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14 pages, 1814 KiB  
Article
Analysis of Phosphorus Soil Sorption Data: Improved Results from Global Least-Squares Fitting
by Joel Tellinghuisen, Paul Holford and Paul J. Milham
Soil Syst. 2025, 9(1), 22; https://doi.org/10.3390/soilsystems9010022 - 4 Mar 2025
Viewed by 161
Abstract
Phosphate sorption data are often analyzed by least-squares fitting to the two- or three-parameter Freundlich model. The standard methods are flawed by (1) treating the measured pseudo-equilibrium concentration C as the independent (hence error-free) variable and (2) neglecting the weighting that should accommodate [...] Read more.
Phosphate sorption data are often analyzed by least-squares fitting to the two- or three-parameter Freundlich model. The standard methods are flawed by (1) treating the measured pseudo-equilibrium concentration C as the independent (hence error-free) variable and (2) neglecting the weighting that should accommodate the varying precision of the data. Here, we address both of these shortfalls and use a global fit model to achieve optimal precision in fitting data for five acidic Australian soil types. Each individual dataset consists of measured C values for up to nine phosphate spiking levels C0. For each soil type, there are three–five such datasets from varying levels of phosphate fertilizer pre-exposure (Pf) two years earlier. These datasets are fitted simultaneously by expressing the Freundlich capacity factor a and exponent b as theoretically predicted functions of the assay amounts of Fe, Al, and P measured for each Pf. The analysis allows for uncertainty in both C and C0, with inverse-variance weighting from variance functions estimated by residuals analysis. The estimated presorbed P amounts Q depend linearly on Pf, with positive intercepts at Pf = 0, indicating residual phosphate in the soils prior to the laboratory phosphate treatments. The key takeaway points are as follows: (1) global analysis yields optimal estimates and improved precision for the fit parameters; (2) allowing for uncertainty in C is essential when the data include C values near 0; (3) varying data precision requires weighting to yield optimal parameter estimates and reliable uncertainties. Full article
(This article belongs to the Special Issue Adsorption Processes in Soils and Sediments)
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Graphical abstract

Graphical abstract
Full article ">Figure 1
<p>Sorbed P vs. pseudo-equilibrium P solution concentration for two MO soils having fertilizer amendments of 71 mg/kg (MO6) and 602 mg/kg (MO11). The curves are LS fit results to the model of Equation (3) with (solid) and without (dashed) <span class="html-italic">Q</span>. Omission of the <span class="html-italic">Q</span> term gives increases in the sums of squared residuals in these unweighted fits by factors of 5 (MO6) and 20. The estimated <span class="html-italic">Q</span> values are 52 (14) and 168 (30) mg/kg for MO6 and MO11, respectively. (Figures in parentheses are estimated SEs in terms of final digits, e.g., 168 ± 30). Note the logarithmic scale for <span class="html-italic">C</span>.</p>
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<p>Sorption <span class="html-italic">Q</span> estimates for KA soils from analyses of individual <span class="html-italic">P</span><sub>f</sub> datasets, using Equation (6) and assuming uncertain <span class="html-italic">C</span> and uncertain <span class="html-italic">C</span><sub>0</sub>, with the other variable treated as error-free. The illustrated lines are results of weighted fits giving intercepts 63 (33) and 8 (7), and slopes 0.21 (9) and 0.27 (4), for <span class="html-italic">C</span> and <span class="html-italic">C</span><sub>0</sub> uncertain, respectively. Displayed error bars are 1 SE. Points have been displaced on the <span class="html-italic">P</span><sub>f</sub> axis for clarity of display.</p>
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<p>Sorption <span class="html-italic">Q</span> estimates for KA soils from global analysis using Equation (6), for three different assumptions about the data error. In the first two, the other variable was taken to be error-free; in the third, both were weighted using the final data VFs (see below). The illustrated lines are results of weighted fits giving, in legend order, intercepts 103 (19), 28 (5), and 51 (7); and slopes 0.14 (4), 0.12 (1), and 0.12 (2).</p>
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<p>Least-squares fit residuals from <span class="html-italic">C</span><sub>0</sub>-uncertain analyses of the KA (left) and FL (right) soils, displayed vs. <span class="html-italic">C</span><sub>0</sub>. From Equation (6), the residuals are 10 times the <span class="html-italic">C</span><sub>0</sub> disparities. Results at top (<b>A</b>,<b>B</b>) are from fitting all data, at bottom (<b>C</b>,<b>D</b>) after removal of the values at <span class="html-italic">C</span><sub>0</sub> = 63.5 (shown with a value of 0.0). (The left-most points in each frame are for <span class="html-italic">C</span><sub>0</sub> = 0 but have been displaced for the log display).</p>
Full article ">Figure 5
<p>Standard deviations from studentized residuals obtained fitting data for all soils except MA to the global model, assuming, in turn, constant uncertainty for <span class="html-italic">C</span> and <span class="html-italic">C</span><sub>0</sub> and no error for the other variable. For <span class="html-italic">C</span><sub>0</sub> (SD scale left), the lowest abscissa values were 0.0 but were increased to 0.01 for this logarithmic display. For <span class="html-italic">C,</span> the abscissa is the mean of close-lying values; for <span class="html-italic">C</span><sub>0</sub>, it is the employed concentration. Dashed lines and open points are results for final estimated VFs (see below and <a href="#app1-soilsystems-09-00022" class="html-app">Supplementary Materials (SI)</a>).</p>
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<p>Results for Freundlich <span class="html-italic">a</span> (frame <b>A</b>) and <span class="html-italic">b</span> (<b>B</b>) from standard and global analyses of the MO data (5 <span class="html-italic">P</span><sub>f</sub> values). All error bars are 1 <span class="html-italic">σ</span>. In (<b>B</b>), the dotted lines represent the 1-<span class="html-italic">σ</span> error bands on the weighted linear fit of the displayed standard points and on the linear fitted function in the global model.</p>
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<p>Sorption <span class="html-italic">Q</span> estimates as a function of phosphate fertilizer amendment for five soils, from global TV analyses using Equations (6) and (7), with inverse-variance weighting using the SD expressions of Equation (11). Displayed error bars are 1 SE. Lines are from weighted LS fits.</p>
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18 pages, 1341 KiB  
Article
Performance Analysis for High-Dimensional Bell-State Quantum Illumination
by Jeffrey H. Shapiro
Physics 2025, 7(1), 7; https://doi.org/10.3390/physics7010007 - 3 Mar 2025
Viewed by 230
Abstract
Quantum illumination (QI) is an entanglement-based protocol for improving LiDAR/radar detection of unresolved targets beyond what a classical LiDAR/radar of the same average transmitted energy can do. Originally proposed by Seth Lloyd as a discrete-variable quantum LiDAR, it was soon shown that his [...] Read more.
