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Search Results (18,012)

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29 pages, 7068 KiB  
Review
A Review on Research Advances and Applications of Basalt Fiber-Reinforced Polymer in the Construction Industry
by Sheng-Jie Duan, Ru-Ming Feng, Xin-Yan Yuan, Liang-Tao Song, Gen-Shu Tong and Jing-Zhong Tong
Buildings 2025, 15(2), 181; https://doi.org/10.3390/buildings15020181 - 9 Jan 2025
Abstract
Compared to glass fiber-reinforced polymer (GFRP) and carbon fiber-reinforced polymer (CFRP), basalt fiber-reinforced polymer (BFRP) offers distinct advantages, including the relatively lower cost and superior creep resistance. As a result, its application in the construction industry has been gaining growing attention. This paper [...] Read more.
Compared to glass fiber-reinforced polymer (GFRP) and carbon fiber-reinforced polymer (CFRP), basalt fiber-reinforced polymer (BFRP) offers distinct advantages, including the relatively lower cost and superior creep resistance. As a result, its application in the construction industry has been gaining growing attention. This paper begins by providing an overview of the fundamental background, as well as the mechanical and microscopic properties, of BFs. By exploring various application types, including one-dimensional (e.g., bars, cables), two-dimensional (e.g., grids, sheets), and three-dimensional (e.g., profiles) applications, the research progress of BFRP products in the construction industry is comprehensively summarized. Research has demonstrated the effectiveness of BFRP in a variety of structural applications, such as reinforcing existing structures (e.g., concrete or masonry) using BFRP bars, grids, or sheets, and the development of novel design concepts that integrate BFRP products with existing structural systems. Furthermore, this paper identifies unresolved challenges and proposes potential research directions, intending to promote BFRP’s broader adoption as a standardized and innovative material in the construction industry. Full article
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<p>Applications of FRP.</p>
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<p>SEM images of the BF surface: (<b>a</b>) surface roughening [<a href="#B33-buildings-15-00181" class="html-bibr">33</a>]; (<b>b</b>) enhancing interactions with nanoparticles [<a href="#B34-buildings-15-00181" class="html-bibr">34</a>]; and (<b>c</b>) plasma treatment [<a href="#B36-buildings-15-00181" class="html-bibr">36</a>].</p>
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<p>BFRP products: (<b>a</b>) bar [<a href="#B44-buildings-15-00181" class="html-bibr">44</a>]; (<b>b</b>) cable [<a href="#B45-buildings-15-00181" class="html-bibr">45</a>]; (<b>c</b>) grid [<a href="#B46-buildings-15-00181" class="html-bibr">46</a>]; (<b>d</b>) sheet [<a href="#B47-buildings-15-00181" class="html-bibr">47</a>]; and (<b>e</b>) profile [<a href="#B48-buildings-15-00181" class="html-bibr">48</a>,<a href="#B49-buildings-15-00181" class="html-bibr">49</a>].</p>
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<p>Failure mode of BFRP bars under different conditions [<a href="#B52-buildings-15-00181" class="html-bibr">52</a>].</p>
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<p>Failure mode of RC beams strengthened with BFRP bars [<a href="#B58-buildings-15-00181" class="html-bibr">58</a>].</p>
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<p>Failure mode of slender rectangular columns strengthened with BFRP bars [<a href="#B63-buildings-15-00181" class="html-bibr">63</a>].</p>
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<p>Failure mode of BFRP tendons [<a href="#B65-buildings-15-00181" class="html-bibr">65</a>].</p>
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<p>Failure mode of an RC beam strengthened with external BFRP tendons [<a href="#B66-buildings-15-00181" class="html-bibr">66</a>].</p>
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<p>Failure mode of a concrete slab strengthened with BFRP tendons [<a href="#B68-buildings-15-00181" class="html-bibr">68</a>].</p>
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<p>Failure mode of concrete slabs strengthened with BFRP bars [<a href="#B73-buildings-15-00181" class="html-bibr">73</a>].</p>
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<p>Failure mode of BFRP cables [<a href="#B45-buildings-15-00181" class="html-bibr">45</a>].</p>
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<p>Failure mode of an RC beam strengthened with a BFRP grid [<a href="#B96-buildings-15-00181" class="html-bibr">96</a>]: (<b>a</b>) concrete crushing; (<b>b</b>) concrete crushing after the rupture of the BFRP grid; and (<b>c</b>) partial debonding of the CRL after the rupture of the BFRP grid.</p>
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<p>Failure of a masonry wall strengthened with BFRP sheets [<a href="#B107-buildings-15-00181" class="html-bibr">107</a>]: (<b>a</b>) FRP debonding; (<b>b</b>) slight shear sliding crack; (<b>c</b>) masonry crushing; (<b>d</b>) FRP buckling; (<b>e</b>) rockling behavior; and (<b>f</b>) FRP rupture.</p>
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<p>Failure of an RC column strengthened with BFRP sheets [<a href="#B108-buildings-15-00181" class="html-bibr">108</a>]: (<b>a</b>) interface failure; and (<b>b</b>) fracture of NSM-BFRP bars.</p>
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<p>Failure of a lightweight rubberized beam strengthened with BFRP sheets [<a href="#B111-buildings-15-00181" class="html-bibr">111</a>].</p>
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<p>Failure of RC beam–column joints strengthened with BFRP sheets [<a href="#B112-buildings-15-00181" class="html-bibr">112</a>]: (<b>a</b>) initial state; (<b>b</b>) epoxy crack; (<b>c</b>) local bulging; (<b>d</b>) rupture of BFRP sheet; and (<b>e</b>) crushing of core concrete.</p>
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<p>Failure mode of a BFRP tube [<a href="#B48-buildings-15-00181" class="html-bibr">48</a>]: (<b>a</b>) <span class="html-italic">λ</span> = 6; (<b>b</b>) <span class="html-italic">λ</span> = 10; (<b>c</b>) <span class="html-italic">λ</span> = 30; (<b>d</b>) <span class="html-italic">λ</span> = 50; (<b>e</b>) <span class="html-italic">λ</span> = 70; and (<b>f</b>) <span class="html-italic">λ</span> = 90.</p>
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<p>Failure mode of a BFRP profile [<a href="#B130-buildings-15-00181" class="html-bibr">130</a>]: (<b>a</b>) circular tube; (<b>b</b>) rectangular tube; and (<b>c</b>) box tube.</p>
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<p>The proportion of research work on different BFRP products.</p>
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20 pages, 3077 KiB  
Article
Fit for the Future: An Assessment of the Sustainability Parameters of Liquid Dairy Product Packaging in the DACH Region and the Implications of Upcoming Regulatory Changes
by Michelle Klein, Charlotte Neumair, Mattia Primoceri, Manfred Tacker and Silvia Apprich
Foods 2025, 14(2), 195; https://doi.org/10.3390/foods14020195 - 9 Jan 2025
Abstract
The European Union aims for climate neutrality by 2050 and has proposed the Packaging and Packing Waste Regulation (PPWR) to promote a circular economy, focusing on reducing packaging waste. In this context, a comprehensive sustainability assessment for liquid dairy product packaging, including beverage [...] Read more.
