Search Results (3,060)

The inflow of saline water reduces water quality and limits its use as drinking water. The risk of seawater intrusion into groundwater along the Polish coastline was assessed using two methods. The vulnerability method (GALDIT) considered six aquifer parameters. The second method focused exclusively on the chemical parameters of groundwater: EC, seawater mixing index (SMI), rHCO₃/rCl, rNa/rCl, and the concentrations of Cl⁻ and Br. The analysis focused on monitoring results collected from points located within 5 km of the Baltic Sea coastline. Both risk assessment methods used a division into three risk classes (low, moderate, and high), but the results differed between the two approaches. A comparison of the results from both classification methods was conducted, followed by a comprehensive risk assessment integrating the outcomes of both approaches. No straightforward relationship was observed between individual threat assessment parameters and distance from the sea. However, when the overall assessment, incorporating multiple parameters, was considered, such a relationship emerged. The classes of seawater intrusion risk differ in terms of the medians and ranges of individual parameters. Ratios such as rHCO₃/rCl, rCa/rMg, and Cl/Br play a significant role in risk assessment, whereas the rNa/rCl ratio has a relatively smaller impact. Seawater intrusion risk should be assessed based on multiple parameters. The highest risk of seawater intrusion occurs within approximately 800 m of the coastline. Full article

Mineralization of groundwater for drinking purposes is a complex parameter of groundwater chemical composition. In the Shaim oil- and gas-bearing area, as in the whole West Siberian megabasin, the main target horizon for solving the issues of domestic and technical water supply is the Oligocene aquifer. It has significant groundwater reserves to cover the needs of the population and production requirements. However, it also faces a huge anthropogenic load in the form of water withdrawal and possible contamination from the surface with oil products. In Western Siberia, various deviations in the chemical composition of groundwater of the Oligocene horizon are recorded in connection with significant water withdrawal; for example, a sharp increase in chromaticity or total iron concentration, with changes in mineralization acting as a factor necessarily accompanying these deviations. Based on the data obtained in the course of monitoring for the period from 2013 to 2023, the main factors and trends of changes in the components of mineralization of the Oligocene horizon were determined. The lithological and mineralogical peculiarities of the water-bearing rocks of the horizon, the paleogeographic conditions of its formation and their relation to trends in mineralization change were studied. Water withdrawal data were processed for two cluster water withdrawal sites (50 and 5 wells, respectively). Analysis of the results showed that the increase in water withdrawal leads to an increase in infiltration from the overlying Neogene-Quaternary aquifer, which leads to the dilution of groundwater of the Oligocene horizon and a decrease in its mineralization. Here, we show that, during further monitoring, it is necessary to pay attention to the appearance of sites where significant amounts of chloride ions are fixed in the anion composition, which can potentially lead to a sharp deterioration in the quality of drinking groundwater. Full article

The Yucatan Peninsula (YP) presents heterogeneous environments in a karstic landscape that has been formed from permeable sedimentary rocks dating from the Cretaceous period. Its aquifers now face significant pressure from tourism, agriculture, soil use changes and population growth. Aquifer delimitation typically relies on environmental and socioeconomic criteria, overlooking the subterranean fauna. Stygobiotic crustaceans are highly diverse in the YP’s subterranean karstic systems, expressing adaptations to extreme environments while often also displaying the primitive morphology of evolutionary relics. With distributions restricted to specific environments, they are potential markers of water reserves. A literature review recovered records of 75 species of crustaceans from 132 subterranean systems in the YP, together with geomorphological, hydrological, hydrogeochemical and historical precipitation data. Fourteen UPGMA clusters were informative for mapping species composition, whereby the “Ring of Cenotes”, “Caribbean Cave” and “Cozumel Island” regions were delineated as consolidated aquifers. These aquifers are distinguished by abiotic factors as well: freshwater species dominate the Ring of Cenotes, while marine-affinity species characterize the Caribbean Cave and Cozumel Island aquifers. Stygobiotic crustaceans, being linked to geologically ancient water reserves and having a restricted distribution, offer a complementary tool for aquifer delimitation. Their presence suggests long-term and stable water availability. The use of these unique organisms for integrative aquifer delimitation can provide a way to improve the monitoring networks of regional aquifers. Full article