Quantum illumination (QI) is an entanglement-based protocol for improving LiDAR/radar detection of unresolved targets beyond what a classical LiDAR/radar of the same average transmitted energy can do. Originally proposed by Seth Lloyd as a discrete-variable quantum LiDAR, it was soon shown that his proposal offered no quantum advantage over its best classical competitor. Continuous-variable, specifically Gaussian-state, QI has been shown to offer a true quantum advantage, both in theory and in table-top experiments. Moreover, despite its considerable drawbacks, the microwave version of Gaussian-state QI continues to attract research attention. A recent QI study by Armanpreet Pannu, Amr Helmy, and Hesham El Gamal (PHE), however, has: (i) combined the entangled state from Lloyd’s QI with the channel models from Gaussian-state QI; (ii) proposed a new positive operator-valued measurement for that composite setup; and (iii) claimed that, unlike Gaussian-state QI, PHE QI achieves the Nair–Gu lower bound on QI target-detection error probability at all noise brightnesses. PHE’s analysis was asymptotic, i.e., it presumed infinite-dimensional entanglement. The current paper works out the finite-dimensional performance of PHE QI. It shows that there is a threshold value for the entangled-state dimensionality below which there is no quantum advantage, and above which the Nair–Gu bound is approached asymptotically. Moreover, with both systems operating with error-probability exponents 1 dB lower than the Nair–Gu bound, PHE QI requires enormously higher entangled-state dimensionality than does Gaussian-state QI to achieve useful error probabilities in both high-brightness (100 photons/mode) and moderate-brightness (1 photon/mode) noise. Furthermore, neither system has an appreciable quantum advantage in low-brightness (much less than 1 photon/mode) noise. Full article
(This article belongs to the Section Atomic Physics)
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Figure 1

Figure 1
<p>The penalty functions <math display="inline"><semantics> <mrow> <mi mathvariant="script">E</mi> <mo>(</mo> <mn>0.001</mn> <mo>,</mo> <mn>1</mn> <mo>,</mo> <mi>M</mi> <mo>)</mo> </mrow> </semantics></math> (top curve) and <math display="inline"><semantics> <mrow> <mi mathvariant="script">E</mi> <mo>(</mo> <mn>0.001</mn> <mo>,</mo> <mn>100</mn> <mo>,</mo> <mi>M</mi> <mo>)</mo> </mrow> </semantics></math> (bottom curve) versus <math display="inline"><semantics> <mrow> <msub> <mo form="prefix">log</mo> <mn>10</mn> </msub> <mrow> <mo>(</mo> <mi>M</mi> <mo>)</mo> </mrow> </mrow> </semantics></math>. Note that for both curves, the <span class="html-italic">M</span> values shown here exceed the penalty functions’ <math display="inline"><semantics> <msub> <mi>M</mi> <mn>0</mn> </msub> </semantics></math> thresholds for <math display="inline"><semantics> <mrow> <msub> <mi>p</mi> <mi>D</mi> </msub> <mo>&gt;</mo> <msub> <mi>p</mi> <mi>F</mi> </msub> </mrow> </semantics></math>, viz., 22.6 for the moderate-brightness noise, and 31.5 for the high-brightness noise. See text for details.</p>
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<p>The Chernoff bound, <math display="inline"><semantics> <mrow> <mi>Pr</mi> <msub> <mrow> <mo>(</mo> <mi>e</mi> <mo>)</mo> </mrow> <mi>CB</mi> </msub> </mrow> </semantics></math>, versus <math display="inline"><semantics> <msub> <mi>N</mi> <mi>T</mi> </msub> </semantics></math> for PHE QI and Gaussian-state (GS) QI, as labelled, for <math display="inline"><semantics> <mrow> <mi>κ</mi> <mo>=</mo> <mn>0.001</mn> </mrow> </semantics></math> with <math display="inline"><semantics> <mrow> <msub> <mi>N</mi> <mi>B</mi> </msub> <mo>=</mo> <mn>100</mn> </mrow> </semantics></math> (top curve) and <math display="inline"><semantics> <mrow> <mi>κ</mi> <mo>=</mo> <mn>0.001</mn> </mrow> </semantics></math> with <math display="inline"><semantics> <mrow> <msub> <mi>N</mi> <mi>B</mi> </msub> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math> (bottom curve), with both systems are operating at 1 dB below the Nair–Gu error-probability exponent. In the high-brightness noise, PHE QI requires <math display="inline"><semantics> <mrow> <mi>M</mi> <mo>=</mo> <mn>2.27</mn> <mo>×</mo> <msup> <mn>10</mn> <mn>13</mn> </msup> </mrow> </semantics></math> to reach this operating point, whereas, in the moderate-brightness noise, <math display="inline"><semantics> <mrow> <mi>M</mi> <mo>=</mo> <mn>2.21</mn> <mo>×</mo> <msup> <mn>10</mn> <mn>11</mn> </msup> </mrow> </semantics></math> suffices for this purpose. In both brightnesses, <math display="inline"><semantics> <msub> <mi>N</mi> <mi>T</mi> </msub> </semantics></math> is the number of transmitted signal photons. For Gaussian-state QI, this operating point requires <math display="inline"><semantics> <mrow> <msub> <mi>N</mi> <mi>S</mi> </msub> <mo>=</mo> <mn>0.01523</mn> </mrow> </semantics></math> in the high-brightness noise and <math display="inline"><semantics> <mrow> <msub> <mi>N</mi> <mi>S</mi> </msub> <mo>=</mo> <mn>0.01421</mn> </mrow> </semantics></math> in the moderate-brightness noise. In both of these cases, <math display="inline"><semantics> <msub> <mi>N</mi> <mi>T</mi> </msub> </semantics></math> is now the average number of transmitted signal photons. See text for details.</p>
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<p><math display="inline"><semantics> <mrow> <msub> <mi>M</mi> <mi>PHE</mi> </msub> <mo>/</mo> <msub> <mi>M</mi> <mi>GS</mi> </msub> </mrow> </semantics></math> versus <math display="inline"><semantics> <mrow> <msub> <mrow> <mi>Pr</mi> <mo>(</mo> <mi>e</mi> <mo>)</mo> </mrow> <mi>CB</mi> </msub> </mrow> </semantics></math> where <math display="inline"><semantics> <msub> <mi>M</mi> <mi>PHE</mi> </msub> </semantics></math> and <math display="inline"><semantics> <msub> <mi>M</mi> <mi>GS</mi> </msub> </semantics></math> are the entangled-state dimensionalities associated with the <math display="inline"><semantics> <mrow> <mi>Pr</mi> <msub> <mrow> <mo>(</mo> <mi>e</mi> <mo>)</mo> </mrow> <mi>CB</mi> </msub> </mrow> </semantics></math> versus <math display="inline"><semantics> <msub> <mi>N</mi> <mi>T</mi> </msub> </semantics></math> curves from <a href="#physics-07-00007-f002" class="html-fig">Figure 2</a>.</p>
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29 pages, 1678 KiB  
Article
A Novel Grey Prediction Model: A Hybrid Approach Based on Extension of the Fractional Order Discrete Grey Power Model with the Polynomial-Driven and PSO-GWO Algorithm
by Baohua Yang, Xiangyu Zeng and Jinshuai Zhao
Fractal Fract. 2025, 9(2), 120; https://doi.org/10.3390/fractalfract9020120 - 15 Feb 2025
Viewed by 286
Abstract
Background: This study addresses the challenge of predicting data sequences characterized by a mix of partial linearity and partial nonlinearity. Traditional forecasting models often struggle to accurately capture the complex patterns of change within the data. Methods: To this end, this study introduces [...] Read more.
Background: This study addresses the challenge of predicting data sequences characterized by a mix of partial linearity and partial nonlinearity. Traditional forecasting models often struggle to accurately capture the complex patterns of change within the data. Methods: To this end, this study introduces a novel polynomial-driven discrete grey power model (PFDPGM(1,1)) that includes time perturbation parameters, enabling a flexible representation of complex variation patterns in the data. The model aims to determine the accumulation order, nonlinear power exponent, time perturbation parameter, and polynomial degree to minimize the fitting error under various criteria. The estimation of unknown parameters is carried out by leveraging a hybrid optimization algorithm, which integrates Particle Swarm Optimization (PSO) and the Grey Wolf Optimization (GWO) algorithm. Results: To validate the effectiveness of the proposed model, the annual total renewable energy consumption in the BRICS countries is used as a case study. The results demonstrate that the newly constructed polynomial-driven discrete grey power model can adaptively fit and accurately predict data series with diverse trend change characteristics. Conclusions: This study has achieved a significant breakthrough by successfully developing a new forecasting model. This model is capable of handling data sequences with mixed trends effectively. As a result, it provides a new tool for predicting complex data change patterns. Full article
(This article belongs to the Special Issue Applications of Fractional-Order Grey Models)
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Figure 1
<p>The transformation relationships between the <span class="html-italic">PFDPGM</span>(1,1) model and the other grey models.</p>
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<p>Flowchart of the proposed hybrid PSO-GWO algorithm.</p>
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<p>Renewable energy consumption (excluding hydropower) and growth rate of China from 2013 to 2023 (EJ).</p>
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<p>The time series of rand generation and noise series with different SNR values.</p>
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<p>The MAPE of the fitting test in the <span class="html-italic">PFDPGM</span>(1,1) model based on synthetic data under different noise levels.</p>
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<p>Forecast error of the <span class="html-italic">PFDPGM</span>(1,1) model based on synthetic data under different noise levels.</p>
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<p>The <span class="html-italic">MAPE</span> of different grey prediction models based on synthetic data under different noise levels.</p>
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<p>Forecast error of different grey prediction models based on synthetic data under different noise levels.</p>
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<p>The fitting error of the sixth data by different grey prediction models.</p>
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11 pages, 7766 KiB  
Article
Nonlinear Gait Variability Increases with Age in Children from 2–10 Years Old
by Bryon C. Applequist, Zachary L. Motz and Anastasia Kyvelidou
Biomechanics 2025, 5(1), 10; https://doi.org/10.3390/biomechanics5010010 - 3 Feb 2025
Viewed by 478
Abstract
Background: Linear methods of analysis of variability are concerned with the magnitude of variability and often consider deviations from a central mean as errors. The utilization of nonlinear tools to examine variability allows for the exploration and measurement of the patterns of variability [...] Read more.