The European Union aims for climate neutrality by 2050 and has proposed the Packaging and Packing Waste Regulation (PPWR) to promote a circular economy, focusing on reducing packaging waste. In this context, a comprehensive sustainability assessment for liquid dairy product packaging, including beverage cartons, bottles and to-go cups, in the DACH region (Germany, Austria and Switzerland) was conducted. The aim was to consider various ecological aspects of environmental impacts and circularity. As the aspect of recyclability is a core aspect in the PPWR, the calculation was of central interest in this project. Here, major differences in the waste management infrastructure between countries could be identified. The majority of assessed packaging falls below the PPWR’s 70% recyclability requirement, with Switzerland showing even lower recyclability due to poor packaging collection and recycling infrastructure. Significant discrepancies in packaging efficiency exist, indicating unnecessary resource consumption, especially in the case of to-go cups. Additionally, the carbon footprint of packaging materials can vary up to ten times within certain product categories, negatively impacting the environment. Good results were identified for the use of certified renewable resources. Overall, the results of the assessment demonstrate several areas for improvement in light of forthcoming regulatory requirements, which must be met in Germany and Austria. Full article
(This article belongs to the Special Issue Advances in the Development of Sustainable Food Packaging)
17 pages, 9648 KiB  
Article
Effects of the Rate Dependency of a Matrix Material on the Tensile Response of Plain Weave Carbon Fabric Reinforced Epoxy Composites
by Taeseong Choi and Wooseok Ji
J. Compos. Sci. 2025, 9(1), 29; https://doi.org/10.3390/jcs9010029 - 9 Jan 2025
Abstract
Textile composites are extensively used in structures subjected to both static and dynamic loads. However, research on how loading rates influence performance remains limited. A better understanding of how the rate dependency of matrix materials affects the mechanical behavior of textile composites could [...] Read more.
Textile composites are extensively used in structures subjected to both static and dynamic loads. However, research on how loading rates influence performance remains limited. A better understanding of how the rate dependency of matrix materials affects the mechanical behavior of textile composites could facilitate more accurate performance predictions and the efficient selection of components based on loading rates. This study investigates the effect of the rate dependency of epoxy on the overall rate dependency of a plain weave carbon fabric-reinforced epoxy composite. Specimens were prepared using only epoxy resin, and tensile tests were conducted at four loading rates (5 mm/min, 50 mm/min, 200 mm/min, and 800 mm/min) to evaluate changes in the tensile properties of epoxy with varying loading rates. Composite specimens were fabricated using the same epoxy, and tensile tests were performed under identical conditions. The results demonstrated that both materials became more brittle at higher loading rates while their stiffness remained largely unaffected. Furthermore, the failure process of the composite at different loading rates was analyzed through micro-scale finite element analysis. The analysis revealed that the onset of failure in textile composites shifted owing to the rate-dependent brittleness of epoxy. To mitigate the high computational cost of explicit simulations accounting for time dependency, a modified Johnson–Cook model and an acceleration model were newly developed and incorporated into the analysis. Full article
(This article belongs to the Section Composites Modelling and Characterization)
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<p>Configuration of the specimen.</p>
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<p>(<b>a</b>) Tensile test setup and (<b>b</b>) DIC setup for composite at S800.</p>
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<p>Cross-section image of the composite before the tensile test.</p>
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<p>Geometry model of FEA for composite.</p>
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<p>Boundary conditions of the FEA for composite.</p>
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<p>Stress–strain curve representing damage evolution mechanisms.</p>
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<p>Representative tensile strain–tensile stress curves of the epoxy at different loading rates.</p>
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<p>Tensile material properties of the epoxy at different loading rates: (<b>a</b>) strength, (<b>b</b>) elongation, and (<b>c</b>) modulus.</p>
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<p>Fracture surface of the epoxy at loading rates of (<b>a</b>) 5 mm/min, (<b>b</b>) 50 mm/min, (<b>c</b>) 200 mm/min, and (<b>d</b>) 800 mm/min.</p>
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<p>Representative tensile strain–tensile stress curves of composites at different loading rates.</p>
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<p>Tensile material properties of the composite at different loading rates: (<b>a</b>) strength, (<b>b</b>) elongation, and (<b>c</b>) modulus.</p>
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<p>(<b>a</b>) Schematic of the field of view, (<b>b</b>) fracture surface of the composite at S5, and (<b>c</b>) fracture surface of the composite at S800.</p>
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<p>Fracture surface of the composite: (<b>a</b>) weft tow at S5, (<b>b</b>) warp tow at S5, (<b>c</b>) weft tow at S800, and (<b>d</b>) warp tow at S800.</p>
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<p>(<b>a</b>) Equivalent plastic strain rate–equivalent plastic strain curve (<b>b</b>) <span class="html-italic">D</span><sub>2</sub> fitting curve.</p>
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<p>Boundary conditions of single-element simulation for the epoxy.</p>
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<p>Stress–strain curve of single-element simulation for the epoxy.</p>
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<p>Stress–strain curves of composite in the FEA.</p>
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<p>Progressive failure pattern of composite.</p>
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17 pages, 842 KiB  
Review
High Rate Stormwater Treatment for Water Reuse and Conservation—Review
by Saravanamuthu Vigneswaran, Jaya Kandasamy and Harsha Ratnaweera
Appl. Sci. 2025, 15(2), 590; https://doi.org/10.3390/app15020590 - 9 Jan 2025
Abstract
Effective stormwater management is increasingly vital due to climate change impacts, such as intensified rainfall and flooding. Urban expansion, water scarcity, and intensified agriculture demand innovative solutions like Green Stormwater Infrastructure (GSI), including vegetated biofilters, green roofs, wetlands, bioretention systems, and high-rate filtration. [...] Read more.
Effective stormwater management is increasingly vital due to climate change impacts, such as intensified rainfall and flooding. Urban expansion, water scarcity, and intensified agriculture demand innovative solutions like Green Stormwater Infrastructure (GSI), including vegetated biofilters, green roofs, wetlands, bioretention systems, and high-rate filtration. These systems, enhanced by natural and engineered filter materials, improve contaminant removal across diverse contexts. Modern practices prioritize retention, infiltration, and groundwater recharge over traditional rapid drainage, reframing stormwater as a resource amid rising extreme weather events. In water-scarce regions, stormwater management offers dual-use potential for drinking and non-drinking applications, addressing freshwater scarcity exacerbated by population growth and climate change. Targeting the “first flush” of pollutants after rainfall allows for more efficient, cost-effective treatment. This paper identifies three key objectives: addressing GSI limitations and exploring new technologies, evaluating treatment train combinations for cost-effective reuse, and advancing urban stormwater treatment research. Various filter media, such as those in green roofs, bioretention systems, and swales, effectively remove pollutants like nutrients, heavy metals, PAHs, and micropollutants. Granular activated carbon (GAC) filters excel at reducing heavy metals and dissolved organic carbon (DOC), with pre-screening via anthracite filters to extend GAC lifespan by trapping sediments and pollutants. Managing emerging contaminants and microplastics remains underexplored and requires further investigation. Full article
(This article belongs to the Special Issue Pathways for Water Conservation)
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<p>Schematic of biofilter system.</p>
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<p>GAC media filter (<b>a</b>) without and (<b>b</b>) with prefilter packed with anthracite (filtration rate = 10 m/h, filter media height = 1 m, filter column height = 1.8 m, filter diameter = 0.1 m).</p>
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28 pages, 7815 KiB  
Article
Design and Characteristics of a Single-Story Building Model Incorporating Waste
by Mohamed Darwish, Mohamed Elnakeb, Marina Moawad, Marwan Mohamed Shawki, Ehab Abdelhamid, Donia Eldwib, Mohamed Nagib Abouzeid, Maram Saudy, Safwan Khedr and Khaled Nassar
Buildings 2025, 15(2), 177; https://doi.org/10.3390/buildings15020177 - 9 Jan 2025
Abstract
The construction field is one of the largest sectors and industries worldwide. This industry is the main industry accused of contributing to greenhouse gases and increasing the effects of climate change. However, the construction industry is indispensable, accordingly in an attempt to decrease [...] Read more.
