text, and these were excluded from classification. The estimated fiber type for the entire macro image is specified below each patch-based result.</p>
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<p>Macro image fiber estimation results based on patch classification using Inception-ResNet-v2 across three patch sizes (500 × 500, 750 × 750, and 1000 × 1000 pixels) for a gampi fiber sample containing text. The colored areas represent patch-level classification results, with green, blue, and red corresponding to kozo, mitsumata, and gampi, respectively. The gray areas in the 750 × 750 patch size image indicate regions at the edges of the original macro image where patches could not be fully extracted, and thus, no classification was performed. Additionally, in all patch sizes, gray areas represent regions where patches contained text, and these were excluded from classification. The estimated fiber type for the entire macro image is mentioned below each patch-based result, with “No majority” indicating the case where the majority voting method could not determine the predominant fiber type because of the equal distribution of classifications.</p>
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