Background: Linear methods of analysis of variability are concerned with the magnitude of variability and often consider deviations from a central mean as errors. The utilization of nonlinear tools to examine variability allows for the exploration and measurement of the patterns of variability displayed by the system. This methodology explores the deterministic properties of biological signals, in this case, gait, or how previous iterations within the gait cycle influence subsequent and future iterations. The nonlinear analysis of gait variability of the joint angle time series has not been investigated in developing children. Methods: We collected 3 min of treadmill walking data for 28 children between the ages of 2 and 10 years old and analyzed their joint angle time series using nonlinear methods of analysis (sample entropy, largest Lyapunov exponent, and recurrence quantification analysis). Results: Our results indicate that the nonlinear variability of children’s gait increases as children age. Interestingly, this contrasts with the findings from our previous work that showed a decrease in linear variability as children age. The combination of a decrease in linear variability, or a refined and improved stability of gait, as well as an increase in nonlinear variability, or an increase in the sophistication and quality of movement patterns, suggest an overall maturation of the neuromuscular system. Conclusions: Our study indicate that there is a refining of gait with age and motor maturation. This refining speaks to the overall multifaceted organization of systems that defines the maturation of gait. Full article
(This article belongs to the Special Issue Gait and Balance Control in Typical and Special Individuals)
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<p>Violin and box plots showing the distribution of the sample entropy of the ankle, hip, and knee joint time series. Data are reported for the age groups.</p>
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<p>Violin and box plots showing the distribution of the largest Lyapunov exponent of the ankle, hip, and knee joint time series. Data are reported for the age groups.</p>
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<p>Violin and box plots showing the distribution of the recurrence quantification analysis (%Determinism, mean line) of the ankle, hip, and knee joint time series. Data are reported for the age groups.</p>
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27 pages, 9883 KiB  
Article
Assessment of RANS Models for Milli-Channel Turbulent Flow in Drip Irrigation Emitter
by Qi Feng, Qingzheng Li, Yaojun Li, Xuefeng Qiu, Jiandong Wang and Xingfa Huang
Agronomy 2025, 15(1), 81; https://doi.org/10.3390/agronomy15010081 - 30 Dec 2024
Viewed by 695
Abstract
Accurate numerical simulation of turbulent flow within the milli-channels of drip irrigation emitters has long been a significant challenge. This paper presents a comprehensive Reynolds-Averaged Navier–Stokes (RANS) modeling-based analysis of the flow dynamics within the labyrinth milli-channel of a tooth-shaped emitter, with partial [...] Read more.
Accurate numerical simulation of turbulent flow within the milli-channels of drip irrigation emitters has long been a significant challenge. This paper presents a comprehensive Reynolds-Averaged Navier–Stokes (RANS) modeling-based analysis of the flow dynamics within the labyrinth milli-channel of a tooth-shaped emitter, with partial experimental validation. The objective was to assess the performances of four RANS turbulence models: RNG k-ε (RNG), Realizable k-ε (RKE), SST k-ω (SST), and baseline k-ω (BSL), alongside three near-wall treatments: scalable wall function (SWF), enhanced wall treatment (EWT), and y+-insensitive wall treatment (YIWT) for emitter flow analysis. The results showed that the RNG and RKE, coupled with EWT, are preferred options for predicting the flow rate—pressure loss relationship of the emitter, with relative errors of 2.08% and 1.02% in the discharge exponent and 5.66% and 7.58% in the flow rate coefficient, respectively. Although both RNG and RKE using SWF are viable for hydraulic performance prediction under high-flow rate conditions, the deviation of predicted flow rate reaches up to 25.46% under low-flow rate conditions. The SST and BSL models, which employ IYPT, captured induced vortices at channel corners; however, they underestimated emitter flow rates. Furthermore, computations using SWF failed to capture the asymptotic characteristics of flow parameters in the near-wall region, resulting in an overestimation of turbulent kinetic energy and turbulence intensity. Additionally, the magnitude of wall shear stress in the channel corners fell below the threshold required for self-cleaning, underscoring the necessity for optimizing channel structures to enhance the anti-clogging performance of the emitter. Full article
(This article belongs to the Section Precision and Digital Agriculture)
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Figure 1

Figure 1
<p>The structure of the tooth-shaped drip irrigation emitter. (<b>a</b>) 2D presentation of the dimension of the geometry; (<b>b</b>) Unit 5 of the emitter; (<b>c</b>) Inlet plan. The red dash lines indicate the specific stations where the results were analyzed. The boundary in red, labeled as ABCDE, is the side wall in mid-span plane to present the wall shear stress profiles.</p>
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<p>Computational mesh. (<b>a</b>) Unstructured mesh on the channel wall; (<b>b</b>) mesh with inflation layers in the inlet plane; (<b>c</b>) surface mesh in the arc region of the baffle; (<b>d</b>) mesh details in the emitter channel.</p>
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<p>Schematic diagrams of the emitter performance test rig.</p>
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<p>Flow rate–pressure loss curves of the emitter.</p>
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<p>Streamlines (<b>top</b>) and velocity modulus contours (<b>bottom</b>) at the mid-span plane (<span class="html-italic">z</span> = 0.3 mm) of unit 5. (<b>a</b>) RNG−SWF; (<b>b</b>) RNG−EWT; (<b>c</b>) RKE−SWF; (<b>d</b>) RKE−EWT; (<b>e</b>) SST; (<b>f</b>) BSL.</p>
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<p>Contours of streamwise velocity (<span class="html-italic">v<sub>x</sub></span>) in the half-span plane (<span class="html-italic">yoz</span>) through L0. (<b>a</b>) RNG−SWF and RNG−EWT; (<b>b</b>) RKE−SWF and RKE−EWT; (<b>c</b>) SST and BSL.</p>
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<p>Streamwise velocity profiles along L0 in the mid-span plane in baffle 5.</p>
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<p>Vertical velocity (<span class="html-italic">v<sub>y</sub></span>) profiles in the initial six baffles and baffles 8 and 15 along the horizontal data extraction lines shown in <a href="#agronomy-15-00081-f001" class="html-fig">Figure 1</a>. (<b>a</b>) RNG−SWF; (<b>b</b>) RNG−EWT; (<b>c</b>) RKE−SWF; (<b>d</b>) RKE−EWT; (<b>e</b>) SST; (<b>f</b>) BSL.</p>
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<p>Contours of turbulent kinetic energy in the mid-span plane (<span class="html-italic">z</span> = 0.3 mm) of unit 5. (<b>a</b>) RNG−SWF; (<b>b</b>) RNG−EWT; (<b>c</b>) RKE−SWF; (<b>d</b>) RKE−EWT; (<b>e</b>) SST; (<b>f</b>) BSL.</p>
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<p>Contours of turbulent kinetic energy in the half-span plane (<span class="html-italic">yoz</span>) through L0. (<b>a</b>) RNG−SWF and RNG−EWT; (<b>b</b>) RKE−SWF and RKE−EWT; (<b>c</b>) SST and BSL.</p>
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<p>Profiles of turbulent kinetic energy and turbulent viscosity along L0 in unit 5. (<b>a</b>) Turbulent kinetic energy; (<b>b</b>) turbulent viscosity.</p>
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<p>Turbulence intensity (<span class="html-italic">TI</span>) distribution in the mid-span plane of unit 5. (<b>a</b>) RNG−SWF; (<b>b</b>) RNG−EWT; (<b>c</b>) RKE−SWF; (<b>d</b>) RKE−EWT; (<b>e</b>) SST; (<b>f</b>) BSL.</p>
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<p>Contours of wall shear stresses. (<b>a</b>) RNG−SWF; (<b>b</b>) RNG−EWT; (<b>c</b>) RKE−SWF; (<b>d</b>) RKE−EWT; (<b>e</b>) SST; (<b>f</b>) BSL.</p>
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<p>Profiles of wall shear stresses along the boundary ABCDE in the mid-span plane of unit 5. (<b>a</b>) AB; (<b>b</b>) BC; (<b>c</b>) CD; (<b>d</b>) DE. Where <span class="html-italic">L<sub>AB</sub></span>, <span class="html-italic">L<sub>BC</sub></span>, <span class="html-italic">L<sub>CD</sub></span>, and <span class="html-italic">L<sub>DE</sub></span> denote the length of the boundary segments, and <span class="html-italic">s</span> denotes the length from the start point of the boundary segment.</p>
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17 pages, 1923 KiB  
Article
Characterization and Prediction of the Ghana Stock Exchange Composite Index Utilizing Bayesian Stochastic Volatility Models
by Osei K. Tweneboah, Kwesi A. Ohene-Obeng and Maria C. Mariani
Risks 2025, 13(1), 3; https://doi.org/10.3390/risks13010003 - 30 Dec 2024
Viewed by 813
Abstract
This study delves into the dynamics of the Ghana Stock Exchange Composite Index (GSE-CI) over the period from 2011 to 2022, a symbolic emerging market index that presents unique challenges and opportunities for financial analysis. We characterize the GSE-CI using advanced analytical tools [...] Read more.