Groundwater is one of the major sources of water supply for human needs. But anthropic activities such as agriculture are causing significant volume depletion and quality deterioration, favoring microbial contamination that has a negative impact on human health. The geological characteristics of the ground can influence the transport of microorganisms, especially if made of permeable rock. Furthermore, irrigation with untreated or partially treated wastewater can represent an additional health risk due to the potential transmission of pathogens to food. The aim of our research is to provide an interdisciplinary perspective on this issue by integrating hygienic, geological, and agronomic skills. Water samplings are scheduled seasonally by four monitoring campaigns in five sampling points placed in two Southern Italy regions, Apulia (one point at the outlet and two wells near the wastewater plant at Carpignano Salentino, Lecce province, Italy) and Sicily (two wells at Scicli and Pozzallo, Ragusa province, Italy) Laboratory experiments of microorganism transport in permeable rocks will be carried out under saturated and unsaturated conditions. A mathematical model of transport through porous media will be implemented and validated with laboratory measurements. The model will be used to develop a monitoring tool to control sites in Apulia and Sicily where periodic cultural and molecular detection of pathogenic bacteria, viruses, and protozoa will also be taken. In addition, an analysis of the microbiological contamination of herbaceous crops due to the use of low-quality water will be conducted to assess the Quantitative Microbial Risk Assessment (QMRA). The project will provide methodological tools to evaluate anthropogenic pressures and their impact on environmental matrices. The results will allow these pressures to be modulated to minimize environmental and agri-food microbiological contamination and protect public health. Full article

With the consequences of climate change becoming more urgent, there has never been a more pressing need for technologies that can help to reduce the carbon dioxide (CO₂) emissions of the most polluting sectors, such as power generation, steel, cement, and the chemical industry. This review summarizes the state-of-the-art technologies for carbon capture, for instance, post-combustion, pre-combustion, oxy-fuel combustion, chemical looping, and direct air capture. Moreover, already established carbon capture technologies, such as absorption, adsorption, and membrane-based separation, and emerging technologies like calcium looping or cryogenic separation are presented. Beyond carbon capture technologies, this review also discusses how captured CO₂ can be securely stored (CCS) physically in deep saline aquifers or depleted gas and oil reservoirs, stored chemically via mineralization, or used in enhanced oil recovery. The concept of utilizing the captured CO₂ (CCU) for producing value-added products, including formic acid, methanol, urea, or methane, towards a circular carbon economy will also be shortly discussed. Real-life applications, e.g., already pilot-scale continuous methane (CH₄) production from flue gas CO₂, are shown. Actual deployment of the most crucial technologies for the future will be explored in real-life applications. This review aims to provide a compact view of the most crucial technologies that should be considered when choosing to capture, store, or convert CO₂, informing future researchers with efforts aimed at mitigating CO₂ emissions and tackling the climate crisis. Full article

Identifying preferential paths for groundwater flow is one of the basics for understanding aquifer systems. Shallow free-surface aquifers often have flow directions (locally) similar to those of their surface counterparts, especially if surface and groundwater bodies are directly connected. This work proposes a novel and simple framework to improve the identification of Preferential Groundwater Networks in free-surface aquifers. This is possible by proposing a quantile mapping procedure borrowed from stochastic hydrology, usually employed to adjust rainfall simulations (for example, achieved via climate models) upon available gauge-based data. This well-known procedure is applied to redistribute simulations of the aquifer bottom elevation for a real case study in Lombardy, Northern Italy. The result is a spatial redistribution of the elevation quantiles that leads to aquifer bottom surfaces carved with Preferential Groundwater Networks that are spatially consistent with the surface river network. This way, groundwater flow directions are redistributed to mimic their surface counterparts, but aquifer bottom elevations and slopes are far gentler as they were previously simulated from borehole data information. Furthermore, the errors in the spatial reframing of borehole data and the discrepancy of variogram structures before and after the redistribution procedure are not dramatically dissimilar. Full article