The construction field is one of the largest sectors and industries worldwide. This industry is the main industry accused of contributing to greenhouse gases and increasing the effects of climate change. However, the construction industry is indispensable, accordingly in an attempt to decrease the greenhouse gas effects of construction this research presents the manuscript for building a one-story building with all components including waste products. The building model used a strip foundation with a concrete mix design incorporating recycled concrete as a partial replacement for aggregates, cement hollow blocks containing granite waste instead of conventional cement blocks, and sandwiched insulated panels made of wood-plastic composites for the roof. The structural soundness of the system was tested by loading it with a load surpassing its design load in addition to measuring the deflection and checking its abidance to the code limitations. The thermal efficiency was tested by measuring the temperatures in comparison with the outside of the building for a span of 7 days with data recorded every 1 h. Analysis of both the short-term and long-term costs and carbon emissions was performed by acquiring the carbon emissions per unit of material from literature and multiplying it by the quantities of the materials used within the different building alternatives. That study showed that the roofs made of Structural Insulated Panels (SIPs) using Wood-Plastic Composite (WPC) facings when used with hollow-block cement block walls have shown enduring cost efficiency and improved thermal insulation, leading to diminished energy usage, life-cycle expenses, and carbon emissions. Furthermore, the proposed system is more environmentally friendly than conventional reinforced concrete technologies due to their lower costs and emissions in addition to improving sustainability through utilizing recycled materials. Full article
(This article belongs to the Section Building Structures)
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<p>Recycled Polypropylene (PP).</p>
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<p>Musky-Waste Wood.</p>
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<p>WPC Panels Materials and Production Technique.</p>
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<p>SAP2000 Model.</p>
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<p>Interaction Diagram to Achieve Un-Supported Spans for SIP Panels due to Various Loads.</p>
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<p>SAP2000 Deflection Diagram.</p>
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<p>Constructed Full-Scale Model.</p>
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<p>Project Timeline.</p>
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<p>Structural testing of the full-scale model.</p>
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<p>Qingping Monitor Interface.</p>
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<p>Qingping Sensor Data.</p>
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<p>Temperature Data retreived from Weather Station in Cairo Airport.</p>
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<p>The Alternatives Detailed Cost Breakdown.</p>
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<p>Alternatives Cost Comparison.</p>
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<p>All Alternatives Detailed Carbon Emissions Breakdown.</p>
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<p>Alternatives Carbon Emissions Comparison.</p>
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<p>Heat Flow of the Alternatives Comparison.</p>
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<p>Life Cycle Cost of the Alternatives Comparison.</p>
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<p>Life Cycle Carbon Emissions of the Alternatives Comparison.</p>
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<p>CBR Ratios of the Alternatives.</p>
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<p>The load-deflection curve for the tested model versus the numerically reached load-deflection curve and the design load.</p>
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<p>Temperature Data Comparison.</p>
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<p>Relative Humidity Comparison.</p>
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15 pages, 4799 KiB  
Article
Carboxylated Graphene: An Innovative Approach to Enhanced IgA-SARS-CoV-2 Electrochemical Biosensing
by Luciana de Souza Freire, Ariamna María Dip Gandarilla, Yonny Romaguera Barcelay, Camila Macena Ruzo, Barbara Batista Salgado, Ana P. M. Tavares, Francisco Xavier Nobre, Julio Nino de Souza Neto, Spartaco Astolfi-Filho, Ștefan Țălu, Pritesh Lalwani, Niranjan Patra and Walter Ricardo Brito
Biosensors 2025, 15(1), 34; https://doi.org/10.3390/bios15010034 - 9 Jan 2025
Abstract
Biosensors harness biological materials as receptors linked to transducers, enabling the capture and transformation of primary biorecognition signals into measurable outputs. This study presents a novel carboxylation method for synthesizing carboxylated graphene (CG) under acidic conditions, enhancing biosensing capabilities. The characterization of the [...] Read more.
Biosensors harness biological materials as receptors linked to transducers, enabling the capture and transformation of primary biorecognition signals into measurable outputs. This study presents a novel carboxylation method for synthesizing carboxylated graphene (CG) under acidic conditions, enhancing biosensing capabilities. The characterization of the CG was performed using scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), Raman spectroscopy, thermogravimetric analysis (TGA), and X-ray diffraction (XRD). We modified screen-printed carbon electrodes (SPCEs) with CG to immobilize the SARS-CoV-2 N-protein, facilitating targeted detection of IgA antibodies (IgA-SARS-CoV-2). The analytical performance was assessed via electrochemical techniques such as cyclic voltammetry and electrochemical impedance spectroscopy, confirming CG synthesis effectiveness and biosensor functionality. The developed biosensor efficiently detects IgA-SARS-CoV-2 across a dilution range of 1:1000 to 1:200 v/v in a phosphate-buffered saline (PBS) solution, with a limit of detection calculated at 1:1601 v/v. This device shows considerable potential because of its fast response time, miniaturized design facilitated by SPCEs, reduced sample volume requirements, high sensitivity and specificity, low detection limits, and signal enhancement achieved through nanomaterial integration. Full article
(This article belongs to the Special Issue Nanomaterial-Enhanced Biosensing for Point-of-Care Diagnostics)
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<p>TG and DTG curves of decomposition of graphene and carboxylated graphene.</p>
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<p>X-ray diffraction pattern of graphene nanoplateles (<b>A</b>) and carboxylated graphene (<b>B</b>).</p>
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<p>Raman spectra of (<b>A</b>) graphene nanoplatelets and (<b>B</b>) carboxylated graphene with the D*, D, G, and 2G band deconvolution.</p>
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<p>SEM images of (<b>A</b>,<b>B</b>) graphene and (<b>C</b>,<b>D</b>) carboxylated graphene.</p>
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<p>EDS spectrum of (<b>A</b>) graphene and (<b>B</b>) carboxylated graphene.</p>
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<p>(<b>A</b>) Schematic representation of biosensor fabrication steps and IgA-SARS-CoV-2 determination, (<b>B</b>,<b>C</b>) CV and EIS for deposition of carboxylated graphene layers in 5 mmol L<sup>−1</sup> [Fe(CN)6]<sup>3−/4−</sup>, prepared in 0.1 mol L<sup>−1</sup> KCl. (<b>D</b>) The linear relationship between the current and square root of sweep speed (10–100 mV s<sup>−1</sup>) for modified SPCE with 3 depositions of CG.</p>
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<p>(<b>A</b>,<b>B</b>) Chronoamperograms were recorded with PBS, as well as negative and positive controls. (<b>C</b>) Chronoamperometric response was measured for different concentrations of human serum with IgA-SARS-CoV-2. (<b>D</b>) Current values registered from 10 to 50 s for different human serum concentrations with IgA-SARS-CoV-2.</p>
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<p>Calibration curve for IgA-SARS-CoV-2 determination through (<b>A</b>) CA technique and (<b>B</b>) ELISA technique. Standard error bars correspond to measurements made on three replicates of each concentration (<span class="html-italic">n</span> = 3).</p>
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<p>Representation of the method of synthesis of carboxylated graphene.</p>
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35 pages, 6541 KiB  
Article
Development of a Life Cycle Inventory Database for Environmental Impact Assessment of Construction Materials in Burkina Faso
by Iliassou Salou Nouhoun, Philbert Nshimiyimana, Césaire Hema and Adamah Messan
Sustainability 2025, 17(2), 471; https://doi.org/10.3390/su17020471 - 9 Jan 2025
Abstract
The construction sector plays a key role in the growth of developing countries but faces major environmental challenges, such as greenhouse gas emissions and resource depletion. Life Cycle Assessment (LCA) is an essential tool for evaluating these impacts and promoting sustainable choices. However, [...] Read more.