This study delves into the dynamics of the Ghana Stock Exchange Composite Index (GSE-CI) over the period from 2011 to 2022, a symbolic emerging market index that presents unique challenges and opportunities for financial analysis. We characterize the GSE-CI using advanced analytical tools such as the Hurst exponent and R/S analysis to uncover its fractal properties and complex dynamics. The paper then advances to predictive modeling, employing an innovative approach with four variations of Stochastic Volatility (SV) models: SV with linear regressors, SV with Student’s t errors, SV with leverage effects, and a hybrid model combining Student’s t errors with leverage. Each model offers a unique perspective on forecasting the behavior of the GSE-CI, with the SV model incorporating Student’s t errors emerging as the most effective, as evidenced by the lowest Root Mean Square Error (RMSE) in our comparative evaluation. The integration of these models highlights their robustness in capturing the intricate volatility patterns of the GSE-CI, making a compelling case for their applicability to similar financial markets in other emerging economies. This research also paves the way for future investigations into other market indices and assets within and beyond the borders of emerging markets. Full article
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<p>Histogram of the daily returns of the GSE-CI time series.</p>
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<p>Daily GSE-CI time series plot.</p>
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<p>Daily returns of the GSE-CI time series plot.</p>
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<p>Estimation of the SV model with linear regressors.</p>
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<p>Estimation of the SV model with Student’s <span class="html-italic">t</span> errors.</p>
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<p>Estimation of the SV model with leverage.</p>
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<p>Estimation of the SV model with Student’s <span class="html-italic">t</span> errors and leverage.</p>
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<p>Predictive distributions and observed values for the SV model with linear regressors.</p>
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<p>Predictive distributions and observed values for the SV model with Student’s <span class="html-italic">t</span> errors.</p>
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<p>Predictive distributions and observed values for the SV model with leverage.</p>
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<p>Predictive distributions and observed values for the SV model with Student’s <span class="html-italic">t</span> errors and leverage.</p>
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26 pages, 7047 KiB  
Article
A Fractal Analysis of the Size Effect in Quasi-Brittle Materials: Experimental Tests and Peridynamic Simulations
by Leandro Ferreira Friedrich, Luis Eduardo Kosteski, Édiblu Silva Cezar, Angélica Bordin Colpo, Caroline Bremm, Giuseppe Lacidogna and Ignacio Iturrioz
Mathematics 2025, 13(1), 94; https://doi.org/10.3390/math13010094 - 29 Dec 2024
Viewed by 645
Abstract
In the design of structures involving quasi-brittle materials such as concrete, it is essential to consider the scale dependence of the mechanical properties of the material. Among the theories used to describe the phenomenon of size effect, the fractal theory proposed by Carpinteri [...] Read more.
In the design of structures involving quasi-brittle materials such as concrete, it is essential to consider the scale dependence of the mechanical properties of the material. Among the theories used to describe the phenomenon of size effect, the fractal theory proposed by Carpinteri and colleagues has attracted attention for its results in the last three decades of research. The present study employs the fractal perspective to examine the scale effect in three-point bending tests conducted on expanded polyethylene (EPS) beam specimens. The influence of size on flexural strength, fracture energy, and critical angle of rotation is investigated. Additionally, numerical simulations based on peridynamic (PD) theory are performed based on the experimental tests. The global behavior, brittleness, failure configuration, and fractal scale effect obtained numerically are evaluated. The numerical results show a good correlation with the experimental ones and, moreover, both the experimental and numerical results are in agreement with the fractal theory of scale effect. More precisely, the error of the sum of the fractal exponents, computed with respect to the theoretical one, is equal to −1.20% and −2.10% for the experimental and numerical results, respectively. Moreover, the classical dimensional analysis has been employed to demonstrate that the scale effect can be naturally described by the PD model parameters, allowing to extend the results for scales beyond those analyzed experimentally. Full article
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<p>(<b>a</b>) Reference configuration and deformed configuration according to PD theory, (<b>b</b>) Prototype Microelastic Brittle (PMB) model.</p>
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<p>Bilinear bond force–stretch relationship used to model the quasi-brittle material behavior.</p>
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<p>Schematic representation of the physical meaning of the horizon (<math display="inline"><semantics> <mrow> <msup> <mi>δ</mi> <mo>′</mo> </msup> </mrow> </semantics></math>) in the PD approach for quasi-brittle materials.</p>
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<p>(<b>a</b>) Test setup and beams dimensions, (<b>b</b>) relative size of EPS specimens.</p>
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<p>3D PD model discretization and boundary conditions for the <span class="html-italic">L</span> size.</p>
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<p>Experimental (solid lines) and numerical results (dotted lines) in terms of flexural stress-strain curves for: (<b>a</b>) small, (<b>b</b>) medium, and (<b>c</b>) large specimens.</p>
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<p>Numerical load–deflection curves in order to show the ductile-to-brittle transition behavior based on the stress brittleness number.</p>
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<p>Kinetic, elastic, and damaged energies normalized with respect to the maximum elastic energy against the normalized time for: (<b>a</b>) L, (<b>b</b>) M, and (<b>c</b>) S sizes.</p>
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<p>Final fracture configuration for the <span class="html-italic">L</span> beam size: (<b>a</b>) experimental and (<b>b</b>) numerical.</p>
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<p>Fracture surface of the experimental samples S, M, and L, together with details of the intergranular failure mechanism (indicated by the red arrows).</p>
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<p>Bending strength vs. beam size diagram (<span class="html-italic">r</span> is Pearson correlation coefficient).</p>
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<p>Load versus deflection to provide dissipated energy (<span class="html-italic">W</span>).</p>
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<p>Fracture energy vs. beam size diagram (<span class="html-italic">r</span> is Pearson correlation coefficient).</p>
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<p>Parameters involved in critical rotation angle.</p>
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<p>Critical rotation vs. beam size diagram (<span class="html-italic">r</span> is Pearson correlation coefficient).</p>
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<p>Scaling laws derived from dimensional analysis of BPD model parameters. (<b>a</b>) Tensile strength and critical strain and (<b>b</b>) fracture energy. (<b>c</b>) Schematic representation of fracture energy scaling law. In (<b>b</b>,<b>c</b>) the numbers 1 to 3 indicate the characteristic dimension, <span class="html-italic">b</span>, of scaled similar structures.</p>
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23 pages, 424 KiB  
Article
Joint Communication and Channel Discrimination
by Han Wu and Hamdi Joudeh
Entropy 2024, 26(12), 1089; https://doi.org/10.3390/e26121089 - 13 Dec 2024
Cited by 2 | Viewed by 805
Abstract
We consider a basic joint communication and sensing setup comprising a transmitter, a receiver and a sensor. The transmitter sends a codeword to the receiver through a discrete memoryless channel, and the receiver is interested in decoding the transmitted codeword. At the same [...] Read more.
We consider a basic joint communication and sensing setup comprising a transmitter, a receiver and a sensor. The transmitter sends a codeword to the receiver through a discrete memoryless channel, and the receiver is interested in decoding the transmitted codeword. At the same time, the sensor picks up a noisy version of the transmitted codeword through one of two possible discrete memoryless channels. The sensor knows the codeword and wishes to discriminate between the two possible channels, i.e., to identify the channel that has generated the output given the input. We study the trade-off between communication and sensing in the asymptotic regime, captured in terms of the channel coding rate against the two types of discrimination error exponents. We characterize the optimal trade-off between the rate and the exponents for general discrete memoryless channels with an input cost constraint. Full article
(This article belongs to the Special Issue Integrated Sensing and Communications)
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<p>Illustration of the considered setting. A precise definition of all blocks is given in <a href="#sec2-entropy-26-01089" class="html-sec">Section 2</a>.</p>
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20 pages, 578 KiB  
Article
Testing the Isotropic Cauchy Hypothesis
by Jihad Fahs, Ibrahim Abou-Faycal and Ibrahim Issa
Entropy 2024, 26(12), 1084; https://doi.org/10.3390/e26121084 - 11 Dec 2024
Cited by 1 | Viewed by 694
Abstract
The isotropic Cauchy distribution is a member of the central α-stable family that plays a role in the set of heavy-tailed distributions similar to that of the Gaussian density among finite second-moment laws. Given a sequence of n observations, we are interested [...] Read more.