As coal seams are mined at greater depths, the threat of high water pressure from the confined aquifer in the floor that mining operations face has become increasingly prominent. Taking the Madaotou mine field in the Datong Coalfield as the research object, in the context of mining under pressure, for the main coal seams in the mining area, first of all, an improved evaluation method for the vulnerability of floor water inrush is adopted for hazard prediction. Secondly, numerical simulation is used to conduct a simulation analysis on the fault zones in high-risk areas. By using the fuzzy C-means clustering method (FCCM) to improve the classification method for the normalized indicators in the original variable-weight vulnerability evaluation, the risk zoning for water inrush from the coal seam floor is determined. Then, through the numerical simulation method, a simulation analysis is carried out on high-risk areas to simulate the disturbance changes of different mining methods on the fault zones so as to put forward reasonable mining methods. The results show that the classification of the variable-weight intervals of water inrush from the coal seam floor is more suitable to be classified by using fuzzy clustering, thus improving the prediction accuracy. Based on the time effect of the delayed water inrush of faults, different mining methods determine the duration of the disturbance on the fault zones. Therefore, by reducing the disturbance time on the fault zones, the risk of karst water inrush from the floor of the fault zones can be reduced. Through prediction evaluation and simulation analysis, the evaluation of the risk of water inrush in coal mines has been greatly improved, which is of great significance for ensuring the safe and efficient mining of mines. Full article

Foundation pit dewatering will impact the surrounding underground environment. To mitigate the adverse effects on adjacent underground structures, groundwater recharge is commonly utilized to control groundwater drawdown outside the pit. However, under a barrier effect of underground structures, the recharge effect may be different from that without the barrier effect. Meanwhile, the results of recharging different aquifers may also be different under the barrier effect. Therefore, based on an actual foundation pit project, this paper establishes a three-dimensional finite element model to investigate the impact of recharge on the surrounding environment under the barrier effect. To be specific, the recharge simulations were conducted in aquifers at different depths, and the effects on groundwater, enclosure wall deflection, and ground settlement under each recharge condition were compared and discussed. Furthermore, the optimal recharge scheme under the barrier effect was proposed. The results show the following: (1) When recharge is conducted in an aquifer that is completely cut off by underground structures, both groundwater levels rise and enclosure deflection induced by recharge are dramatic; therefore, caution should be taken when recharging under this condition to avoid an excessive response of recharge on the surrounding environment. (2) When recharge is conducted in an aquifer that is not cut off, most of the recharged water flows far away from the foundation pit, resulting in a low recharge efficiency. (3) When recharge is conducted in an aquifer with a direct hydraulic connection between the inside and outside of the foundation pit, it can significantly raise the groundwater levels of each aquifer, and effectively control the ground settlement without obviously increasing the deflection of the enclosure; engineers could benefit from this recharge scheme to achieve a better recharge effect under the barrier effect. Full article

Hydrogen is a pivotal energy carrier for achieving sustainability and stability, but safe and efficient geological underground hydrogen storage (UHS) is critical for its large-scale application. This study investigates the impacts of geochemical and biochemical reactions on UHS, addressing challenges that threaten storage efficiency and safety. Geochemical reactions in saline aquifers, particularly the generation of hydrogen sulfide (H2S), were analyzed using advanced compositional and geochemical modeling calibrated with experimental kinetic data. The results indicate that geochemical reactions have a minimal effect on hydrogen consumption. However, by year 10 of storage operations, H₂S levels could reach 12–13 ppm, necessitating desulfurization to maintain storage performance and safety. The study also examines the methanogenesis reaction, where microorganisms consume hydrogen and carbon dioxide to produce methane. Numerical simulations reveal that microbial activity under suitable conditions can reduce in situ hydrogen volume by up to 50%, presenting a critical hurdle to UHS feasibility. These findings highlight the necessity of conducting microbial analyses of reservoir brines during the screening phase to mitigate hydrogen losses. The novelty of this work lies in its comprehensive field-scale analysis of impurity-induced geochemical and microbial reactions and their implications for underground hydrogen storage. By integrating kinetic parameters derived from experimental data with advanced computational modeling, this study uncovers the mechanisms driving these reactions and highlights their impact on storage efficiency, and safety. By offering a detailed field-scale perspective, the findings provide a pivotal framework for advancing future hydrogen storage projects and ensuring their practical viability. Full article