The construction sector plays a key role in the growth of developing countries but faces major environmental challenges, such as greenhouse gas emissions and resource depletion. Life Cycle Assessment (LCA) is an essential tool for evaluating these impacts and promoting sustainable choices. However, its effective application is limited by the lack of local databases. This study introduces a systematic framework (LOCAL-LCID2) for creating local Life Cycle Inventory (LCI) databases for developing countries. Its application is demonstrated in Burkina Faso’s (BF) context through a comparative LCA of commonly used materials, covering the cradle-to-gate stage. The methodology follows seven steps: (1) identification of materials, (2) data collection, (3) analysis of material and energy flows, (4) development of LCI database, (5) structuring the database using SimaPro 9.6.0, (6) calculation of environmental impacts via ReCiPe 2016 Midpoint, and (7) uncertainty analysis using the pedigree matrix and Monte Carlo simulation. The materials are categorized into two main groups (imported and locally produced) with five subcategories: materials for roofs, walls/structures, floors, openings, and others. The results show that for wall materials, concrete blocks have the highest Global Warming Potential (GWP), with 88.3% of CO2 emissions attributed to cement, implying an urgent need to optimize cement use and explore alternative binders for sustainable construction. Stabilized earth blocks show intermediate GWP at 65% of concrete block emissions, while straw-stabilized adobe demonstrates the lowest environmental impact, suggesting significant potential for reducing construction’s carbon footprint through traditional material optimization. The importation of steel sheets and ceramic tiles shows high GWP due to their energy-intensive production processes and long-distance transport (4 to 40% of emissions), highlighting opportunities to reduce impacts through local manufacturing and optimization of supply chains. The diversification of BF’s energy mix through clean energy imports from neighboring countries decreases GWP by 26.9%, indicating that regional energy partnerships and renewable energy investments are key pathways for minimizing environmental impacts related to energy consumption in the construction industry. Finally, the uncertainty analysis reveals the need for primary data updates in the current LCI database, highlighting both data quality enhancement opportunities and future research perspectives for industrial process assessment. The methodological framework equips decision-makers in developing countries with tools to implement sustainable construction practices through strategic material selection and regional resource optimization. Full article
(This article belongs to the Section Sustainable Materials)
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<p>Methodological framework (LOCAL-LCID2) for adapting and developing LCI databases applied to BF. Red arrows indicate sequential steps (actions to be taken), green dashed arrow indicate iterative feedback loops, and diamonds mark decision nodes based on data quality.</p>
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<p>Geographical distribution of raw material flows and transportation in BF for material production.</p>
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<p>Supply chain of construction materials and life cycle flow of construction materials in BF: from origin to final use.</p>
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<p>Ecological footprint of 1 kWh high-voltage (HV) electricity production in BF compared with Côte d’Ivoire (CI), Ghana (GH), and Togo (TG).</p>
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<p>Comparison of the ecological footprint resulting from the production of 1 kg of materials used in the BF wall.</p>
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<p>Comparison of environmental impacts resulting from the production of 1 m<sup>3</sup> of conventional concrete.</p>
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<p>Comparative LCIA associated with 1 kg production and importation for roofing materials.</p>
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<p>Comparative LCIA of 1 kg production and importation for opening materials.</p>
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<p>Comparative LCIA of 1 kg production and importation for flooring materials.</p>
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<p>Uncertainty analysis of 1 kg of wall material for GWP (kg CO<sub>2</sub> eq).</p>
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13 pages, 3574 KiB  
Article
Effects of Forest Land Mulching on the Soil CO2 Emission Rate of Phyllostachys violascens Forests
by Zhan Shen, Dongping Zha, Xinglan Zu, Jianmin Shi, Zuyao Li and Shuangshuang Chu
Forests 2025, 16(1), 106; https://doi.org/10.3390/f16010106 - 9 Jan 2025
Abstract
This study investigates the dynamics of soil CO2 emissions during the cover period of Phyllostachys violascens and the impact of different cover measures, aiming to provide references for reducing the environmental effects of bamboo cover. An L27 (913) orthogonal [...] Read more.
This study investigates the dynamics of soil CO2 emissions during the cover period of Phyllostachys violascens and the impact of different cover measures, aiming to provide references for reducing the environmental effects of bamboo cover. An L27 (913) orthogonal experimental design was employed, setting the following variables: (1) heating materials: chicken manure, straw cake, and wheat ash; (2) thickness of husk layer: 15 cm, 25 cm, and 35 cm; (3) soil moisture levels before covering: moisture to 10 cm, 15 cm, and 20 cm. The soil CO2 emission rate showed a unimodal curve, with a significant overall increase during the cover period. Throughout the entire cover period, the average soil CO2 emission rate (25.39 μmol·m−2·s−1) was 5.1 times higher than that of the uncovered Lei bamboo forest (5.02 μmol·m−2·s−1) during the same period. Thicker husk layers (25 cm and 35 cm) corresponded to higher soil CO2 emission rates, with significant differences noted among the thicknesses. When the soil was moist to 10 cm, the CO2 emission rate was highest (62.51 μmol·m−2·s−1); moisture to 15 cm and 20 cm resulted in significantly lower emission rates. Chicken manure produced the highest peak CO2 emissions in the third week, at 70.64 μmol·m−2·s−1, while straw cake and wheat ash reached their peaks in the fifth week, at 66.56 μmol·m−2·s−1 and 57.58 μmol·m−2·s−1, respectively. The interactions between the three factors (heating materials, husk layer thickness, and moisture levels) significantly affected the soil CO2 emission rates. By optimally configuring these factors, CO2 emissions can be regulated. This study recommends using wheat ash or straw cake as heating materials, combined with a 25 cm husk layer thickness, and moistening the soil to 15 cm before covering. This approach effectively reduces the peak and total soil CO2 emissions while ensuring suitable soil temperatures for the growth of bamboo shoots in spring. This research provides a scientific basis for the environmental management of bamboo forests, aiding in the optimization of covering measures to achieve low-carbon and sustainable bamboo management. Full article
(This article belongs to the Special Issue Forest Inventory: The Monitoring of Biomass and Carbon Stocks)
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<p>The experimental area.</p>
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<p>Dynamic changes in soil CO<sub>2</sub> emission rate in <span class="html-italic">Ph. violascens</span> forest during the mulching period. The bars in the figure refer to the standard errors.</p>
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<p>Dynamic changes in soil CO<sub>2</sub> emission rate in <span class="html-italic">Ph. violascens</span> forest mulched by different heating substances. The bars in the figure refer to the standard errors.</p>
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<p>Dynamic changes in soil CO<sub>2</sub> emission rate by different heating substances under different conditions of chaff layer thickness and water supplement.</p>
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<p>Dynamic changes in soil CO<sub>2</sub> emission rate under different rice husk layer thicknesses. The bars in the figure refer to the standard errors.</p>
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<p>Dynamic changes in soil CO<sub>2</sub> emission rate under different pre-cover irrigation levels. The bars in the figure refer to the standard errors.</p>
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25 pages, 3472 KiB  
Review
Research Progress on the Extraction and Separation of Rare-Earth Elements from Waste Phosphors
by Guocai Tian, Zhongbin Xu, Xiaofen Li, Zhiqiang Hu and Baichuan Zhou
Minerals 2025, 15(1), 61; https://doi.org/10.3390/min15010061 - 9 Jan 2025
Viewed by 68
Abstract
Rare earth is an important strategic resource and a key mineral resource for global competition. As the depletion of primary rare-earth resources increases, a great number of rare-earth secondary resources, such as waste phosphor powder collected from fluorescent lamps, cathode-ray tubes, and other [...] Read more.