The isotropic Cauchy distribution is a member of the central α-stable family that plays a role in the set of heavy-tailed distributions similar to that of the Gaussian density among finite second-moment laws. Given a sequence of n observations, we are interested in characterizing the performance of Likelihood Ratio Tests, where two hypotheses are plausible for the observed quantities: either isotropic Cauchy or isotropic Gaussian. Under various setups, we show that the probability of error of such detectors is not always exponentially decaying with n, with the leading term in the exponent shown to be logarithmic instead, and we determine the constants in that leading term. Perhaps surprisingly, the optimal Bayesian probabilities of error are found to exhibit different asymptotic behaviors. Full article
(This article belongs to the Section Information Theory, Probability and Statistics)
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<p><math display="inline"><semantics> <mrow> <mo>ℓ</mo> <mo>(</mo> <mi>r</mi> <mo>)</mo> </mrow> </semantics></math> for <math display="inline"><semantics> <mrow> <msup> <mi>ξ</mi> <mn>2</mn> </msup> <mo>=</mo> <mn>1</mn> </mrow> </semantics></math>, with <math display="inline"><semantics> <mrow> <mi>n</mi> <mo>=</mo> <mn>5</mn> </mrow> </semantics></math> (solid blue), <math display="inline"><semantics> <mrow> <mi>n</mi> <mo>=</mo> <mn>8</mn> </mrow> </semantics></math> (dashed green), and <math display="inline"><semantics> <mrow> <mi>n</mi> <mo>=</mo> <mn>13</mn> </mrow> </semantics></math> (pointed red).</p>
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<p><math display="inline"><semantics> <msub> <mi>P</mi> <mi>e</mi> </msub> </semantics></math> vs. <span class="html-italic">n</span> for <math display="inline"><semantics> <mrow> <mi>η</mi> <mo>=</mo> <mn>0.5</mn> <mo>,</mo> <mn>1</mn> <mo>,</mo> <mn>1.5</mn> </mrow> </semantics></math>. Solid line: numerical computations. Dashed line: approximate expression.</p>
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<p><math display="inline"><semantics> <msub> <mi>P</mi> <mrow> <mi mathvariant="normal">G</mi> <mo>|</mo> <mi mathvariant="normal">C</mi> </mrow> </msub> </semantics></math> vs. n for <math display="inline"><semantics> <mrow> <msub> <mi>P</mi> <mrow> <mi mathvariant="normal">C</mi> <mo>|</mo> <mi mathvariant="normal">G</mi> </mrow> </msub> <mo>=</mo> <mn>0.01</mn> <mo>,</mo> <mn>0.05</mn> <mo>,</mo> <mn>0.09</mn> </mrow> </semantics></math>. Solid line: numerical computations. Dashed line: approximate expression.</p>
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<p><math display="inline"><semantics> <mrow> <mo>−</mo> <mo form="prefix">ln</mo> <msub> <mi>P</mi> <mrow> <mi mathvariant="normal">C</mi> <mo>|</mo> <mi mathvariant="normal">G</mi> </mrow> </msub> </mrow> </semantics></math> vs. n for <math display="inline"><semantics> <mrow> <msub> <mi>P</mi> <mrow> <mi mathvariant="normal">G</mi> <mo>|</mo> <mi mathvariant="normal">C</mi> </mrow> </msub> <mo>=</mo> <mn>0.07</mn> <mo>,</mo> <mn>0.14</mn> </mrow> </semantics></math>.</p>
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20 pages, 4974 KiB  
Article
An Analysis of WiFi Coverage Modeling for a Hotspot in the Parish of Checa Employing Deterministic and Empirical Propagation Models
by Iván Sánchez, Fabricio Vallejo, Pablo Palacios Játiva and Ali Dehghan Firoozabadi
Appl. Sci. 2024, 14(23), 11120; https://doi.org/10.3390/app142311120 - 28 Nov 2024
Viewed by 830
Abstract
This study presents the analysis and comparison of Wi-Fi coverage modeling for a hotspot using deterministic and empirical propagation models developed by researchers from the Universidad de Las Américas in Quito, Ecuador. Signal intensity measurements were taken from both the hotspot and the [...] Read more.
This study presents the analysis and comparison of Wi-Fi coverage modeling for a hotspot using deterministic and empirical propagation models developed by researchers from the Universidad de Las Américas in Quito, Ecuador. Signal intensity measurements were taken from both the hotspot and the repeater at various locations within the Checa parish using a Raspberry Pi and a Global Positioning System (GPS). To assess the accuracy of the models, heat maps were generated using Matlab (R2023A). The results showed that the adjusted model, comparing the received signal levels of the hotspot with the Stanford University Interim Propagation Model (SUI), exhibited a significant error margin, especially at distances below 60 m. However, starting at −70 dBm and beyond 60 m, the sampled data aligned better with the adjusted model. The discrepancy in the heatmaps was explained by the hotspot’s higher transmission power compared to the Wi-Fi repeater. Furthermore, the reception levels of the hotspot were low near the transmitter, which led to new measurements being taken with the Wi-Fi repeater (Raspberry Pi 3). With the new measurements, the adjusted model using logarithmic regression showed a better fit, particularly in the range from −40 dBm to −98 dBm, with a path loss exponent of 8.96. This demonstrated a significant improvement in prediction accuracy, particularly at short distances. The results emphasize the importance of using tools such as Matlab and reference models to optimize network planning, providing the Universidad de Las Américas with a valuable tool to generate heat maps in areas with characteristics similar to those of Checa in the context of their community outreach programs. This approach could be crucial for future research and optimization of community Wi-Fi networks in similar environments. Full article
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<p>Flowchart for adjusting a radio frequency signal propagation model.</p>
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<p>Photograph of Checa’s central park, showing the location of the repeater at the top, and the location of the hotspot at the bottom.</p>
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<p>Radiation pattern lobes to 2.4 GHz and 5 GHz.</p>
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<p>Received power vs distance according to the SUI mode. Parameters: receiver height <math display="inline"><semantics> <msub> <mi>h</mi> <mi>m</mi> </msub> </semantics></math> = 1.7 m, frequency <span class="html-italic">f</span> = 2.412 GHz, and Category C suburban areas [Equation (<a href="#FD6-applsci-14-11120" class="html-disp-formula">6</a>)].</p>
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<p>Empirical samples obtained by the Raspberry Pi 3 of hotspot power levels vs distance in meters. Parameters: 560 samples of the reception level power.</p>
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<p>Received Power levels vs distance using Equation (<a href="#FD6-applsci-14-11120" class="html-disp-formula">6</a>) of SUI model.</p>
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<p>Comparison between received power levels of the hotspot based on the SUI model [Equtation (<a href="#FD6-applsci-14-11120" class="html-disp-formula">6</a>)], the empirical data collected in the field, and the adjusted model [Equation (<a href="#FD8-applsci-14-11120" class="html-disp-formula">8</a>)] vs. distance.</p>
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<p>Received power levels vs distance using Equation (<a href="#FD8-applsci-14-11120" class="html-disp-formula">8</a>) the fitted model, at the site where the hotspot is installed.</p>
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<p>Received power levels vs distance using Equation (<a href="#FD8-applsci-14-11120" class="html-disp-formula">8</a>) the fitted model, at the site where the WiFi signal repeater is installed.</p>
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<p>Location map of the 560 empirical samples obtained the received power levels by Raspberry Pi 3 and GPS from the repeater the señal WiFi.</p>
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<p>Heatmap of the 560 empirical samples of the received power levels by Raspberry Pi 3 and GPS from the repeater of the signal WiFi.</p>
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<p>Model fitting graph based on the linear regression method [Equation (<a href="#FD13-applsci-14-11120" class="html-disp-formula">13</a>)].</p>
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<p>Model fitting graph based on the generation of a probabilistic logarithmic function [Equation (<a href="#FD14-applsci-14-11120" class="html-disp-formula">14</a>)].</p>
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<p>Comparison between received power levels of repeater WiFi based on the empirical data collected in the field, adjusted linear model [Equation (<a href="#FD13-applsci-14-11120" class="html-disp-formula">13</a>)], and the adjusted logarithmic model [Equation (<a href="#FD14-applsci-14-11120" class="html-disp-formula">14</a>)] vs distance at which WiFi signal repeater is installed.</p>
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<p>Model fitting graph based on the logarithmic regression method. Parameters: base height <span class="html-italic">h<sub>b</sub></span> = 5 m, receiver height <span class="html-italic">h<sub>m</sub></span> = 1.7 m, frequency <span class="html-italic">f</span> = 2.412 GHz, and suburban areas Category C.</p>
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21 pages, 3387 KiB  
Article
How Gait Nonlinearities in Individuals Without Known Pathology Describe Metabolic Cost During Walking Using Artificial Neural Network and Multiple Linear Regression
by Arash Mohammadzadeh Gonabadi, Farahnaz Fallahtafti and Judith M. Burnfield
Appl. Sci. 2024, 14(23), 11026; https://doi.org/10.3390/app142311026 - 27 Nov 2024
Viewed by 801
Abstract
This study uses Artificial Neural Networks (ANNs) and multiple linear regression (MLR) models to explore the relationship between gait dynamics and the metabolic cost. Six nonlinear metrics—Lyapunov Exponents based on Rosenstein’s algorithm (LyER), Detrended Fluctuation Analysis (DFA), the Approximate Entropy (ApEn), the correlation [...] Read more.