Coastal aquifers are critical freshwater resources that face increasing threats from contamination and saltwater intrusion. Traditional approaches for characterizing these aquifers are challenged by complex dynamics, high-dimensional parameter spaces, and significant computational demands. This study presents an innovative method that combines an Auto-Regressive Convolutional Neural Network (AR-CNN) surrogate model with the Iterative Local Updating Ensemble Smoother (ILUES) for the joint inversion of contamination source parameters and hydraulic conductivity fields. The AR-CNN surrogate model, trained on synthetic data generated by the SEAWAT model, effectively approximates the complex input–output relationships of coastal aquifer systems, substantially reducing computational burden. The ILUES framework utilizes observational data to iteratively update model parameters. A case study involving a heterogeneous coastal aquifer with multipoint pollution sources demonstrates the efficacy of the proposed method. The results indicate that AR-CNN-ILUES successfully estimates pollution source strengths and characterizes the hydraulic conductivity field, although some limitations are observed in areas with sparse monitoring points and complex geological structures. Compared to the traditional SEAWAT-ILUES framework, the AR-CNN-ILUES approach reduces the total inversion time from approximately 70.4 h to 16.2 h, improving computational efficiency by about 77%. These findings highlight the potential of the AR-CNN-ILUES framework as a promising tool for efficient and accurate characterization of coastal aquifers. By enhancing computational efficiency without significantly compromising accuracy, this method offers a viable solution for the sustainable management and protection of coastal groundwater resources. Full article

Elevated concentrations of nitrate in potable water supplies have been linked to negative health outcomes such as methemoglobinemia and various cancers. Groundwater can become contaminated with nitrate from sources including onsite wastewater treatment systems (OWTSs). A groundwater well down-gradient from an OWTS serving an elementary school in Eastern North Carolina USA had 15 consecutive water samples collected over a 5-year period that exceeded the maximum contaminant level of 10 mg/L for nitrate. Corrective actions were required. A permeable reactive barrier (PRB) filled with woodchips was installed between the OWTS drainfield and the contaminated well. The concentration of nitrate in groundwater from the well steadily decreased after the PRB was installed, and a significant (p = 0.001) inverse correlation (−0.859) was observed between the mean annual nitrate concentration and years after the PRB. The nitrate concentration in groundwater from the well has been below 10 mg/L for the last 17 consecutive sampling events. The median nitrate concentration in the well was significantly lower (p = 0.007) post (6.93 mg/L) relative to pre (12.66 mg/L) PRB. The PRB has not required any maintenance over the past 10 years. The implemented PRB directly influences the sampling results from a monitoring well, but it is not necessarily confirmed that it intercepts the entire groundwater flow or fully prevents aquifer contamination. To confirm this, additional monitoring wells would need to be installed. This research has shown that PRBs can be an effective, low-maintenance, best-management practice to reduce the groundwater transport of nitrate. Full article

In this study, hydrogeochemistry and environmentally stable isotopes were employed to examine the processes involved in recharging aquifer systems and the changes in the groundwater chemistry caused by the interaction between the water and the aquifer matrix. Based on data derived from 113 groundwater wells, various tools and techniques, including stable environmental isotopes Oxygen-18 and Deuterium (δ¹⁸O and δD) for 33 samples and geochemical modeling with NETPATH, were used to evaluate the recharge mechanism and the evolution of the groundwater, combining GIS with hydrological and hydrochemical methods. The results revealed that groundwater from the Quaternary was the main source for irrigation; the water quality was categorized as relatively fresh to saline, with the total dissolved solids (TDSs) ranging from 261.3 to 8628.56 mg/L, exhibiting an average value of 2311.68 mg/L. The results of the environmental isotope analysis showed that the range of oxygen δ¹⁸O isotopes in the groundwater was from −5.65‰ to +0.39‰, while the range of hydrogen δD isotopes was from −32.60‰ to 4.73‰. Moreover, the δ¹⁸O–δD relationship indicated that the groundwater samples fell around the global meteoric precipitation line, showing a strong relationship, with a coefficient (R²) of approximately 0.82. The NETPATH model revealed that the dissolved chemical species within the groundwater system primarily originated from processes such as mineral weathering and dissolution, ion exchange, and evaporation. Full article