Rare earth is an important strategic resource and a key mineral resource for global competition. As the depletion of primary rare-earth resources increases, a great number of rare-earth secondary resources, such as waste phosphor powder collected from fluorescent lamps, cathode-ray tubes, and other luminescent materials, continue to be generated and accumulated. How to achieve the low-carbon extraction and green and efficient utilization of these resources has become an urgent problem to be solved. In recent years, preliminary enrichment methods, such as flotation, magnetic separation, and adsorption, chemical methods, such as acid leaching and alkaline fusion, external-field-enhanced methods (including mechanical activation, microwave and oxidant, green solvent, etc.), and solvent extraction have been used for the separation and extraction of rare-earth elements (REEs), such as Y, Eu, Ce, Tb, La, and Ga, from waste phosphors. In this article, we systematically summarized the research progress of commonly used separation and extraction methods for REEs in waste phosphor powders, analyzed the advantages, disadvantages, and existing problems of different methods, and proposed potential directions for future research. Full article
(This article belongs to the Special Issue Recovery of Rare Earth Elements Minerals: 2nd Edition)
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<p>Global rare-earth reserves and production in 2023.</p>
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<p>Flow diagram of recycling waste fluorescent devices.</p>
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<p>(<b>a</b>) Effects of alkaline fusion of different chemicals on the leaching efficiency of REEs [Reproduced with permission from Ref. [<a href="#B59-minerals-15-00061" class="html-bibr">59</a>] published by Elsevier]. (<b>b</b>) Decomposition mechanism of BAM phosphors.</p>
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<p>Flow diagram of alkaline fusion roasting to recover REEs from waste phosphors. (<b>a</b>) alkaline fusion-water wash-acid leaching process (<b>b</b>) acid leaching-alkaline fusion-water wash process.</p>
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<p>Comparison of the effects of acid leaching, mechanical activation, and alkali activation on the leaching rate of rare earths (<b>a</b>) and leaching rates of REEs dissolved from waste phosphors (<b>b</b>). Reproduced with permission from Ref. [<a href="#B26-minerals-15-00061" class="html-bibr">26</a>] published by Elsevier.</p>
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<p>Composition, property of green solvents for REE separation.The HBA:Hydrogen Bond Acceptors; HBD: Hydrogen Bond Donors; DES:Deep Eutectic Solvents; ILS: Ionic Liquids.</p>
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<p>The extraction mechanism of REEs in ILs.</p>
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20 pages, 7699 KiB  
Review
Improving Performance and Safety of Lithium Metal Batteries Through Surface Pretreatment Strategies
by Gyuri Youk, Jeongmin Kim and Oh B. Chae
Energies 2025, 18(2), 261; https://doi.org/10.3390/en18020261 - 9 Jan 2025
Viewed by 115
Abstract
Lithium metal batteries (LMBs) are promising candidates for electric vehicles (EVs) and next-generation energy storage systems owing to their high energy densities. The solid electrolyte interphase (SEI) on the Li metal anode plays an important role in influencing the Li deposition form and [...] Read more.
Lithium metal batteries (LMBs) are promising candidates for electric vehicles (EVs) and next-generation energy storage systems owing to their high energy densities. The solid electrolyte interphase (SEI) on the Li metal anode plays an important role in influencing the Li deposition form and the cycle life of the LMB. However, the SEI on Li metal differs from that for other anodes, such as graphite, owing to its instability and reactivity. In addition, dendrite growth has hindered the commercial application of Li metal batteries in regular portable electronics to EVs. This review summarizes SEI formation on Li metal, dendrite formation and growth, and their impact on battery performance. In addition, we reviewed the recent progress in pretreatment strategies using materials such as polymers, carbon materials, and inorganic compounds to suppress dendritic growth. Full article
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<p>Schematic of pretreatment strategies according to materials.</p>
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<p>Schematic of SEI formation processes on (<b>a</b>) Li, (<b>b</b>) Graphite, and (<b>c</b>) Si-negative electrodes. (Reprinted with permission from Ref. [<a href="#B31-energies-18-00261" class="html-bibr">31</a>]; Copyright © 2020 Wiley-VCH GmbH); (<b>d</b>) Schematic of the formation process of SEI film on Li surfaces. (<b>e</b>) Schematic of the positive and negative potential limits of electrolyte stability and the energy levels of LUMO and HOMO. (Reprinted with permission from Ref. [<a href="#B34-energies-18-00261" class="html-bibr">34</a>]; Copyright © 2019 American Chemical Society).</p>
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<p>Model diagram of SEI formation mechanism. (<b>a</b>) Peled model, (<b>b</b>) Mosaic model (Reprinted with permission from Ref. [<a href="#B46-energies-18-00261" class="html-bibr">46</a>]; Copyright © 2023 The Authors. Published by Elsevier B.V.); (<b>c</b>) Plum-pudding model (Reprinted with permission from Ref. [<a href="#B31-energies-18-00261" class="html-bibr">31</a>]; Copyright © 2020 Wiley-VCH GmbH).</p>
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<p>Photograph of a dendrite obtained in the (<b>a</b>) high current densities (J = 0.7 mA cm<sup>−2</sup>) regime, (<b>b</b>) low current densities (J = 0.1 mA cm<sup>−2</sup>) regime. (Reprinted with permission from Ref. [<a href="#B59-energies-18-00261" class="html-bibr">59</a>]; Copyright © 1999 Elsevier Science S.A. All rights reserved).</p>
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<p>Morphology of dendrites. (<b>a</b>) Needle-like dendrites. (<b>b</b>) Branched dendrites. (<b>c</b>) Moss-like dendrites. (Reprinted with permission from Ref. [<a href="#B67-energies-18-00261" class="html-bibr">67</a>]; Copyright © 2019 Elsevier Ltd. (Amsterdam, The Netherlands) All rights reserved).</p>
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<p>(<b>a</b>) Design of the flexible SEI. (<b>b</b>) Comparison of the cycling stability of pristine Li and LiPAA-Li in a symmetrical cell at 0.5 mA cm<sup>−2</sup> (Reprinted with permission from Ref. [<a href="#B80-energies-18-00261" class="html-bibr">80</a>]; Copyright © 2018 Wiley-VCH Verlag GmbH &amp; Co. KGaA, Weinheim); (<b>c</b>) Schematics of Li deposition on bare Cu foil and the Cu foil coated with PDMS thin film. (<b>d</b>) Cross-section SEM image of the PDMS film, and (<b>e</b>) top view SEM image of PDMS film after HF acid treatment (red circles: nanopores). (Reprinted with permission from Ref. [<a href="#B81-energies-18-00261" class="html-bibr">81</a>]; Copyright © 2016 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim); (<b>f</b>) Li<sub>3</sub>PO<sub>4</sub>/PVA protective layer on the Li foil. Voltage profiles of Li metal plating/stripping in a Li|Li symmetrical cell under different current densities: (<b>g</b>) 2 mA cm<sup>–2</sup> with 1 mA h cm<sup>–2</sup> and (<b>h</b>) 5 mA cm<sup>–2</sup> with 2.5 mA h cm<sup>–2</sup> (Reprinted with permission from Ref. [<a href="#B82-energies-18-00261" class="html-bibr">82</a>]; Copyright © 2020 American Chemical Society).</p>
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<p>(<b>a</b>) Scheme depicting LBL deposition of oppositely charged polymer layers. (<b>b</b>) “Open spaces” that are cleared by modifying the ionic character of post-assembly of a pH-sensitive polymer can be observed to accommodate the non-dendritic deposition of Li metal.</p>
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<p>(<b>a</b>) Modified electrode (stainless steel (SS)) with a nanochannel layer coating. (<b>b</b>) Simulation performed for the bare electrode. (Reprinted with permission from Ref. [<a href="#B87-energies-18-00261" class="html-bibr">87</a>]; Copyright © 2016 American Chemical Society).</p>
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<p>(<b>a</b>) Schematics of different coating methods and their effects on Li deposition in Li anodes. (<b>b</b>) Overpotential plotted with respect to cycle number for B-Li, D-GO-Li, D-GOAl-Li, and S-GO-Li symmetrical cells tested at a current density of 5 mA cm<sup>–2</sup> and a deposition capacity of 1 mA h cm<sup>–2</sup> for 2000 cycles. (Reprinted with permission from Ref. [<a href="#B97-energies-18-00261" class="html-bibr">97</a>]; Copyright © 2018 American Chemical Society); (<b>c</b>) Schematic of the exfoliation process for df-G. EIS Nyquist plots (<b>d</b>) df-G, (<b>e</b>) r-GO. (Reprinted with permission from Ref. [<a href="#B90-energies-18-00261" class="html-bibr">90</a>]; Copyright © 2018 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim, Germany).</p>