This study uses Artificial Neural Networks (ANNs) and multiple linear regression (MLR) models to explore the relationship between gait dynamics and the metabolic cost. Six nonlinear metrics—Lyapunov Exponents based on Rosenstein’s algorithm (LyER), Detrended Fluctuation Analysis (DFA), the Approximate Entropy (ApEn), the correlation dimension (CD), the Sample Entropy (SpEn), and Lyapunov Exponents based on Wolf’s algorithm (LyEW)—were utilized to predict the metabolic cost during walking. Time series data from 10 subjects walking under 13 conditions, with and without hip exoskeletons, were analyzed. Six ANN models, each corresponding to a nonlinear metric, were trained using the Levenberg–Marquardt backpropagation algorithm and compared with MLR models. Performance was assessed based on the mean squared error (MSE) and correlation coefficients. ANN models outperformed MLR, with DFA and Lyapunov Exponent models showing higher R2 values, indicating stronger predictive accuracy. The results suggest that gait’s nonlinear characteristics significantly impact the metabolic cost, and ANNs are more effective for analyzing these dynamics than MLR models. The study emphasizes the potential of focusing on specific nonlinear gait variables to enhance assistive device optimization, particularly for hip exoskeletons. These findings support the development of personalized interventions that improve walking efficiency and reduce metabolic demands, offering insights into the design of advanced assistive technologies. Full article
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<p>Flow diagram of the research development process for predicting the metabolic cost using multiple linear regression (MLR) and Artificial Neural Network (ANN) models, based on six gait nonlinearity measures: the Lyapunov Exponent based on Rosenstein’s algorithm (LyER), Detrended Fluctuation Analysis (DFA), the Approximate Entropy (ApEn), the correlation dimension (CD), the Sample Entropy (SpEn), and the Lyapunov Exponent based on Wolf’s algorithm (LyEW). The diagram outlines the sequential steps, from data collection and preparation through model design, cross-validation, and evaluation, and a comparative analysis of ANN and MLR models. Each variable represents specific gait parameters, including joint angles, velocities, moments, ground reaction forces (GRFs), and center of mass (COM) metrics. Key nonlinear measures for accurate metabolic cost prediction are emphasized, along with conclusions on the strengths and limitations of each model.</p>
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<p>Partial Dependence Plots (PDPs), the graphical analysis of gait nonlinearity measures, and their prediction errors. This figure illustrates the relationship between various gait parameters—such as joint angles, velocities, moments, center of mass (COM) displacement in the sagittal plane, and ground reaction force (GRF) magnitudes in vertical and anterior–posterior directions—and their influence on the prediction of the metabolic cost. Subfigures represent the mean of nonlinearity measures, (<b>A</b>) the Lyapunov Exponent based on Rosenstein’s algorithm (LyE<sub>R</sub>), (<b>B</b>) Detrended Fluctuation Analysis (DFA), (<b>C</b>) the Approximate Entropy (ApEn), (<b>D</b>) the correlation dimension (CD), (<b>E</b>) the Sample Entropy (SpEn), and (<b>F</b>) the Lyapunov Exponent based on Wolf’s algorithm (LyE<sub>w</sub>), respectively. Blue bars (left vertical axis) indicate the measure values, while red bars (right vertical axis) show the corresponding prediction error of energy expenditure percentages, highlighting the impact of each gait parameter on the precision of metabolic cost estimation.</p>
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20 pages, 2094 KiB  
Article
Fractional Calculus Applied to the Generalized Model and Control of an Electrohydraulic System
by Edgar Hiram Robles, Felipe J. Torres, Antonio J. Balvantín-García, Israel Martínez-Ramírez, Gustavo Capilla and Juan-Pablo Ramírez-Paredes
Fractal Fract. 2024, 8(12), 679; https://doi.org/10.3390/fractalfract8120679 - 21 Nov 2024
Viewed by 787
Abstract
In this paper, fractional calculus is used to develop a generalized fractional dynamic model of an electrohydraulic system composed of a servo valve and a hydraulic cylinder, where a fractional position controller PIγDμ is proposed for minimizing the performance [...] Read more.
In this paper, fractional calculus is used to develop a generalized fractional dynamic model of an electrohydraulic system composed of a servo valve and a hydraulic cylinder, where a fractional position controller PIγDμ is proposed for minimizing the performance index according to the integral of the time-weighted absolute error (ITAE). First, the general mathematical equations of the cylinder and servo valve are used to obtain the transfer functions in fractional order by applying Caputo’s definition and a Laplace transform. Then, through a block diagram of the closed-loop system without a controller, the fractional model is validated by comparing its performance concerning the integer-order electrohydraulic system model reported in the literature. Subsequently, a fractional PID controller is designed to control the cylinder position. This controller is included in the closed-loop system to determine the fractional exponents of the transfer functions of the servo valve, cylinder, and control, as well as to tune the controller gains, by using the ITAE objective function, with a comparison of the following: (1) the electrohydraulic system model in integer order and the controller in fractional order; (2) the electrohydraulic system model in fractional order and the controller in integer order; and (3) both the system model and the controller in fractional order. For each of the above alternatives, numerical simulations were carried out using MATLAB®/Simulink® R2023b and adding white noise as a perturbation. The results show that strategy (3), where electrohydraulic system and controller model are given in fractional order, develops the best performance because it generates the minimum value of ITAE. Full article
(This article belongs to the Special Issue Fractional-Order Approaches in Automation: Models and Algorithms)
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<p>The electrohydraulic system.</p>
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<p>Closed-loop fractional system.</p>
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<p>Fractional block in MATLAB<sup>®</sup>/Simulink<sup>®</sup>.</p>
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<p>Comparison of the system simulation results under step signal input in fractional and integer order.</p>
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<p>Experimental test bench of the electrohydraulic system.</p>
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<p>Output response of the electrohydraulic system.</p>
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<p>Fractal spectrum of the electrohydraulic system.</p>
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<p>Experimental data of a flow rate measurement.</p>
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<p>Simulation results of the system without noise under (<b>a</b>) step signal input, (<b>b</b>) sinusoidal signal input. Area of interest for the results under (<b>c</b>) step input, (<b>d</b>) sinusoidal signal input.</p>
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<p>Simulation results of the integer-order system model with a fractional-order controller under (<b>a</b>) step signal input, (<b>b</b>) sinusoidal signal input. Area of interest for the results under (<b>c</b>) step input, (<b>d</b>) sinusoidal signal input.</p>
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<p>Simulation results of the fractional-order system model with the integer-order controller under (<b>a</b>) step signal input, (<b>b</b>) sinusoidal signal input. Area of interest for the results under (<b>c</b>) step input; (<b>d</b>) sinusoidal signal input.</p>
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<p>Simulation results of the fractional-order system model and controller under (<b>a</b>) step signal input, (<b>b</b>) sinusoidal signal input. Area of interest for the results under (<b>c</b>) step input, (<b>d</b>) sinusoidal signal input.</p>
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<p>Simulation results of the fractional-order system model and controller with a signal of 0.002 power under (<b>a</b>) step signal input, (<b>b</b>) sinusoidal signal input. Area of interest for the results under (<b>c</b>) step input, (<b>d</b>) sinusoidal signal input.</p>
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27 pages, 11457 KiB  
Article
From Polar Day to Polar Night: A Comprehensive Sun and Star Photometer Study of Trends in Arctic Aerosol Properties in Ny-Ålesund, Svalbard
by Sandra Graßl, Christoph Ritter, Jonas Wilsch, Richard Herrmann, Lionel Doppler and Roberto Román
Remote Sens. 2024, 16(19), 3725; https://doi.org/10.3390/rs16193725 - 7 Oct 2024
Viewed by 1655
Abstract
The climate impact of Arctic aerosols, like the Arctic Haze, and their origin are not fully understood. Therefore, long-term aerosol observations in the Arctic are performed. In this study, we present a homogenised data set from a sun and star photometer operated in [...] Read more.