To investigate the excavation characteristics and mechanisms of a deep foundation under lateral confined water pressure, a model test was conducted with real-time monitoring of the stress and deformation of the foundation strut system. The results indicate that in stages 1 and 3 (the process of raising the lateral confined water level, O and F), the rise in lateral confined water levels caused the diaphragm wall to shift inward. However, the reduction in earth pressure due to the inward shift of the diaphragm wall exceeded the increase in water pressure from the raised confined water level, resulting in an overall decrease in lateral pressure on the diaphragm wall. During stage 2 (the excavation and supporting process, K1–Z4), as excavation and strut installation progressed, the lateral pressure on the diaphragm wall decreased, while both bending moment and horizontal displacement increased, with the most pronounced changes occurring when excavation reached the depth of the lateral confined aquifer. Upon reaching the soil layers within the depth of the lateral confined aquifer, the axial force of struts increased significantly, with the second level of strut experiencing the greatest axial force. In deep foundation design, it is essential to account for the maximum bending moment and horizontal displacement of the diaphragm wall within the depth range of the lateral confined aquifer, as well as the maximum vertical displacement in the range of 0.50%D–0.83%D outside the pit. Due to the rapid transmission of lateral confined water pressure changes in fine sand, and the delayed transmission in clay due to their low permeability, the diaphragm wall response is most pronounced within the depth range of the lateral confined aquifer. Full article

Water scarcity in coastal tourist areas constitutes a critical environmental and socioeconomic sustainability issue. Hence, it is crucial to implement an integrated water resource management and protection plan. In this research, the DPSIR framework is coupled with hydrochemical data on groundwater resources in the fractured aquifer of the Sithonia Peninsula in Chalkidiki, North Greece. Geographical and demographic data, together with morphology, geology, hydrology, and groundwater quality data, were collected and evaluated to categorize the hydrosystem’s driving forces, pressures, states, impacts, and responses. The main pressures that affect groundwater quality in the study area are tourism, geological formation, and land use. Based on the analysis of the DPSIR framework, the absence of a landfill site, the inadequate operation of sewage treatment plants and biological wastewater treatment systems, and tourist activity contribute significantly to the degradation of groundwater quality. Additionally, the fractured rock aquifer develops preferential flow paths to pollutants through preexisting faults, which influence groundwater quality. The hydrochemical analysis of groundwater indicates seawater intrusion in the coastal area. The combination of DPSIR analysis and a water quality index based on ion ratios of groundwater samples identifies high-risk areas of seawater intrusion. Thus, it is essential to reinforce groundwater resources by implementing managed aquifer recharge, limiting unnecessary use of groundwater during the tourist season, and storing surface water during the wet period. Full article

The radiological impact of radionuclide transport via groundwater pathways at the Wolsong Low- and Intermediate-Level Waste (LILW) Disposal Center was estimated by considering site-specific characteristics, including hydrogeology, geochemistry, and land use. Human intrusion scenarios, such as groundwater well development, were analyzed to evaluate potential pumping volumes and radionuclide migration pathways. Particular attention was given to the hydrological and geochemical aspects of radionuclide transport, with a focus on local aquifer heterogeneity, flow dynamics, and interactions with engineered barriers and surrounding rock formations that delay radionuclide migration through sorption and other retention mechanisms. Sorption coefficients (K_d), calibrated using site-specific geochemical data, were incorporated to ensure realistic modeling of radionuclide behavior. A hierarchical approach integrating scenario screening, particle tracking techniques, and mass transfer modeling was employed. Numerical simulations using FEFLOW ver. 7.3 and GoldSim ver. 14.0 software provided insights into near-field and far-field transport phenomena under well pumping conditions. The results revealed distinct spatial flux behaviors, where carbon-14 (¹⁴C) dominated near-field flux due to its high inventory, while technetium-99 (⁹⁹Tc) emerged as the primary dose contributor in the far-field flux, owing to its anionic nature and limited sorption capacity. Additionally, under high-pH conditions near concrete barriers, cellulose degradation into isosaccharinic acid was identified, enhancing radionuclide mobility through complex formation. These findings underscore the importance of site-specific sorption and speciation parameters in safety assessment and highlight the need for accurate geochemical modeling to optimize waste placement and ensure long-term disposal safety. The outcomes provide valuable insights for optimizing waste placement and contribute to the development of evidence-based safety strategies for long-term performance assessment. Full article