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<p>Electrochemical impedance spectra of pristine and 20 nm Al<sub>2</sub>O<sub>3</sub>-modified Li electrodes obtained at an open circuit voltage after charge–discharge cycles at a current density of 0.5 mA/cm<sup>2</sup>. (<b>a</b>) Fresh cell state, (<b>b</b>) after 100 cycles, and (<b>c</b>) after 200 cycles. (Reprinted with permission from Ref. [<a href="#B101-energies-18-00261" class="html-bibr">101</a>]; Copyright © 2017 Elsevier B.V. (Amsterdam, The Netherlands) All rights reserved); (<b>d</b>) Illustration of the process for fabricating LiF-coated Li. (<b>e</b>) Cycling performance of the LiF-coated Li|LiCoO<sub>2</sub> cell. (<b>f</b>) LiF-coated Li electrode and (<b>g</b>) bare Li electrode after 100 cycles at a current density of 1 mA cm<sup>−2</sup>. (Reprinted with permission from Ref. [<a href="#B103-energies-18-00261" class="html-bibr">103</a>]; Copyright © 2018 Published by Elsevier B.V. (Amsterdam, The Netherlands)); (<b>h</b>) Schematics of Li deposition on bare Li anode without protection, with a pure PVDF-HFP layer and with APL composed of organic PVDF-HFP and inorganic LiF protective layer Li anode. (Reprinted with permission from Ref. [<a href="#B106-energies-18-00261" class="html-bibr">106</a>]; Copyright © 2018 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim, Germany); (<b>i</b>) Schematics of Li deposition patterns for the single-ion-conducting LLN coating with rigid LLZTO and elastic Li-Nafion protected Li metal anode. (Reprinted with permission from Ref. [<a href="#B107-energies-18-00261" class="html-bibr">107</a>]; Copyright © 2019 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim, Germany).</p>
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34 pages, 12217 KiB  
Review
Significance of the Powder Metallurgy Approach and Its Processing Parameters on the Mechanical Behavior of Magnesium-Based Materials
by Sachin Kumar Sharma, Sandra Gajević, Lokesh Kumar Sharma, Dhanesh G. Mohan, Yogesh Sharma, Mladen Radojković and Blaža Stojanović
Nanomaterials 2025, 15(2), 92; https://doi.org/10.3390/nano15020092 - 9 Jan 2025
Viewed by 183
Abstract
Magnesium-based materials, which are known for their light weight and exceptional strength-to-weight ratio, hold immense promise in the biomedical, automotive, aerospace, and military sectors. However, their inherent limitations, including low wear resistance and poor mechanical properties, have driven the development of magnesium-based metal [...] Read more.
Magnesium-based materials, which are known for their light weight and exceptional strength-to-weight ratio, hold immense promise in the biomedical, automotive, aerospace, and military sectors. However, their inherent limitations, including low wear resistance and poor mechanical properties, have driven the development of magnesium-based metal matrix composites (Mg-MMCs). The pivotal role of powder metallurgy (PM) in fabricating Mg-MMCs was explored, enhancing their mechanical and corrosion resistance characteristics. The mechanical characteristics depend upon the fabrication methodology, composition, processing technique, and reinforcement added to the magnesium. PM is identified as the most efficient due to its ability to produce near-net shape composites with high precision, cost-effectiveness, and minimal waste. Furthermore, PM enables precise control over critical processing parameters, such as compaction pressure, sintering temperature, and particle size, which directly influence the composite’s microstructure and properties. This study highlights various reinforcements, mainly carbon nanotubes (CNTs), graphene nanoparticles (GNPs), silicon carbide (SiC), and hydroxyapatite (HAp), and their effects on improving wear, corrosion resistance, and mechanical strength. Among these, CNTs emerge as a standout reinforcement due to their ability to enhance multiple properties when used at optimal weight fractions. Further, this study delves into the interaction between reinforcement types and matrix materials, emphasizing the importance of uniform dispersion in preventing porosity and improving durability. Optimal PM conditions, such as a compaction pressure of 450 MPa, sintering temperatures between 550 and 600 °C, and sintering times of 2 h, are recommended for achieving superior mechanical performance. Emerging trends in reinforcement materials, including nanostructures and bioactive particles, are also discussed, underscoring their potential to widen the application spectrum of Mg-MMCs. Full article
(This article belongs to the Section Nanofabrication and Nanomanufacturing)
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<p>Comparative study of powder metallurgy with other processes [<a href="#B30-nanomaterials-15-00092" class="html-bibr">30</a>].</p>
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<p>Primary processing parameters and secondary operations of powder metallurgy.</p>
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<p>SEM image of Mg-based alloy formed at different compaction pressures: (<b>a</b>) 100 MPa, (<b>b</b>) 200 MPa, (<b>c</b>) 300 MPa, (<b>d</b>) 400 MPa, and (<b>e</b>) 500 MPa. (<b>f</b>) Variation in density of composite with compaction pressure [<a href="#B67-nanomaterials-15-00092" class="html-bibr">67</a>].</p>
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<p>SEM micrograph of the composite (<b>a</b>) Mg-1wt.%Al-1wt.%Sn-0.18wt.%GNP, (<b>b</b>–<b>f</b>) X-ray mapping of Mg-1wt.%Al-1wt.%Sn-0.18wt.%GNP, and (<b>g</b>,<b>h</b>) fracture image of Mg-1wt.%Al-1wt.%Sn-0.18wt.%GNP [<a href="#B82-nanomaterials-15-00092" class="html-bibr">82</a>].</p>
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<p>TEM image relating the grain distribution for (<b>a</b>,<b>b</b>) 5 wt.%, (<b>c</b>,<b>d</b>) 7.5 wt.%, and (<b>e</b>,<b>f</b>) 10 wt.% of vanadium. (<b>g</b>–<b>l</b>) SEM image and EDS mapping for 5 wt.% of vanadium in the AZ31 alloy, revealing the uniform dispersion of the reinforcing agent, along with the other elements, such as Al, Mn, and Zn [<a href="#B83-nanomaterials-15-00092" class="html-bibr">83</a>].</p>
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<p>(<b>A</b>) FESEM image and EDS mapping for (<b>a</b>) 2 wt.% of Al<sub>2</sub>O<sub>3</sub> and (<b>b</b>) 8 wt.% Al<sub>2</sub>O<sub>3</sub> of Mg composites. (<b>B</b>) XRD analysis of the composite depicting (X = 0 wt.%, I = 2 wt.%, II = 4 wt.%, III = 6 wt.%, IV = 8 wt.%). (<b>C</b>(<b>a</b>–<b>c</b>)) shows the EDS analysis of the samples after immersion, showcasing the different elemental components in the composite and showing that pitting corrosion is found in the presence of a high Al<sub>2</sub>O<sub>3</sub> content [<a href="#B100-nanomaterials-15-00092" class="html-bibr">100</a>].</p>
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<p>Variation in microhardness of composites subject to reinforcement.</p>
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<p>SEM micrograph of worn-out surfaces of Mg /SiC (<b>a</b>) Mg/SiC for 0.4 m/s at 5 N, (<b>b</b>) Mg/SiC for 0.4 m/s at 10 N, (<b>c</b>) Mg/SiC for 0.6 m/s at 5 N, (<b>d</b>) Mg/SiC for 0.6 m/s at 10 N, (<b>e</b>) Mg/SiC for 0.8 m/s at 5 N, and (<b>f</b>) Mg/SiC for 0.8 m/s at 10 N [<a href="#B109-nanomaterials-15-00092" class="html-bibr">109</a>]. (<b>g</b>–<b>i</b>) Optical characterization of TiC-reinforced (3 wt.%, 6 wt.%, and 9 wt.%) magnesium composites [<a href="#B111-nanomaterials-15-00092" class="html-bibr">111</a>].</p>
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<p>Surface morphology of worn-out sample of Mg/0.5 wt.% BN composites at a normal load of 5 N and a sliding velocity of (<b>a</b>) 0.6 m/s, (<b>d</b>) 0.9 m/s, and (<b>g</b>) 1.2 m/s; composites at a normal load of 7 N and a sliding velocity of (<b>b</b>) 0.6 m/s, (<b>e</b>) 0.9 m/s, and (<b>h</b>) 1.2 m/s; and composites at a normal load of 10 N and a sliding velocity of (<b>c</b>) 0.6 m/s, (<b>f</b>) 0.9 m/s, (<b>i</b>), 1.2 m/s [<a href="#B143-nanomaterials-15-00092" class="html-bibr">143</a>].</p>
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<p>Compressive strength of composites with reinforcement.</p>
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<p>Mechanical properties of Mg-based material composites formed using different reinforcements (vol.%) in MMCs.</p>
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<p>Variation in compressive strength of composites with different particle sizes of reinforcement in MMCs.</p>
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<p>Variation in microhardness of composites at different sintering temperatures in MMCs.</p>
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<p>Variation in the mechanical properties of composites via different sintering times in MMCs.</p>
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19 pages, 11104 KiB  
Article
Microbially Induced Calcite Precipitation (MICP) Improved Drilling Fluid Optimization for Gravel Stratum
by Rui Pan, Zhou Shu, Yumin Chen, Xiaobing Sha, Xinquan Zhang and Yi Han
Processes 2025, 13(1), 162; https://doi.org/10.3390/pr13010162 - 9 Jan 2025
Viewed by 153
Abstract
During the exploration of the gravel stratum, incidents such as wellbore leakage, stuck drilling, and unstable wellbore walls frequently occur. These issues lead to diminished drilling efficiency and prolonged construction timelines, ultimately adversely affecting the core recovery rate, resulting in a significant waste [...] Read more.