The climate impact of Arctic aerosols, like the Arctic Haze, and their origin are not fully understood. Therefore, long-term aerosol observations in the Arctic are performed. In this study, we present a homogenised data set from a sun and star photometer operated in the European Arctic, in Ny-Ålesund, Svalbard, of the 20 years from 2004–2023. Due to polar day and polar night, it is crucial to use observations of both instruments. Their data is evaluated in the same way and follows the cloud-screening procedure of AERONET. Additionally, an improved method for the calibration of the star photometer is presented. We found out, that autumn and winter are generally more polluted and have larger particles than summer. While the monthly median Aerosol Optical Depth (AOD) decreases in spring, the AOD increases significantly in autumn. A clear signal of large particles during the Arctic Haze can not be distinguished from large aerosols in winter. With autocorrelation analysis, we found that AOD events usually occur with a duration of several hours. We also compared AOD events with large-scale processes, like large-scale oscillation patterns, sea ice, weather conditions, or wildfires in the Northern Hemisphere but did not find one single cause that clearly determines the Arctic AOD. Therefore the observed optical depth is a superposition of different aerosol sources. Full article
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<p>Different relevant processes during polar day (<b>a</b>) and polar night (<b>b</b>). The numbers indicate (1) sea spray formation; (2a–b and 8) (non-)marine secondary aerosol formation; (3) particle processing in fog; (4) Arctic Ice Nucleation Particles (INP) concentrations; (5 and 7) Long-range transport; (6, 10 and 11) cloud formation; (9) blowing snow. Figure is adapted from Schmale et al. [<a href="#B14-remotesensing-16-03725" class="html-bibr">14</a>].</p>
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<p>Map of Ny-Ålesund on Svalbard in the European Arctic (source: Svalbardkartet (<a href="https://geokart.npolar.no/Html5Viewer/index.html?viewer=Svalbardkartet" target="_blank">https://geokart.npolar.no/Html5Viewer/index.html?viewer=Svalbardkartet</a>, accessed on 2 October 2024)); courtesy of Norwegian Polar Institute.</p>
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<p>Relative availability of cloud-screened measurements <math display="inline"><semantics> <mrow> <mo>[</mo> <mo>%</mo> <mo>]</mo> </mrow> </semantics></math> over the course of a year separated between sun and star photometer.</p>
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<p>Overview of combined photometer data. Every point is a daily median AOD.</p>
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<p>The monthly median values for the AOD is shown for each year of 2004–2023 in grey. The blue lines indicate the median (solid) and mean (dashed) of these values.</p>
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<p>Box-and-whisker plots for AOD for every month measured by sun and star photometer. All individual data points after cloud-screening are taken into account. As a reference for the amount of data per month and year, see <a href="#remotesensing-16-03725-t001" class="html-table">Table 1</a>. 25th and 75th percentile are shown by the blue boxes, whiskers indicated 9th and 91th percentile, median is shown by <span style="color: #FF0000">−</span> and mean by <span style="color: #FF0000">+</span>.</p>
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<p>Deviation from monthly mean AOD values in dependency of the year.</p>
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<p>One exemplary day with PSC (9 February 2020), measured by the Raman Lidar KARL in Ny-Ålesund. The PSC is clearly visible in about 20 km altitude throughout the entire day.</p>
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<p>Daily median of Ångström Exponent for sun and star photometer.</p>
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<p>Density plot of AOD and Ångström Exponent (<math display="inline"><semantics> <mrow> <mi>A</mi> <mi>E</mi> </mrow> </semantics></math>) for Sun (<b>left</b>) and star photometer (<b>right</b>) for all individual measurements from 2004 to 2023.</p>
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<p>Monthly median values of the Ångström Exponent is shown in grey for all of the years 2004 to 2023. The median (solid) and mean (dashed) of these annual cycle is given in orange.</p>
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<p>Box-and-whisker plots for Ångström Exponent for every month measured by sun and star photometer. All individual data points after cloud screening are taken into account. As a reference for the amount of data per month and year, see <a href="#remotesensing-16-03725-t001" class="html-table">Table 1</a>. The 25th and 75th percentile are shown by the blue boxes, whiskers indicate the 9th and 91st percentile, and the median is shown by <span style="color: #FF0000">−</span> and mean by <span style="color: #FF0000">+</span>.</p>
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<p>Deviation from monthly <math display="inline"><semantics> <mrow> <mi>A</mi> <mi>E</mi> </mrow> </semantics></math> mean values to long-term median <math display="inline"><semantics> <mrow> <mi>A</mi> <mi>E</mi> </mrow> </semantics></math> values.</p>
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<p>Autocorrelations for each month across the 20-year period (shown in grey) are displayed. The green line represents the median autocorrelation function derived from all individual monthly autocorrelations. Vertical lines indicate key time intervals at 1 h and 1 day. Additionally, black diamonds highlight the vertexes within the data.</p>
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<p>Monthly median AOD values are given in blue. With a multiple linear regression this AOD is reconstructed by using the above-mentioned parameter coefficients.</p>
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18 pages, 5813 KiB  
Article
Micromechanical Characterization of AlCu Films for MEMS Using Instrumented Indentation Method
by Dongyang Hou, Yuhang Ouyang, Zhen Zhou, Fang Dong and Sheng Liu
Materials 2024, 17(19), 4891; https://doi.org/10.3390/ma17194891 - 5 Oct 2024
Viewed by 3113
Abstract
The micromechanical properties (i.e., hardness, elastic modulus, and stress–strain curve) of AlCu films were determined by an instrumented indentation test in this work. For three AlCu films with different thicknesses (i.e., 1 µm, 1.5 µm, and 2 µm), the same critical ratio ( [...] Read more.
The micromechanical properties (i.e., hardness, elastic modulus, and stress–strain curve) of AlCu films were determined by an instrumented indentation test in this work. For three AlCu films with different thicknesses (i.e., 1 µm, 1.5 µm, and 2 µm), the same critical ratio (hmax/t) of 0.15 and relative indentation depth range of 0.15–0.5 existed, within which the elastic modulus (i.e., 59 GPa) and nanoindentation hardness (i.e., 0.75 GPa, 0.64 GPa and 0.63 GPa for 1 µm, 1.5 µm and 2 µm films) without pile-up and substrate influence can be determined. The yield strength (i.e., 0.754 GPa, 0.549 GPa and 0.471 GPa for 1 µm, 1.5 µm and 2 µm films) and hardening exponent (i.e., 0.073, 0.131 and 0.150 for 1 µm, 1.5 µm and 2 µm films) of Al-(4 wt.%)Cu films for MEMS were successfully reported for the first time using a nanoindentation reverse method. In dimensional analysis, the ideal representative strain εr was determined to be 0.038. The errors of residual depth hr between the simulations and the nanoindentation experiments was less than 5% when the stress–strain curve obtained by the nanoindentation reverse method was used for simulation. Full article
(This article belongs to the Special Issue Advances of Indentation Technology in Materials)
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Figure 1

Figure 1
<p>Schematic illustration of the geometry and mesh of 2D axisymmetric model used for nanoindentation simulations: (<b>a</b>) global view and (<b>b</b>) local view.</p>
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<p>Flow chart of the proposed reverse analysis method.</p>
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<p>The microstructural characterization of AlCu films with different thicknesses: SEM images of the cross-section for (<b>a</b>) 1 µm, (<b>b</b>) 1.5 µm and (<b>c</b>) 2 µm films; AFM images of surface topography for (<b>d</b>) 1 µm, (<b>e</b>) 1.5 µm and (<b>f</b>) 2 µm films; the roughness profile of surface topography for (<b>g</b>) 1 µm, (<b>h</b>) 1.5 µm and (<b>i</b>) 2 µm films; and (<b>j</b>) EDS spectra.</p>
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<p>Variation in <span class="html-italic">H</span><sub>IT</sub> and <span class="html-italic">E</span><sub>IT</sub> of Si (111) substrate with <span class="html-italic">h</span><sub>max</sub>.</p>
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<p>Variations in (<b>a</b>) <math display="inline"><semantics> <msubsup> <mi>E</mi> <mrow> <mi>IT</mi> </mrow> <mrow> <mi>OP</mi> </mrow> </msubsup> </semantics></math> and (<b>b</b>) <math display="inline"><semantics> <msubsup> <mi>H</mi> <mrow> <mi>I</mi> <mi>T</mi> </mrow> <mrow> <mi>O</mi> <mi>P</mi> </mrow> </msubsup> </semantics></math> obtained by the OP method with <span class="html-italic">h</span><sub>max</sub>/<span class="html-italic">t</span>.</p>
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<p>Optical images of residual imprints of AlCu films with different thicknesses under applied load of 50 mN: (<b>a</b>) 1 µm, (<b>b</b>) 1.5 µm, and (<b>c</b>) 2 µm; (<b>d</b>) schematic illustration for calculating the projected area considering pile-up.</p>
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<p>Variations in (<b>a</b>) <math display="inline"><semantics> <msubsup> <mi>E</mi> <mrow> <mi>IT</mi> </mrow> <mrow> <mi>CA</mi> </mrow> </msubsup> </semantics></math> and (<b>b</b>) <math display="inline"><semantics> <msubsup> <mi>H</mi> <mrow> <mi>IT</mi> </mrow> <mrow> <mi>CA</mi> </mrow> </msubsup> </semantics></math> obtained by the CACA method with <span class="html-italic">h</span><sub>max</sub>/<span class="html-italic">t</span>.</p>
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<p>(<b>a</b>) Variations in <span class="html-italic">C</span> with <span class="html-italic">h</span><sub>max</sub>/<span class="html-italic">t</span>; <span class="html-italic">F</span>-<span class="html-italic">h</span> curves of AlCu films with different thicknesses under different <span class="html-italic">F</span><sub>max</sub>: (<b>b</b>) 1 µm, (<b>c</b>) 1.5 µm, and (<b>d</b>) 2 µm.</p>
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<p>(<b>a</b>) Variations in <span class="html-italic">C</span> with <span class="html-italic">h</span><sub>max</sub>/<span class="html-italic">t</span>; <span class="html-italic">F</span>-<span class="html-italic">h</span> curves of AlCu films with different thicknesses under different <span class="html-italic">F</span><sub>max</sub>: (<b>b</b>) 1 µm, (<b>c</b>) 1.5 µm, and (<b>d</b>) 2 µm.</p>
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<p>Variation in <span class="html-italic">C</span>/<span class="html-italic">σ</span><sub>r</sub> with <span class="html-italic">E</span>*/<span class="html-italic">σ</span><sub>r</sub> for 2 µm AlCu film at different <span class="html-italic">n</span> and <span class="html-italic">ε</span><sub>r</sub>: (<b>a</b>) <span class="html-italic">ε</span><sub>r</sub> = 0.010, (<b>b</b>) <span class="html-italic">ε</span><sub>r</sub> = 0.038, and (<b>c</b>) <span class="html-italic">ε</span><sub>r</sub> = 0.290; and (<b>d</b>) the relationships between <span class="html-italic">h</span><sub>r</sub> and <span class="html-italic">h</span><sub>max</sub> for 0.15 &lt; <span class="html-italic">h</span><sub>max</sub>/<span class="html-italic">t</span> &lt; 0.5.</p>
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<p>Variation in <span class="html-italic">h</span><sub>r</sub>/<span class="html-italic">h</span><sub>max</sub> as a function of <span class="html-italic">E</span>*/<span class="html-italic">σ</span><sub>r</sub> and <span class="html-italic">n</span> for 2 µm AlCu film.</p>
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<p>The results and validation of <span class="html-italic">σ</span><sub>y</sub> obtained by the nanoindentation reverse method for Al-(4 wt.%)Cu films with different thicknesses: (<b>a</b>) stress–strain curves; (<b>b</b>) the comparison of <span class="html-italic">h</span><sub>r</sub> between simulation and experimental results; (<b>c</b>) the comparison of <span class="html-italic">σ</span><sub>y</sub> between this work and that reported by various methods in the literature: Macionczyk [<a href="#B79-materials-17-04891" class="html-bibr">79</a>], Nix [<a href="#B60-materials-17-04891" class="html-bibr">60</a>], Doerner [<a href="#B80-materials-17-04891" class="html-bibr">80</a>], Cai [<a href="#B81-materials-17-04891" class="html-bibr">81</a>], Yeo [<a href="#B5-materials-17-04891" class="html-bibr">5</a>], Stone [<a href="#B82-materials-17-04891" class="html-bibr">82</a>], Yu [<a href="#B83-materials-17-04891" class="html-bibr">83</a>], Hommel [<a href="#B84-materials-17-04891" class="html-bibr">84</a>], Balk [<a href="#B85-materials-17-04891" class="html-bibr">85</a>], Gouldstone [<a href="#B22-materials-17-04891" class="html-bibr">22</a>], Keller [<a href="#B71-materials-17-04891" class="html-bibr">71</a>], Flinn [<a href="#B72-materials-17-04891" class="html-bibr">72</a>], and Zhang [<a href="#B86-materials-17-04891" class="html-bibr">86</a>].</p>
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<p>The independence test results of FEM mesh.</p>
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15 pages, 603 KiB  
Article
Using Short Time Series of Monofractal Synthetic Fluctuations to Estimate the Foreign Exchange Rate: The Case of the US Dollar and the Chilean Peso (USD–CLP)
by Juan L. López, David Morales-Salinas and Daniel Toral-Acosta
Economies 2024, 12(10), 269; https://doi.org/10.3390/economies12100269 - 4 Oct 2024
Viewed by 983
Abstract
Short time series are fundamental in the foreign exchange market due to their ability to provide real-time information, allowing traders to react quickly to market movements, thus optimizing profits and mitigating risks. Economic transactions show a strong connection to foreign currencies, making exchange [...] Read more.
Short time series are fundamental in the foreign exchange market due to their ability to provide real-time information, allowing traders to react quickly to market movements, thus optimizing profits and mitigating risks. Economic transactions show a strong connection to foreign currencies, making exchange rate prediction challenging. In this study, the exchange rate estimation between the US dollar (USD) and the Chilean peso (CLP) for a short period, from 2 August 2021 to 31 August 2022, is modeled using the nonlinear Schrödinger equation (NLSE) and calculated with the fourth-order Runge–Kutta method, respectively. Additionally, the daily fluctuations of the current exchange rate are characterized using the Hurst exponent, H, and later used to generate short synthetic fluctuations to predict the USD–CLP exchange rate. The results show that the USD–CLP exchange rate can be estimated with an error of less than 5%, while when using short synthetic fluctuations, the exchange rate shows an error of less than 10%. Full article
(This article belongs to the Section Macroeconomics, Monetary Economics, and Financial Markets)
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Figure 1
<p>Evolution of exchange rate between the USD and the CLP. (<b>a</b>) The original record containing 283 data points from 2 August 2021 to 31 August 2022. (<b>b</b>) The logarithmic differences record of the daily exchange rate.</p>
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<p>The exchange rate between the USD and the CLP. The blue line is the actual data from 2 August 2021 to 31 August 2022, and the red line is the estimate using NLSE by RK4.</p>
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<p>Second-order fluctuations by applied of DFA on differences of the exchange rate USD–CLP in consecutive days.</p>
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<p>(<b>a</b>) Synthetic fluctuations with the Hurst exponent close to white noise <span class="html-italic">H</span> = 0.58. (<b>b</b>) The cumulative data for the synthetic fluctuations case.</p>
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<p>The exchange rate between the USD and the CLP from 2 August 2021 to 31 August 2022. (<b>a</b>) The blue line is the actual data, and the color lines are the estimated exchange rate results of each aleatory and independent realization when synthetics fluctuation is used. (<b>b</b>) The blue line is the actual data, the red line is the estimate using NLSE by RK4, and the green line is the mean value of the estimated exchange rate for the synthetics fluctuations.</p>
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