During the exploration of the gravel stratum, incidents such as wellbore leakage, stuck drilling, and unstable wellbore walls frequently occur. These issues lead to diminished drilling efficiency and prolonged construction timelines, ultimately adversely affecting the core recovery rate, resulting in a significant waste of manpower and material resources. To address the issue of hole collapse during drilling, the microbially induced calcite carbonate precipitation (MICP) technique was employed to enhance the properties of bentonite mud drilling fluids. This study analyzed the effects of three factors, i.e., bentonite, biological solution, and barite powder, on the bentonite mud bio-cementation effectiveness through an orthogonal experiment and response surface methodology (RSM). The biological mechanism was examined using scanning electron microscopy (SEM). The experimental results indicated that optimal formulation was achieved when the mass fraction of bentonite was 13.96%, the biological solution comprised 0.6% xanthan gum and 0.4% carboxymethyl cellulose, and the mass fraction of barite was 25%. This research explores the application potential of MICP in enhancing the rheological properties of bentonite mud drilling fluids, which provides new insights and technical references for optimizing their performance. Full article
(This article belongs to the Section Chemical Processes and Systems)
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<p>Sample preparation.</p>
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<p>Correlation analysis between various factors and responses. scatter plots: (<b>a</b>) the interactions between B and PV; (<b>b</b>) the interactions between B and D; (<b>c</b>) the interactions between B and YP. (A: Bentonite; B: biological solution; C: barite; PV: plastic viscosity; D: density; YP: yield point. The symbol ‘-’ indicates a negative correlation between variables; “Run” refers to the number of experiments conducted).</p>
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<p>Three-dimensional response surface plots for various factors: (<b>a</b>) A and B, (<b>b</b>) A and C, (<b>c</b>) B and C; (<b>d</b>) diagnostic chart of predicted and actual values of plastic viscosity; (<b>e</b>) the normal graph of residuals; (<b>f</b>) residual and running chart.</p>
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<p>Three-dimensional response surface plots of various factors: (<b>a</b>) A and B, (<b>b</b>) A and C, (<b>c</b>) B and C; (<b>d</b>) diagnostic chart of predicted and actual densities; (<b>e</b>) the normal graph of residuals; (<b>f</b>) residual and running chart.</p>
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<p>Three-dimensional response surface plots of various factors: (<b>a</b>) A and B, (<b>b</b>) A and C, (<b>c</b>) B and C; (<b>d</b>) diagnosis chart of predicted and actual values of yield point; (<b>e</b>) the normal graph of residuals; (<b>f</b>) residual and running chart.</p>
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<p>EDS spectrum of biological mud (<b>a</b>–<b>d</b>).</p>
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<p>Microscopic morphology diagram of biological mud: (<b>a</b>) Calcium carbonate distribution; (<b>b</b>) ribbon-like connection; (<b>c</b>) calcium carbonate distribution on the fibrous connector.</p>
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16 pages, 7152 KiB  
Article
Micro-Scale Numerical Simulation for Residual Strength of CFRP After Cyclic Tensile or Out-of-Plane Shear Loadings Fatigue
by Takumi Sekino, Natsuko Kudo and Jun Koyanagi
J. Compos. Sci. 2025, 9(1), 28; https://doi.org/10.3390/jcs9010028 - 8 Jan 2025
Viewed by 319
Abstract
In this study, micro-scale numerical simulations were performed to evaluate the residual strength of carbon fiber-reinforced polymers (CFRPs) subjected to cyclic transverse and out-of-plane shear loading fatigue. The simulations utilized a finite element method, incorporating an entropy-based damage criterion for the matrix resin. [...] Read more.
In this study, micro-scale numerical simulations were performed to evaluate the residual strength of carbon fiber-reinforced polymers (CFRPs) subjected to cyclic transverse and out-of-plane shear loading fatigue. The simulations utilized a finite element method, incorporating an entropy-based damage criterion for the matrix resin. This method aimed to link entropy generation to strength degradation, with the parameter αo(s) determined as a function of entropy. Cyclic tensile and shear analyses were conducted to correlate residual strength with entropy accumulation, establishing a linear relationship for αo(s). The results demonstrated meso-scale strength degradation based on micro-scale numerical simulations. Material constants for the epoxy resin matrix were determined through creep and tensile tests, and a generalized Maxwell model with 15 elements was used to represent viscoelastic behavior. Numerical simulations employed the Abaqus/Standard 2020 software, with the epoxy resin matrix behavior implemented via a UMAT subroutine. The analysis revealed a linear relationship between entropy and residual strength for both cyclic tensile and out-of-plane shear loading. This approach enhances experimental insights with numerical predictions, offering a comprehensive understanding of CFRP strength degradation under fatigue loading. This study represents the first numerical approach to link the entropy of the matrix resin at the micro-scale with macro-scale residual strength in CFRP, providing a novel and comprehensive framework for understanding and predicting strength degradation under cyclic loading. Full article
(This article belongs to the Section Polymer Composites)
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<p><math display="inline"><semantics> <mrow> <mi>ε</mi> <mo>(</mo> <mi>t</mi> <mo>)</mo> </mrow> </semantics></math> fitted to the results of creep test.</p>
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<p>Analytical curve fitted to master curve.</p>
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<p>Experimental and analytical stress–strain curve for determining nonlinear coefficient.</p>
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<p>Generalized Maxwell model for analyzing viscoelastic behavior.</p>
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<p>Overall flowchart for updating stress.</p>
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<p>Finite element model of CFRPs.</p>
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<p>Finite element model for analyzing cyclic tensile and global strain.</p>
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<p>Finite element model for analyzing cyclic-out-of-plane shear and global strain.</p>
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<p>Damage coefficient after cyclic tensile loading (strain 0.8%, 10 cycle (<b>upper left</b>), 20 cycle (<b>upper right</b>), 40 cycle (<b>lower left</b>), and 80 cycle (<b>lower right</b>)).</p>
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<p>Damage coefficient after cyclic out-of-plane shear loading (strain 0.8%, 10 cycle (<b>upper left</b>), 20 cycle (<b>upper right</b>), 40 cycle (<b>lower left</b>), and 80 cycle (<b>lower right</b>)).</p>
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<p><math display="inline"><semantics> <mrow> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>o</mi> </mrow> </msub> <mo>(</mo> <mi>s</mi> <mo>)</mo> </mrow> </semantics></math> fitted to the relationship between entropy and standardized residual strength under cyclic tensile loading.</p>
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<p><math display="inline"><semantics> <mrow> <msub> <mrow> <mi>α</mi> </mrow> <mrow> <mi>o</mi> </mrow> </msub> <mo>(</mo> <mi>s</mi> <mo>)</mo> </mrow> </semantics></math> fitted to the relationship between entropy and standardized residual strength under cyclic out-of-plane shear loading.</p>
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18 pages, 6953 KiB  
Article
Modelling of High-Velocity Impact on Woven Carbon Fibre-Reinforced Plastic Laminate
by Nenad Djordjevic, Rade Vignjevic, Kevin Hughes and Tom De Vuyst
Appl. Sci. 2025, 15(2), 555; https://doi.org/10.3390/app15020555 - 8 Jan 2025
Viewed by 345
Abstract
This paper describes a constitutive model for progressive damage in carbon fibre-reinforced composites (CFRPs), developed in the framework of thermodynamics and coupled with a vector equation of state. This made the constitutive model capable of modelling shock wave propagation within orthotropic materials. Damage [...] Read more.
This paper describes a constitutive model for progressive damage in carbon fibre-reinforced composites (CFRPs), developed in the framework of thermodynamics and coupled with a vector equation of state. This made the constitutive model capable of modelling shock wave propagation within orthotropic materials. Damage is incorporated in the model by using reduction in the principal material stiffness based on the effective stress concept and the hypothesis of strain energy equivalence. Damage evolution was defined in terms of a modified Tuler–Bucher criteria. The constitutive model was implemented into Lawrence Livermore National Laboratory (LLNL) DYNA3D nonlinear hydrocode. Simulation results were validated against post-impact experimental data of spherical projectile impact on an aerospace-grade woven CFRP composite panel. Two plate thicknesses were considered and a range of impact velocities above the ballistic limit of the plates, ranging from 194 m/s to 1219 m/s. Other than for the size of the delamination zone in the minor material direction, the discrepancy between the experiments and numerical results for damage and delamination in the CFRP target plates was within 8%. Full article
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<p>Sphere projectile impact on woven CFRP laminate.</p>
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<p>(<b>a</b>) Rear side of a target CFRP panel impacted at 186 m/s; petalling type of failure with red lines denoting cracks [<a href="#B39-applsci-15-00555" class="html-bibr">39</a>] and (<b>b</b>) post-impact XCT image of the cross-section of the target.</p>
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<p>Cross-section of a target CFRP panel after the impact with red lines showing the extent of damage: (<b>a</b>) impact at 305 m/s; shear-dominated failure and conical shape of the crater [<a href="#B39-applsci-15-00555" class="html-bibr">39</a>] and (<b>b</b>) impact at 1199 m/s; hourglass shape of the hole [<a href="#B39-applsci-15-00555" class="html-bibr">39</a>].</p>
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<p>Post-impact images of 6 mm thick target plate in the vicinity of impact (A3): (<b>a</b>) impact face and (<b>b</b>) rear face.</p>
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<p>Post-impact images of 12 mm thick target plate in the vicinity of impact (C3): (<b>a</b>) impact face and (<b>b</b>) rear face.</p>
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<p>(<b>a</b>) FEM model of a quarter of the sphere impact on woven CFRP composite target—6 mm thick target plate and (<b>b</b>) stack sequence of 6 mm thick woven CFRP composite plate.</p>
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<p>FEM models of a quarter of the CFRP target plates, were the different colors represent different plies: (<b>a</b>) 6 mm thick composite A3 and (<b>b</b>) 12 mm thick composite C3 modelled.</p>
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<p>Damage area calculated from simulation results and XCT data for the normal impact at 194 m/s.</p>
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<p>Damage area calculated from simulation results and XCT data for the normal impact at 354 m/s.</p>
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<p>Simulation results for damage distribution in 6 mm thick CFRP after impact at 1199 m/s; t = 20 µs.</p>
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<p>Simulation results for damage distribution for impact at 1200 m/s in the 6 mm thick CFRP: at t = 20 µs: (<b>a</b>) the top and (<b>b</b>) bottom plies.</p>
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<p>Damage distribution in 6 mm thick CFRP obtained in the simulation (<b>left</b>) and observed by C Scan (<b>right</b>) of the specimen after the impact at 1199 m/s.</p>
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<p>Damage distribution in 12 mm thick CFRP target plate C3 at response time t = 35 μs; 3 solid elements per layer.</p>
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<p>Damage distribution in 12 mm thick CFRP target plate C3 at response time t = 35 μs: (<b>a</b>) impact side and (<b>b</b>) rear side.</p>
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<p>Damage distribution in midplane of the 12 mm thick CFRP target plate C3 at response time t = 35 μs.</p>
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15 pages, 663 KiB  
Systematic Review
Graphene-Based Materials for Bone Regeneration in Dentistry: A Systematic Review of In Vitro Applications and Material Comparisons
by Azahara María Narváez-Romero, Francisco Javier Rodríguez-Lozano and María Pilar Pecci-Lloret
Nanomaterials 2025, 15(2), 88; https://doi.org/10.3390/nano15020088 - 8 Jan 2025
Viewed by 339
Abstract
Introduction: Graphene, a two-dimensional arrangement of carbon atoms, has drawn significant interest in medical research due to its unique properties. In the context of bone regeneration, graphene has shown several promising applications. Its robust structure, electrical conductivity, and biocompatibility make it an ideal [...] Read more.
Introduction: Graphene, a two-dimensional arrangement of carbon atoms, has drawn significant interest in medical research due to its unique properties. In the context of bone regeneration, graphene has shown several promising applications. Its robust structure, electrical conductivity, and biocompatibility make it an ideal candidate for enhancing bone tissue regeneration and repair processes. Studies have revealed that the presence of graphene can stimulate the proliferation and differentiation of bone cells, thereby promoting the formation of new bone tissue. Additionally, its ability to act as an effective carrier for growth factors and drugs allows controlled release, facilitating the engineering of specific tissues for bone regeneration. Aim: To assess the efficacy of graphene in enhancing bone regeneration through in vitro studies, identify key safety concerns, and propose directions for future research to optimize its clinical applicability. Materials and methods: The present systematic review was carried out using the PRISMA 2020 guideline. A first search was carried out on 20 November 2023 and was later updated on 14 February and 15 April 2024 in the databases of PubMed, Scopus, and Web of Science. Those in vitro studies published in English that evaluated the potential for bone regeneration with graphene in dentistry and also those which met the search terms were selected. Furthermore, the quality of the studies was assessed following the modified CONSORT checklist of in vitro studies on dental materials. Results: A total of 17 in vitro studies met the inclusion criteria. Among these, 12 showed increased osteoblast adhesion, proliferation, and differentiation, along with notable enhancements in mineralized matrix formation. Additionally, they exhibited a significant upregulation of osteogenic markers such as RUNX and COL1 (p < 0.05). However, the variability in methodologies and a lack of long-term assessments were noted as critical gaps. Conclusions: The evaluation of the efficacy and safety of graphene in bone regeneration in dentistry revealed significant potential. However, it is recognized that clinical implementation should be approached with caution, considering identified areas of improvement and suggestions for future research. Future studies should focus on standardized experimental designs, including in vivo studies to evaluate long-term safety, immune responses, and vascularization processes in realistic biological environments. Full article
(This article belongs to the Section Biology and Medicines)
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<p>PRISMA 2020 flow diagram. Identification of studies via databases and registers.</p>
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